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1. 发明授权

US3981930A Diacetylene diol derivatives and process for preparing the same 失效
标题翻译：二乙炔二醇衍生物及其制备方法
公开(公告)号：US3981930A
公开(公告)日：1976-09-21
申请号：US573569
申请日：1975-05-01
申请人： Takashi Nishida , Yoichi Ninagawa , Yoshiaki Omura , Fumio Mori , Yoshin Tamai , Takeo Hosogai , Yoshiji Fujita , Kazuo Itoi
发明人： Takashi Nishida , Yoichi Ninagawa , Yoshiaki Omura , Fumio Mori , Yoshin Tamai , Takeo Hosogai , Yoshiji Fujita , Kazuo Itoi
IPC分类号： C07C33/04
CPC分类号： C07C33/04 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/755 , C10M2203/02 , C10M2203/022 , C10M2203/024 , C10M2203/04
摘要： Novel 2,6,10,15,19,23-hexamethyltetracosa-11,13-diin-10,15-diol derivatives. Such derivatives are prepared by oxydative coupling of 3,7,11-trimethyldodeca-1-in-3-ol derivatives or by ethynylation of 6,10-dimethylundecan-2-on derivatives with diacetylene and used as starting materials for preparing squalane.
摘要翻译：新颖的2,6,10,15,19,23-六甲基四川-11,13-二 - 10,15-二醇衍生物。这样的衍生物通过3,7,11-三甲基十二碳-1-烯-3-醇衍生物的氧化偶联或通过6,10-二甲基十一烷-2-酮衍生物与二乙炔的乙炔化反应制备，并用作制备角鲨烷的起始原料。

2. 发明授权

US3984475A Process for the production of substituted ketones 失效
标题翻译：制备取代酮的方法
公开(公告)号：US3984475A
公开(公告)日：1976-10-05
申请号：US581854
申请日：1975-05-29
申请人： Yoshin Tamai , Takashi Nishida , Fumio Mori , Yoshiaki Omura , Masahisa Tanomura , Takeo Hosogai , Yoichi Ninagawa , Kazuo Itoi
发明人： Yoshin Tamai , Takashi Nishida , Fumio Mori , Yoshiaki Omura , Masahisa Tanomura , Takeo Hosogai , Yoichi Ninagawa , Kazuo Itoi
IPC分类号： C07C49/20 , C07C45/00
CPC分类号： C07C45/68
摘要： Process for producing substituted ketones from the reaction between organic halides and ketones having replaceable active hydrogen atoms on the carbon atom(s) alpha to the carbonyl group, in the presence of an alkali metal hydroxide unitilizing phosphonium salts as the catalyst, which salts have the following formula: ##EQU1## wherein said R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are the same or different and are branched or straight chain alkyl of 1-30 carbon atoms, cycloalkyl of 6-10 carbon atoms, aryl of 6-10 carbon atoms aralkyl or alkaryl wherein the aryl and alkyl are as above defined and X.sup.- is an inorganic or organic anion.
摘要翻译：在碱金属氢氧化物的存在下，在鏻盐作为催化剂的存在下，在有机卤化物和在羰基的α原子上具有可取代的活性氢原子的酮之间的反应生成取代的酮的方法，该盐具有其中所述R 1，R 2，R 3和R 4相同或不同，为具有1-30个碳原子的支链或直链烷基，其中R 1，R 2，R 3和R 4相同或不同， 6-10个碳原子，6-10个碳原子的芳基芳烷基或烷芳基，其中芳基和烷基如上定义，X - 是无机或有机阴离子。

3. 发明授权

US3983175A Process for the production of a substituted ketone 失效
标题翻译：制备取代酮的方法
公开(公告)号：US3983175A
公开(公告)日：1976-09-28
申请号：US581841
申请日：1975-05-29
申请人： Yoshin Tamai , Takashi Nishida , Fumio Mori , Yoshiaki Omura , Masahisa Tanomura , Takeo Hosogai , Yoichi Ninagawa , Kazuo Itoi
发明人： Yoshin Tamai , Takashi Nishida , Fumio Mori , Yoshiaki Omura , Masahisa Tanomura , Takeo Hosogai , Yoichi Ninagawa , Kazuo Itoi
IPC分类号： C07C45/68 , C07C49/20 , C07C45/00
CPC分类号： C07C45/68 , C07C49/20 , Y02P20/582
摘要： A process for producing substituted ketones is disclosed comprising reacting an organic halide with a ketone which has a replaceable hydrogen atom on the carbon atom in the .alpha.-position to the carbonyl group, in the presence of an aqueous alkali metal hydroxide and at least one basic nitrogen catalyst such as certain primary amines, secondary amines, tertiary amines, quaternary ammonium salts or betaine-type quaternary ammonium salts.
摘要翻译：公开了一种制备取代酮的方法，其包括在碱金属氢氧化物水溶液和至少一种碱性金属氢氧化物存在下使有机卤化物与在羰基的α-位上的碳原子上具有可置换氢原子的酮反应，氮气催化剂如某些伯胺，仲胺，叔胺，季铵盐或甜菜碱型季铵盐。

4. 发明授权

US4299839A Novel pesticides and pesticidal compositions cyclopropanecarboxylates and pesticidal method 失效
标题翻译：新型农药和杀虫剂组合物环丙烷羧酸酯和杀虫剂方法
公开(公告)号：US4299839A
公开(公告)日：1981-11-10
申请号：US79180
申请日：1979-09-26
申请人： Yoshiaki Omura , Fumio Mori , Yoshiji Fujita , Takashi Nishida , Takeo Hosogai , Sukeji Aihara , Yoshin Tamai , Fumio Wada , Kazuo Itoi
发明人： Yoshiaki Omura , Fumio Mori , Yoshiji Fujita , Takashi Nishida , Takeo Hosogai , Sukeji Aihara , Yoshin Tamai , Fumio Wada , Kazuo Itoi
IPC分类号： A01N53/00 , C07C153/057 , C07D307/52
CPC分类号： A01N53/00
摘要： Novel pesticidal compositions are comprised of a 2,2-dimethyl-3-(substituted ethyl)cyclopropanecarboxylic acid ester as the active ingredient, said cyclopropanecarboxylate having the structural formula: ##STR1## wherein X, Y and Z are the same or different and at least two of same are chlorine or bromine, with the remaining one being hyrogen, methyl, chlorine or bromine; R is an alcohol residue represented by one of the following structural formulae (II), (III), (IV) and (V): ##STR2## where A represents hydrogen, cyano, ethynyl or thiocarbamoyl; Q is hydrogen, chlorine, bromine, fluorine, methyl or trifluoromethyl; R.sup.1 is propargyl or benzyl; R.sup.2 represents 2-halogeno-3-phenyl-1-propen-1-yl, (dihalogenovinyloxy)phenyl, benzylphenyl, phthalimido, thiophthalimido, di- or tetrahydrophthalimido or dialkylmaleido; R.sup.3 represents allyl, 2,4-pentadienyl, propargyl or benzyl.
摘要翻译：新型杀虫剂组合物由2,2-二甲基-3-（取代的乙基）环丙烷甲酸酯作为活性成分组成，所述环丙烷羧酸酯具有以下结构式：其中X，Y和Z相同或不同，其中至少两个是氯或溴，剩下的一个是氢，甲基，氯或溴; R是由以下结构式（II），（III），（IV）和（V）之一表示的醇残基：其中A表示氢，氰基，乙炔基或硫代氨基甲酰基; Q是氢，氯，溴，氟，甲基或三氟甲基; R1是炔丙基或苄基; R 2表示2-卤代-3-苯基-1-丙烯-1-基，（二卤代乙烯基氧基）苯基，苄基苯基，邻苯二甲酰亚氨基，硫代邻苯二甲酰亚氨基，二或四氢邻苯二甲酰亚氨基或二烷基马来酰亚胺; R3表示烯丙基，2,4-戊二烯基，炔丙基或苄基。

5. 再颁专利

USRE31330E 1,1,1-Trihalogeno-4-methylpentenes, method of preparing the same and use of the same in the preparation of 1,1-dihalogeno-4-methyl-1,3-pentadienes 失效
标题翻译： 1,1,1-三卤代-4-甲基戊烯，其制备方法和用于制备1,1-二卤代-4-甲基-1,3-戊二烯的方法
公开(公告)号：USRE31330E
公开(公告)日：1983-08-02
申请号：US200087
申请日：1980-10-23
申请人： Yoshiji Fujita , Yoshiaki Omura , Fumio Mori , Kazuo Itoi , Takashi Nishida , Yoshin Tamai , Sukeji Aihara , Takeo Hosogai , Fumio Wada
发明人： Yoshiji Fujita , Yoshiaki Omura , Fumio Mori , Kazuo Itoi , Takashi Nishida , Yoshin Tamai , Sukeji Aihara , Takeo Hosogai , Fumio Wada
IPC分类号： C07C17/00 , C07C17/10 , C07C17/25 , C07C17/278 , C07C17/35 , C07C17/358 , C07C17/361 , C07C21/02 , C07C21/04 , C07C29/62 , C07C31/36 , C07C43/12 , C07C43/174
CPC分类号： C07C21/04 , C07C17/00 , C07C17/10 , C07C17/25 , C07C17/278 , C07C17/35 , C07C17/358 , C07C17/361 , C07C21/02 , C07C29/62 , C07C31/36 , C07C43/12 , C07C43/174
摘要： 1,1,1-Trihalogeno-4-methyl pentenes and 1,1-dihalogeno-4-methyl-1,3-pentadienes are produced. These compounds are of value as intermediates for the production of pyrethrin analogs which are of use as insecticides or agricultural chemicals.

6. 发明授权

US4315029A Racemic modification consisting of specific isomers of .alpha.-cyano-3-phenoxybenzyl cis- or trans-2,2-dimethyl-3-(2,2,2-trichloroethyl)cyclopropanecarboxylate, production thereof and pesticidal compositions containing the same 失效
标题翻译：外消旋改性由α-氰基-3-苯氧基苄基顺式或反式-2,2-二甲基-3-（2,2,2-三氯乙基）环丙烷羧酸酯的特殊异构体组成，其生产和含有它们的杀虫组合物
公开(公告)号：US4315029A
公开(公告)日：1982-02-09
申请号：US128717
申请日：1980-03-10
申请人： Fumio Mori , Yoshiaki Omura , Yoshiji Fujita , Takashi Nishida , Takeo Hosogai , Fumio Wada , Sukeji Aihara , Yoshin Tamai , Kazuo Itoi
发明人： Fumio Mori , Yoshiaki Omura , Yoshiji Fujita , Takashi Nishida , Takeo Hosogai , Fumio Wada , Sukeji Aihara , Yoshin Tamai , Kazuo Itoi
IPC分类号： A01N53/00 , A01N53/08 , C07C121/75
CPC分类号： A01N53/00
摘要： Racemic modifications each consisting of specific isomers of .alpha.-cyano-3-phenoxybenzyl cis- or trans-2,2-dimethyl-3-(2,2,2-trichloroethyl)cyclopropanecarboxylate with the absolute configurations [.alpha.S, 1R] an [.alpha.R, 1S] with respect to the asymmetric carbon atoms in the alcohol and acid moieties, a method of producing the same and pesticidal compositions containing the same as active ingredient are provided. .alpha.-Cyano-3-phenoxybenzyl cis- or trans-2,2-dimethyl-3-(2,2,2-trichloroethyl)cyclopropanecarboxylate has higher pesticidal activities than those pesticides that are in general use and consequently selective production of the above specific racemic modification as defined by the combinations of the absolute configuration with respect to the asymmetric carbon atom at the position in the alcohol moiety and the absolute configuration with respect to the asymmetric carbon atom in the acid moiety provides compounds having still higher pesticidal activities.
摘要翻译：由绝对构型[α，1R]代表的α-氰基-3-苯氧基苄基顺式或反式-2,2-二甲基-3-（2,2,2-三氯乙基）环丙烷羧酸酯的外消旋体改性， αR，1S]相对于醇和酸部分中的不对称碳原子，提供其制备方法和含有与活性成分相同的杀虫组合物。环烷基-3-苯氧基苄基顺式或反式-2,2-二甲基-3-（2,2,2-三氯乙基）环丙烷羧酸酯的杀虫活性高于一般使用的农药，因此选择性地生产上述具体的通过绝对构型相对于醇部分中位置上的不对称碳原子和相对于酸部分中的不对称碳原子的绝对构型的组合定义的外消旋改性提供具有更高杀虫活性的化合物。

7. 发明授权

US4053380A 1,1,1-Trihalogeno-4-methylpentenes, method of preparing the same and use of the same in the preparation of 1,1-dihalogeno-4-methyl-1,3-pentadienes 失效
标题翻译： 1,1,1-三甲基-4-甲基戊酸酯，其制备方法及其在制备1,1-二氢-4-甲基-1,3-苯二甲酸中的用途
公开(公告)号：US4053380A
公开(公告)日：1977-10-11
申请号：US676517
申请日：1976-04-13
申请人： Yoshiji Fujita , Yoshiaki Omura , Fumio Mori , Kazuo Itoi , Takashi Nishida , Yoshin Tamai , Sukeji Aihara , Takeo Hosogai , Fumio Wada
发明人： Yoshiji Fujita , Yoshiaki Omura , Fumio Mori , Kazuo Itoi , Takashi Nishida , Yoshin Tamai , Sukeji Aihara , Takeo Hosogai , Fumio Wada
IPC分类号： C07C17/00 , C07C17/10 , C07C17/25 , C07C17/278 , C07C17/35 , C07C17/358 , C07C17/361 , C07C21/02 , C07C21/04 , C07C29/62 , C07C31/36 , C07C43/12 , C07C43/174 , B01J1/10
CPC分类号： C07C17/25 , C07C17/00 , C07C17/10 , C07C17/278 , C07C17/35 , C07C17/358 , C07C17/361 , C07C17/363 , C07C21/02 , C07C21/04 , C07C29/62 , C07C31/36 , C07C43/12 , C07C43/174
摘要： 1,1,1-Trihalogeno-4-methyl pentenes and 1,1-dihalogeno-4-methyl-1,3-pentadienes are produced. These compounds are of value as intermediates for the production of pyrethrin analogs which are of use as insecticides or agricultural chemicals.

8. 发明授权

US4532258A Certain cyclopropane carboxylic acid esters and their pesticidal use 失效
标题翻译：某些环丙烷羧酸酯及其农药使用
公开(公告)号：US4532258A
公开(公告)日：1985-07-30
申请号：US79179
申请日：1979-09-26
申请人： Yoshiaki Omura , Fumio Mori , Yoshiji Fujita , Takashi Nishida , Takeo Hosogai , Sukeji Aihara , Yoshin Tamai , Fumio Wada , Kazuo Itoi
发明人： Yoshiaki Omura , Fumio Mori , Yoshiji Fujita , Takashi Nishida , Takeo Hosogai , Sukeji Aihara , Yoshin Tamai , Fumio Wada , Kazuo Itoi
IPC分类号： A01N53/00 , A01N53/02 , C07D307/45
CPC分类号： A01N53/00
摘要： Novel pesticidal compositions are comprised of a 2,2-dimethyl-3-(substituted ethyl)cyclopropanecarboxylic acid ester as the active ingredient, said cyclopropanecarboxylate having the structural formula: ##STR1## wherein X, Y and Z are the same or different and at least two of same are chlorine or bromine, with the remaining one being hydrogen, methyl, chlorine or bromine; R is an alcohol residue represented by one of the following structural formulae (II), (III), (IV) and (V): ##STR2## where A represents hydrogen, cyano, ethynyl or thiocarbamoyl; Q is hydrogen, chlorine, bromine, fluorine, methyl or trifluoromethyl; R.sup.1 is propargyl or benzyl; R.sup.2 represents 2-halogeno-3-phenyl-1-propen-1-yl, (dihalogenovinyloxy)phenyl, benzylphenyl, phthalimido, thiophthalimido, di- or tetrahydrophthalimido or dialkylmaleimido; R.sup.3 represents allyl, 2,4-pentadienyl, propargyl or benzyl.
摘要翻译：新型杀虫剂组合物由2,2-二甲基-3-（取代的乙基）环丙烷甲酸酯作为活性成分组成，所述环丙烷羧酸酯具有以下结构式：其中X，Y和Z相同或不同，其中至少两个是氯或溴，剩下的一个是氢，甲基，氯或溴; R是由以下结构式（II），（III），（IV）和（V）之一表示的醇残基：其中A表示氢，氰基，乙炔基或硫代氨基甲酰基; Q是氢，氯，溴，氟，甲基或三氟甲基; R1是炔丙基或苄基; R 2表示2-卤代-3-苯基-1-丙烯-1-基，（二卤代乙烯基氧基）苯基，苄基苯基，苯二甲酰亚氨基，硫代邻苯二甲酰亚氨基，二或四氢邻苯二甲酰亚氨基或二烷基马来酰亚胺; R3表示烯丙基，2,4-戊二烯基，炔丙基或苄基。

9. 发明授权

US4390547A 2,2-Dimethyl-3-(substituted ethyl)cyclopropane carboxylate pesticidal compositions and methods 失效
标题翻译： 2,2-二甲基-3-（取代乙基）环丙烷羧酸酯农药组合物和方法
公开(公告)号：US4390547A
公开(公告)日：1983-06-28
申请号：US259507
申请日：1981-05-01
申请人： Yoshiaki Omura , Fumio Mori , Yoshiji Fujita , Takashi Nishida , Yoshin Tamai , Fumio Wada , Kazuo Itoi
发明人： Yoshiaki Omura , Fumio Mori , Yoshiji Fujita , Takashi Nishida , Yoshin Tamai , Fumio Wada , Kazuo Itoi
IPC分类号： A01N53/00 , A01N53/02
CPC分类号： A01N53/00
摘要： Novel pesticidal compositions are comprised of a 2,2-dimethyl-3-(substituted ethyl)cyclopropanecarboxylic acid ester as the active ingredient, said cyclopropanecarboxylate having the structural formula: ##STR1## wherein X, Y and Z are the same or different and at least two of same are chlorine or bromine, with the remaining one being hydrogen, methyl, chlorine or bromine; R is an alcohol residue represented by one of the following structural formulae (II), (III), (IV) and (V): ##STR2## where A represents hydrogen, cyano, ethynyl or thiocarbamoyl; Q is hydrogen, chlorine, bromine, fluorine, methyl or trifluoromethyl; R.sup.1 is propargyl or benzyl; R.sup.2 represents 2-halogeno-3-phenyl-1-propen-1-yl, (dihalogenovinyloxy)phenyl, benzylphenyl, phthalimido, thiophthalimido, di- or tetrahydrophthalimido or dialkylmaleimido; R.sup.3 represents allyl, 2,4-pentadienyl, propargyl or benzyl.
摘要翻译：新型杀虫剂组合物由2,2-二甲基-3-（取代的乙基）环丙烷甲酸酯作为活性成分组成，所述环丙烷羧酸酯具有以下结构式：其中X，Y和Z相同或不同，其中至少两个是氯或溴，剩下的一个是氢，甲基，氯或溴; （II），（IV）和（V）表示的醇残基：R是由下列结构式（II），（III），（IV）和（V）之一表示的醇残基：（Ⅴ）其中A代表氢，氰基，乙炔基或硫代氨基甲酰基; Q是氢，氯，溴，氟，甲基或三氟甲基; R1是炔丙基或苄基; R 2表示2-卤代-3-苯基-1-丙烯-1-基，（二卤代乙烯基氧基）苯基，苄基苯基，苯二甲酰亚氨基，硫代邻苯二甲酰亚氨基，二或四氢邻苯二甲酰亚氨基或二烷基马来酰亚胺; R3表示烯丙基，2,4-戊二烯基，炔丙基或苄基。

10. 发明授权

US4222963A Substituted propargyl alcohols, allylic alcohols and unsaturated ketones, and methods for the production thereof 失效
标题翻译：取代的炔丙醇，烯丙醇和不饱和酮，及其制备方法
公开(公告)号：US4222963A
公开(公告)日：1980-09-16
申请号：US16195
申请日：1979-02-28
申请人： Yoshiji Fujita , Fumio Wada , Takashi Ohnishi , Takashi Nishida , Yoshiaki Omura , Fumio Mori , Takeo Hosogai , Sukeji Aihara
发明人： Yoshiji Fujita , Fumio Wada , Takashi Ohnishi , Takashi Nishida , Yoshiaki Omura , Fumio Mori , Takeo Hosogai , Sukeji Aihara
IPC分类号： C07C1/22 , C07C29/42 , C07C33/02 , C07C33/048 , C07C45/51 , C07C45/67 , C07C45/68 , C07C45/82 , C07C49/203 , C07C49/24
CPC分类号： C07C49/203 , C07C1/22 , C07C29/42 , C07C33/02 , C07C33/048 , C07C45/51 , C07C45/512 , C07C45/67 , C07C45/68 , C07C45/82 , C07C2521/18 , C07C2523/44
摘要： Novel substituted propargyl alcohols of the formula: ##STR1## novel allylic alcohols of the formula: ##STR2## and; .delta.,.epsilon.-unsaturated ketones of the formula: ##STR3## are provided. In the above formulas, R represents a group of the formula: ##STR4## wherein X.sub.1 and X.sub.2 are both hydrogen atoms or wherein one of X.sub.1 and X.sub.2 is a hydrogen atom, the other jointly with Z represents a bond; Z jointly with X.sub.1 or X.sub.2 represents a bond or separately represent a hydrogen atom, a hydroxyl group or a lower alkoxy group; R.sub.1 and R.sub.2 are the same or different and represents hydrogen atoms or lower alkyl groups; n is 1 or 2; and when n is 2, X.sub.1, X.sub.2, X, R.sub.1 and R.sub.2 may be the same or different. These novel compounds are easily produced and are useful as perfumes and as interrelated intermediates for the production of terpenoid compounds.
摘要翻译：新型的下式的炔丙醇：下式的新型烯丙醇：＆lt; IMAGE＆gt;和; δ，ε-不饱和酮，具有下式：。在上式中，R表示下式的基团：其中X1和X2都是氢原子，或其中X1和X2之一是氢原子，另一个与Z代表键; Z与X 1或X 2一起表示键或分别表示氢原子，羟基或低级烷氧基; R1和R2相同或不同，表示氢原子或低级烷基; n为1或2; 当n为2时，X 1，X 2，X，R 1和R 2可以相同或不同。这些新型化合物容易生产，并且可用作香料和用作生产萜类化合物的相互关联的中间体。

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