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1. 发明授权

US10414150B2 Active-energy-ray-curable composition, composition stored container, two-dimensional or three-dimensional image forming apparatus, method for forming two-dimensional or three-dimensional image, and cured product 有权
公开(公告)号：US10414150B2
公开(公告)日：2019-09-17
申请号：US15196863
申请日：2016-06-29
申请人： Takao Hiraoka , Masato Iio , Daisuke Miki
发明人： Takao Hiraoka , Masato Iio , Daisuke Miki
IPC分类号： C08F2/46 , C08F2/50 , C08G61/04 , B33Y80/00 , C09D167/00 , C08J7/04 , B41J2/01 , C08F283/02 , C09D11/101 , C09D11/104 , C09D11/106 , C09D11/324 , B33Y10/00 , B33Y70/00 , B41M7/00
摘要： An active-energy-ray-curable composition including at least one monofunctional (meth)acrylate, at least one multifunctional (meth)acrylate, and at least one polyester-structure-containing polymer. Preferable is an aspect where the active-energy-ray-curable composition further includes a polymer obtained through polymerization of at least one selected from the group consisting of styrene, styrene derivatives, acrylic acid esters, and acrylic acid.

2. 发明授权

US10227497B2 Active energy ray curable composition, active energy ray curable ink, inkjet ink, stereoscopic modeling material, active energy ray curable composition container, two-dimensional or three dimensional image forming apparatus, two-dimensional or three-dimensional image forming method, cured product, and processed product 有权
公开(公告)号：US10227497B2
公开(公告)日：2019-03-12
申请号：US15205776
申请日：2016-07-08
申请人： Masato Iio , Takao Hiraoka
发明人： Masato Iio , Takao Hiraoka
IPC分类号： C09D4/06 , B29C64/124 , C09D11/101 , C09D11/106 , B41J2/01 , C09D11/322 , B33Y70/00 , B29K67/00
摘要： An active energy ray curable composition is provided. The active energy ray curable composition includes a polymerizable monomer, a polymer component, a polymeric dispersant, and a pigment. The active energy ray curable composition is non-aqueous. The active energy ray curable composition has a yield value of 0.1 Pa or less either when having an initial weight or when being dried to have a weight 70% by mass of the initial weight.

3. 发明授权

US10995226B2 Active-energy-ray-curable composition, active-energy-ray-curable ink composition, composition stored container, two-dimensional or three-dimensional image forming apparatus, method for forming two-dimensional or three-dimensional image, cured product, and laminated cured product 有权
公开(公告)号：US10995226B2
公开(公告)日：2021-05-04
申请号：US15184477
申请日：2016-06-16
申请人： Masato Iio , Takao Hiraoka
发明人： Masato Iio , Takao Hiraoka
IPC分类号： C09D11/101 , C09D4/06 , C09D11/30 , B33Y10/00 , B33Y70/00 , B33Y80/00 , B41J2/475 , C09D11/10 , C08F220/18 , C08F2/48 , B29C64/135
摘要： An active-energy-ray-curable composition including at least one monofunctional (meth)acrylate, at least one multifunctional (meth)acrylate, and at least one chlorinated-olefin-structure-containing polymer.

4. 发明授权

US09187658B2 Photopolymerizable inkjet ink, ink cartridge, and inkjet recording device 有权
标题翻译：可光聚合喷墨油墨，墨盒和喷墨记录装置
公开(公告)号：US09187658B2
公开(公告)日：2015-11-17
申请号：US14310452
申请日：2014-06-20
申请人： Shizuka Kohzuki , Takao Hiraoka
发明人： Shizuka Kohzuki , Takao Hiraoka
IPC分类号： C08F2/50 , C08F2/46 , C08G61/04 , C09D11/101 , C09D11/30 , C09D11/38
CPC分类号： C09D11/101 , C09D11/30 , C09D11/38
摘要： To provide a photopolymerizable inkjet ink including: diethylene glycol dimethacrylate; caprolactone-modified dipentaerythritol hexaacrylate; and a photopolymerization initiator represented by the following general formula (1): where X1 is represented by the following general formula (1-1), and X2 is represented by the following general formula (1-2): where R1 to R4 are each independently a C1-C6 alkyl group, and R1 and R2 may be linked to form a ring, and R3 and R4 may be linked to form a ring; Z1 and Z2 is —NR5R6 or OR7; R5 and R6 are each independently a C1-C6 alkyl group, and R5 and R6 may be linked to form a ring; and R7 is a hydrogen atom, a methyl group, or a trimethylsilyl group.
摘要翻译：提供一种可光聚合喷墨油墨，其包含：二甘醇二甲基丙烯酸酯; 己内酯改性二季戊四醇六丙烯酸酯; 和由以下通式（1）表示的光聚合引发剂：其中X1由以下通式（1-1）表示，X2由以下通式（1-2）表示：其中R1至R4各自为独立地为C1-C6烷基，R1和R2可以连接形成环，R3和R4可以连接形成环; Z 1和Z 2是-NR 5 R 6或OR 7; R5和R6各自独立地为C1-C6烷基，R5和R6可以连接形成环; 并且R 7是氢原子，甲基或三甲基甲硅烷基。

5. 发明授权

US09051481B2 Active energy ray-curable ink, ink cartridge containing ink, image or cured product forming method, and image or cured product forming device 有权
标题翻译：活性能量射线固化油墨，含有油墨的墨盒，图像或固化产物形成方法，以及图像或固化产物形成装置
公开(公告)号：US09051481B2
公开(公告)日：2015-06-09
申请号：US14474781
申请日：2014-09-02
申请人： Mie Yoshino , Takao Hiraoka , Shizuka Kohzuki
发明人： Mie Yoshino , Takao Hiraoka , Shizuka Kohzuki
IPC分类号： G01D11/00 , C09D11/101 , B41J2/01 , C09D11/30
CPC分类号： C09D11/101 , B41J2/01 , C09D11/30 , C09D11/322 , C09D11/324
摘要： An active energy ray-curable ink which contains: polymerizable compounds containing a monofunctional polymerizable monomer a homopolymer of which has Tg of 90° C. or higher, wherein a cured product obtained by forming a coating film having an average thickness of 10 μm on a polycarbonate substrate using the ink, and 15 seconds later, and applying active energy rays having a light quantity of 1,500 mJ/cm2 to the coating film to cure satisfies the following (1) and (2): (1) a stretchability of the cured product represented by the following equation is 2 or greater, when the cured product is stretched by a tensile tester at a tensile speed of 20 mm/min, and temperature of 180° C., and Stretchability=(length after tensile test)/(length before tensile test) (2) adhesion between the substrate and the cured product as measured by a cross-cut test in accordance with JIS K5400 is 70 or greater.
摘要翻译：一种活性能量射线固化型油墨，其含有：含有Tg为90℃以上的均聚物的单官能性聚合性单体的聚合性化合物，其中，将通过在平均厚度为10μm的涂膜上形成的固化物使用该油墨的聚碳酸酯基板15秒钟后，向涂膜施加光量为1,500mJ / cm 2的活性能量射线，使其固化，满足以下（1）和（2）：（1）固化的当拉伸试验机以拉伸速度为20mm / min，温度为180℃，伸长率=（拉伸试验后的长度）/（拉伸试验机）拉伸固化产物时，由下式表示的产物为2以上，拉伸试验前的长度）（2）根据JIS K5400的横切试验测定的基材与固化物的粘合性为70以上。

6. 发明申请

US20150091986A1 ACTIVE ENERGY RAY CURING TYPE COMPOSITION, CONTAINER THAT ACCOMMODATES COMPOSITION, INKJET DISCHARGING DEVICE HAVING CONTAINER, AND CURED MATTER 有权
标题翻译：活性能量固化型组合物，容纳组合物的容器，具有容器的喷射装置和固化物
公开(公告)号：US20150091986A1
公开(公告)日：2015-04-02
申请号：US14493555
申请日：2014-09-23
申请人： Shinya Seno , Takao Hiraoka
发明人： Shinya Seno , Takao Hiraoka
IPC分类号： C09D133/10 , C09D11/30
CPC分类号： C09D133/10 , B41J2/17513 , B41J2/17553 , C08F2/48 , C08F222/10 , C08F222/1006 , C08F2222/1013 , C08F2222/1026 , C08F2222/104 , C08F2222/1093 , C08G77/46 , C08L83/04 , C08L83/12 , C08L2312/06 , C09D11/101 , C09D11/102 , C09D11/30 , C09D183/12 , C09J133/06
摘要： An active energy ray curing type composition contains (meth)acrylic acid ester; and polyether-modified polysiloxane, wherein (meth)acrylic acid ester comprises diethylene glycol dimethacrylate and alkoxy-modified (meth)acrylic acid ester.
摘要翻译：活性能量射线固化型组合物含有（甲基）丙烯酸酯; 和聚醚改性的聚硅氧烷，其中（甲基）丙烯酸酯包括二乙二醇二甲基丙烯酸酯和烷氧基改性的（甲基）丙烯酸酯。

7. 发明申请

US20150077481A1 ACTIVE ENERGY RAY-CURABLE INK, INK CARTRIDGE CONTAINING INK, IMAGE OR CURED PRODUCT FORMING METHOD, AND IMAGE OR CURED PRODUCT FORMING DEVICE 有权
标题翻译：活性能量可固化油墨，含有墨水的墨盒，图像或固化产品形成方法，图像或固化产品形成装置
公开(公告)号：US20150077481A1
公开(公告)日：2015-03-19
申请号：US14474781
申请日：2014-09-02
申请人： Mie Yoshino , Takao Hiraoka , Shizuka Kohzuki
发明人： Mie Yoshino , Takao Hiraoka , Shizuka Kohzuki
IPC分类号： C09D11/101 , C09D11/30 , B41J2/01
CPC分类号： C09D11/101 , B41J2/01 , C09D11/30 , C09D11/322 , C09D11/324
摘要： An active energy ray-curable ink which contains: polymerizable compounds containing a monofunctional polymerizable monomer a homopolymer of which has Tg of 90° C. or higher, wherein a cured product obtained by forming a coating film having an average thickness of 10 μm on a polycarbonate substrate using the ink, and 15 seconds later, and applying active energy rays having a light quantity of 1,500 mJ/cm2 to the coating film to cure satisfies the following (1) and (2): (1) a stretchability of the cured product represented by the following equation is 2 or greater, when the cured product is stretched by a tensile tester at a tensile speed of 20 mm/min, and temperature of 180° C., and Stretchability=(length after tensile test)/(length before tensile test) (2) adhesion between the substrate and the cured product as measured by a cross-cut test in accordance with JIS K5400 is 70 or greater.
摘要翻译：一种活性能量射线固化型油墨，其含有：含有Tg为90℃以上的均聚物的单官能性聚合性单体的聚合性化合物，其中，将通过在平均厚度为10μm的涂膜上形成的固化物使用该油墨的聚碳酸酯基板15秒钟后，向涂膜施加光量为1,500mJ / cm 2的活性能量射线，使其固化，满足以下（1）和（2）：（1）固化的当拉伸试验机以拉伸速度为20mm / min，温度为180℃，伸长率=（拉伸试验后的长度）/（拉伸试验机）拉伸固化产物时，由下式表示的产物为2以上，拉伸试验前的长度）（2）根据JIS K5400的横切试验测定的基材与固化物的粘合性为70以上。

8. 发明申请

US20130220846A1 TRANSDERMAL PATCH 有权
标题翻译：透明贴
公开(公告)号：US20130220846A1
公开(公告)日：2013-08-29
申请号：US13581673
申请日：2012-02-28
申请人： Takao Hiraoka , Shuta Nakanami , Toru Koga
发明人： Takao Hiraoka , Shuta Nakanami , Toru Koga
IPC分类号： A61M35/00 , B32B37/24 , B32B37/12 , B65D81/00
CPC分类号： A61K9/7084 , A61K31/27 , B32B37/1284 , B32B37/144 , B32B2309/02 , B32B2333/08 , B32B2333/12 , B32B2405/00 , B32B2535/00 , B65B5/04
摘要： A transdermal patch for the treatment of Alzheimer's disease includes: a backing, a rivastigmine-containing layer, a pressure-sensitive adhesive layer, and a release liner. In the transdermal patch, the rivastigmine-containing layer contains rivastigmine and an alkyl (meth)acrylate resin, the pressure-sensitive adhesive layer is composed of an acrylic pressure-sensitive adhesive containing a (meth)acrylic acid ester having a hydroxy group, and neither the rivastigmine-containing layer nor the pressure-sensitive adhesive layer contains an anti-oxidizing agent.
摘要翻译：用于治疗阿尔茨海默氏病的透皮贴剂包括：背衬，含有伐他斯他明的层，压敏粘合剂层和剥离衬垫。在透皮贴剂中，含有伐罗斯的明和（甲基）丙烯酸烷基酯树脂，该压敏粘合剂层由含有具有羟基的（甲基）丙烯酸酯的丙烯酸系压敏粘合剂构成，利伐斯的明含有层和压敏粘合剂层都不含有抗氧化剂。

9. 发明申请

US20130065024A1 METHOD OF PRODUCING FILM BY INKJET PROCESS, AND FILM 有权
标题翻译：通过喷墨工艺生产薄膜的方法和薄膜
公开(公告)号：US20130065024A1
公开(公告)日：2013-03-14
申请号：US13640198
申请日：2011-04-08
申请人： Tamotsu Aruga , Shinya Seno , Masayuki Koyano , Eiji Noda , Noriyasu Takeuchi , Tsutomu Maekawa , Takao Hiraoka , Tomoko Hasegawa , Okitoshi Kimura , Soh Noguchi
发明人： Tamotsu Aruga , Shinya Seno , Masayuki Koyano , Eiji Noda , Noriyasu Takeuchi , Tsutomu Maekawa , Takao Hiraoka , Tomoko Hasegawa , Okitoshi Kimura , Soh Noguchi
IPC分类号： B05D1/36 , B29C35/08 , B05D1/26 , B05D5/06
CPC分类号： B05D1/36 , B05D1/26 , B05D3/067 , B05D5/02 , B05D5/06 , B29C35/08 , B41M3/003 , B41M7/0081 , C09D5/006 , C09D11/101 , Y10T428/24612 , Y10T428/24802
摘要： To provide a method of producing a film, comprising: ejecting a liquid B over a liquid surface of an active energy ray-curable liquid as a liquid A by an inkjet process, according to a predetermined periodic signal; and subsequently applying an active energy ray to the liquid A and the liquid B so as to perform curing and obtain a film which comprises a pattern according to any one of (1) to (4) below, (1) a smooth pattern having a periodic amplitude based upon a trigonometric function, (2) a pattern having a periodic depression, (3) a pattern in the form of a periodic flat surface, and (4) a pattern having a periodic semicylindrical shape.
摘要翻译：提供一种膜的制造方法，其特征在于，包括：根据预定的周期信号，通过喷墨工序将液体B喷射到作为液体A的活性能量射线固化型液体的液面上; 然后将活性能量射线施加到液体A和液体B上以进行固化，并获得包括根据下述（1）至（4）中任一项所述的图案的膜，（1）具有基于三角函数的周期幅度，（2）具有周期性凹陷的图案，（3）周期性平坦表面形式的图案，以及（4）具有周期性半圆柱形状的图案。

10. 发明申请

US20160257818A1 LAYERED PRODUCT AND METHOD FOR PRODUCING SAME, AND LAYERED PRODUCT PRODUCING APPARATUS 审中-公开
标题翻译：分层产品及其生产方法，以及生产装置的层状产品
公开(公告)号：US20160257818A1
公开(公告)日：2016-09-08
申请号：US14837423
申请日：2015-08-27
申请人： Daisuke Mezaki , Takao Hiraoka , Shinya Seno
发明人： Daisuke Mezaki , Takao Hiraoka , Shinya Seno
IPC分类号： C09D4/00 , C09D5/00 , B05D3/00
摘要： Provided is a layered product, including: a base material, and a first layer and a second layer over the base material in this order, wherein the first layer is made of a first photopolymerizable composition containing at least a polymerizable compound having a hydroxyl group, wherein the second layer is made of a second photopolymerizable composition containing at least diethylene glycol dimethacrylate, and wherein an average thickness of the first layer is equal to or greater than 35% of a total average thickness of the first layer and the second layer.
摘要翻译：本发明提供一种层叠体，其特征在于，包括：基材，以及依次形成在所述基材上的第一层和第二层，其中，所述第一层由至少含有具有羟基的聚合性化合物的第一可光聚合组合物，其中所述第二层由至少包含二甘醇二甲基丙烯酸酯的第二可光聚合组合物制成，并且其中所述第一层的平均厚度等于或大于所述第一层和所述第二层的总平均厚度的35％。

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