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    • 2. 发明授权
    • Positive-tone radiation-sensitive resin composition
    • 正色辐射敏感树脂组合物
    • US07335457B2
    • 2008-02-26
    • US11235101
    • 2005-09-27
    • Daisuke ShimizuTomoki NagaiYuuji YadaKentarou Gotou
    • Daisuke ShimizuTomoki NagaiYuuji YadaKentarou Gotou
    • G03F7/004
    • G03F7/0045G03F7/0392G03F7/091Y10S430/106Y10S430/111Y10S430/127
    • A positive-tone radiation-sensitive resin composition containing an anthracene-based carboxylic acid component with low sublimation properties and excellent compatibility with other components is provided. The composition exhibits optimum controllability of radiation transmittance as a chemically amplified positive-tone resist effectively responding to active radiation, particularly to deep ultraviolet rays, effectively controlling line width variation in resist patterns due to fluctuation in the resist film thickness on a highly refractive substrate, and exhibiting excellent focal depth allowance.The composition comprises (A) an anthracene derivative of the following formula (1), (B) a photoacid generator comprising a sulfonimide compound, and, (C) a resin containing an acid-dissociable group, wherein R1 is a hydrogen atom or a monovalent organic group, R2 is a monovalent organic group, e is an integer of 0-3, and f is an integer of 0-8. The metal impurity content in the component (A), in terms of the total ion content, is preferably 5,000 ppb or less.
    • 提供了含有具有低升华性和与其它成分的良好相容性的蒽类羧酸成分的正色散辐射敏感性树脂组合物。 该组合物作为化学扩增的正色调抗蚀剂具有最佳的辐射透射性可控性,其有效地响应于有源辐射,特别是对深紫外线,有效地控制由于高折射性基底上的抗蚀剂膜厚度的波动导致的抗蚀剂图案的线宽度变化, 并表现出优异的焦深度补偿。 该组合物包含(A)下式(1)的蒽衍生物,(B)包含磺酰亚胺化合物的光酸产生剂,和(C)含有酸解离基团的树脂,其中R 1, SUP>是氢原子或一价有机基团,R 2是一价有机基团,e是0-3的整数,f是0-8的整数。 组分(A)中的金属杂质含量相对于总离子含量优选为5,000ppb以下。
    • 3. 发明申请
    • Positive-tone radiation-sensitive resin composition
    • 正色辐射敏感树脂组合物
    • US20060078821A1
    • 2006-04-13
    • US11235101
    • 2005-09-27
    • Daisuke ShimizuTomoki NagaiYuuji YadaKentarou Gotou
    • Daisuke ShimizuTomoki NagaiYuuji YadaKentarou Gotou
    • G03C1/76
    • G03F7/0045G03F7/0392G03F7/091Y10S430/106Y10S430/111Y10S430/127
    • A positive-tone radiation-sensitive resin composition containing an anthracene-based carboxylic acid component with low sublimation properties and excellent compatibility with other components is provided. The composition exhibits optimum controllability of radiation transmittance as a chemically amplified positive-tone resist effectively responding to active radiation, particularly to deep ultraviolet rays, effectively controlling line width variation in resist patterns due to fluctuation in the resist film thickness on a highly refractive substrate, and exhibiting excellent focal depth allowance. The composition comprises (A) an anthracene derivative of the following formula (1), (B) a photoacid generator comprising a sulfonimide compound, and, (C) a resin containing an acid-dissociable group, wherein R1 is a hydrogen atom or a monovalent organic group, R2 is a monovalent organic group, e is an integer of 0-3, and f is an integer of 0-8. The metal impurity content in the component (A), in terms of the total ion content, is preferably 5,000 ppb or less.
    • 提供了含有具有低升华性和与其它成分的良好相容性的蒽类羧酸成分的正色散辐射敏感性树脂组合物。 该组合物作为化学扩增的正色调抗蚀剂具有最佳的辐射透射性可控性,其有效地响应于主动辐射,特别是对深紫外线,有效地控制由于高折射性基底上的抗蚀剂膜厚度的波动导致的抗蚀剂图案的线宽变化, 并表现出优异的焦深度补偿。 该组合物包含(A)下式(1)的蒽衍生物,(B)包含磺酰亚胺化合物的光酸产生剂,和(C)含有酸解离基团的树脂,其中R 1, SUP>是氢原子或一价有机基团,R 2是一价有机基团,e是0-3的整数,f是0-8的整数。 组分(A)中的金属杂质含量相对于总离子含量优选为5,000ppb以下。
    • 4. 发明授权
    • Radiation-sensitive resin composition
    • 辐射敏感树脂组合物
    • US08206888B2
    • 2012-06-26
    • US12094820
    • 2006-11-21
    • Yuuji YadaTomoki Nagai
    • Yuuji YadaTomoki Nagai
    • G03F7/004
    • G03F7/0045G03F7/0392Y10S430/106Y10S430/122Y10S430/123
    • It is intended to provide a radiation-sensitive resin composition, which comprises a radiation-sensitive acid generator excellent in resolution performance, heat stability, and storage stability, suppresses fluctuations in line width and deterioration in pattern profile attributed to standing waves, and produces a resist pattern improved in nano edge roughness and LEF. The radiation-sensitive resin composition is characterized by (A) a radiation-sensitive acid generator comprising: a sulfonium salt compound typified by 2,4,6-trimethylphenyldiphenylsulfonium 2,4-difluorobenzenesulfonate, 2,4,6-trimethylphenyldiphenylsulfonium 4-trifluoromethylbenzenesulfonate, or the like; and a sulfonimide compound. It is preferred that the composition should further comprise (B) a resin typified by a 4-hydroxystyrene/4-t-butoxystyrene copolymer, a 4-hydroxystyrene/t-butyl (meth)acrylate, or the like.
    • 旨在提供一种辐射敏感性树脂组合物,其包含分辨率性能,热稳定性和储存稳定性优异的辐射敏感性酸发生剂,抑制线宽的波动和归因于驻波的图案轮廓的劣化,并产生 抗蚀剂图案改善了纳米边缘粗糙度和LEF。 辐射敏感性树脂组合物的特征在于:(A)辐射敏感性酸产生剂,其包含:以2,4,6-三甲基苯基二苯基锍2,4-二氟苯磺酸为代表的锍盐化合物,4-三氟甲基苯磺酸2,4,6-三甲基苯基二苯基锍, 或类似物; 和磺酰亚胺化合物。 优选组合物还应包含(B)以4-羟基苯乙烯/ 4-叔丁氧基苯乙烯共聚物为代表的树脂,(甲基)丙烯酸4-羟基苯乙烯/叔丁酯等。
    • 5. 发明申请
    • RADIATION-SENSITIVE RESIN COMPOSITION
    • 辐射敏感性树脂组合物
    • US20100028800A1
    • 2010-02-04
    • US12094820
    • 2006-11-21
    • Yuuji YadaTomoki Nagai
    • Yuuji YadaTomoki Nagai
    • G03F7/039G03F7/004
    • G03F7/0045G03F7/0392Y10S430/106Y10S430/122Y10S430/123
    • It is intended to provide a radiation-sensitive resin composition, which comprises a radiation-sensitive acid generator excellent in resolution performance, heat stability, and storage stability, suppresses fluctuations in line width and deterioration in pattern profile attributed to standing waves, and produces a resist pattern improved in nano edge roughness and LEF. The radiation-sensitive resin composition is characterized by (A) a radiation-sensitive acid generator comprising: a sulfonium salt compound typified by 2,4,6-trimethylphenyldiphenylsulfonium 2,4-difluorobenzenesulfonate, 2,4,6-trimethylphenyldiphenylsulfonium 4-trifluoromethylbenzenesulfonate, or the like; and a sulfonimide compound. It is preferred that the composition should further comprise (B) a resin typified by a 4-hydroxystyrene/4-t-butoxystyrene copolymer, a 4-hydroxystyrene/t-butyl (meth)acrylate, or the like.
    • 旨在提供一种辐射敏感性树脂组合物,其包含分辨率性能,热稳定性和储存稳定性优异的辐射敏感性酸发生剂,抑制线宽的波动和归因于驻波的图案轮廓的劣化,并产生 抗蚀剂图案改善了纳米边缘粗糙度和LEF。 辐射敏感性树脂组合物的特征在于:(A)辐射敏感性酸产生剂,其包含:以2,4,6-三甲基苯基二苯基锍2,4-二氟苯磺酸为代表的锍盐化合物,4-三氟甲基苯磺酸2,4,6-三甲基苯基二苯基锍, 或类似物; 和磺酰亚胺化合物。 优选组合物还应包含(B)以4-羟基苯乙烯/ 4-叔丁氧基苯乙烯共聚物为代表的树脂,(甲基)丙烯酸4-羟基苯乙烯/叔丁酯等。