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1. 发明授权

US5061307A Crystallized glass having natural-marble-like surface patterns and method of producing the same 失效
标题翻译：具有天然大理石样表面图案的结晶玻璃及其制造方法
公开(公告)号：US5061307A
公开(公告)日：1991-10-29
申请号：US636873
申请日：1991-01-02
申请人： Takahiro Matano , Yoshio Hashibe , Masayuki Ninomiya , Takehiro Shibuya
发明人： Takahiro Matano , Yoshio Hashibe , Masayuki Ninomiya , Takehiro Shibuya
IPC分类号： C03C10/00 , C03C10/04
CPC分类号： C03C10/0045 , C03C10/0054
摘要： A crystallized glass having natural-marble-like surface patterns comprising 45 to 75 wt. % of SiO.sub.2, 1 to 25 wt. % of Al.sub.2 O.sub.3, 1 to 20 wt. % of CaO, 0.5 to 17 wt. % of MgO, 0.1 to 18 wt. % of BaO, 0 to 18 wt. % of ZnO, 1 to 15 wt. % of Na.sub.2 O, 0 to 7 wt. % of K.sub.2 O, 0 to 5 wt. % of Li.sub.2 O, 0 to 10 wt. % of B.sub.2 O.sub.3, 0 to 10 wt. % of P.sub.2 O.sub.5, 0 to 1 wt. % of As.sub.2 O.sub.3, and 0 to 1 wt. % of Sb.sub.2 O.sub.3, substantially free from nucleating agent, in which diopside type crystals are precipitated, and a method of producing the crystallized glass are disclosed.
摘要翻译：具有天然大理石样表面图案的结晶玻璃，其包含45至75重量％％的SiO 2，1〜25wt。％的Al 2 O 3，1〜20wt。 CaO％，0.5〜17重量％％的MgO，0.1〜18wt。％的BaO，0〜18wt。％的ZnO，1〜15wt。％的Na 2 O，0〜7wt。 K 2 O％，0〜5重量％％的Li 2 O，0〜10wt。％的B2O3，0〜10wt。％的P 2 O 5，0〜1重量％％As2O3，0〜1wt。基本上不含成核剂的Sb 2 O 3，其中析出透辉石型晶体的％，以及生产结晶玻璃的方法。

2. 发明授权

US5089345A Crystallized glass article having an irregular rough surface pattern and a method for producing the same 失效
标题翻译：具有不规则粗糙表面图案的结晶玻璃制品及其制造方法
公开(公告)号：US5089345A
公开(公告)日：1992-02-18
申请号：US430632
申请日：1989-11-01
申请人： Yoshio Hashibe , Takahiro Matano , Takehiro Shibuya , Takashi Sakane , Yasuhiro Baba , Masanori Moritake
发明人： Yoshio Hashibe , Takahiro Matano , Takehiro Shibuya , Takashi Sakane , Yasuhiro Baba , Masanori Moritake
IPC分类号： B32B17/06 , C03B19/06 , E04C2/54
CPC分类号： C03B19/06 , Y10T428/24942 , Y10T428/252
摘要： In a crystallized glass article consisting of crystallized glass masses fusion bonded together and having a principal surface, said principal surface having a surface pattern determined by said masses in a surface layer including said principal surface, said small crystallized glass masses in said surface layer are mainly of flaky crystallized glass pieces, each being a relatively large flattened piece, said flaky pieces overlapping one another at random to make said principal surface rough, said crystallized glass masses in another layer adjacent to and fused to said surface layer being considerably smaller than said flaky pieces. The article is produced by preparing flaky pieces and the smaller masses both of a SiO.sub.2 --Al.sub.2 O.sub.3 --CaO crystallizable glass, putting the former pieces on a bottom of a mold to form a flaky-piece layer, then putting the latter masses on the flaky-piece layer to form a small-mass layer, and heat treating the both layers at a temperature higher than a softening point of the crystallizable glass to fusion bond the pieces and masses together as well as crystallizing the glass.
摘要翻译：在由结晶化玻璃质量结合在一起并具有主表面的结晶玻璃制品中，所述主表面具有由包括所述主表面的表面层中的所述质量确定的表面图案，所述表面层中的所述小结晶玻璃质量主要片状结晶玻璃片各自是相当大的扁平片，所述片状片随机地彼此重叠以使所述主表面粗糙，所述相邻并融合到所述表面层的另一层中的结晶玻璃质量比所述片状物件该制品通过制备SiO 2 -Al 2 O 3 -EA CaO可结晶玻璃的片状片和较小的质量块，将前者放在模具的底部上以形成片状层，然后将后者放在片状片上，以形成小质量层，并且在高于可结晶玻璃的软化点的温度下对两层进行热处理，以将这些块和块结合在一起并使玻璃结晶。

3. 发明授权

US5066524A Crystallized glass article with colored small masses dispersed in a surface thereof 失效
标题翻译：具有分散在其表面中的着色小质量的结晶玻璃制品
公开(公告)号：US5066524A
公开(公告)日：1991-11-19
申请号：US412851
申请日：1989-09-26
申请人： Yasuhiro Baba , Masanori Moritake , Takashi Sakane , Yoshio Hashibe , Takehiro Shibuya
发明人： Yasuhiro Baba , Masanori Moritake , Takashi Sakane , Yoshio Hashibe , Takehiro Shibuya
IPC分类号： C03C10/02 , B44F9/04 , C03C10/04 , C03C17/04
CPC分类号： C03C17/04 , B44F9/04 , Y10T428/22 , Y10T428/24802
摘要： A crystallized glass article with a colored surface pattern, which comprises a crystallized glass substrate having a surface and small glass masses having a color different from the substrate and dispersed and fusion-bonded in the surface to form the colored surface pattern. The crystallized glass article is produced by depositing and dispersing small glass masses with a color on a surface of a substrate of a crystallizable glass with a different color which can precipitate crystals therein with softening and deforming by heat-treating at a heat treating temperature higher than the softening point of the crystallizable glass, then heating the substrate together with the small glass masses at the heat treating temperature.
摘要翻译：具有着色表面图案的结晶玻璃制品，其包括具有表面的结晶玻璃基板和具有与基板不同的颜色的小玻璃块，并且在表面中分散和熔合以形成着色表面图案。结晶化玻璃制品通过在具有不同颜色的可结晶玻璃的基材的表面上沉积和分散小玻璃块而制成，其可以通过在高于可结晶玻璃的软化点，然后在热处理温度下与小玻璃块一起加热基底。

4. 发明授权

US5275978A Colored crystallized glass article and method for producing the same 失效
标题翻译：彩色结晶玻璃制品及其制造方法
公开(公告)号：US5275978A
公开(公告)日：1994-01-04
申请号：US4663
申请日：1993-01-14
申请人： Takehiro Shibuya , Takashi Sakane , Yoshio Hashibe
发明人： Takehiro Shibuya , Takashi Sakane , Yoshio Hashibe
IPC分类号： C03C1/06 , C03C10/00 , C03C10/04 , C03C14/00
CPC分类号： C03C1/06 , C03C10/0036 , C03C14/004 , C03C2214/04 , C03C2214/20
摘要： A crystallized glass article having a surface pattern like granite, marble or other natural stones with a line pattern of a desired color or colors, which is formed by fusion bonding small masses of a crystallizable glass material mixed with inorganic pigment powder at a heat-treating temperature higher than the softening point. The surface pattern comprises crystallized glass areas defined by the small masses in the surface layer of the article and the colored line pattern defined by the pigment dispersed in the interfaces between adjacent ones of the small masses in the surface layer.
摘要翻译：一种具有花岗岩，大理石或其他天然石材的表面图案的结晶玻璃制品，其具有所需颜色或颜色的线条图案，其通过将小块可结晶玻璃材料与无机颜料粉末混合而形成，所述可结晶玻璃材料在热处理温度高于软化点。表面图案包括由物品表面层中的小质量限定的结晶玻璃区域和由分散在表面层中的相邻小块之间的界面中的颜料限定的着色线图案。

5. 发明授权

US5034353A Biocompatible glass ceramics 失效
标题翻译：生物相容性玻璃陶瓷
公开(公告)号：US5034353A
公开(公告)日：1991-07-23
申请号：US443743
申请日：1989-11-30
申请人： Takehiro Shibuya , Akira Matsui , Yoshinori Morita , Kiyoyuki Okunaga , Masayuki Ninomiya
发明人： Takehiro Shibuya , Akira Matsui , Yoshinori Morita , Kiyoyuki Okunaga , Masayuki Ninomiya
IPC分类号： A61K6/027 , A61F2/00 , A61K6/06 , A61L27/10 , A61L27/12 , C03C3/097 , C03C3/112 , C03C4/00 , C03C10/02 , C03C10/16
CPC分类号： C03C4/0007 , A61K6/0085 , A61K6/0094 , A61K6/0215 , A61K6/024 , A61K6/0273 , A61L27/10 , A61L27/12 , C03C10/16 , C03C3/097 , C03C3/112 , A61F2310/00293
摘要： A high-mechanical strength biocompatible crystallized glass essentially comprises both crystallines consisting of tetrasilicic fluorine mica series and calcium phosphate series. The crystallized glass has substantially non-sodium oxide and useful in a dental medical care, as repairing material of tooth.
摘要翻译：高机械强度生物相容性结晶玻璃基本上包含由四硅氟云母系列和磷酸钙系列组成的结晶。结晶玻璃具有基本上非氧化钠并且可用于牙科医疗护理，作为牙齿的修复材料。

6. 发明申请

US20120046385A1 BONE CEMENT COMPOSITION AND PRODUCTION METHOD THEREOF, AND KIT FOR PRODUCING THE SAME 有权
标题翻译：骨水泥组合物及其生产方法及其生产方法
公开(公告)号：US20120046385A1
公开(公告)日：2012-02-23
申请号：US13202850
申请日：2010-02-23
申请人： Takashi Nakamura , Koji Goto , Takehiro Shibuya , Yoshimichi Ueda , Tokuo Suita , Hiroaki Nishii
发明人： Takashi Nakamura , Koji Goto , Takehiro Shibuya , Yoshimichi Ueda , Tokuo Suita , Hiroaki Nishii
IPC分类号： A61L24/06
CPC分类号： A61L24/0089 , A61L27/446 , A61L2430/02 , C08L33/10
摘要： The invention has as its objects the provision of a bone cement composition and a bone cement composition kit for obtaining the bone cement composition having bioactivity and capable of forming a hardened material having high mechanical strength practically required, and the provision of a bone cement formed material having both bioactivity and high mechanical strength practically required and a production method thereof.The bone cement composition of the invention contains titanium dioxide particles having a median diameter of 0.5 to 7.0 μm as measured by a laser diffraction/scattering type particle size distribution analyzer and a BET specific surface area of 0.5 to 7.0 m2/g as measured by a nitrogen adsorption method, and a base-forming component comprising a (meth)acrylate polymer and a (meth)acrylate monomer, wherein the content of the titanium dioxide particles is 5 to 50% by mass based on the total mass of the composition.
摘要翻译：本发明的目的是提供一种骨水泥组合物和骨水泥组合物试剂盒，用于获得具有生物活性的骨水泥组合物，并且能够形成具有实际需要的高机械强度的硬化材料，并且提供骨水泥成形材料具有生物活性和实际需要的高机械强度及其制造方法。本发明的骨水泥组合物含有通过激光衍射/散射型粒度分布分析仪测定的中值粒径为0.5〜7.0μm，BET比表面积为0.5〜7.0m 2 / g的二氧化钛粒子，氮气吸附法和含有（甲基）丙烯酸酯系聚合物和（甲基）丙烯酸酯单体的基材形成成分，其中，相对于组合物的总质量，二氧化钛粒子的含量为5〜50质量％。

7. 发明授权

US4835121A Infrared transparent glass ceramic articles with beta-quarts solid solution crystals without any other crystals 失效
标题翻译：红外透明玻璃陶瓷制品，具有β-quarts固溶体晶体，无任何其他晶体
公开(公告)号：US4835121A
公开(公告)日：1989-05-30
申请号：US11298
申请日：1987-02-04
申请人： Takehiro Shibuya , Kazuhiro Matsui , Makoto Matsumoto
发明人： Takehiro Shibuya , Kazuhiro Matsui , Makoto Matsumoto
IPC分类号： C03C3/085 , C03C4/10 , C03C10/00 , C03C10/14 , H05B3/74
CPC分类号： H05B3/74 , C03C10/0027 , C03C10/0045 , C03C4/10 , Y02B30/26
摘要： An infrared transparent glass ceramic article is useful for top plates of cooking stoves and has a black appearance but an infrared transmittance of about 80% or more for an infrared light of a wavelength 1,500 nm, and .beta.-quartz solid solution crystals substantially alone dispersed within glassy matrix without any other crystals. The article consists essentially, by weight, of 60-72% SiO.sub.2, 14-28% Al.sub.2 O.sub.3, 2.5-5.5% Li.sub.2 O, 0.1-0.9% MgO, 0.1-0.9% ZnO, 3-6% TiO.sub.2, 0.03-0.5% V.sub.2 O.sub.5, 0.1-1% Na.sub.2 O, 0-1% K.sub.2 O, 0-2% CaO, 0-2% BaO, 0-2% PbO, 0-2% As.sub.2 O.sub.3, 0-3% ZrO.sub.2, and 0-3% P.sub.d O.sub.5. The article is produced by forming a desired shape of glass article having the ingredients, heating the glass article at a temperature of 650.degree.-800.degree. C. to nucleate in the glass, heating the glass article at a temperature of 800.degree.-950.degree. C. to thereby precipitate .beta.-quartz solid solution crystals alone in the glass, and cooling the article to the room temperature.
摘要翻译：红外透明玻璃陶瓷制品对于烹饪炉的顶板是有用的，并且对于波长为1500nm的红外光具有黑色外观，但是红外透射率为约80％或更高，而基本上分散在其中的β-石英固溶体晶体没有任何其他晶体的玻璃质基体。该制品主要由60-72％SiO 2，14-28％Al 2 O 3，2.5-5.5％Li 2 O，0.1-0.9％MgO，0.1-0.9％ZnO，3-6％TiO 2，0.03-0.5％V 2 O 5 ，0.1-1％Na2O，0-1％K2O，0-2％CaO，0-2％BaO，0-2％PbO，0-2％As2O3,0-3％ZrO2和0-3％PdO5。通过形成具有这些成分的所需形状的玻璃制品，在650-800℃的温度下加热该玻璃制品以在玻璃中成核，制得该制品，在800-950℃的温度下加热该玻璃制品从而将β-石英固溶体晶体单独沉淀在玻璃中，并将制品冷却至室温。

8. 发明授权

US3966372A Injection molding apparatus for forming a composite, foam-skin, article 失效
标题翻译：用于形成复合材料，泡沫 - 皮肤，制品的注塑设备
公开(公告)号：US3966372A
公开(公告)日：1976-06-29
申请号：US470662
申请日：1974-05-16
申请人： Akio Yasuike , Takehiro Shibuya , Kaoru Toyouchi , Susumu Imai
发明人： Akio Yasuike , Takehiro Shibuya , Kaoru Toyouchi , Susumu Imai
IPC分类号： B29C45/16 , B29D27/00
CPC分类号： B29C45/1645 , Y10S264/83
摘要： A first thermoplastic resin for forming the shell of an article is charged into the front portion of an injection cylinder and a second thermoplastic resin for forming the core of the article is charged into the rear portion of the injection cylinder. Both resins are substantially separated, being in contact only a central area of the cross-sectional plane of the injection cylinder. These thermoplastic resins are injected in a mass into a mold cavity with the second resin enveloped by the first resin, and finally solidified in the mold cavity resulting in a molded article having sandwich construction. Various sandwich articles can be obtained easily by means of a single injection molding machine. The process also allows repeated injection operations without exposure of the core material on the surface of the molded article.
摘要翻译：将用于形成制品外壳的第一热塑性树脂装入注射圆筒的前部，并将用于形成制品的芯的第二热塑性树脂装入注射圆筒的后部。两种树脂基本上分开，仅与注射筒的横截面平面的中心区域接触。将这些热塑性树脂以质量注射到模腔中，第二树脂被第一树脂包封，最终在模腔中固化，形成具有夹层结构的模塑制品。可以通过单个注射成型机容易地获得各种夹层物品。该方法还允许重复的注射操作，而不会在模制品的表面上暴露核心材料。

9. 发明授权

US08658713B2 Bone cement composition and production method thereof, and kit for producing the same 有权
标题翻译：骨水泥组合物及其制造方法以及其制造用试剂盒
公开(公告)号：US08658713B2
公开(公告)日：2014-02-25
申请号：US13202850
申请日：2010-02-23
申请人： Takashi Nakamura , Koji Goto , Takehiro Shibuya , Yoshimichi Ueda , Tokuo Suita , Hiroaki Nishii
发明人： Takashi Nakamura , Koji Goto , Takehiro Shibuya , Yoshimichi Ueda , Tokuo Suita , Hiroaki Nishii
IPC分类号： A61F2/28 , C08K3/22
CPC分类号： A61L24/0089 , A61L27/446 , A61L2430/02 , C08L33/10
摘要： A bone cement composition which contains titanium dioxide particles having a median diameter of 0.5 to 7.0 μm as measured by a laser diffraction/scattering particle size distribution analyzer and a BET specific surface area of 0.5 to 7.0 m2/g as measured by a nitrogen adsorption method, and a base-forming component comprising a (meth)acrylate polymer and a (meth)acrylate monomer, wherein the content of the titanium dioxide particles is 5 to 50% by mass based on the total mass of the composition. The bone cement composition has bioactivity and is capable of forming a hardened material having a high mechanical strength.
摘要翻译：一种骨水泥组合物，其含有通过激光衍射/散射粒度分布分析仪测定的中值粒径为0.5〜7.0μm的二氧化钛粒子，并且通过氮吸附法测定的BET比表面积为0.5〜7.0m 2 / g ，和包含（甲基）丙烯酸酯聚合物和（甲基）丙烯酸酯单体的基底形成组分，其中二氧化钛颗粒的含量相对于组合物的总质量为5〜50质量％。骨水泥组合物具有生物活性并且能够形成具有高机械强度的硬化材料。

10. 发明申请

US20120035296A1 BONE CEMENT COMPOSITION, BONE CEMENT COMPOSITION KIT AND FORMING METHOD OF BONE CEMENT HARDENED MATERIAL 有权
标题翻译：骨水泥组合物，骨水泥组合物包装和骨水泥硬化材料的成型方法
公开(公告)号：US20120035296A1
公开(公告)日：2012-02-09
申请号：US13203221
申请日：2010-02-23
申请人： Takashi Nakamura , Koji Goto , Takehiro Shibuya , Yoshimichi Ueda , Tokuo Suita , Masashi Imamura , Hiroaki Nishii
发明人： Takashi Nakamura , Koji Goto , Takehiro Shibuya , Yoshimichi Ueda , Tokuo Suita , Masashi Imamura , Hiroaki Nishii
IPC分类号： A61K47/02 , C08L33/10
CPC分类号： A61L24/0089 , A61L24/06 , A61L2430/02 , C08L33/06
摘要： The invention has as its objects the provision of a bone cement composition, a bone cement composition kit for obtaining the bone cement composition, and a production method of a bone cement hardened material, which are short in doughing time that is a time required to become a state in which a good handling operation can be conducted, and have consequently capable of achieving a high working efficiency by shortening the time required before the handling operation is started.The bone cement composition of the invention contains large-diameter (meth)acrylate polymer particles having an average particle diameter of 10 to 60 μm, small-diameter (meth)acrylate polymer particles having an average particle diameter of 0.1 to 2.0 μm, a (meth)acrylate monomer and a polymerization initiator, wherein the content of the small-diameter (meth)acrylate polymer particles is 5 to 30% by mass based on the total mass of the small-diameter (meth)acrylate polymer particles and the large-diameter (meth)acrylate polymer particles.
摘要翻译：本发明的目的是提供一种骨水泥组合物，用于获得骨水泥组合物的骨水泥组合物试剂盒和骨水泥硬化材料的制造方法，其在加热时间短，是成为能够进行良好的操作操作的状态，因此能够通过缩短开始处理操作之前所需的时间来实现高工作效率。本发明的骨水泥组合物含有平均粒径为10〜60μm的大直径（甲基）丙烯酸酯聚合物粒子，平均粒径为0.1〜2.0μm的小直径（甲基）丙烯酸酯聚合物粒子，（（甲基）丙烯酸酯单体和聚合引发剂，其中小直径（甲基）丙烯酸酯聚合物颗粒的含量相对于小直径（甲基）丙烯酸酯聚合物颗粒的总质量为5〜30质量％（甲基）丙烯酸酯聚合物颗粒。

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