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    • 3. 发明授权
    • Heat accumulating material
    • 蓄热材料
    • US4406804A
    • 1983-09-27
    • US303985
    • 1981-09-21
    • Takahiro WadaShoichi IshiharaRyoichi Yamamoto
    • Takahiro WadaShoichi IshiharaRyoichi Yamamoto
    • C09K5/06C09K3/34C09K5/00
    • C09K5/063
    • The heat accumulating material provided according to this invention makes use of the latent heat of fusion of sodium acetate trihydrate, and it comprises, as blended in a system consisting of sodium acetate and water, at least one nucleation catalyst selected from the group of compounds consisting of tetrasodium pyrophosphate, trisodium monohydrogenpyrophosphate, disodium dihydrogenpyrophosphate and monosodium trihydrogenpyrophosphate. In use of this heat accumulating material, the sodium acetate trihydrate would not be overcooled owing to the overcooling preventing function of the nucleation catalyst but is unfailingly crystallized at a temperature close to the fusion point thereof to radiate latent heat of fusion. The overcooling preventing performance of the nucleation catalyst is not deteriorated even if it is subjected to more than 1,000 cycles of repetition of fusion and solidification, and thus the heat accumulating material maintains a very stabilized heat absorbing and radiating capacity.
    • 根据本发明提供的蓄热材料利用乙酸钠三水合物的融合潜热,并且包括在由乙酸钠和水组成的体系中共混的至少一种成核催化剂,所述成核催化剂选自: 焦磷酸四钠,一氢焦磷酸三钠,焦磷酸二氢二钠和焦磷酸三钠。 在使用这种蓄热材料时,由于成核催化剂的过冷预防功能,乙酸钠三水合物不会过冷,而是在接近其熔点的温度下不断地结晶,从而辐射潜热融化。 成核催化剂的过冷预防性能即使经历1000次以上的熔融和凝固重复循环也不会劣化,因此蓄热材料保持非常稳定的吸热和辐射能力。
    • 4. 发明授权
    • Heat accumulating material
    • 蓄热材料
    • US4431558A
    • 1984-02-14
    • US397450
    • 1982-07-12
    • Takahiro WadaRyoichi Yamamoto
    • Takahiro WadaRyoichi Yamamoto
    • F28F23/02C09K5/06
    • C09K5/063
    • The heat accumulating material of this invention comprising three components of calcium chloride (CaCl.sub.2), urea [CO(NH.sub.2).sub.2 ] and water (H.sub.2 O) can have varied temperatures of heat accumulating and heat releasing between 15.degree. C. and 29.5.degree. C. by varying the proportion of said three components, and also has a large latent heat. Hence, much expectation can be placed on it as a heat accumulating material for air conditioning. Moreover, by adding BaFeO.sub.3-x (0.ltoreq.x.ltoreq.0.53) as a nucleating agent to the above-mentioned composition, supercooling can be greatly decreased and wider application of this heat accumulating material becomes possible.
    • 包含氯化钙(CaCl 2),尿素[CO(NH 2)2]和水(H 2 O)的三种组分的本发明的蓄热材料可以具有不同的蓄热温度和在15℃至29.5℃之间的放热温度。 通过改变所述三种成分的比例,也具有大的潜热。 因此,作为空调的蓄热材料,可以期待很多。 此外,通过向上述组合物中添加作为成核剂的BaFeO 3-x(0≤x≤0.53),可以大幅降低过冷却,能够更广泛地应用该蓄热材料。
    • 5. 发明授权
    • Heat accumulative material
    • 蓄热材料
    • US4426307A
    • 1984-01-17
    • US395707
    • 1982-07-06
    • Takahiro WadaRyoichi Yamamoto
    • Takahiro WadaRyoichi Yamamoto
    • C09K5/06
    • C09K5/063
    • A novel latent heat accumulative material capable of accumulating heat in a temperature range best suited for the storage of solar energy was obtained by adding an organic compound or compounds such as urea [CO(NH.sub.2).sub.2 ]to a system consisting of sodium acetate (CH.sub.3 CO.sub.2 Na) and water (H.sub.2 O). Further addition of a crystal nucleus forming material or materials such as sodium pyrophosphate decahydrate (Na.sub.4 P.sub.2 O.sub.7.10H.sub.2 O) to said composition could minimize supercooling and allowed a wider scope of application of the present heat accumulative material.
    • 通过在由乙酸钠(CH 3 CO 2 Na)组成的体系中加入有机化合物或诸如脲[CO(NH 2)2)等有机化合物,能够在最适合储存太阳能的温度范围内积累热量的新型潜热蓄热材料 )和水(H 2 O)。 进一步加入形成晶核的材料或诸如焦磷酸钠十水合物(Na 4 P 2 O7.10H 2 O)的材料可以使过冷却最小化,并允许现有的蓄热材料的应用范围更广。
    • 6. 发明授权
    • Supercooling inhibitor and process for preparing the same
    • 过冷抑制剂及其制备方法
    • US4381245A
    • 1983-04-26
    • US315456
    • 1981-10-27
    • Takahiro WadaShoichi IshiharaRyoichi Yamamoto
    • Takahiro WadaShoichi IshiharaRyoichi Yamamoto
    • C09K5/06C09K3/18C01B25/42
    • C09K5/063
    • A supercooling inhibitor comprising a supercooling inhibitor base having all or part of its surface coated with sodium acetate trihydrate. The supercooling inhibitor base comprises one or more members selected from the group consisting of sodium pyrophosphate (Na.sub.4 P.sub.2 O.sub.7), trisodium monohydrogen pyrophosphate (Na.sub.3 HP.sub.2 O.sub.7), disodium dihydrogen pyrophosphate (Na.sub.2 H.sub.2 P.sub.2 O.sub.7), monosodium trihydrogen pyrophosphate (NaH.sub.3 P.sub.2 O.sub.7), sodium pyrophosphate decahydrate (Na.sub.4 P.sub.2 O.sub.7.10H.sub.2 O), and disodium dihydrogen pyrophosphate hexahydrate (Na.sub.2 H.sub.2 P.sub.2 O.sub.7.6H.sub.2 O). The supercooling inhibitor of the present invention is useful for inhibiting the supercooling of sodium acetate trihydrate which is used as a heat regenerating material utilizing heat of fusion.
    • 一种过冷却抑制剂,其包含具有用乙酸钠三水合物包覆的其全部或部分表面的过冷抑制剂基质。 过冷却抑制剂基质包括选自焦磷酸钠(Na 4 P 2 O 7),焦磷酸氢二钠(Na 3 HP 2 O 7),焦磷酸二氢二钠(Na 2 H 2 P 2 O 7),焦磷酸三氢钠(NaH 3 P 2 O 7),焦磷酸钠十水合物(Na 4 P 2 O7.10H 2 O) ,和二水合焦磷酸二钠六水合物(Na2H2P2O7.6H2O)。 本发明的过冷却抑制剂可用于抑制作为利用热熔融热的热再生材料的乙酸钠三水合物的过冷。
    • 7. 发明授权
    • Aqueous pharmaceutical compositions
    • 水性药物组合物
    • US07612115B2
    • 2009-11-03
    • US11374450
    • 2006-03-13
    • Hidekazu SuzukiTakahiro WadaMasanobu KiritaMasanobu Takeuchi
    • Hidekazu SuzukiTakahiro WadaMasanobu KiritaMasanobu Takeuchi
    • A61K47/00A61K31/715A61K31/47
    • A61K31/5383A61K9/0048A61K47/10A61K47/12A61K47/38
    • The present invention has an object to provide an antibacterial aqueous pharmaceutical composition and an aqueous pharmaceutical composition which have a sufficiently low gelation temperature even when new quinolone antibacterial agents such as ofloxacin as the active ingredient and can be retained at the administration site for a long time by virtue of rapid viscosity increase after administration in spite of their being liquid at administration and thereby attain high availability of pharmaceutical agent.The present invention relates to an antibacterial aqueous pharmaceutical composition which comprises: 2.8 to 4 w/v % of methylcellulose, the 2 w/v % aqueous solution of which has a viscosity of 12 mPa·s or below at 20° C.; 1.5 to 2.3 w/v % of citric acid; 2 to 4 w/v % of polyethylene glycol; and 0.1 to 0.5 w/v % of ofloxacin.
    • 本发明的目的在于提供一种抗菌水性药物组合物和含水药物组合物,即使新的喹诺酮类抗菌剂如氧氟沙星作为活性成分,也能够在施用部位长时间保留,具有足够低的凝胶化温度 由于施用后的粘度快速增加,尽管它们在施用时是液体,从而获得药剂的高可用性。 本发明涉及一种抗菌水性药物组合物,其包含:2.8〜4w / v%的甲基纤维素,其2w / v%水溶液在20℃下的粘度为12mPa·s或更低。 1.5至2.3w / v%的柠檬酸; 2至4w / v%的聚乙二醇; 和0.1至0.5w / v%的氧氟沙星。