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1. 发明申请

US20050077498A1 Polymerizable ion-conductive liquid-crystalline composite, anisotropically ion-conductive polymeric liquid-crystal composite, and process for producing the same 审中-公开
标题翻译：可聚合离子导电液晶复合材料，各向异性离子导电聚合液晶复合材料及其制造方法
公开(公告)号：US20050077498A1
公开(公告)日：2005-04-14
申请号：US10501761
申请日：2003-01-22
申请人： Takashi Kato , Kenji Kishimoto , Hiroyuki Ohno
发明人： Takashi Kato , Kenji Kishimoto , Hiroyuki Ohno
IPC分类号： C08F2/44 , C08F2/46 , C09K19/00 , C09K19/12 , C09K19/38 , C09K19/52 , C09K19/58
CPC分类号： C09K19/38 , C09K19/00 , C09K19/12 , C09K19/3852 , C09K19/52 , C09K19/582 , C09K2019/123
摘要： A composite of an organic monomer compound and an organic or inorganic salt, wherein the organic monomer compound comprises an ion-complexing moiety, a mesogen moiety that expresses a liquid crystalline phase and a polymerizable moiety in its molecular structure, is polymerized at the polymerizable moiety of the organic monomer compound, thereby forming an anisotropic ion-conductive polymeric liquid crystalline composite as a novel material having high ion conductivity characteristic of polymeric electrolytes, anisotropy due to orientation of a liquid crystal, and self-supporting properties characteristic of polymeric compounds.
摘要翻译：有机单体化合物和有机或无机盐的复合物，其中有机单体化合物包含离子络合部分，表达液晶相的介晶部分和分子结构中的可聚合部分在可聚合部分聚合的有机单体化合物，从而形成各向异性离子导电聚合物液晶复合材料作为具有高聚合电解质的高离子电导率特性的新型材料，由于液晶取向引起的各向异性以及聚合物的自支撑特性。

2. 发明授权

US5641123A Expandable nozzle mechanism for a rocket engine 失效
标题翻译：用于火箭发动机的可扩展喷嘴机构
公开(公告)号：US5641123A
公开(公告)日：1997-06-24
申请号：US360421
申请日：1994-12-21
申请人： Kenji Kishimoto , Yojiro Kakuma , Masaaki Yasui
发明人： Kenji Kishimoto , Yojiro Kakuma , Masaaki Yasui
IPC分类号： F02K9/97 , B64D33/04
CPC分类号： F02K9/976
摘要： A nozzle extension mechanism for a rocket engine is applied to an engine in an upper stage rocket in a multi-stage rocket. Since a high expansion nozzle to be used in the upper stage rocket engine is long, the rocket is divided at a nozzle portion in view of volume efficiency. The nozzle portion is retracted and received around the upper stage rocket engine and is shifted to a high altitude space. The nozzle portion is assembled for use prior to operation. For this reason, in order to bring the nozzle portion from the retracted condition to the operative condition, it has been necessary to use a drive source, a power device or a shifting device for shifting the nozzle portion. This leads to a weight problem. The devices left in the upper rocket adversely affect the payload. This is resolved by using a fastening portion provided at a rear end of the high expansion nozzle that is received by and then separated from a coupling mechanism provided at a front end portion of the lower stage rocket. Both components are shifted to a high altitude space. The high expansion nozzle is retracted to a rocket engine joint portion following rearward movement of the lower stage rocket upon separation of the lower stage rocket.
摘要翻译：用于火箭发动机的喷嘴延伸机构被施加到多级火箭中的上级火箭中的发动机。由于在上级火箭发动机中使用的高膨胀喷嘴长，因此考虑到体积效率，火箭在喷嘴部分被分割。喷嘴部分被收回并被接收在上级火箭发动机周围并被转移到高空间。在操作之前组装喷嘴部分使用。为此，为了将喷嘴部从缩回状态转移到工作状态，必须使用用于使喷嘴部移动的驱动源，动力装置或换档装置。这导致重量问题。留在上层火箭中的装置对有效载荷产生不利影响。这通过使用设置在高膨胀喷嘴的后端处的紧固部分来解决，该紧固部分由设置在下级火箭的前端部分处的联接机构接收并且随后与其分离。两个组件都转移到高空间。随着下级火箭分离，后级火箭向后移动后，高膨胀喷嘴缩回到火箭发动机接头部分。

3. 发明申请

US20120129077A1 ION-CONDUCTING COMPOSITE ELECTROLYTE MEMBRANE AND FUEL CELL USING THE SAME 有权
标题翻译：导电复合电解质膜和使用它的燃料电池
公开(公告)号：US20120129077A1
公开(公告)日：2012-05-24
申请号：US13387320
申请日：2010-07-21
申请人： Takuro Hirakimoto , Kazuaki Fukushima , Kenji Kishimoto
发明人： Takuro Hirakimoto , Kazuaki Fukushima , Kenji Kishimoto
IPC分类号： H01M8/10 , B82Y99/00
CPC分类号： H01M8/1041 , H01B1/122 , H01M8/1011 , H01M8/1023 , H01M8/1032 , H01M8/1081 , H01M2300/0088 , Y02E60/523 , Y02P70/56
摘要： An ion-conducting composite electrolyte membrane with strength improved without impairing ionic conductivity, and a fuel cell using the same are provided. The proton conductive composite electrolyte membrane includes an electrolyte which includes an ion-dissociating functional group and is made of a fullerene derivative or sulfonated pitch within a range of 5 wt % to 85 wt % both inclusive, and a binder which has a weight-average molecular weight of 550000 or over and a logarithmic viscosity of 2 dL/g or over, and is made of a fluorine-based polymer such as polyvinylidene fluoride and a copolymer of polyvinylidene fluoride and hexafluoropropylene within a range of 15 wt % to 95 wt % both inclusive.
摘要翻译：提供了强度提高而不损害离子导电性的离子导电复合电解质膜和使用其的燃料电池。质子传导复合电解质膜包括电解质，其包含离子解离官能团，并且由富勒烯衍生物或磺化沥青构成，其含量在5重量％至85重量％的范围内，并且具有重均分子量分子量为550000以上，对数粘度为2dL / g以上，由聚偏氟乙烯等氟系聚合物和聚偏二氟乙烯与六氟丙烯的共聚物构成，为15重量％〜95重量％包括在内

4. 发明申请

US20120115065A1 ION-CONDUCTIVE COMPOSITE ELECTROLYTE, MEMBRANE-ELECTRODE ASSEMBLY USING THE SAME, ELECTROCHEMICAL DEVICE USING MEMBRANE-ELECTRODE ASSEMBLY, AND METHOD FOR PRODUCING ION-CONDUCTIVE COMPOSITE ELECTROLYTE MEMBRANE 审中-公开
标题翻译：导电复合电解质，使用其的膜电极组件，使用膜电极组件的电化学装置以及用于生产导电复合电解质膜的方法
公开(公告)号：US20120115065A1
公开(公告)日：2012-05-10
申请号：US13384146
申请日：2010-07-16
申请人： Takuro Hirakimoto , Kazuaki Fukushima , Kenji Kishimoto
发明人： Takuro Hirakimoto , Kazuaki Fukushima , Kenji Kishimoto
IPC分类号： H01M8/10 , B05D5/12 , B82Y99/00
CPC分类号： H01M8/1018 , H01B1/122
摘要： Provided are an ion-conductive composite electrolyte that improves ionic conductivity, a membrane-electrode assembly and an electrochemical device using the same, and a method for producing an ion-conductive composite electrolyte membrane.A proton-conductive composite electrolyte contains an electrolyte having a proton-dissociative group (—SO3H) and a compound having a Lewis acid group MXn-1, wherein the Lewis acid group and the proton-dissociative group interact with each other. The compound having the Lewis acid group is a Lewis acid compound MXn or a polymer having a Lewis acid group MXn-1. The electrolyte having a proton-dissociative group is, for example, a fullerene derivative. A proton-conductive composite electrolyte membrane is formed using a solvent having a donor number of 25 or less, and a membrane-electrode assembly using the same is suitable for use in a fuel cell.
摘要翻译：提供了提高离子导电性的离子传导复合电解质，膜电极组件和使用其的电化学装置，以及用于制造离子导电复合电解质膜的方法。质子传导性复合电解质含有具有质子解离基团（-SO 3 H）的电解质和具有路易斯酸基团MXn-1的化合物，其中路易斯酸基团和质子解离基团相互作用。具有路易斯酸基团的化合物是路易斯酸化合物MXn或具有路易斯酸基团MXn-1的聚合物。具有质子解离基团的电解质是例如富勒烯衍生物。使用供体数为25以下的溶剂形成质子传导复合电解质膜，使用该质子传导复合电解质膜的膜 - 电极组合体适用于燃料电池。

5. 发明授权

US08962216B2 Ion-conducting composite electrolyte membrane and fuel cell using the same 有权
标题翻译：离子导电复合电解质膜和使用其的燃料电池
公开(公告)号：US08962216B2
公开(公告)日：2015-02-24
申请号：US13387320
申请日：2010-07-21
申请人： Takuro Hirakimoto , Kazuaki Fukushima , Kenji Kishimoto
发明人： Takuro Hirakimoto , Kazuaki Fukushima , Kenji Kishimoto
IPC分类号： H01M8/10 , H01B1/12
CPC分类号： H01M8/1041 , H01B1/122 , H01M8/1011 , H01M8/1023 , H01M8/1032 , H01M8/1081 , H01M2300/0088 , Y02E60/523 , Y02P70/56
摘要： An ion-conducting composite electrolyte membrane with strength improved without impairing ionic conductivity, and a fuel cell using the same are provided. The proton conductive composite electrolyte membrane includes an electrolyte which includes an ion-dissociating functional group and is made of a fullerene derivative or sulfonated pitch within a range of 5 wt % to 85 wt % both inclusive, and a binder which has a weight-average molecular weight of 550000 or over and a logarithmic viscosity of 2 dL/g or over, and is made of a fluorine-based polymer such as polyvinylidene fluoride and a copolymer of polyvinylidene fluoride and hexafluoropropylene within a range of 15 wt % to 95 wt % both inclusive.
摘要翻译：提供了强度提高而不损害离子导电性的离子导电复合电解质膜，以及使用其的燃料电池。质子传导复合电解质膜包括电解质，其包含离子解离官能团，并且由富勒烯衍生物或磺化沥青构成，其含量在5重量％至85重量％的范围内，并且具有重均分子量分子量为550000以上，对数粘度为2dL / g以上，由聚偏氟乙烯等氟系聚合物和聚偏二氟乙烯与六氟丙烯的共聚物构成，为15重量％〜95重量％包括在内

6. 发明申请

US20120100458A1 ION-CONDUCTING MICROPARTICLE AND METHOD OF MANUFACTURING THE SAME, ION-CONDUCTING COMPOSITE, MEMBRANE ELECTRODE ASSEMBLY (MEA), AND ELECTROCHEMICAL DEVICE 审中-公开
标题翻译：离子导电微粒及其制造方法，导电复合材料，膜电极组件（MEA）和电化学装置
公开(公告)号：US20120100458A1
公开(公告)日：2012-04-26
申请号：US13382261
申请日：2010-07-07
申请人： Kenji Kishimoto , Kazuaki Fukushima , Takuro Hirakimoto
发明人： Kenji Kishimoto , Kazuaki Fukushima , Takuro Hirakimoto
IPC分类号： H01M8/10 , C07F9/30 , C07F7/18 , C07F9/48 , B82Y99/00
CPC分类号： H01B1/06 , H01B1/122 , H01M8/1011 , H01M8/1016 , H01M8/1048 , H01M8/1081 , Y02E60/523 , Y02P70/56
摘要： There are provided an ion-conducting microparticle including an ion-dissociative group and exhibiting an affinity for a fluorine-containing resin, and a method of manufacturing the same, an ion-conducting composite including the ion-conducting microparticle, a membrane electrode assembly (MEA) including the ion-conducting composite as an electrolyte, and an electrochemical device such as a fuel cell. A reacting molecule 13, which includes, in only one end, a second reacting group 14 capable of being bonded to a first reacting group 12, and includes, in a main part and/or the other end, an atom group 5 having an affinity for a fluorine-containing resin, acts on a material microparticle 11 including an ion-dissociative group 3 and the first reacting group 12 on a surface of a base-material microparticle 2, and a reformed group 4, which is bonded at only one end to the surface of the base-material microparticle 2, and includes, in a main part and/or the other end, the atom group 5 having an affinity for a fluorine-containing resin, is introduced into the surface of the base-material microparticle 2 by a reaction between the first reacting group 12 and the second reacting group 14 to form an ion-conducting microparticle 1.
摘要翻译：提供了包含离子解离基团并对含氟树脂具有亲和性的离子传导性微粒及其制造方法，包括离子传导性微粒的离子传导性复合体，膜电极接合体 MEA），以及诸如燃料电池的电化学装置。反应分子13，其仅在一端包含能够与第一反应基团12键合的第二反应基团14，并且在主要部分和/或另一端包括具有亲和力的原子团5 对于含氟树脂，在基材微粒2的表面上作用于包含离子解离基团3和第一反应基团12的材料微粒11和仅在一端结合的重整基团4 在基材微粒2的表面，并且在主体部分和/或另一端包含对含氟树脂具有亲和性的原子团5引入基材微粒的表面 2通过第一反应基团12和第二反应基团14之间的反应形成离子传导微粒子1。

7. 发明申请

US20120094209A1 ION-CONDUCTIVE COMPOSITE, MEMBRANE ELECTRODE ASSEMBLY (MEA), AND ELECTROCHEMICAL DEVICE 审中-公开
标题翻译：离子导电复合材料，膜电极组件（MEA）和电化学装置
公开(公告)号：US20120094209A1
公开(公告)日：2012-04-19
申请号：US13380713
申请日：2010-06-24
申请人： Kenji Kishimoto , Kazuaki Fukushima , Takuro Hirakimoto
发明人： Kenji Kishimoto , Kazuaki Fukushima , Takuro Hirakimoto
IPC分类号： H01M8/10 , B82Y30/00
CPC分类号： H01B1/122 , H01M8/102 , H01M8/1039
摘要： Provided are an ion-conductive composite containing ion-conductive fine particles and a vinylidene fluoride homopolymer or copolymer and having excellent ion conductivity, a membrane electrode assembly (MEA) including the ion-conductive composite as an electrolyte, and an electrochemical device, such as a fuel cell.An ion-conductive composite is formed of ion-conductive fine particles having an ion-dissociative group and a vinylidene fluoride homopolymer or copolymer. Here, a vinylidene fluoride homopolymer or copolymer having a β-type crystal structure is used. Since polyvinylidene fluoride having the β-type crystal structure has a large dipole moment in a direction that is orthogonal to the direction of the molecular chain, permittivity in the vicinity of ion-conductive fine particles can be kept high, thus facilitating ionic conduction. As a result, the decrease in ion conductivity can be minimized when the composite is formed.
摘要翻译：提供了含有离子导电性微粒和偏二氟乙烯均聚物或共聚物并且离子传导性优异的离子传导性复合体，包含作为电解质的离子传导性复合物的膜电极接合体（MEA），以及电化学装置燃料电池离子导电性复合体由具有离子解离基团和偏二氟乙烯均聚物或共聚物的离子导电性微粒形成。这里，使用具有“b”型晶体结构的偏二氟乙烯均聚物或共聚物。由于具有“b”型晶体结构的聚偏二氟乙烯在与分子链方向正交的方向上具有大的偶极矩，所以可以将离子导电性微粒附近的介电常数保持为高，从而促进离子传导。结果，当形成复合物时，离子电导率的降低可以最小化。

8. 发明申请

US20120064431A1 POLYMER ELECTROLYTE-CATALYST COMPOSITE STRUCTURE PARTICLE AND MANUFACTURING METHOD THEREOF, ELECTRODE, MEMBRANE ELECTRODE ASSEMBLY (MEA), AND ELECTROCHEMICAL DEVICE 审中-公开
标题翻译：聚合物电解质催化剂复合结构颗粒及其制备方法，电极，膜电极组件（MEA）和电化学装置
公开(公告)号：US20120064431A1
公开(公告)日：2012-03-15
申请号：US13321955
申请日：2010-06-04
申请人： Atsushi Sato , Kenji Kishimoto , Azumi Nakamura
发明人： Atsushi Sato , Kenji Kishimoto , Azumi Nakamura
IPC分类号： H01M8/10 , B05D3/00 , B05D5/12
CPC分类号： H01M4/925 , H01M4/8605 , H01M4/926 , H01M8/1004 , Y02P70/56
摘要： Polymer electrolyte-catalyst particles that are effective in preventing agglomeration of catalyst particles and polymer electrolyte particles, effective in the formation of ion pathways by polymer electrolyte particles and electron pathways by catalyst particles, and that are able to realize strong catalytic performance by improving the use efficiency of the catalyst particles and a manufacturing method thereof, electrodes formed using such composite structure particles, a membrane electrode assembly (MEA), and an electrochemical device are provided.First, the dispersion liquid in which an ion conducting polymer electrolyte material is dispersed and microparticles 1 are mixed, and the surfaces of the microparticles 1 are coated by an ion conducting polymer electrolyte layer 2 that does not contain a catalyst material. Next, catalyst particles 3 with electron conductivity are added and mixed into the dispersion liquid of after the above step, the catalyst particles 3 are arranged in contact with the polymer electrolyte layer 2, and polymer electrolyte-catalyst composite structure particles 4 are produced. A porous layer that contains the polymer electrolyte-catalyst composite structure particles 4 formed in contact with a power collector becomes an electrode with ion conductivity.
摘要翻译：能有效防止催化剂颗粒和聚合物电解质颗粒附聚的聚合物电解质 - 催化剂颗粒，有效地通过聚合物电解质颗粒形成离子通道和催化剂颗粒的电子通路，并且能够通过改进使用来实现强催化性能提供催化剂颗粒的效率及其制造方法，使用这种复合结构颗粒形成的电极，膜电极组件（MEA）和电化学装置。首先，将分散有离子导电性聚合物电解质材料的分散液和微粒1混合，将微粒1的表面用不含催化剂材料的离子导电性聚合物电解质层2涂布。接着，将上述工序后的分散液中加入具有电子传导性的催化剂粒子3，使催化剂粒子3与高分子电解质层2接触，制作高分子电解质 - 催化剂复合结构体4。含有与集电体接触形成的高分子电解质 - 催化剂复合结构体4的多孔层成为具有离子传导性的电极。

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