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    • 1. 发明授权
    • Silver halide color photographic light-sensitive material
    • 卤化银彩色摄影感光材料
    • US4491630A
    • 1985-01-01
    • US460512
    • 1983-01-24
    • Takatoshi IshikawaAkio MitsuiMasakazu MorigakiTakashi Nakamura
    • Takatoshi IshikawaAkio MitsuiMasakazu MorigakiTakashi Nakamura
    • G03C7/20G03C7/26G03C7/38G03C7/384G03C7/392G03C7/16
    • G03C7/39252G03C7/384
    • A silver halide color photographic light-sensitive material comprising a support having thereon a silver halide emulsion layer containing at least one kind of compound represented by the following general formula (I): ##STR1## wherein each substituent represented by R.sub.1, R.sub.2, R.sub.3, X, or Ar and m are defined within the specification, said silver halide color photographic light-sensitive material comprises a compound represented by the following general formula (II) in the silver halide emulsion layer containing the compound represented by the above general formula (I) and/or a hydrophilic colloid layer which is positioned at the remoter side than the silver halide emulsion layer from the support: ##STR2## wherein each substituent represented by Y, R.sub.4, R.sub.5, R.sub.6, R.sub.7 or Ar is defined within the specification.The silver halide color photographic light-sensitive material can provide a magenta color image having excellent photographic properties without the occurrence of stain, even when the color photographic material is processed in a processing solution under the running condition.A method of forming a color image using the silver halide color photographic light-sensitive material is also disclosed.
    • 一种卤化银彩色照相感光材料,其包含其上具有卤化银乳剂层的载体,所述卤化银乳剂层含有由以下通式(I)表示的至少一种化合物:其中每个由R 1,R 2表示的取代基 所述卤化银彩色照相感光材料包含由以上通式表示的化合物的卤化银乳剂层中的由以下通式(II)表示的化合物:其中,R 3,X或Ar和m定义在本说明书中, 式(I)和/或位于距离载体的卤化银乳剂层更远侧的亲水胶体层:其中由Y,R4,R5,R6,R7或Ar表示的每个取代基 在规范内定义。 卤化银彩色摄影感光材料即使当在运行状态下在处理溶液中处理彩色照相材料时,也可以提供具有优异的照相性能的品红色图像,而不会发生污渍。 还公开了使用卤化银彩色照相感光材料形成彩色图像的方法。
    • 2. 发明授权
    • Silver halide color photographic material
    • 卤化银彩色照相材料
    • US4456682A
    • 1984-06-26
    • US420689
    • 1982-09-21
    • Takatoshi IshikawaAkio MitsuiMasakazu MorigakiTakashi Nakamura
    • Takatoshi IshikawaAkio MitsuiMasakazu MorigakiTakashi Nakamura
    • G03C7/26C07D231/08G03C1/42G03C7/30G03C7/392G03C7/00
    • G03C7/39252
    • A silver halide color photographic material is disclosed. The material has improved developing characteristics which are obtained by containing both a substantially light-insensitive silver halide and at least one specific 3-pyrazolidone compound. The substantially light-insensitive silver halide includes a halogen composition consisting of 0 to 100 percent of bromide, 0 to 2 percent of iodine and the residual percent of chlorine, a mean grain size of 0.01 to 0.3.mu., and a coverage of 5 to 500 mg/m.sup.2. The 3-pyrazolidone compound has the following general formula (I): ##STR1## wherein X represents a hydrogen atom or an acetyl group; R represents an aryl group; and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents a hydrogen atom, an alkyl group or an aryl group, and they may be the same as or different from one another. The material can be developed at an increased speed and is not accompanied by undesirable photographic effects such as fogging.
    • 公开了一种卤化银彩色照相材料。 该材料具有改善的显影特性,其通过含有基本上不受光的卤化银和至少一种特定的3-吡唑烷酮化合物而获得。 基本上不光敏的卤化银包括卤素组合物,其由0-100%的溴化物,0-2%的碘和氯的残余百分比组成,平均粒径为0.01至0.3μm,覆盖率为5至500 mg / m2。 3-吡唑烷酮化合物具有以下通式(I):其中X表示氢原子或乙酰基;(I) R表示芳基; 并且R 1,R 2,R 3和R 4各自表示氢原子,烷基或芳基,并且它们可以彼此相同或不同。 该材料可以以增加的速度进行显影,并且不伴随不期望的照相效果,如起雾。
    • 5. 发明授权
    • Color photographic light-sensitive material
    • 彩色摄影感光材料
    • US4463085A
    • 1984-07-31
    • US449812
    • 1982-12-14
    • Akio MitsuiMasakazu Morigaki
    • Akio MitsuiMasakazu Morigaki
    • G03C7/26G03C7/30G03C7/392G03C7/40
    • G03C7/39248G03C7/3012
    • A silver halide color photographic light-sensitive material comprising a support having coated thereon at least one silver halide emulsion layer, the color photographic light-sensitive material containing at least one kind of 2-equivalent magenta coupler represented by the following general formula (Ia): ##STR1## wherein Ar represents phenyl substituted with at least one halogen, alkyl, alkoxy, alkoxycarbonyl or cyano; Y represents acylamino or anilino; and Z represents a group capable of being released by coupling, and at least one kind of piperidine compound represented by the following general formula (II): ##STR2## wherein R.sub.1 represents hydrogen or alkyl; R.sub.2 represents alkyl, hydroxyalkyl, alkenyl alkynyl or benzyl; W represents hydrogen, alkyl, hydroxy, silyloxy, alkylamino, aryloxy, allyl, alkoxy, acylamino, sulfonamido, alkoxycarbonyl, carboxy, acyloxy or phosphoric acid oxy. The silver halide color photographic light-sensitive material can provide a good magenta color image without the occurrence of strain, even when the color photographic material is processed in a processing solution under the running condition.
    • 一种卤化银彩色照相感光材料,其包含在其上涂覆有至少一个卤化银乳剂层的载体,所述彩色照相感光材料含有至少一种由以下通式(Ia)表示的2-当量品红成色剂, (Ia)其中Ar表示被至少一个卤素,烷基,烷氧基,烷氧基羰基或氰基取代的苯基; Y表示酰氨基或苯胺基; Z表示可通过偶联而释放的基团,以及由以下通式(II)表示的至少一种哌啶化合物:其中R 1表示氢或烷基; R2代表烷基,羟基烷基,烯基炔基或苄基; W表示氢,烷基,羟基,甲硅烷氧基,烷基氨基,芳氧基,烯丙基,烷氧基,酰氨基,亚磺酰氨基,烷氧基羰基,羧基,酰氧基或磷酸氧基。 即使在运行条件下在处理溶液中处理彩色照相材料,卤化银彩色照相感光材料也可以提供良好的品红色图像而不产生应变。
    • 6. 发明授权
    • Color reversal image forming process using high chloride emulsions and
high chloride developing solutions
    • 使用高氯化物乳液和高氯化物显影液的彩色反转成像方法
    • US5356759A
    • 1994-10-18
    • US978743
    • 1992-11-19
    • Akio MitsuiTakatoshi Ishikawa
    • Akio MitsuiTakatoshi Ishikawa
    • G03C1/035G03C1/06G03C5/50G03C7/00G03C7/407G03C7/46G03C1/08G03C7/26G03C7/32
    • G03C5/50
    • A color reversal image forming process using a color reversal photographic material is disclosed. The process comprises an exposure step, a black and white development step, a reversal step, a color development step and a desilvering step. The color reversal photographic material comprises a support and one or more silver halide emulsion layers. According to one embodiment of the present invention, at least one silver halide emulsion layer comprises silver halide containing chloride of not less than 90 mole %, iodide of 0 mole % and bromide of not more than 10 mole %. According to another embodiment, at least one silver halide emulsion layer comprises silver halide containing chloride of not less than 88 mole %, iodide of 0.1 to 2 mole % and bromide of not more than 10 mole %. The silver halide emulsion layer further contains a compound represented by the formula (Ia) or (Ib): ##STR1## wherein R.sup.11 is an alkyl group, an alkenyl group, a heterocyclic group or an aryl group; X.sup.1 is hydrogen, an alkali metal atom, an ammonium group or a precursor thereof; V.sup.1 is an oxygen atom, a sulfur atom, .dbd.NH or .dbd.N--(L).sub.n, --R.sup.12 ; L is a divalent linking group; and n is 0 or 1.
    • 公开了使用彩色反转照相材料的彩色反转图像形成方法。 该方法包括曝光步骤,黑白显影步骤,反转步骤,显色步骤和脱银步骤。 彩色反转照相材料包括载体和一个或多个卤化银乳剂层。 根据本发明的一个实施方案,至少一个卤化银乳剂层包含卤化银,其含有不小于90摩尔%的氯化物,0摩尔%的碘化物和不大于10摩尔%的溴化物。 根据另一个实施方案,至少一个卤化银乳剂层包含卤化银,其含有不低于88摩尔%的氯化物,0.1-2摩尔%的碘化物和不大于10摩尔%的溴化物。 卤化银乳剂层还含有式(Ia)或(Ib)表示的化合物:其中R11是烷基,烯基,杂环基或芳基; X1是氢,碱金属原子,铵基或其前体; V1是氧原子,硫原子,= NH或= N-(L)n,-R12; L是二价连接基团; n为0或1。
    • 10. 发明授权
    • Silver halide photographic photosensitive materials
    • 卤化银感光材料
    • US5336590A
    • 1994-08-09
    • US952157
    • 1992-09-28
    • Akio Mitsui
    • Akio Mitsui
    • G03C7/32G03C1/06G03C7/00G03C7/30G03C7/333G03C7/22
    • G03C7/3003Y10S430/141
    • A silver halide color photographic photosensitive material is disclosed which comprises a transparent support on which there are provided at least one cyan color forming coupler containing layer, at least one magenta color forming coupler containing layer, and at least one yellow color forming coupler containing layer, and at least one light-insensitive layer, wherein a compound represented by formula (I), a compound represented by formula (IIa) or (IIb) or both, and an internal latent image forming silver halide grain are contained in the photographic material: ##STR1## wherein Z.sup.11 represents a group of non-metal atoms which is required to form a five or six membered heterocyclic ring, and Z.sup.11 may be substituted with substituent groups; R.sup.11 is an aliphatic group; and R.sup.12 is a hydrogen atom, an aliphatic group or an aromatic group; R.sup.11 and R.sup.12 may be substituted with substituent groups; R.sup.12 may be joined to the heterocyclic ring completed by Z.sup.11 to form a ring; provided that at least one of the groups R.sup.11, R.sup.12 and Z.sup.11 contains an alkyl group, an acyl group, a hydrazine group or a hydrazone group, R.sup.11 and R.sup.12 may be combined to form a dihydropyridinium skeleton; moreover, at least one of the groups R.sup.11, R.sup.12 and Z.sup.11 may have a group which promotes adsorption on silver halide; and Y.sup.11 is a charge balancing counter ion and n is 0 or 1: ##STR2## wherein R.sub.21, R.sub.22 and R.sub.23 each represents an aliphatic group, an aromatic group, or a heterocyclic group; R.sub.25 represents an aniline group or an acylamino group; R.sub.24 represents a substituted phenyl group; X.sup.21 represents a linkage group and X.sup.21 may not exist; R.sub.26 represents a group which can be substituted on a benzene ring; and m represents an integer of 0 to 4.
    • 公开了一种卤化银彩色照相感光材料,其包括透明支撑体,在该透明支撑体上设置有至少一种形成青色的成色剂,含有至少一种品红色形成成色剂的含有层,以及至少一种形成黄色的成色剂的层, 和至少一种不透光层,其中由式(I)表示的化合物,由式(IIa)或(IIb)表示的化合物或两者,以及内部潜像形成卤化银颗粒包含在照相材料中: (I)其中Z11表示形成五或六元杂环所需的一组非金属原子,Z 11可以被取代基取代; R11是脂族基团; R 12为氢原子,脂肪族基团或芳香族基团; R 11和R 12可以被取代基取代; R12可以连接到由Z11完成的杂环以形成环; 条件是组R11,R12和Z11中的至少一个含有烷基,酰基,肼基或腙基,R 11和R 12可以结合形成二氢吡啶骨架; 此外,基团R11,R12和Z11中的至少一个可以具有促进卤化银吸附的基团; (IIa)(IIb)其中R21,R22和R23各自表示脂族基团,芳族基团或杂环基团;并且Y11为电荷平衡反离子,n为0或1。 R25表示苯胺基或酰氨基; R 24表示取代的苯基; X21表示连接基,X21可以不存在; R26表示可在苯环上取代的基团; m表示0〜4的整数。