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    • 1. 发明申请
    • METHOD FOR PRODUCTION OF WATER/OIL REPELLENT COMPOSITION AND ARTICLE
    • 水/油组合物和制品的生产方法
    • US20100113665A1
    • 2010-05-06
    • US12652785
    • 2010-01-06
    • Takao HIRONOKazunori SugiyamaYuuichi OomoriMinako Shimada
    • Takao HIRONOKazunori SugiyamaYuuichi OomoriMinako Shimada
    • C08K5/37C08K5/06
    • C08F220/24C08F14/18C08F214/06C08F214/18C08F220/36C08F220/58C08F2220/1891D06M15/263D06M15/277D06M15/3566D06M2200/11D06M2200/12C08F2/04
    • To provide a method for producing a water/oil repellent composition which can impart water/oil repellency to a surface of an article and has excellent durability (wash durability and heavy-rain durability) and an article which has water/oil repellency and is less susceptible to deterioration of water/oil repellency when it is washed or in heavy rain.A method for producing a water/oil repellent composition which comprises polymerizing a monomer component comprising the following monomer (a) in coexistence with the following compound (x) in a medium in the presence of a surfactant and a polymerization initiator: monomer (a) is a compound of the formula (Z—Y)nX wherein Z is a C1-20 polyfluoroalkyl group or the like, Y is a bivalent organic group or a single bond, n is 1 or 2, and X is a polymerizable unsaturated group; and the compound (x) is a compound of Rf1—(CH2)b-Q-(CH2)a—SH, wherein Rf1 is a C1-30 polyfluoroalkyl group, Q is a bivalent organic group or a single bond, a is an integer of from 1 to 20, and b is an integer of from 0 to 20.
    • 本发明提供一种斥水斥油剂组合物的制造方法,其能够对制品的表面赋予斥水斥油性,并具有优异的耐久性(耐洗涤耐久性和耐雨性),耐水斥油性低的物品 当洗涤或大雨时易受水/拒油性的劣化。 一种防水斥油剂组合物的制造方法,其特征在于,在表面活性剂和聚合引发剂:单体(a)的存在下,在介质中,将包含下述单体(a)的单体成分与下列化合物(x)共存, 是式(Z-Y)n X的化合物,其中Z是C 1-20多氟烷基等,Y是二价有机基团或单键,n是1或2,X是可聚合不饱和基团; 化合物(x)为Rf1-(CH2)bQ-(CH2)a-SH的化合物,其中Rf1为C1-30多氟烷基,Q为二价有机基团或单键,a为 1〜20,b为0〜20的整数。
    • 5. 发明授权
    • Copolymer and method for producing the same
    • 共聚物及其制造方法
    • US08901264B2
    • 2014-12-02
    • US12878045
    • 2010-09-09
    • Kazunori SugiyamaToyomichi ShimadaNobuyuki OtozawaYuuichi OomoriMinako Shimada
    • Kazunori SugiyamaToyomichi ShimadaNobuyuki OtozawaYuuichi OomoriMinako Shimada
    • C08F214/26C08F214/08C08F220/24C08F214/00C08F214/06C08F220/18C08F220/26
    • C08F214/00C08F214/06C08F214/08C08F220/18C08F220/24C08F220/26Y10T428/3154
    • To provide a copolymer which can impart sufficient dynamic water repellency, after air-drying water repellency and friction durability to a surface of an article, and which has low impact on the environment, a method for producing the same, a water repellent composition and an article excellent in dynamic water repellency, after air-drying water repellency and friction durability. A copolymer which is characterized in that it has structural units based on the following monomer (a) and structural units based on the following monomer (b), wherein the content of structural units based on the monomer (a) is from 5 to 95 mass % in the total structural units (100 mass %), the content of structural units based on the monomer (b) is from 5 to 60 mass % in the total structural units (100 mass %) and the sum of the contents of structural units based on the monomer (a) and structural units based on the monomer (b) is at least 65 mass % in the total structural units (100 mass %), and a water repellent composition which comprises the copolymer: Monomer (a): a (meth)acrylate having no Rf group and having a C20-30 alkyl group; Monomer (b): a halogenated olefin.
    • 为了提供赋予足够的动态防水性的共聚物,对制品表面的空气干燥防水性和摩擦耐久性,对环境的影响较小的共聚物,其制造方法,防水组合物和 具有优异的动态防水性,空气干燥防水性和摩擦耐久性。 一种共聚物,其特征在于其具有基于以下单体(a)的结构单元和基于以下单体(b)的结构单元,其中基于单体(a)的结构单元的含量为5至95质量份 (100质量%),基于单体(b)的结构单元的含量在总结构单位(100质量%)中为5〜60质量%,结构单元的含量之和 基于单体(a)和基于单体(b)的结构单元在总结构单元(100质量%)中为至少65质量%,以及包含共聚物的防水组合物:单体(a):a (甲基)丙烯酸酯,不具有Rf基且具有C20-30烷基; 单体(b):卤代烯烃。
    • 6. 发明申请
    • METHOD FOR PRODUCTION OF WATER/OIL REPELLENT COMPOSITION AND ARTICLE
    • 水/油组合物和制品的生产方法
    • US20100105825A1
    • 2010-04-29
    • US12652765
    • 2010-01-06
    • Kazunori SugiyamaYuuichi OomoriMinako Shimada
    • Kazunori SugiyamaYuuichi OomoriMinako Shimada
    • C09K3/18
    • C08F220/24C08F14/18C08F2220/1891C08F2220/308C08F2/04
    • To provide a method for producing a water/oil repellent composition which can impart water/oil repellency to a surface of an article and has excellent durability (wash durability and heavy-rain durability) and an article which has water/oil repellency and is less susceptible to deterioration of water/oil repellency when it is washed or in heavy rain.A method for producing a water/oil repellent composition which comprises polymerizing a monomer component comprising the following monomer (a) in coexistence with the following compound (x) in a medium in the presence of a surfactant and a polymerization initiator: monomer (a) is a compound of the formula (Z—Y)nX wherein Z is a C1-20 polyfluoroalkyl group or the like, Y is a bivalent organic group or a single bond, n is 1 or 2, and X is a polymerizable unsaturated group; and the compound (x) is a compound having at least two groups of —(CH2)a—CHR1—(CH2)b—SH, wherein R1 is a methyl group or an ethyl group, a is an integer of from 0 to 2, and b is 0 or 1.
    • 本发明提供一种斥水斥油剂组合物的制造方法,其能够对制品的表面赋予斥水斥油性,并具有优异的耐久性(耐洗涤耐久性和耐雨性),耐水斥油性低的物品 当洗涤或大雨时易受水/拒油性的劣化。 一种防水斥油剂组合物的制造方法,其特征在于,在表面活性剂和聚合引发剂:单体(a)的存在下,在介质中,将包含下述单体(a)的单体成分与下列化合物(x)共存, 是式(Z-Y)n X的化合物,其中Z是C 1-20多氟烷基等,Y是二价有机基团或单键,n是1或2,X是可聚合不饱和基团; 化合物(x)是具有至少两个 - (CH 2)a -CHR 1-(CH 2)b -SH的基团的化合物,其中R 1是甲基或乙基,a是0-2的整数 ,b为0或1。
    • 9. 发明授权
    • Method for production of water/oil repellent composition and article
    • 防水/防油组合物和制品的生产方法
    • US07989567B2
    • 2011-08-02
    • US12652765
    • 2010-01-06
    • Kazunori SugiyamaYuuichi OomoriMinako Shimada
    • Kazunori SugiyamaYuuichi OomoriMinako Shimada
    • C08F2/38C08F218/00C09K3/18
    • C08F220/24C08F14/18C08F2220/1891C08F2220/308C08F2/04
    • To provide a method for producing a water/oil repellent composition which can impart water/oil repellency to a surface of an article and has excellent durability (wash durability and heavy-rain durability) and an article which has water/oil repellency and is less susceptible to deterioration of water/oil repellency when it is washed or in heavy rain.A method for producing a water/oil repellent composition which comprises polymerizing a monomer component comprising the following monomer (a) in coexistence with the following compound (x) in a medium in the presence of a surfactant and a polymerization initiator: monomer (a) is a compound of the formula (Z—Y)nX wherein Z is a C1-20 polyfluoroalkyl group or the like, Y is a bivalent organic group or a single bond, n is 1 or 2, and X is a polymerizable unsaturated group; and the compound (x) is a compound having at least two groups of —(CH2)a—CHR1—(CH2)b—SH, wherein R1 is a methyl group or an ethyl group, a is an integer of from 0 to 2, and b is 0 or 1.
    • 本发明提供一种斥水斥油剂组合物的制造方法,其能够对制品的表面赋予斥水斥油性,并具有优异的耐久性(耐洗涤耐久性和耐雨性),耐水斥油性低的物品 当洗涤或大雨时易受水/拒油性的劣化。 一种防水斥油剂组合物的制造方法,其特征在于,在表面活性剂和聚合引发剂:单体(a)的存在下,在介质中,将包含下述单体(a)的单体成分与下列化合物(x)共存, 是式(Z-Y)n X的化合物,其中Z是C 1-20多氟烷基等,Y是二价有机基团或单键,n是1或2,X是可聚合不饱和基团; 化合物(x)是具有至少两个 - (CH 2)a -CHR 1-(CH 2)b -SH的基团的化合物,其中R 1是甲基或乙基,a是0-2的整数 ,b为0或1。
    • 10. 发明申请
    • WATER/OIL REPELLENT COMPOSITION AND ARTICLE
    • 水/油组合物和物品
    • US20100179287A1
    • 2010-07-15
    • US12731489
    • 2010-03-25
    • Kazunori SugiyamaYuuichi OomoriMinako Shimada
    • Kazunori SugiyamaYuuichi OomoriMinako Shimada
    • C09K3/18C08L27/12
    • D06M15/277C09K3/18D06M2200/11D06M2200/12D06M2200/35
    • To provide a water/oil repellent composition which can impart water/oil repellency with excellent friction durability to a surface of an article, even though while having structural units based on a monomer having an Rf group having at most 6 carbon atoms, structural units based on a monomer having an Rf group having at least 8 carbon atoms are reduced as much as possible, and an article which has little impact on environment and is less susceptible to deterioration of water/oil repellency by friction.A water/oil repellent composition which comprises polymer (A) having units of monomer (a) and units of monomer (b), having no units of monomer (c) and having at least 15 mass % and less than 45 mass % of fluorine atoms, and polymer (B) having units of monomer (a), having no units of monomer (c) and having at least 45 mass % of fluorine atoms: monomer (a): a monomer having a C4-6 Rf group; monomer (b): a monomer having an alkyl group having at least 12 carbon atoms, vinyl chloride or vinylidene chloride; monomer (c): a monomer having Rf group having at least 8 carbon atoms.
    • 为了提供一种斥油斥油剂组合物,即使具有基于具有至多6个碳原子的Rf基团的单体的结构单元,也可以赋予防水/拒油性,对制品的表面具有优异的摩擦耐久性, 对具有至少8个碳原子的Rf基团的单体尽可能地减少,并且对环境影响小并且不易受摩擦导致的斥水斥斥性影响的物品。 一种斥水斥油剂组合物,其包含具有单体(a)单元和单体(b)单元的单体(c)单元的聚合物(A),并且具有至少15质量%且小于45质量%的氟 原子和具有单体(a)单元的聚合物(B),不具有单体(c)单元,并且具有至少45质量%的氟原子:单体(a):具有C4-6RR基团的单体; 单体(b):具有至少12个碳原子的烷基的单体,氯乙烯或偏二氯乙烯; 单体(c):具有至少8个碳原子的具有Rf基团的单体。