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    • 2. 发明申请
    • Porphyrazine Coloring Matter And Ink Composition Containing The Same
    • 紫菜色素和含有它的油墨组合物
    • US20100279082A1
    • 2010-11-04
    • US12810376
    • 2008-12-25
    • Shinsuke ShimizuTakashi Yoneda
    • Shinsuke ShimizuTakashi Yoneda
    • C09D11/02C09B47/00B05D5/00B32B5/00B41J2/01
    • C07D487/22B41M5/0023C07D471/22C09B47/26C09D11/328Y10T428/24802
    • The present invention relates to a porphyrazine coloring matter represented by the following formula (1) or a salt thereof [wherein, the rings A, B, C and D shown by broken lines each independently represent a 6-membered ring having aromaticity, at least 1.0 of said rings A to D is a benzene ring and at least 0.5 of them is a nitrogen-containing heteroaromatic ring, when shown as an average value; E represents an alkylene group; X and Y are each independently an anilino group having 1 to 3 carboxy groups; and b is 0 to 3.4, c is 0.1 to 3.5, and the sum of b and c is 1.0 to 3.5, when shown as an average value]. The present invention can provide a porphyrazine coloring matter suitable for inkjet recording, which has characteristics of having a good hue as cyan ink, excellent fastnesses, in particular, extremely excellent water fastness when printed on plain paper, and high solubility in water or a water-soluble organic solvent.
    • 本发明涉及由下式(1)表示的四氮杂卟啉色素或其盐[其中,虚线表示的环A,B,C和D各自独立地表示具有芳香性的6元环,至少 所述环A至D中的一个为苯环,当其为平均值时,其中至少0.5个为含氮杂芳族环; E表示亚烷基; X和Y各自独立地为具有1至3个羧基的苯胺基; b为0〜3.4,c为0.1〜3.5,b和c之和为1.0〜3.5,以平均值表示。 本发明可以提供一种适用于喷墨记录的四氮杂卟啉色素,其具有青色油墨具有良好色调的特性,优异的坚牢度,特别是在普通纸上印刷时耐水性极好,在水或水中的溶解度高 - 可溶性有机溶剂。
    • 3. 发明授权
    • Porphyrazine coloring matter and ink composition containing the same
    • 紫菜色素和含有相同成分的油墨组合物
    • US07981204B2
    • 2011-07-19
    • US12810376
    • 2008-12-25
    • Shinsuke ShimizuTakashi Yoneda
    • Shinsuke ShimizuTakashi Yoneda
    • C09D11/02C07D487/22B32B3/10B41J2/01
    • C07D487/22B41M5/0023C07D471/22C09B47/26C09D11/328Y10T428/24802
    • The present invention relates to a porphyrazine coloring matter represented by the following formula (1) or a salt thereof: wherein, the rings A, B, C and D shown by broken lines each independently represent a 6-membered ring having aromaticity, at least 1.0 of said rings A to D is a benzene ring and at least 0.5 of them is a nitrogen-containing heteroaromatic ring, when shown as an average value; E represents an alkylene group; X and Y are each independently an anilino group having 1 to 3 carboxy groups; and b is 0 to 3.4, c is 0.1 to 3.5, and the sum of b and c is 1.0 to 3.5, when shown as an average value. The present invention can provide a porphyrazine coloring matter suitable for inkjet recording, which has characteristics of having a good hue as cyan ink, excellent fastnesses, in particular, extremely excellent water fastness when printed on plain paper, and high solubility in water or a water-soluble organic solvent.
    • 本发明涉及由下式(1)表示的四氮杂卟啉色素或其盐:其中,虚线所示的环A,B,C和D各自独立地表示具有芳香性的6元环,至少 所述环A至D中的一个为苯环,当其为平均值时,其中至少0.5个为含氮杂芳族环; E表示亚烷基; X和Y各自独立地为具有1至3个羧基的苯胺基; b为0〜3.4,c为0.1〜3.5,b与c的和为平均值时为1.0〜3.5。 本发明可以提供一种适用于喷墨记录的四氮杂卟啉色素,其具有青色油墨具有良好色调的特性,优异的坚牢度,特别是在普通纸上印刷时耐水性极好,在水或水中的溶解度高 - 可溶性有机溶剂。
    • 5. 发明申请
    • TRISAZO COMPOUND, INK COMPOSITION, PRINTING METHOD AND COLORED PRODUCT
    • TRISAZO化合物,墨水组合物,印刷方法和着色产品
    • US20100309246A1
    • 2010-12-09
    • US12734655
    • 2008-11-25
    • Koji HirotaTakahiko MatsuiTakashi YoshimotoShinsuke Shimizu
    • Koji HirotaTakahiko MatsuiTakashi YoshimotoShinsuke Shimizu
    • B41J2/015C09B31/16
    • C07D471/04B41M5/0023C09B31/28C09D11/328
    • The present invention relates to a trisazo compound represented by the following formula (1): (wherein, n represents 0 or 1, the group A represents a substituted heterocyclic group, R1 represents a C1-C4 alkyl group which may be substituted or the like, R2 represents a cyano group or the like, R3 and R4 each independently represent a hydrogen atom, a sulfo group or the like, R5 to R7 each independently represent a hydrogen atom, a C1-C4 alkyl group which may be substituted, a C1-C4 alkoxy group which may be substituted or the like, respectively) or a salt thereof. Said trisazo compound or a salt thereof provides a coloring matter compound for black ink and an ink composition thereof where they have high solubility in medium where water is a principal component, their aqueous solution and ink having high concentration is stable even when stored for a long period of time, printed images therewith have very high density, no bronzing is caused on the images printed even with their high concentration solution, and they give black recorded images excellent in fastnesses, particularly in both light fastness and ozone gas fastness.
    • 本发明涉及由下式(1)表示的三偶氮化合物:其中,n表示0或1,A组代表取代的杂环基,R 1表示可被取代的C 1 -C 4烷基等 ,R 2表示氰基等,R 3和R 4各自独立地表示氢原子,磺基等,R 5〜R 7各自独立地表示氢原子,可以被取代的C 1〜C 4烷基,C 1 可以被取代的C 1-4烷氧基或类似物)或其盐。 所述三偶氮化合物或其盐提供了黑色墨水的着色剂化合物及其油墨组合物,其中以水为主要成分的介质中它们具有高溶解度,即使长时间储存​​,其浓度高的水溶液和油墨也是稳定的 时间段,印刷图像具有非常高的密度,即使在高浓度溶液下印刷图像也不会导致烫伤,并且它们具有耐光性优异的黑色记录图像,特别是耐光牢度和耐臭氧气体牢度。
    • 7. 发明授权
    • Trisazo compound, ink composition, printing method and colored product
    • 三唑烷化合物,油墨组合物,印刷方法和有色产品
    • US07901498B2
    • 2011-03-08
    • US12734655
    • 2008-11-25
    • Koji HirotaTakahiko MatsuiTakashi YoshimotoShinsuke Shimizu
    • Koji HirotaTakahiko MatsuiTakashi YoshimotoShinsuke Shimizu
    • C09D11/02C09B31/16
    • C07D471/04B41M5/0023C09B31/28C09D11/328
    • The present invention relates to a trisazo compound represented by the following formula (1): wherein, n represents 0 or 1, the group A represents a substituted heterocyclic group, R1 represents a C1-C4 alkyl group which may be substituted or the like, R2 represents a cyano group or the like, R3 and R4 each independently represent a hydrogen atom, a sulfo group or the like, R5 to R7 each independently represent a hydrogen atom, a C1-C4 alkyl group which may be substituted, a C1-C4 alkoxy group which may be substituted or the like, respectively or salt thereof. Said trisazo compound or salt thereof provides a coloring matter compound for black ink and an ink composition thereof where they have high solubility in medium where water is a principal component, their aqueous solution and ink having high concentration is stable even when stored for a long period of time, printed images therewith have very high density, no bronzing is caused on the images printed even with their high concentration solution, and they give black recorded images excellent in fastness, particularly in both light fastness and ozone gas fastness.
    • 本发明涉及由下式(1)表示的三偶氮化合物:其中,n表示0或1,A组代表取代的杂环基,R 1表示可被取代的C 1 -C 4烷基等, R2表示氰基等,R3和R4各自独立地表示氢原子,磺基等,R5〜R7各自独立地表示氢原子,可以被取代的C1-C4烷基,C1- 分别为可被取代的C 4烷氧基或类似物或其盐。 所述三偶氮化合物或其盐提供黑色墨水的着色剂化合物及其油墨组合物,其中以水为主要成分的介质中具有高溶解性,即使长期储存,其浓度高的水溶液和油墨也是稳定的 的时间,印刷图像具有非常高的密度,即使在高浓度溶液下印刷的图像也不会导致烫伤,并且它们给出耐光性优异的黑色记录图像,特别是耐光牢度和耐臭氧气体牢度。
    • 9. 发明申请
    • Multicast packet routing arrangements for group-membership handling
    • 用于组成员处理的组播包路由布置
    • US20050281265A1
    • 2005-12-22
    • US11155723
    • 2005-06-20
    • Yoshitaka SakamotoHisao TaguchiMigaku OtaShinsuke Shimizu
    • Yoshitaka SakamotoHisao TaguchiMigaku OtaShinsuke Shimizu
    • H04L12/18H04L12/28H04L12/66H04L12/70H04L12/56
    • H04L12/185H04L45/00H04L45/16H04L49/201
    • A packet routing arrangement, when receiving a request to join or leave a multicast group from a host unregistered to that group, a response is sent exclusively to the unregistered host. In the packet routing arrangement, when receiving request packet from a host to join or leave a group, including the identifier of the group, it is determined whether the source host of the packet is registered to that group; and, if it is not registered, the first group identifier is changed to a second group identifier assigned to another delivery server delivering information to the other unregistered host and the packet is transferred to this other delivery server. When receiving a packet containing certain information from this delivery server, the second group identifier included in the received packet is changed to the first group identifier and the packet is transmitted to the unregistered host.
    • 分组路由布置当从未登记到该组的主机接收到加入或离开多播组的请求时,响应被专门发送到未注册的主机。 在分组路由布置中,当从主机接收请求分组以加入或离开组(包括组的标识符)时,确定分组的源主机是否被注册到该组; 并且如果未注册,则将第一组标识符改变为分配给另一个递送服务器的第二组标识符,以向另一个未注册的主机传送信息,并且该分组被传送到该另一个传送服务器。 当从该发送服务器接收到包含某些信息的分组时,包含在接收到的分组中的第二组标识符被改变为第一组标识符,并且该分组被发送到未注册的主机。