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    • 1. 发明授权
    • Masterbatch method for processing polyester resin and articles thereof
    • 用于加工聚酯树脂的母粒方法及其制品
    • US06803442B2
    • 2004-10-12
    • US10297177
    • 2002-12-03
    • Takashi FujimakiYukio KobayashiYoshitomo UrataToshio Tanaka
    • Takashi FujimakiYukio KobayashiYoshitomo UrataToshio Tanaka
    • C08G6302
    • C08J3/226C08J11/04C08J2367/00C08J2367/02C08J2463/00Y02P20/143Y02W30/70
    • The present invention provides a masterbatch method for producing a polyester resin and articles thereof; comprising reacting following materials uniformly at a temperature equal to or greater than the melting point of a polyester, the materials comprising: (1) 100 parts by weight of saturated straight-chain polyester A; (2) 1 to 10 parts by weight of binder masterbatch D comprising: a mixture containing a compound having two epoxy groups and a compound having an average number of epoxy groups of 2.1 or more; (3) 0.25 to 10 parts by weight of catalyst masterbatch G comprising: a metal carboxylate, whereby the melt viscosity of the polyester increases so that the melt flow rate (MFR) becomes 50 g/10 min or less, and the degree of swelling of the polyester increases to between 5% and 200%, thus resulting in a high-quality resin having excellent mechanical properties. The resin can be advantageously used for films, sheets, foamed materials, pipes, cushioning, heat insulators, packing materials, and so forth.
    • 本发明提供一种生产聚酯树脂的母料及其制品; 包括在等于或大于聚酯熔点的温度下均匀地使下列材料反应,所述材料包括:(1)100重量份的饱和直链聚酯A; (2)1〜10重量份粘合剂母料D,其包含:含有具有两个环氧基的化合物和平均环氧基数为2.1以上的化合物的混合物; (3)0.25至10重量份的催化剂母料G,其包含:金属羧酸盐,由此聚酯的熔体粘度增加,使得熔体流动速率(MFR)变为50g / 10min或更小,并且溶胀度 的聚酯增加到5%至200%之间,从而得到具有优异机械性能的高品质树脂。 树脂可以有利地用于薄膜,片材,发泡材料,管材,缓冲,绝热体,包装材料等。
    • 3. 发明授权
    • Production method of polyethylene terephthalate graft copolymerized resin and molded product thereof
    • 聚对苯二甲酸乙二醇酯接枝共聚树脂的制造方法及其成型体
    • US08258239B2
    • 2012-09-04
    • US12667312
    • 2007-12-28
    • Takashi FujimakiYoshitomo UrataHiroshi Shibano
    • Takashi FujimakiYoshitomo UrataHiroshi Shibano
    • C08L67/03
    • C08G63/916C08J9/04C08J2367/02C08L63/00
    • The present invention provides a method of producing a polyethylene terephthalate graft copolymerized resin, comprising subjecting the following mixture to a homogeneous reaction at a temperature of 250° C. or higher to impart a high melt viscosity to the mixture, the mixture containing (A) 100 parts by weight of a polyethylene terephthalate polyester as a main material, (B) 0.01 to 2 parts by weight of a polymeric polyfunctional epoxy compound containing 7 to 100 epoxy groups in a molecule and having a molecular weight of 1,000 to 300,000 as a coupling agent, (C) 0.01 to 1 part by weight of a metal salt of an organic acid as a coupling reaction catalyst, and (D) 0 to 100 parts by weight of an aromatic alicyclic polyester and/or an aromatic aliphatic polyester each having a carboxyl group in an aromatic nucleus as an auxiliary material.
    • 本发明提供了一种聚对苯二甲酸乙二醇酯接枝共聚树脂的制造方法,其特征在于,在250℃以上的温度下对下述混合物进行均相反应,赋予混合物高熔融粘度,含有(A) 100重量份的聚对苯二甲酸乙二醇酯聚酯作为主要材料,(B)0.01至2重量份的分子中含有7至100个环氧基并且分子量为1,000至300,000的环氧基的聚合多官能环氧化合物作为偶联剂 (C)0.01〜1重量份的作为偶联反应催化剂的有机酸的金属盐,和(D)0〜100重量份的芳族脂环族聚酯和/或芳香族脂肪族聚酯, 芳族核中的羧基作为辅助材料。
    • 4. 发明授权
    • Foamed polyester resin molding and process for producing the same
    • 发泡聚酯树脂成型及其制造方法
    • US06841106B1
    • 2005-01-11
    • US09787627
    • 1999-10-01
    • Takashi FujimakiYoshitomo Urata
    • Takashi FujimakiYoshitomo Urata
    • C08J9/04C08G63/91C08K5/098C08K5/15C08K5/1515C08L67/02B29C44/02B29C44/20C08J9/16
    • C08J9/16C08G63/916C08J9/0023C08J9/04C08J9/22C08J2201/03C08J2367/02Y10S264/911
    • The invention provides a method for producing a foamed article comprising the steps of: heating a mixture comprising (a) 100 parts by weight of linear saturated polyester, (b) 0.1 to 10 parts by weight of a mixture as a coupling agent of 0 to 100% by weight of a compound having two epoxy groups in the molecule, and 100 to 0% by weight of a compound having two or more epoxy groups, and (c) 0.01 to 5 parts by weight of a metal salt of a carboxylic acid as a coupling reaction catalyst, at a temperature of a melting point of the polyester or more to provide a melt flow rate of 50 g/10 minutes or less and swell of 10 to 200%, whereby a polyester resin is formed; and heating and foaming the polyester resin using a foaming agent . A foamed article useful as cushioning material, heat insulating material, packaging material, food container, and dividers can be produced by increasing the molecular weight, melt viscosity, and swell (degree of swelling) of PET-based polyesters that have relatively low molecular weight and are brittle, especially recovered polyester, that is used as a prepolymer.
    • 本发明提供一种生产发泡制品的方法,包括以下步骤:加热混合物,该混合物包含(a)100重量份的直链饱和聚酯,(b)0.1至10重量份作为偶联剂的混合物0至 100重量%的分子中具有两个环氧基的化合物和100〜0重量%的具有两个以上环氧基的化合物,和(c)0.01〜5重量份的羧酸金属盐 作为偶联反应催化剂,在聚酯的熔点以上的温度下,提供50g / 10分钟以下的熔体流动速率和10〜200%的溶胀,由此形成聚酯树脂; 并使用发泡剂加热和发泡聚酯树脂。 可以通过增加分子量比较低的PET类聚酯的分子量,熔融粘度和膨胀(膨胀度)来制造用作缓冲材料,隔热材料,包装材料,食品容器和分隔件的发泡制品。 并且是脆性的,特别是回收的聚酯,用作预聚物。