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1. 发明授权

US06939580B2 Water- and oil-repellent treatment of textile 有权
标题翻译：防水和拒油处理纺织品
公开(公告)号：US06939580B2
公开(公告)日：2005-09-06
申请号：US10239994
申请日：2001-03-29
申请人： Takashi Enomoto , Ikuo Yamamoto , Norihito Otsuki , Teruyuki Fukuda
发明人： Takashi Enomoto , Ikuo Yamamoto , Norihito Otsuki , Teruyuki Fukuda
IPC分类号： A47G27/02 , C03C25/26 , C09K3/18 , D06M13/236 , D06M13/428 , D06M15/277 , D06M15/576 , B05D3/02 , B05D3/04 , B05D3/10
CPC分类号： C03C25/26 , D06M13/236 , D06M13/428 , D06M15/277 , D06M15/576 , D06M2200/11 , D06M2200/12
摘要： A textile having durability of maintaining water- and sufficient oil-repellency and soil releasability before and after cleaning can be obtained by a method of preparing a treated textile, having steps of: (1) preparing a treatment liquid containing a water- and oil-repellent agent, (2) adjusting pH of the treatment liquid to at most 7, preferably at most 3, (3) applying the treatment liquid to a textile, (4) treating the textile with steam, and (5) washing the textile with water and dehydrating the textile, wherein the water- and oil-repellent agent is an emulsion containing a fluorine-containing compound and an emulsifier, the fluorine-containing compound is a fluorine-containing polymer and/or a fluorine-containing low molecular weight compound, and the emulsifier contains an anionic surface active agent having pKa of at least 2.
摘要翻译：可以通过制备经处理的织物的方法获得在清洁之前和之后保持水和足够的防油性和污垢释放性的耐久性的织物，其具有以下步骤：（1）制备含有水和油 - （2）将处理液的pH调节至7以下，优选为3以下，（3）将处理液施加到织物上，（4）用蒸汽处理织物，（5）用纺织品洗涤水和脱水剂，其中拒水拒油剂是含有含氟化合物和乳化剂的乳液，含氟化合物是含氟聚合物和/或含氟低分子化合物，乳化剂含有pKa为2以上的阴离子表面活性剂。

2. 发明授权

US07758656B2 Water-and-oil repellent treatment of textile 有权
标题翻译：防水和拒油处理纺织品
公开(公告)号：US07758656B2
公开(公告)日：2010-07-20
申请号：US10258067
申请日：2001-04-16
申请人： Takashi Enomoto , Ikuo Yamamoto , Norihito Otsuki , Teruyuki Fukuda , Kayo Kusumi
发明人： Takashi Enomoto , Ikuo Yamamoto , Norihito Otsuki , Teruyuki Fukuda , Kayo Kusumi
IPC分类号： D06M15/00 , B05D7/00
CPC分类号： D06M13/184 , D06M15/277 , D06M2200/11 , D06M2200/12 , Y10T442/2164 , Y10T442/2189 , Y10T442/2197
摘要： A textile having excellent water- and oil-repellency can be obtained by a method of preparing a treated textile, having steps of: (1) preparing a treatment liquid comprising a water- and oil-repellent agent, (2) adjusting pH of the treatment liquid to at most 7, preferably at most 3, (3) applying the treatment liquid to a textile, (4) treating the textile with steam, and (5) washing the textile with water and dehydrating the textile, wherein the water- and oil-repellent agent is at least one fluorine-containing compound selected from the group consisting of a fluorine-containing polymer and a fluorine-containing low molecular weight compound, and the water- and oil-repellent agent or the treatment liquid contains an organic salt.
摘要翻译：通过制备处理过的纺织品的方法可以获得具有优异的拒水拒油性的织物，其具有以下步骤：（1）制备包含拒水拒油剂的处理液，（2）调节（3）将处理液施加到纺织品上，（4）用蒸汽处理织物，和（5）用水洗涤织物并使织物脱水，其中，防油剂为选自含氟聚合物和含氟低分子化合物中的至少一种含氟化合物，防水防油剂或处理液含有有机物盐。

3. 发明授权

US06355753B1 Polymer and antifouling agent composition containing the same 有权
标题翻译：含有其的聚合物和防污剂组合物
公开(公告)号：US06355753B1
公开(公告)日：2002-03-12
申请号：US09424215
申请日：2000-01-19
申请人： Masayuki Yamana , Ikuo Yamamoto , Norihito Otsuki , Teruyuki Fukuda
发明人： Masayuki Yamana , Ikuo Yamamoto , Norihito Otsuki , Teruyuki Fukuda
IPC分类号： C08F1800
CPC分类号： D06M15/233 , C08F222/16 , C08F222/18 , C08F222/20 , C08F246/00 , C09K3/18 , D06M15/263 , D06M15/277 , D06M15/353 , D06M2400/01
摘要： A stainproofing polymer having: (i) a reactive group selected from the group consisting of a carboxyl group or its salt, a hydroxyl group, an epoxy group, a phosphoric acid group, an alkoxysilane group, an imine group, a sulfonic acid group, an amino group, an isocyanate group and a blocked isocyanate group; and (ii) a fluoroalkyl group, characterized in that a melting point of a monomer having a fluoroalkyl group, which constitutes the polymer, is at least 70° C. and a melting point of the stainproofing polymer is at least 50° C., gives durability capable of maintaining sufficient water- and oil-repellency after cleaning.
摘要翻译：一种防污聚合物，其具有：（i）选自羧基或其盐，羟基，环氧基，磷酸基，烷氧基硅烷基，亚胺基，磺酸基，氨基，异氰酸酯基和封端异氰酸酯基; 和（ii）氟代烷基，其特征在于构成聚合物的具有氟代烷基的单体的熔点至少为70℃，防污聚合物的熔点至少为50℃，提供了在清洁后能够保持足够的防水和防油性的耐久性。

4. 发明授权

US06284853B1 Copolymer and stainproofing agent containing the same 失效
标题翻译：含有该共聚物和防污剂
公开(公告)号：US06284853B1
公开(公告)日：2001-09-04
申请号：US09015764
申请日：1998-01-29
申请人： Masayuki Yamana , Ikuo Yamamoto , Norihito Otsuki , Teruyuki Fukuda
发明人： Masayuki Yamana , Ikuo Yamamoto , Norihito Otsuki , Teruyuki Fukuda
IPC分类号： C08F1820
CPC分类号： C08F20/36 , C08F220/22 , C08F220/36 , Y10T428/2969
摘要： The present invention provides a copolymer whose durability on cleaning is improved while maintaining good water- and oil-repellency. Disclosed is a copolymer having: (i) a fluoroalkyl group, (ii) a urethane or urea linkage, and (iii) a functional group selected from the group consisting of a carboxyl group, a carboxylic anhydride group, an epoxy group, a phosphoric group, an alkoxysilane group, a imine group, a sulfonic group, an amino group, an isocyanate group and a chlorine atom, and a stainproof agent containing the copolymer as an active component.
摘要翻译：本发明提供了一种在保持良好的拒水拒油性的同时提高了清洗耐久性的共聚物。公开了具有以下的共聚物：（i）氟烷基，（ii）氨基甲酸酯或脲键，（iii）选自羧基，羧酸酐基，环氧基，磷酸基团，烷氧基硅烷基，亚胺基，磺酸基，氨基，异氰酸酯基和氯原子，以及含有该共聚物作为活性成分的防污剂。

5. 发明授权

US6013732A Stainproofing agent 失效
标题翻译：防污剂
公开(公告)号：US6013732A
公开(公告)日：2000-01-11
申请号：US8484
申请日：1998-01-16
申请人： Masayuki Yamana , Ikuo Yamamoto , Teruyuki Fukuda
发明人： Masayuki Yamana , Ikuo Yamamoto , Teruyuki Fukuda
IPC分类号： D06M15/256 , C08L33/16 , D06M13/428 , D06M15/227 , D06M15/233 , D06M15/248 , D06M15/263 , D06M15/277 , D06M15/31 , D06M15/333 , D06M15/576 , D06M15/00
CPC分类号： D06M15/576 , C08L33/16 , D06M13/428 , D06M15/227 , D06M15/233 , D06M15/248 , D06M15/263 , D06M15/277 , D06M15/31 , D06M15/333 , Y10T428/23986
摘要： The present invention provides a stainproofing agent having the durability capable of maintaining sufficient water- and oil-repellency as well as stainproofing properties before and after cleaning. Disclosed is a stainproofing agent containing (A) a fluroalkyl group-containg copolymer having (I) a structure unit derived from a monomer having a fluoroalkyl group, (II) a structure unit derived from a monomer containing no fluorine, (III) a structure unit derived from vinyl chloride, and (IV) a structure unit derived from a crosslinking monomer; (B) a urethane compound having a fluoroalkyl group, or a copolymer having (V) a structure unit derived from a monomer having a fluoroalkyl group and a carbon-carbon double bond, and (VI) a structure unit derived from a monomer which contains no fluorine atom and has at least one urethane or urea linkage and one carbon-carbon double bond; and (C) an acrylic copolymer containing no fluorine.
摘要翻译：本发明提供了一种具有耐清洗性和防污性的耐久性以及清洗前后的防污性的防污剂。公开了含有（A）含氟烷基基团的共聚物的防污剂，其具有（I）来自具有氟代烷基的单体的结构单元，（II）来自不含氟的单体的结构单元，（III）衍生自氯乙烯的单元，和（IV）衍生自交联单体的结构单元; （B）具有氟代烷基的氨基甲酸酯化合物或具有（V）衍生自具有氟代烷基和碳 - 碳双键的单体的结构单元的共聚物，和（VI）衍生自含有无氟原子，并具有至少一个氨基甲酸酯或脲键和一个碳 - 碳双键; 和（C）不含氟的丙烯酸共聚物。

6. 发明授权

US06833082B2 Stain block treatment of textile 失效
标题翻译：纺织品的污渍处理
公开(公告)号：US06833082B2
公开(公告)日：2004-12-21
申请号：US10058376
申请日：2002-01-30
申请人： Fumihiko Yamaguchi , Ikuo Yamamoto , Teruyuki Fukuda , Kayo Kusumi
发明人： Fumihiko Yamaguchi , Ikuo Yamamoto , Teruyuki Fukuda , Kayo Kusumi
IPC分类号： D06M1555
CPC分类号： D06M15/263 , D06M11/56 , D06M11/66 , D06M13/188 , D06M13/2243 , D06M13/262 , D06M15/412 , D06M2200/25 , Y10T428/23986
摘要： Excellent stain block property, WAQE resistance and yellowing resistance are imparted to a textile by a method of preparing a treated textile has the steps of (1) preparing a treatment liquid comprising a stain blocking agent and a sulfated castor oil and having pH of at most 7, (2) applying the treatment liquid to the textile, (3) treating the textile with steam, and (4) washing the textile with water and dehydrating the textile.
摘要翻译：通过制备经处理的织物的方法赋予纺织品优异的防污性，耐WAQE性和耐黄变性，具有以下步骤：（1）制备包含防污剂和硫酸化蓖麻油并具有最多pH值的处理液 7，（2）将处理液施加到纺织品上，（3）用蒸汽处理织物，（4）用水洗涤织物并使织物脱水。

7. 发明申请

US20110274936A1 FLUORINE- AND SILICON-CONTAINING TREATMENT AGENT FOR CONCRETES 审中-公开
标题翻译：含氟和含硅的混凝土处理剂
公开(公告)号：US20110274936A1
公开(公告)日：2011-11-10
申请号：US13123754
申请日：2009-10-09
申请人： Teruyuki Fukuda , Shinichi Minami , Peter Cheshire Hupfield , Samantha Reed , Janet Smith
发明人： Teruyuki Fukuda , Shinichi Minami , Peter Cheshire Hupfield , Samantha Reed , Janet Smith
IPC分类号： B32B13/12 , C08L83/04 , C08G77/04
CPC分类号： C04B41/63 , C04B41/4842 , C08F283/122 , C08L51/085 , Y10T428/31663 , C04B41/483 , C04B41/4961 , C08F220/24
摘要： The present invention provides a surface treatment agent comprising a fluorine-containing polymer having repeating units derived from a monomer comprising a fluorine-containing monomer, wherein the fluorine-containing polymer has a silicone moiety possessed by a mercapto group-containing silicone. When a porous substrate is treated under drying at normal temperature, the surface treatment agent comprising the fluorine-containing acrylate polymer can impart the excellent water- and oil-repellency and soil resistance to the porous substrate.
摘要翻译：本发明提供一种表面处理剂，其含有含有含有含氟单体的单体的重复单元的含氟聚合物，其中含氟聚合物具有含有巯基的硅酮所具有的硅氧烷部分。当在常温下干燥处理多孔基材时，包含含氟丙烯酸酯聚合物的表面处理剂可赋予多孔基材优异的拒水拒油性和耐污性。

8. 发明申请

US20110110995A1 SURFACE-TREATED POWDER AND COSMETIC COMPRISING THE SAME 审中-公开
标题翻译：表面处理粉末和化妆品包装
公开(公告)号：US20110110995A1
公开(公告)日：2011-05-12
申请号：US12993346
申请日：2009-03-03
申请人： Yukio Hasegawa , Yasushi Takeuchi , Masafumi Imazeki , Hiroshi Tsuboyama , Koji Noguchi , Masahiko Maeda , Teruyuki Fukuda , Shigeru Maruyama
发明人： Yukio Hasegawa , Yasushi Takeuchi , Masafumi Imazeki , Hiroshi Tsuboyama , Koji Noguchi , Masahiko Maeda , Teruyuki Fukuda , Shigeru Maruyama
IPC分类号： A61K8/81 , A61K8/02 , A61Q17/04 , A61Q1/12 , A61Q5/00
CPC分类号： A61K8/11 , A61K8/8123 , A61Q1/02 , A61Q1/06 , A61Q1/10 , A61Q1/12 , A61Q3/02 , A61Q5/12 , A61Q15/00 , A61Q17/04 , A61Q19/008 , C09C1/0021 , C09C1/043 , C09C1/24 , C09C1/3676 , C09C1/42 , C09C3/10 , C09C2200/102 , C09C2200/406
摘要： Provided is a surface-treated powder having excellent usability and adhesion to skin. The powder is coated with a surface-treating agent including (a) a fluorine-containing monomer of a general formula (I) and (b) an alkoxy group-containing monomer of a general formula (II). The powder is used for various cosmetics. [Chemical formula 3] CH2=C(—X)—C(═O)—Y—[—(CH2)m-Z-]p-(CH2)n-Rf (I) [Chemical formula 4) CH2=C(X1)-C(═O)—O—(RO)q-X2 (II)
摘要翻译：提供具有优异的使用性和对皮肤的粘附性的表面处理粉末。粉末涂覆有表面处理剂，其包括（a）通式（I）的含氟单体和（b）通式（II）的含烷氧基的单体。粉末用于各种化妆品。 [化学式3] CH2 = C（-X）-C（= O）-Y- [ - （CH2）mZ-] p-（CH2）n-Rf（I）[化学式4] CH2 = C ）-C（= O）-O-（RO）q -X 2（II）

9. 发明申请

US20110069108A1 AQUEOUS INK FOR INKJET PRINTING 有权
标题翻译：喷墨打印墨水
公开(公告)号：US20110069108A1
公开(公告)日：2011-03-24
申请号：US12990169
申请日：2009-04-04
申请人： Teruyuki Fukuda
发明人： Teruyuki Fukuda
IPC分类号： B41J2/015 , C09D11/02 , C09D11/10
CPC分类号： B41M5/0023 , C09D11/322 , C09D11/38
摘要： An aqueous ink for inkjet printing which includes a pigment, a compound represented by formula (1) and/or a compound represented by formula (2): R1—O—(CH2CH2O)n—H (1) R1—O—(CH2CH2O)m—R2 (2) wherein R1 and R2 are each an aliphatic group having 2 to 5 carbon atoms or an alicyclic group having 3 to 5 carbon atoms, and n and in are each an average molar number of addition of 6 to 9, and water in a content of 50 to 65% by weight. The total content of the compound represented by formula (1) and the compound represented by formula (2) is 10 to 30% by weight. The aqueous ink is excellent in the curl prevention after print and print density as well as in the storage stability. In a method of inkjet-printing images using the aqueous ink on plain paper by one-pass print, the water content in the aqueous ink which is jetted onto unit area of the plain paper is regulated within 0.2 to 1.0 mg/cm2.
摘要翻译：用于喷墨印刷的水性油墨，其包含颜料，由式（1）表示的化合物和/或由式（2）表示的化合物：R1-O-（CH2CH2O）n-H（1）R1-O-（CH2CH2O ）m-R2（2）其中R1和R2各自为具有2至5个碳原子的脂族基团或具有3至5个碳原子的脂环族基团，n和n各自的平均加成摩尔数为6至9，和含水量为50〜65重量％的水。由式（1）表示的化合物和由式（2）表示的化合物的总含量为10〜30重量％。水性油墨在印刷和印刷密度以及储存稳定性之后的卷曲预防性优异。在通过一次通过印刷在普通纸上使用水性墨水进行喷墨打印图像的方法中，喷射到普通纸的单位面积上的水性墨水中的含水量被调节在0.2至1.0mg / cm 2之内。

10. 发明申请

US20070066780A1 Masonry-treating agent 审中-公开
标题翻译：砖石处理剂
公开(公告)号：US20070066780A1
公开(公告)日：2007-03-22
申请号：US10559810
申请日：2004-06-07
申请人： Akihiko Ueda , Masahiko Maeda , Teruyuki Fukuda , Tetsuya Masutani
发明人： Akihiko Ueda , Masahiko Maeda , Teruyuki Fukuda , Tetsuya Masutani
IPC分类号： C08F16/24
CPC分类号： C08F220/24 , C04B41/4842
摘要： A fluoropolymer for masonry treatment produced from (A) a fluoromonomer which has been substituted in the α-position by a X group and is represented by the formula (I): and (B) a monomer having a functional group reactive with active hydrogen. It imparts excellent water- and oil-repellency and unsusceptibility to fouling to masonries.
摘要翻译：（A）通过X基团在α位被X基团取代并由式（I）表示的（A）含氟单体制备的用于石工处理的含氟聚合物：和（B）具有与活性氢反应的官能团的单体。它赋予了优异的拒水拒油性和对砖石结垢的不可接受性。

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