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1. 发明授权

US4786558A Composite film and antistatic composite film comprising a swellable inorganic silicate 失效
标题翻译：复合薄膜和抗静电复合薄膜，包括可膨胀的无机硅酸盐
公开(公告)号：US4786558A
公开(公告)日：1988-11-22
申请号：US9300
申请日：1987-01-30
申请人： Takashi Sumiya , Kenji Yabe , Takashi Mimura , Satoyuki Minami
发明人： Takashi Sumiya , Kenji Yabe , Takashi Mimura , Satoyuki Minami
IPC分类号： C08J7/04 , C09D1/00 , G03C1/85 , G11B5/73 , B32B19/02 , B32B19/04 , B32B27/14
CPC分类号： C09D1/00 , C08J7/047 , G03C1/85 , G11B5/7305 , Y10T428/24967 , Y10T428/251 , Y10T428/2911 , Y10T428/31507 , Y10T428/31663 , Y10T428/31721 , Y10T428/31725 , Y10T428/31786 , Y10T428/31855 , Y10T428/31942 , Y10T428/31971
摘要： The present invention relates to a composite film comprising a plastic film and a protective layer which is formed on at least one surface of the film, wherein the protective layer is made of a mixture comprising (a) an inorganic swellable silicate having a layered structure and (b) a compound containing a silanol group at a weight ratio of (a) to (b) of between 1:1000 and 2:1 and an antistatic composite film comprising a plastic film and a coating layer which is formed on at least one surface of the film, wherein said coating layer is made of a mixture comprising (a) a swellable inorganic silicate having a layered structure and containing at least one ion selected from among aliphatic ammonium ions having at most 6 carbon atoms, sodium ion, silver ion and lithium ion as an interlayer ion and (b) at least one member selected from among water-soluble compounds and water-dispersible resins at a weight ratio of (a) to (b) of between 1:1000 and 2:1. These composite films are excellent in electrical characteristics, smoothness, slipperiness, anti-scratching properties, antistatic properties and the like, so that they are suitable for various uses such as electrical insulating material, wrapping material, labels, writable and erasable materials, print lamination film, magnetic recording medium, micro-film or the like.
摘要翻译：本发明涉及一种复合膜，其包括塑料膜和形成在膜的至少一个表面上的保护层，其中保护层由以下混合物制成：（a）具有层状结构的无机可溶胀硅酸盐和（b）含有重量比（a）至（b）为1：1000和2：1的硅烷醇基的化合物和包含塑料膜和涂层的抗静电复合膜，所述抗静电复合膜形成在至少一个膜的表面，其中所述涂层由以下混合物制成：（a）具有层状结构且含有至少一种选自具有至多6个碳原子的脂族铵离子中的至少一种离子的可溶胀无机硅酸盐，钠离子，银离子和锂离子作为层间离子，和（b）选自水溶性化合物和水分散性树脂中的至少一种以（a）至（b）的重量比为1:1000至2:1的组分。这些复合膜的电气特性，光滑性，光滑性，耐刮擦性，抗静电性等优异，因此适用于各种用途，例如电绝缘材料，包装材料，标签，可写和可擦除材料，印刷层压薄膜，磁记录介质，微膜等。

2. 发明授权

US5061565A Film for heat-sensitive mimeograph stencil 失效
标题翻译：用于敏感MIME图像的电影
公开(公告)号：US5061565A
公开(公告)日：1991-10-29
申请号：US329895
申请日：1990-01-11
申请人： Seizo Aoki , Kenji Tsunashima , Toshiya Yoshii , Yasuji Nakahara , Takashi Sumiya , Takashi Mimura
发明人： Seizo Aoki , Kenji Tsunashima , Toshiya Yoshii , Yasuji Nakahara , Takashi Sumiya , Takashi Mimura
IPC分类号： C08J5/18 , B29C55/12 , B29K67/00 , B29L7/00 , B41N1/24
CPC分类号： B41N1/245 , Y10T428/24802 , Y10T428/31 , Y10T428/31551 , Y10T428/31786
摘要： A film for heat-sensitive mimeograph stencil and a heat-sensitive mimeograph stencil comprising a porous support and the film laminated thereon are disclosed. Since the film of the present invention has an energy of crystal fusion .DELTA.Hu of 3-11 cal/g and has a difference Tm in temperature of the crystal fusion-starting point and the crystal fusion-terminating point of 50.degree. C. to 100.degree. C., the heat sensitivity is high, so that the characters and symbols or figures can be printed clearly, and the unevenness in the thickness and the light and shade of the printed characters may substantially be eliminated. Further, since it is not necessary to make the film thin, productivity and ease of handling may be promoted.

3. 发明授权

US5051475A Polyester-based film 失效
标题翻译：聚酯类薄膜
公开(公告)号：US5051475A
公开(公告)日：1991-09-24
申请号：US453715
申请日：1989-12-20
申请人： Kenji Tsunashima , Takashi Mimura , Takashi Sumiya , Hiroshi Kuboyama
发明人： Kenji Tsunashima , Takashi Mimura , Takashi Sumiya , Hiroshi Kuboyama
IPC分类号： B32B27/08 , B05D7/02 , B05D7/24 , B29C55/02 , B29K67/00 , B32B27/30 , B32B27/36 , C08J5/18 , C08J7/04
CPC分类号： C08J7/047 , C08J5/18 , C08J2367/02 , C08J2425/00 , Y10T428/31786 , Y10T428/31797 , Y10T428/31913
摘要： The present invention is directed to a polyester film comprising at least at its surface portion oriented sulfonic acid groups and/or salts thereof with an orientation degree of 5-100, which has an excellent adhesiveness, especially excellent anti-alkaline adhesiveness. The present invention also makes it possible to provide a polyester film having, in addition to the excellent adhesiveness, an excellent transparency, antistatic property and waterproof property.

4. 发明授权

US4908277A Polyester film 失效
标题翻译：聚酯薄膜
公开(公告)号：US4908277A
公开(公告)日：1990-03-13
申请号：US168944
申请日：1988-03-16
申请人： Kenji Tsunashima , Takashi Mimura , Takashi Sumiya , Hiroshi Kuboyama
发明人： Kenji Tsunashima , Takashi Mimura , Takashi Sumiya , Hiroshi Kuboyama
IPC分类号： B32B27/08 , B05D7/02 , B05D7/24 , B29C55/02 , B29K67/00 , B32B27/30 , B32B27/36 , C08J5/18 , C08J7/04
CPC分类号： C08J7/047 , C08J5/18 , C08J2367/02 , C08J2425/00 , Y10T428/31786 , Y10T428/31797 , Y10T428/31913
摘要： The present invention is directed to a polyester film comprising at least at its surface portion oriented sulfonic acid groups and/or salts thereof with an orientation degree of 5-100, which has an excellent adhesiveness, especially excellent anti-alkaline adhesiveness. The present invention also makes it possible to provide a polyester film having, in addition to the excellent adhesiveness, an excellent transparency, antistatic property and waterproof property.

5. 发明授权

US5724915A Material for the treatment of pet excretion and method of producing the same material 失效
标题翻译：用于处理宠物排泄物的材料和生产相同材料的方法
公开(公告)号：US5724915A
公开(公告)日：1998-03-10
申请号：US676008
申请日：1996-07-05
申请人： Kengo Ochi , Yuko Kawasaki , Takashi Sumiya , Yukio Zenitani
发明人： Kengo Ochi , Yuko Kawasaki , Takashi Sumiya , Yukio Zenitani
IPC分类号： A01K1/015 , A01K29/00
CPC分类号： A01K1/0154 , A01K1/0155
摘要： A material and a method for preparing the same for treating excretions of pet animals comprising: 100 parts by weight of substrate (A) selected from an inorganic powder, short organic fibers, crushed cellulose, or granulated forms thereof coated with from 5-300 parts by weight of a water-absorbent resin/fiber composite (B), the composite (B) being a mixture of a water-absorbent resin fine powder, a fibrous substance and optionally a hydrophilic thermoplastic substance.
摘要翻译：一种用于处理宠物动物排泄物的材料及其制备方法，包括：将100重量份选自无机粉末，短有机纤维，粉碎的纤维素或其颗粒形式的基材（A）的吸水性树脂/纤维复合材料（B），复合物（B）是吸水性树脂细粉末，纤维状物质和任选的亲水性热塑性物质的混合物。

6. 发明授权

US5384368A Process for producing water absorbent resin 失效
标题翻译：吸水树脂的制造方法
公开(公告)号：US5384368A
公开(公告)日：1995-01-24
申请号：US201234
申请日：1994-02-24
申请人： Masashi Date , Takashi Sumiya , Hitoshi Takai
发明人： Masashi Date , Takashi Sumiya , Hitoshi Takai
IPC分类号： C08F8/30 , A61L15/60 , B01J20/26 , C08G81/00 , C08K5/3412 , C08L101/00
CPC分类号： B01J20/26 , A61L15/60
摘要： The present invention relates to a process for producing water absorbent resin comprising a step of adding a high-molecular crosslinking agent which has at least 2 azetidinium salt groups in the molecule and has at least 1000 weight-average molecular weight to the water absorbent resin paticles having carboxylic groups and carboxylic acid salt groups and a step of efficiently crosslinking the vicinity of the surface of the water absorbent resin particles. In the process for producing water absorbent resin according to the present invention, the use of high-molecular crosslinking agent achieves less permeation of the crosslinking agent into the water absorbent resin particles and enables efficient crosslinking of the vicinity of the surface of the water absorbent resin particles. Consequently, the water absorbent resin having high water absorbency both under pressure-free state and under loading can be manufactured. Because the crosslinking agent contains a large amount of azetidinium salt groups highly reactive to carboxylic acid groups or carboxylic acid salt groups in the molecule, the water absorbent resin having high crosslinking efficiency, good safety, and good flowability can be manufactured.
摘要翻译：本发明涉及一种生产吸水性树脂的方法，其包括在分子中加入至少具有2个氮杂环丁烷鎓盐基并且具有至少1000重量平均分子量的高分子交联剂的步骤，具有羧基和羧酸盐基团以及有效地交联吸水性树脂颗粒表面附近的步骤。在本发明的吸水性树脂的制造方法中，使用高分子交联剂使交联剂在吸水性树脂粒子中的渗透性降低，能够使吸水性树脂表面附近的高效交联粒子。因此，可以制造在无压力状态和负载下都具有高吸水性的吸水性树脂。由于交联剂含有大量与分子中的羧酸基团或羧酸盐基团反应性高的氮杂环丁烷鎓盐基，所以可以制造交联效率高，安全性好，流动性良好的吸水性树脂。

7. 发明授权

US5698308A Polyester film for use of a laminate with a metal plate 失效
标题翻译：聚酯薄膜，用于与金属板的层压板
公开(公告)号：US5698308A
公开(公告)日：1997-12-16
申请号：US623928
申请日：1996-03-28
申请人： Takashi Sumiya , Iwao Tanaka , Kunio Shibatsuji , Hirokazu Kurome , Seiya Sugiura , Wataru Ooe
发明人： Takashi Sumiya , Iwao Tanaka , Kunio Shibatsuji , Hirokazu Kurome , Seiya Sugiura , Wataru Ooe
IPC分类号： B32B15/08 , B32B27/36 , C08J5/18 , C08K3/00 , B32B3/26
CPC分类号： C08J5/18 , B32B15/08 , B32B27/36 , C08K3/0033 , C08J2367/02 , Y10T428/249986 , Y10T428/249987 , Y10T428/31681 , Y10T428/31786
摘要： Disclosed is a polyester film for use of a laminate with a metal plate comprising a polyester=group resin containing a white pigment having a mean particle diameter of 0.01 to 1.8 .mu.m at a content of 10 to 30% by weight. The film has (a) a void ratio of 4 to 30%, (b) a melting peak temperature of 150.degree. to 245.degree. C., (c) an amount of oligomer of not more than 3% by weight and (d) an orientation degree of 0.7 to 4.0. When the film is laminated on a metal, it can indicate excellent light interruptive property, lamination property, forming property and processing property.
摘要翻译：公开了使用含有含有10〜30重量％的平均粒径为0.01〜1.8μm的白色颜料的聚酯=基团树脂的金属板的层叠体的聚酯膜。（a）空隙率为4〜30％，（b）熔融峰温度为150〜245℃，（c）低于3重量％的低聚物量，（d）取向度为0.7〜4.0。当膜层压在金属上时，可以表现出优异的光中断性，层叠性，成形性和加工性。

8. 发明授权

US5380808A Process for producing water-absorbing resins 失效
标题翻译：生产吸水树脂的方法
公开(公告)号：US5380808A
公开(公告)日：1995-01-10
申请号：US728294
申请日：1991-07-11
申请人： Takashi Sumiya , Masashi Date , Kenji Tanaka
发明人： Takashi Sumiya , Masashi Date , Kenji Tanaka
IPC分类号： C08F2/10 , C08F220/06
CPC分类号： C08F220/06 , C08F2/10 , C08F222/1006 , C08F222/385
摘要： The invention concerns a process for producing water-insoluble water-absorbing resins, which comprises the steps of initiating polymerization of an aqueous solution containing 30 to 80% by weight of (a) a hydrophilic vinyl monomer having a functional group and (b) a crosslinking agent by supplying the aqueous solution together with (c) a polymerization initiator to a polymerizing apparatus capable of heating and/or cooling surfaces in contact with the aqueous solution, subsequently causing constant temperature polymerization of the solution without agitating the same by controlling the temperature of the system being polymerized to 20.degree. to 70.degree. C., and elevating, if necessary, the temperature ok the system to be in excess of 70.degree. C. in a stage with a polymerization percentage of 70% or above before completion of polymerization. Obtainable water-insoluble water-absorbing resins have excellent water-absorbing property and have less water-soluble components. Thus, the water-absorbing resins according to the invention are useful for physiological commodities, paper diapers or like sanitary materials, drip absorbing materials, cold water retainers, dew condensation prevention materials for construction materials and so forth.
摘要翻译：本发明涉及一种生产水不溶性吸水树脂的方法，其包括以下步骤：引发含有30至80重量％的（a）具有官能团的亲水乙烯基单体的水溶液的聚合，和（b）通过将水溶液与（c）聚合引发剂一起供给到能够加热和/或冷却与水溶液接触的表面的聚合装置的交联剂，随后通过控制温度来搅拌溶液的恒温聚合，的体系聚合至20〜70℃，如果需要，在聚合反应完成前，在70％以上聚合率的阶段，将体系升温至超过70℃ 。可获得的水不溶性吸水树脂具有优异的吸水性，并且具有较少的水溶性成分。因此，本发明的吸水性树脂可用于生理用品，纸尿布等卫生材料，滴水吸收材料，冷水保持器，建筑材料的防结露材料等。

9. 发明授权

US06667133B1 Gelating agent for alkaline cell and alkaline cell 有权
标题翻译：碱性电池和碱性电池的凝胶剂
公开(公告)号：US06667133B1
公开(公告)日：2003-12-23
申请号：US09913102
申请日：2001-08-09
申请人： Takashi Sumiya , Masami Koike , Yukio Zenitani
发明人： Takashi Sumiya , Masami Koike , Yukio Zenitani
IPC分类号： H01M614
CPC分类号： H01M4/622 , H01M4/02 , H01M4/621 , H01M6/06 , H01M6/08 , H01M6/22 , H01M2300/0014 , H01M2300/0085
摘要： A gelating agent for an alkaline cell is a cross-linked polymer (A) comprising (meth)acrylic acid and/or its alkali metal salt as a main constituent monomer unit and obtained by an aqueous solution polymerization or a reversed phase suspension polymerization and satisfies the following required conditions (1), (2). The gelating agent has good draining property, satisfactorily high speed charging property of the alkaline electrolytic solution and is therefore effective to produce cells with little unevenness of the charging amount of the electrolytic solution and having uniform quality by mass production and an alkaline cell using the gelating agent is provided with durable discharge time and remarkably excellent impact resistance for a long duration. The said required conditions are required condition (1); that the gelating agent contains 50% by weight or more of a particle whose swollen particle size becomes 300 to 4,000 &mgr;m when the gelating agent is swollen in an aqueous potassium hydroxide solution of 40% by weight concentration and required condition (2); that the aqueous potassium hydroxide solution of 40% by weight concentration containing 3% by weight of the gelating agent has 0 to 20 mm stringiness.
摘要翻译：碱性电池用凝胶剂是含有（甲基）丙烯酸和/或其碱金属盐作为主要构成单体单元并通过水溶液聚合或反相悬浮聚合得到的交联聚合物（A），并且满足以下条件（1），（2）。凝胶剂具有良好的排水性能，碱性电解液具有令人满意的高速充电性能，因此有效地生产电解液的充电量不均匀且通过大规模生产具有均匀质量的电池和使用凝胶化的碱性电池具有耐久的放电时间和长时间显着优异的耐冲击性。所需条件为条件（1）; 当凝胶剂在40重量％浓度的浓度的氢氧化钾水溶液中溶胀并且所需条件（2）时，凝胶剂含有50重量％以上的溶胀粒径为300〜4000μm的颗粒; 含有3重量％凝胶剂的40重量％浓度的氢氧化钾溶液的拉伸强度为0〜20mm。

10. 发明授权

US6130304A Water-absorbent or water-retention material and production method thereof 失效
标题翻译：吸水剂或保水材料及其制造方法
公开(公告)号：US6130304A
公开(公告)日：2000-10-10
申请号：US855226
申请日：1997-05-13
申请人： Takashi Sumiya , Masami Koike , Yoji Fujiura , Mihoko Nomoto
发明人： Takashi Sumiya , Masami Koike , Yoji Fujiura , Mihoko Nomoto
IPC分类号： C08F220/06 , C08F220/28 , C09K17/22 , C08F120/06 , C08F118/02 , C08F120/10
CPC分类号： C08F220/28 , C08F220/06 , C09K17/22
摘要： The present invention can provide a water-absorbent or water-retention material comprising water-absorbent resin derived from monomer unit components comprising 40 to 99 wt. % of hydroxyl alkyl (meth)acrylate, 1 to 60 wt. % of (meth)acrylic acid and/or alkali metal salt thereof and 0.00001 to 3 wt. % of crosslinking agent; and a water-absorbent or water-retention material comprising water-swellable polymer which is obtained by further thermally crosslinking a particles of partially alkaline neutralized product of a copolymer of 20 to 99 mol % of acrylamide and 1 to 80 mol % of acrylic acid. The water-absorbent or water-retention material of the present invention is not readily subject to an influence of salts, and the absorbency does not deteriorate with respect to an aqueous solution containing a great amount of metallic ion of salts.
摘要翻译：本发明可以提供一种吸水或保水材料，其包含衍生自单体单元组分的吸水性树脂，其包含40至99wt。％（甲基）丙烯酸羟基烷基酯，1〜60重量％％的（甲基）丙烯酸和/或其碱金属盐和0.00001〜3重量％％的交联剂; 以及包含水溶胀性聚合物的吸水剂或保水材料，其通过将20至99mol％的丙烯酰胺和1至80mol％的丙烯酸的共聚物的部分碱性中和产物的颗粒进一步热交联而获得。本发明的吸水剂或保水剂不容易受到盐的影响，相对于含有大量的金属离子盐的水溶液，吸水性不劣化。

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