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    • 9. 发明申请
    • REFERENCE ELECTRODE, ITS MANUFACTURING METHOD, AND AN ELECTROCHEMICAL CELL
    • 参考电极,其制造方法和电化学细胞
    • US20120027926A1
    • 2012-02-02
    • US13193439
    • 2011-07-28
    • Takuhiro MiyukiTakashi MukaiTetsuo SakaiYukio YamakawaYoshiyuki HonjoHironori Yamasaki
    • Takuhiro MiyukiTakashi MukaiTetsuo SakaiYukio YamakawaYoshiyuki HonjoHironori Yamasaki
    • B05D5/12C25D3/42C25D7/06C25D3/56
    • H01M4/134H01M4/0426H01M4/0438H01M4/1395H01M4/36H01M4/366H01M4/661H01M4/667
    • [PROBLEM] The purpose of the present invention is to provide a reference electrode which is easy to manufacture and handle, its manufacturing method, and an electrochemical cell using this.[METHOD FOR SOLVING THE PROBLEM] The reference electrode 10 comprises a core material 11 extending parallel to the anode 14 or the cathode 16 from a terminal, a lithium membrane 12 coating from a tip of the core material 11 to a field with predetermined length, and an insulator 13 partially coating a field uncoated with the lithium membrane 12 on the core material 11. The material consisting of at least a surface of the core material 11 is a conductive material which is substantially unresponsive to lithium or lithium alloy. The maximum width in a cross section of the core material 11 is preferably in the range of not less than 5 micrometers but not more than 50 micrometers, and thickness of the lithium membrane is preferably in the range of not less than 0.1 micrometers but not more than 20 micrometers. By using the core material 11 with higher rigidity than lithium or lithium alloy, handling and manufacturing the reference material 10 is easy, for example, the material can be processed easily and its shape can be stabilized.[SELECTED FIGURE] FIG. 2
    • 本发明的目的是提供一种容易制造和处理的参比电极,其制造方法和使用该电极的电化学电池。 [解决问题的方法]参考电极10包括从端子平行于阳极14或阴极16延伸的芯材11,从芯材11的尖端涂覆到具有预定长度的磁场的锂膜12, 以及将芯膜材料11上的锂膜12未涂覆的场部分地覆盖的绝缘体13.由芯材11的至少一个表面构成的材料是对锂或锂合金基本上无响应的导电材料。 芯材11的截面的最大宽度优选为5μm以上且50μm以下的范围,锂膜的厚度优选为0.1μm以上,更优选为0.1μm以上 超过20微米。 通过使用具有比锂或锂合金更高的刚性的芯材11,容易进行参考材料10的处理和制造,例如可以容易地处理材料并且可以使其形状稳定。 [选择的图] 2