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    • 2. 发明授权
    • Polymer dye
    • 聚合物染料
    • US08816040B2
    • 2014-08-26
    • US13461933
    • 2012-05-02
    • Takaki KanbaraJunpei KuwabaraHikaru YamadaNobutaka Fujimoto
    • Takaki KanbaraJunpei KuwabaraHikaru YamadaNobutaka Fujimoto
    • C08G73/06
    • C08G73/02C09B69/101C09B69/104C09B69/109
    • A polymer dye has repeating units of formula (I): Each of R1, R2, and R3 is independently a monocyclic carbocyclic group, a condensed polycyclic carbocyclic group, a monocyclic heterocyclic group, or a condensed polycyclic heterocyclic group. In any case, each of R1, R2, and R3 independently may have a substituent. R1 is a divalent group, and R2 and R3 are monovalent groups. D is an organic dye group and n is an integer of from 0 to 10. The polymer dye has a number-average molecular weight of from 500 to 500,000. The dye can be a component in a film. The dye can also be included in various industrial materials in automobiles; communication instruments, such as mobile phones, PDA, remote controllers, mobile information terminals, electronic dictionaries, and electronic organizers; home electric appliances; construction parts; and the like.
    • 聚合物染料具有式(I)的重复单元:R 1,R 2和R 3各自独立地为单环碳环基,稠合多环碳环基,单环杂环基或缩合多环杂环基。 在任何情况下,R 1,R 2和R 3各自独立地可以具有取代基。 R1是二价基团,R2和R3是一价基团。 D为有机染料基团,n为0〜10的整数。聚合物染料的数均分子量为500〜500,000。 染料可以是膜中的一种成分。 染料也可以包含在汽车的各种工业材料中; 通讯仪器,如手机,PDA,遥控器,移动信息终端,电子词典和电子组织者; 家用电器; 施工部件; 等等。
    • 3. 发明申请
    • POLYMER DYE
    • US20120329978A1
    • 2012-12-27
    • US13461933
    • 2012-05-02
    • Takaki KanbaraJunpei KuwabaraHikaru YamadaNobutaka Fujimoto
    • Takaki KanbaraJunpei KuwabaraHikaru YamadaNobutaka Fujimoto
    • C08G73/06
    • C08G73/02C09B69/101C09B69/104C09B69/109
    • A polymer dye has repeating units of formula (I): Each of R1, R2, and R3 is independently a monocyclic carbocyclic group, a condensed polycyclic carbocyclic group, a monocyclic heterocyclic group, or a condensed polycyclic heterocyclic group. In any case, each of R1, R2, and R3 independently may have a substituent. R1 is a divalent group, and R2 and R3 are monovalent groups. D is an organic dye group and n is an integer of from 0 to 10. The polymer dye has a number-average molecular weight of from 500 to 500,000. The dye can be a component in a film. The dye can also be included in various industrial materials in automobiles; communication instruments, such as mobile phones, PDA, remote controllers, mobile information terminals, electronic dictionaries, and electronic organizers; home electric appliances; construction parts; and the like.
    • 聚合物染料具有式(I)的重复单元:R 1,R 2和R 3各自独立地为单环碳环基,稠合多环碳环基,单环杂环基或稠合多环杂环基。 在任何情况下,R 1,R 2和R 3各自独立地可以具有取代基。 R1是二价基团,R2和R3是一价基团。 D为有机染料基团,n为0〜10的整数。聚合物染料的数均分子量为500〜500,000。 染料可以是膜中的一种成分。 染料也可以包含在汽车的各种工业材料中; 通讯仪器,如手机,PDA,遥控器,移动信息终端,电子词典和电子组织者; 家用电器; 施工部件; 等等。
    • 4. 发明授权
    • Method for producing crosslinked poly(meth)acrylate compound
    • 交联聚(甲基)丙烯酸酯化合物的制备方法
    • US07816457B2
    • 2010-10-19
    • US11569819
    • 2005-05-30
    • Nobutaka FujimotoKoji UedaMasato Fujikake
    • Nobutaka FujimotoKoji UedaMasato Fujikake
    • C08F20/02C08F16/00C08F26/06C08F2/00
    • H01M10/052C08F8/00C08F220/36C08F222/1006H01M4/137H01M4/1399H01M4/60H01M4/602C08F20/00
    • It is an object of the invention to provide a method of producing a crosslinked poly(meth)acrylic acid compound, in particular a method of producing a crosslinked poly(meth)acrylic acid nitroxide compound, which is a radical compound excellent in solvent stability.The invention is a method of producing a crosslinked poly(meth)acrylic acid compound resulting from crosslinking of a poly(meth)acrylic acid compound represented by the general formula (1): (in the formula, n Z1s represent a hydrogen atom(s) and/or an oxygen atom(s) having one unpaired electron, R represents a hydrogen atom or a methyl group and n represents an integer of 5 to 1000000), which method is characterized by comprising a polymerization step of polymerizing a (meth)acrylic acid compound represented by the general formula (2): (in the formula, Z2 represents a hydrogen atom when Z1 is a hydrogen atom, or a hydrogen atom or an oxygen atom having one unpaired electron when Z1 is an oxygen atom having one unpaired electron; and R represents the same group as R in the above general formula (1)) in the presence of a crosslinking agent.
    • 本发明的目的是提供一种生产交联聚(甲基)丙烯酸化合物的方法,特别是制备交联聚(甲基)丙烯酸氮氧化合物的方法,其是溶剂稳定性优异的自由基化合物。 本发明是由通式(1)表示的聚(甲基)丙烯酸化合物交联而得到的交联聚(甲基)丙烯酸化合物的制造方法:(式中,n Z1表示氢原子 )和/或具有一个不成对电子的氧原子,R表示氢原子或甲基,n表示5〜1000000的整数),该方法的特征在于包括聚合(甲基) 由通式(2)表示的丙烯酸化合物:(式中Z 1表示氢原子,Z 1表示氢原子时的氢原子,Z 1表示不成对的氧原子时的氢原子或具有1个不成对电子的氧原子) 电子; R表示与上述通式(1)中的R相同的基团)。
    • 5. 发明申请
    • Method for Producing Crosslinked Poly (Meth) Acrylate Compound
    • 生产交联聚(甲基)丙烯酸酯化合物的方法
    • US20080319149A1
    • 2008-12-25
    • US11569819
    • 2005-05-30
    • Nobutaka FujimotoKoji UedaMasato Fujikake
    • Nobutaka FujimotoKoji UedaMasato Fujikake
    • C08F226/06C08F2/00
    • H01M10/052C08F8/00C08F220/36C08F222/1006H01M4/137H01M4/1399H01M4/60H01M4/602C08F20/00
    • It is an object of the invention to provide a method of producing a crosslinked poly(meth)acrylic acid compound, in particular a method of producing a crosslinked poly(meth)acrylic acid nitroxide compound, which is a radical compound excellent in solvent stability.The invention is a method of producing a crosslinked poly(meth)acrylic acid compound resulting from crosslinking of a poly(meth)acrylic acid compound represented by the general formula (1): (in the formula, n Z1s represent a hydrogen atom(s) and/or an oxygen atom(s) having one unpaired electron, R represents a hydrogen atom or a methyl group and n represents an integer of 5 to 1000000), which method is characterized by comprising a polymerization step of polymerizing a (meth)acrylic acid compound represented by the general formula (2): (in the formula, Z2 represents a hydrogen atom when Z1 is a hydrogen atom, or a hydrogen atom or an oxygen atom having one unpaired electron when Z1 is an oxygen atom having one unpaired electron; and R represents the same group as R in the above general formula (1)) in the presence of a crosslinking agent.
    • 本发明的目的是提供一种生产交联聚(甲基)丙烯酸化合物的方法,特别是制备交联聚(甲基)丙烯酸氮氧化合物的方法,其是溶剂稳定性优异的自由基化合物。 本发明是由通式(1)表示的聚(甲基)丙烯酸化合物交联而得到的交联聚(甲基)丙烯酸化合物的制造方法:(式中,n Z1表示氢原子 )和/或具有一个不成对电子的氧原子,R表示氢原子或甲基,n表示5〜1000000的整数),该方法的特征在于包括聚合(甲基) 由通式(2)表示的丙烯酸化合物:(式中Z 1表示氢原子,Z 1表示氢原子时的氢原子,Z 1表示不成对的氧原子时的氢原子或具有1个不成对电子的氧原子) 电子; R表示与上述通式(1)中的R相同的基团)。
    • 7. 发明授权
    • Process for production of crosslinked poly(meth) acrylic acid nitroxide compounds
    • 交联聚(甲基)丙烯酸硝基氧化合物的制备方法
    • US08252869B2
    • 2012-08-28
    • US11989722
    • 2006-06-29
    • Nobutaka FujimotoKoji UedaMasato Fujikake
    • Nobutaka FujimotoKoji UedaMasato Fujikake
    • C08F8/06C08F26/06
    • H01M4/60C08F8/06C08F220/34C08F220/36C08F2800/10H01M4/608C08F2222/1013
    • The present invention relates to a crosslinked poly(meth)acrylic acid nitroxide compound resulting from crosslinking of a poly(meth)acrylic acid nitroxide compound, and an object of the present invention is to provide a method of inexpensively and easily producing a crosslinked poly(meth)acrylic acid nitroxide compound having a high radical concentration.The present invention is a method of producing a crosslinked poly(meth)acrylic acid nitroxide compound including a repeating unit represented by the general formula (2): (in the formula, R represents a hydrogen atom or a methyl group), comprising a nitroxidation step carried out in a state that a crosslinked poly(meth)acrylic acid imino compound resulting from crosslinking of a poly(meth)acrylic acid imino compound including a repeating unit represented by the general formula (1): (in the formula, R represents the same group as that represented by R in said general formula (2)) is dispersed in water.
    • 本发明涉及由聚(甲基)丙烯酸氮氧化合物交联而得到的交联的聚(甲基)丙烯酸氮氧化合物,本发明的目的是提供一种廉价且容易地制备交联聚( 甲基)丙烯酸硝基氧化合物。 本发明是一种包含由通式(2)表示的重复单元的交联聚(甲基)丙烯酸氮氧化合物的方法:(式中,R表示氢原子或甲基),其包含硝基氧化 在由通式(1)表示的重复单元的聚(甲基)丙烯酸亚氨基化合物交联而得到的交联聚(甲基)丙烯酸亚氨基化合物:(式中,R表示 与通式(2)中的R表示的基团相同)分散在水中。
    • 9. 发明申请
    • METHOD FOR PRODUCING ALIPHATIC POLYCARBONATE
    • 生产聚氨酯的方法
    • US20120123066A1
    • 2012-05-17
    • US13321118
    • 2010-05-06
    • Nobutaka FujimotoMasafumi Okamoto
    • Nobutaka FujimotoMasafumi Okamoto
    • C08G64/34
    • C08G64/34C08G64/42
    • The present invention provides an aliphatic polycarbonate production method which, using carbon dioxide and an epoxide, easily produces aliphatic polycarbonates having a low metal catalyst content.The invention relates to an aliphatic polycarbonate production method which includes a step of polymerization by reacting carbon dioxide with an epoxide in the presence of a metal catalyst; and a step of treating a polymer obtainable in the polymerization step with a surfactant. High-purity aliphatic polycarbonate having a low metal catalyst content can be easily provided by the aliphatic polycarbonate production method of the invention.
    • 本发明提供一种使用二氧化碳和环氧化物容易制造具有低金属催化剂含量的脂族聚碳酸酯的脂肪族聚碳酸酯制造方法。 本发明涉及一种脂族聚碳酸酯制备方法,其包括在金属催化剂存在下使二氧化碳与环氧化物反应的聚合步骤; 以及用表面活性剂处理在聚合步骤中可获得的聚合物的步骤。 通过本发明的脂肪族聚碳酸酯制造方法可以容易地提供具有低金属催化剂含量的高纯度脂肪族聚碳酸酯。