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    • 5. 发明授权
    • Fibrous electrically-conductive filler and process for producing the same
    • 纤维导电填料及其制造方法
    • US5273822A
    • 1993-12-28
    • US798102
    • 1991-11-26
    • Takao HayashiNorihiro SatoChikara OmotaniManabu HosoiNobuyoshi KasaharaWolf-Dieter GrieblerJorg HockenGunther Rudolph
    • Takao HayashiNorihiro SatoChikara OmotaniManabu HosoiNobuyoshi KasaharaWolf-Dieter GrieblerJorg HockenGunther Rudolph
    • C01B35/12C08K3/22C08K5/55C08K7/00C08K7/08C08K9/02C08L101/00C09D5/24D01F9/10H01B1/08B05D3/02B32B9/00
    • H01B1/08C08K9/02Y10S428/902Y10S428/934Y10T428/2929Y10T428/2931Y10T428/2933Y10T428/2958
    • A fibrous electrically-conductive filler comprises fibrous aluminum borate as a core material and a layer of a electrically-conductive substance which covers the core material or comprises fibrous aluminum borate as a core material, a layer of titanium oxide which covers the fibrous aluminum borate and a layer of a electrically-conductive substance which covers the titanium oxide layer. The fibrous electrically-conductive filler can be prepared by a process comprising the step of directly forming a layer of a electrically-conductive substance doped with antimony or fluorine on the surface of fibrous aluminum borate, or the steps of forming, on the surface of the fibrous aluminum borate, an intermediate layer of titanium oxide in an amount ranging from 2 to 50% by weight on the basis of the weight of the fibrous aluminum borate and then forming a layer of a electrically-conductive substance doped with antimony or fluorine on the surface of fibrous aluminum borate. The filler has a low volume specific resistivity and is substantially excellent in electrical conductivity-imparting effect per unit weight thereof when it is added to a basic material such as a resin. The electrically-conductive substance coated on the filler surface is not peeled off and hence the filler does not cause loss of the electrical conductivity when it is incorporated into a basic material such as paper, a plastic, a rubber, a resin or a paint. The filler per se is white or transparent and, therefore, the color tone of such a basic material may be arbitrarily changed by the addition of a coloring agent.
    • 纤维状导电填料包括纤维状硼酸铝作为芯材料和覆盖芯材的导电物质层或包含纤维状硼酸铝作为核心材料,覆盖纤维状硼酸铝的二氧化钛层和 覆盖氧化钛层的导电物质层。 纤维状导电性填充剂可以通过以下工序来制备,所述方法包括在纤维状硼酸铝的表面上直接形成掺杂有锑或氟的导电物质的层的步骤,或者在 纤维状的硼酸铝,基于纤维状硼酸铝的重量的2-50重量%的二氧化钛中间层,然后在其上形成掺杂有锑或氟的导电物质层 纤维状硼酸铝的表面。 填料具有低体积比电阻率,并且当其添加到诸如树脂的基础材料中时,其每单位重量的导电性赋予效果基本上优异。 涂覆在填料表面上的导电物质不会被剥离,因此当其被引入诸如纸,塑料,橡胶,树脂或涂料的基本材料中时,填料不会导致导电性的损失。 填料本身是白色或透明的,因此通过添加着色剂可以任意地改变这种碱性物质的色调。