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    • 2. 发明授权
    • Permanent antistatic resin composition
    • US5002992A
    • 1991-03-26
    • US320392
    • 1989-03-08
    • Hiroyoshi HamanakaTetsuji Kakizaki
    • Hiroyoshi HamanakaTetsuji Kakizaki
    • C08L23/14C08L23/00C08L23/10C08L43/00C08L71/00C08L85/04C08L87/00C09K3/16
    • C09K3/16C08L23/10C08L85/04Y10S524/912
    • An antistatic resin composition comprising the components (1) and (2) shown below:component (1): a propylene copolymer comprising (A) and/or (B) shown below:(A) a propylene random copolymer having a melt flow rate of 0.1 to 70 g/10 min. obtained by feeding 0.5 to 4.0% by weight of ethylene, 66.0 to 98.5% by weight of propylene and 1.0 to 30.0% by weight of an .alpha.-olefin having 4 to 12 carbon atoms (all ratios based on the total amount of the three components) into a polymerization system;(B) a propylene random copolymer having a melt flow rate of 0.1 to 70 g/10 min. obtained by feeding 2.5 to 10.0% by weight of ethylene and 90.0 to 97.5% by weight of propylene (both ratios based on the total amount of the two components) into a polymerization system;component (2): a polymeric charge-transfer type complex which is the reaction produce of one or more of semi-polar organic boron polymeric compounds represented by the formula I shown below with one or more of tertiary amines with total carbon atoms of 5 to 82 having at least one hydroxyl group, produced through reaction at a ratio of one boron atom to one basic nitrogen atom: ##STR1## wherein q is 0 or 1, and when q=1, A represents --(X)a--(Y)b--(Z)c-- group [X and Z each represent an oxygen-containing hydrocarbon residue with a total of 100 carbon atoms or less having one terminal ether residue, and Y represents ##STR2## group (R is a hydrocarbon group having 1 to 82 carbon atoms) or ##STR3## group (R' is a hydrocarbon group having 2 to 13 carbon atoms). a, b and c are each 0 or 1]; and p is 10 to 1000.
    • 6. 发明授权
    • Thermoplastic fluorine-containing resin blend composition
    • 热塑性含氟树脂共混组合物
    • US4575533A
    • 1986-03-11
    • US730149
    • 1985-05-03
    • Shinji HorieTetsuji KakizakiToshikazu Mizutani
    • Shinji HorieTetsuji KakizakiToshikazu Mizutani
    • C08L1/00C08L23/00C08L27/00C08L27/12C08L51/00C08L51/02C08L51/06C08L57/00C08L101/00C08L101/04C08L27/14C08L27/16
    • C08L27/12C08L51/06
    • 1. A thermoplastic fluorine-containing resin blend composition comprising(a) from 5 to 95% by weight of a thermoplastic fluorine-containing resin, and(b) from 95 to 5% by weight of at least one modified ethylene polymer selected from the group consisting of the following components (i) and (ii).(i) A modified ethylene polymer obtained by subjecting an ethylene polymer and an alkyl acrylate to graft reaction conditions, wherein the total alkyl acrylate content including the alkyl acrylate which has been previously contained is from 5 to 70% by weight based on the weight of the modified ethylene polymer;(ii) A modified ethylene polymer obtained by subjecting an ethylene polymer having a crystallinity of from 4 to 50% and vinyl acetate to graft reaction conditions, wherein the total vinyl acetate content including the vinyl acetate which has been previously contained is from 5 to 70% by weight based on the weight of the modified ethylene polymer and the boiling xylene insoluble content is 10% by weight or less based on the weight of the modified ethylene polymer.
    • 1.一种热塑性含氟树脂共混组合物,其包含(a)5至95重量%的热塑性含氟树脂,和(b)95至5重量%的至少一种改性乙烯聚合物,其选自 组由以下组分(i)和(ii)组成。 (i)通过使乙烯聚合物和丙烯酸烷基酯进行接枝反应条件而获得的改性乙烯聚合物,其中包含以前含有的丙烯酸烷基酯的总烷基酯含量为5-70重量% 改性乙烯聚合物; (ii)通过使结晶度为4〜50%的乙烯聚合物和乙酸乙烯酯进行接枝反应而得到的改性乙烯聚合物,其中包含先前含有的乙酸乙烯酯的总乙酸乙烯酯含量为5〜70 相对于改性乙烯聚合物的重量,基于改性乙烯聚合物的重量和沸点二甲苯不溶成分的重量%为10重量%以下。
    • 8. 发明授权
    • Permanent antistatic resin composition
    • 永久抗静电树脂组合物
    • US5002991A
    • 1991-03-26
    • US333260
    • 1989-04-05
    • Hiroyoshi HamanakaTetsuji Kakizaki
    • Hiroyoshi HamanakaTetsuji Kakizaki
    • C08L23/08C08L85/04
    • C08L23/0815C08L85/04Y10S524/912
    • An antistatic resin composition comprising the components (1) and (2) shown below:component (1): an ethylene random copolymer having a melt flow rate of 0.1 to 50 g/10 min. obtained by copolymerizing 99 to 70% by weight of ethylene and 1 to 30% by weight of a comonomer represented by the formula I: ##STR1## wherein n is 0 or 1, and when n=0, R represents an alkyl group having 2 to 8 carbon atoms and A represents hydrogen, and when n=1, R represents an alkyl group having 1 to 20 carbon atoms and A represents hydrogen or a methyl group;component (2): a polymeric charge-transfer type complex which is the reaction product of one or more of semi-polar organic boron polymeric compounds represented by the formula II shown below with one or more of tertiary amines with total carbon atoms of 5 to 82 having at least one hydroxyl group, produced through reaction at a ratio of one boron atom to one basic nitrogen atom: ##STR2## wherein q is 0 or 1, and when 1=1, A represents -(X)a-(Y)b-(Z)c- group [X and Z each represent an oxygen-containing hydrocarbon residue with a total of 100 carbon atoms or less having one terminal ether residue, and Y represents ##STR3## group (R is a hydrocarbon group having 1 to 82 carbon atoms) or ##STR4## group (R' is a hydrocarbon group having 2 to 13 carbon atoms), a, b and c are each 0 or 1]; and p is 10 to 1000.