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    • 2. 发明申请
    • ORGANIC ELECTROLUMINESCENCE ELEMENT
    • 有机电致发光元件
    • US20090134779A1
    • 2009-05-28
    • US11915348
    • 2006-05-23
    • Shin KawamiTaishi TsujiHideki SatoMasayoshi Yabe
    • Shin KawamiTaishi TsujiHideki SatoMasayoshi Yabe
    • H01J1/63
    • H01L51/5016H01L51/005H01L51/0072H01L51/008H01L51/0081H01L51/0085H01L51/5004H01L51/5048H01L51/5088H01L2251/558
    • Disclosed is an organic electroluminescent device having a longer drive life. Specifically disclosed is an organic electroluminescent device (100) comprising an organic material layer (16), which is composed of a hole transporting layer (164), a light-emitting layer (166) and an electron transporting layer (167), between a pair of electrodes, namely a cathode (18) and an anode (12). The light-emitting layer (166) (having a film thickness (dM) of 5-3000 nm) contains a luminescent dye and a host material. The first oxidation potential (ED+) of the luminescent dye is lower than the first oxidation potential (EH+) of the host material, while the first reduction potential (ED−) of the luminescent dye is lower than the first reduction potential (EH−) of the host material. The film thickness (dE: 5-3000 nm) of the electron transporting layer (167) and the film thickness (dH: 5-3000 nm) of the hole transporting layer (164) satisfy the following relation: dH≦dE.
    • 公开了具有较长驱动寿命的有机电致发光器件。 具体公开了一种有机电致发光器件(100),包括由空穴传输层(164),发光层(166)和电子传输层(167)组成的有机材料层(16) 一对电极,即阴极(18)和阳极(12)。 发光层(166)(膜厚(dM)为5-3000nm)含有发光染料和主体材料。 发光染料的第一氧化电位(ED +)低于主体材料的第一氧化电位(EH +),而发光染料的第一还原电位(ED-)低于第一还原电位(EH-) 的主体材料。 电子输送层(167)的膜厚(dE:5-3000nm)和空穴传输层(164)的膜厚(dH:5-3000nm)满足以下关系:dH <= dE。
    • 4. 发明授权
    • Organic electroluminescence element
    • 有机电致发光元件
    • US08933622B2
    • 2015-01-13
    • US11915348
    • 2006-05-23
    • Shin KawamiTaishi TsujiHideki SatoMasayoshi Yabe
    • Shin KawamiTaishi TsujiHideki SatoMasayoshi Yabe
    • H01L51/54H01L51/50H01L51/00
    • H01L51/5016H01L51/005H01L51/0072H01L51/008H01L51/0081H01L51/0085H01L51/5004H01L51/5048H01L51/5088H01L2251/558
    • Disclosed is an organic electroluminescent device having a longer drive life. Specifically disclosed is an organic electroluminescent device (100) comprising an organic material layer (16), which is composed of a hole transporting layer (164), a light-emitting layer (166) and an electron transporting layer (167), between a pair of electrodes, namely a cathode (18) and an anode (12). The light-emitting layer (166) (having a film thickness (dM) of 5-3000 nm) contains a luminescent dye and a host material. The first oxidation potential (ED+) of the luminescent dye is lower than the first oxidation potential (EH+) of the host material, while the first reduction potential (ED−) of the luminescent dye is lower than the first reduction potential (EH−) of the host material. The film thickness (dE: 5-3000 nm) of the electron transporting layer (167) and the film thickness (dH: 5-3000 nm) of the hole transporting layer (164) satisfy the following relation: dH≦dE.
    • 公开了具有较长驱动寿命的有机电致发光器件。 具体公开了一种有机电致发光器件(100),包括由空穴传输层(164),发光层(166)和电子传输层(167)组成的有机材料层(16) 一对电极,即阴极(18)和阳极(12)。 发光层(166)(膜厚(dM)为5-3000nm)含有发光染料和主体材料。 发光染料的第一氧化电位(ED +)低于主体材料的第一氧化电位(EH +),而发光染料的第一还原电位(ED-)低于第一还原电位(EH-) 的主体材料。 电子输送层(167)的膜厚(dE:5-3000nm)和空穴传输层(164)的膜厚(dH:5-3000nm)满足以下关系:dH&nlE; dE。
    • 6. 发明授权
    • Organic electroluminescence device
    • 有机电致发光器件
    • US08436345B2
    • 2013-05-07
    • US13057343
    • 2008-08-04
    • Takahito OyamadaTaishi TsujiYasuhiro Takahashi
    • Takahito OyamadaTaishi TsujiYasuhiro Takahashi
    • H01L51/30
    • H01L51/5076H01L51/0085H01L51/0087
    • An organic electroluminescence device includes a plurality of organic semiconductor layers including an organic light-emitting layer and layered or disposed between a pair of anode and cathode opposed to each other. The device includes n-type-dopant-containing electron transport layer disposed between the cathode and the organic light-emitting layer. The n-type-dopant-containing electron transport layer includes an organic compound capable of transporting electrons as a first component which mixed with an n-type dopant of an electron donor of metallic atom or ion thereof as a second component. The organic electroluminescence device further includes an n-type-dopant blocking layer having an interface contacting with the n-type-dopant-containing electron transport layer to block the n-type dopant. The n-type-dopant blocking layer includes a heavy atom compound including at least one kind of heavy atoms with an atomic weight of 79 or more.
    • 有机电致发光器件包括多个有机半导体层,包括有机发光层,层叠或设置在彼此相对的一对阳极和阴极之间。 该器件包括设置在阴极和有机发光层之间的含有n型掺杂剂的电子传输层。 含有n型掺杂剂的电子传输层包括能够作为第一组分传输电子的有机化合物,其与作为第二组分的金属原子的电子给体的n型掺杂剂或其离子混合。 有机电致发光元件还包括具有与含n型掺杂剂的电子传输层接触以阻挡n型掺杂剂的界面的n型掺杂剂阻挡层。 n型掺杂剂阻挡层包括重原子化合物,其包含至少一种原子量为79以上的重原子。
    • 7. 发明申请
    • ORGANIC ELECTROLUMINESCENCE DEVICE
    • 有机电致发光器件
    • US20110253991A1
    • 2011-10-20
    • US13142259
    • 2009-11-25
    • Takahito OyamadaTaishi TsujiTakahiro KaiJunya OgawaMitsuru Suda
    • Takahito OyamadaTaishi TsujiTakahiro KaiJunya OgawaMitsuru Suda
    • H01L51/54
    • H01L51/0052H01L51/0058H01L51/0067H01L51/5048H01L51/5052H01L51/5088
    • [Problem to be Solved] To provide an organic electroluminescence device with heat resistance capable of being driven by a low voltage.[Solution] An organic electroluminescence device includes a pair of anode and cathode opposed to each other; and a plurality of organic semiconductor layers layered or disposed between the anode and the cathode, the organic semiconductor layers including a light-emitting layer. At least one of the organic semiconductor layers contains a bulky organic semiconductor compound having an aromatic multi-membered ring structure and at least three aromatic substituents bonded thereto. Each of the aromatic substituents is arranged in a manner that a dihedral angle between a ring plane of the aromatic multi-membered ring structure and the ring plane of the aromatic substituent is within 70 to 90° determined by a semiempirical molecular orbital calculation method.
    • [待解决的问题]提供能够由低电压驱动的耐热性的有机电致发光器件。 [解决方案]有机电致发光器件包括彼此相对的一对阳极和阴极; 以及在所述阳极和所述阴极之间层叠或配置的多个有机半导体层,所述有机半导体层包括发光层。 有机半导体层中的至少一个包含具有芳族多元环结构的大体积有机半导体化合物和与其结合的至少三个芳香族取代基。 芳香族取代基中的芳香族多元环结构的环面与芳香族取代基的环面之间的二面角度通过半经验分子轨道计算法确定在70〜90°以内。
    • 8. 发明申请
    • Organic Electroluminescent Element
    • 有机电致发光元件
    • US20070285008A1
    • 2007-12-13
    • US11660673
    • 2005-08-15
    • Shinji MatsuoHiroshi MiyazakiTaishi Tsuji
    • Shinji MatsuoHiroshi MiyazakiTaishi Tsuji
    • H01J1/63
    • H05B33/14C09K11/06C09K2211/1007C09K2211/1029C09K2211/1037C09K2211/1092C09K2211/185C09K2211/186H01L51/0081H01L51/0085H01L51/0087H01L51/5016
    • This invention relates to an organic electroluminescent element (organic EL element) utilizing phosphorescence which shows improved luminous efficiency and driving stability and has a simple structure. The organic EL element comprises an anode, organic layers containing a hole-transporting layer, a light-emitting layer, and an electron-transporting layer, and a cathode piled one upon another on a substrate with the hole-transporting layer disposed between the light-emitting layer and the anode and the electron-transporting layer disposed between the light-emitting layer and the cathode. The light-emitting layer contains a compound represented by the following general formula (I) as a guest material and an organic metal complex containing at least one metal selected from ruthenium, rhodium, palladium, silver, rhenium, osmium, iridium, platinum, and gold as a guest material; in general formula (I), R1-R6 are independently hydrogen atoms, alkyl groups, aralkyl groups, alkenyl groups, cyano groups, alkoxy groups, aromatic hydrocarbon groups, or aromatic heterocyclic groups.
    • 本发明涉及利用磷光的有机电致发光元件(有机EL元件),其显示出改善的发光效率和驱动稳定性并且具有简单的结构。 有机EL元件包括阳极,含有空穴传输层的有机层,发光层和电子传输层,以及在基板上彼此堆叠的阴极,空穴传输层设置在光 设置在发光层和阴极之间的阳极和电子传输层。 发光层含有作为客体材料的由以下通式(I)表示的化合物和含有选自钌,铑,钯,银,铼,锇,铱,铂的至少一种金属的有机金属络合物和 金作为客人材料; 在通式(I)中,R 1 -R 6独立地是氢原子,烷基,芳烷基,烯基,氰基,烷氧基,芳族烃基, 或芳族杂环基。