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    • 2. 发明授权
    • Thiazolidine compound and fungicidal composition containing it
    • 噻唑烷化合物和含有它的杀真菌组合物
    • US4510154A
    • 1985-04-09
    • US484502
    • 1983-04-13
    • Kenji YoshidaMakoto NakazawaToyohiko ShikeMasayuki TomidaMasataka TsudaToru Teraoka
    • Kenji YoshidaMakoto NakazawaToyohiko ShikeMasayuki TomidaMasataka TsudaToru Teraoka
    • A01N43/78C07D521/00C07D417/06
    • C07D231/12A01N43/78C07D233/56C07D249/08
    • A thiazolidine compound represented by the following general formula I or its acid addition salt ##STR1## where X is --CH.dbd. or --N.dbd., Y is ##STR2## (where R is a hydrogen atom, a methyl group or an ethyl group) or --CH.sub.2 CH.sub.2 --, Ar is a phenyl group which may be substituted by halogen, lower alkyl, lower alkoxy, phenyl or trifluoromethyl, a thienyl group or a naphthyl group, R.sup.1 is a hydrogen atom, a straight chain or branched chain alkyl group having from 1 to 10 carbon atoms or a phenyl group which may be substituted, R.sup.2 is a hydrogen atom, a straight chain or branched chain alkyl group having from 1 to 10 carbon atoms, a phenyl group which may be substituted, a lower alkoxycarbonyl group, a lower alkylcarbamoyl group or a lower alkenylcarbamoyl group, and R.sup.3 is a hydrogen atom, a lower alkyl group, a lower acyl group, a lower alkylcarbamoyl group, a lower alkylthiocarbamoyl group or a phenylcarbamoyl group. The compound is useful as fungicide.
    • 由以下通式I表示的噻唑烷化合物或其酸加成盐(I)其中X为-CH =或-N =,Y为(其中R为氢原子,甲基或 乙基)或-CH 2 CH 2 - ,Ar是可以被卤素,低级烷基,低级烷氧基,苯基或三氟甲基取代的苯基,噻吩基或萘基,R 1是氢原子,直链或支链 具有1至10个碳原子的烷基或可被取代的苯基,R 2是氢原子,具有1至10个碳原子的直链或支链烷基,可被取代的苯基,低级 烷氧基羰基,低级烷基氨基甲酰基或低级链烯基氨基甲酰基,R3为氢原子,低级烷基,低级酰基,低级烷基氨基甲酰基,低级烷硫基氨基甲酰基或苯基氨基甲酰基。 该化合物可用作杀真菌剂。
    • 8. 发明授权
    • High corrosion resistance hot dip galvanized steel material
    • 高耐腐蚀热浸镀锌钢材
    • US08663818B2
    • 2014-03-04
    • US12224967
    • 2007-03-14
    • Koichi NoseKohei TokudaYuichi SatoMakoto Nakazawa
    • Koichi NoseKohei TokudaYuichi SatoMakoto Nakazawa
    • B32B15/00B32B15/01
    • C23C2/06B32B15/013C22C18/00C22C18/04C22C21/06C22C21/08C22C23/02C22C23/04C22C30/06C22C45/00C22C45/005C23C2/28Y10T428/12757Y10T428/12771Y10T428/12792Y10T428/12799Y10T428/12951
    • The present invention provides a high corrosion resistance hot dip galvannealed steel material comprised of a Zn-based hot dip plated steel material achieving both a higher corrosion resistance of the plated layer itself by the added elements and sacrificial protection of iron metal by the plated layer or workability free of degradation caused of formation of intermetallic compounds by added elements, that is, a high corrosion resistance hot dip Zn plated steel material characterized in that an alloy plated layer containing Zn: 35 mass % or more, preferably 40 mass % or more, contains a non-equilibrium phase having a heat capacity by differential scanning calorimetry of 1 J/g or more. Furthermore, 5% or more, preferably 50% or more in terms of vol % is an amorphous phase. The alloy layer may contain, by mass %, Mg: 1 to 60% and Al: 0.07 to 59%, may further contain one or more elements selected from Cr, Mn, Fe, Co, Ni, and Cu in a total of 0.1 to 10%, and may in addition contain one or more elements of 0.1 to 10% of La, 0.1 to 10% of Ce, 0.1 to 10% of Ca, 0.1 to 10% of Sn, 0.005 to 2% of P, and 0.02 to 7% of Si.
    • 本发明提供一种耐腐蚀性高的浸镀热镀锌钢材,其由Zn基热浸镀钢材组成,通过添加的元素实现镀层本身的较高的耐腐蚀性,并通过镀层牺牲铁金属的牺牲保护,或 不含添加元素形成金属间化合物的劣化的可加工性,即耐腐蚀性高的镀锌钢材,其特征在于,含有Zn:35质量%以上,优选为40质量%以上的合金镀层, 含有通过差示扫描量热法测定的热容量为1J / g以上的非平衡相。 此外,以体积%计为5%以上,优选为50%以上是非晶相。 合金层可以以质量%计含有Mg:1〜60%,Al:0.07〜59%,还可以含有选自Cr,Mn,Fe,Co,Ni和Cu中的一种或多种元素,总计0.1 〜10%,另外可以含有0.1〜10%的La,0.1〜10%的Ce,0.1〜10%的Ca,0.1〜10%的Sn,0.005〜2%的P,以及 0.02〜7%的Si。
    • 9. 发明申请
    • High Corrosion Resistance Hot dip Galvanized Steel Material
    • 耐腐蚀性高浸镀锌钢材料
    • US20090053555A1
    • 2009-02-26
    • US12224967
    • 2007-03-14
    • Koichi NoseKohei TokudaYuichi SatoMakoto Nakazawa
    • Koichi NoseKohei TokudaYuichi SatoMakoto Nakazawa
    • B32B15/20B32B15/01B32B15/18
    • C23C2/06B32B15/013C22C18/00C22C18/04C22C21/06C22C21/08C22C23/02C22C23/04C22C30/06C22C45/00C22C45/005C23C2/28Y10T428/12757Y10T428/12771Y10T428/12792Y10T428/12799Y10T428/12951
    • The present invention provides a high corrosion resistance hot dip galvannealed steel material comprised of a Zn-based hot dip plated steel material achieving both a higher corrosion resistance of the plated layer itself by the added elements and sacrificial protection of iron metal by the plated layer or workability free of degradation caused of formation of intermetallic compounds by added elements, that is, a high corrosion resistance hot dip Zn plated steel material characterized in that an alloy plated layer containing Zn: 35 mass % or more, preferably 40 mass % or more, contains a non-equilibrium phase having a heat capacity by differential scanning calorimetry of 1 J/g or more. Furthermore, 5% or more, preferably 50% or more in terms of vol % is an amorphous phase. The alloy layer may contain, by mass %, Mg: 1 to 60% and Al: 0.07 to 59%, may further contain one or more elements selected from Cr, Mn, Fe, Co, Ni, and Cu in a total of 0.1 to 10%, and may in addition contain one or more elements of 0.1 to 10% of La, 0.1 to 10% of Ce, 0.1 to 10% of Ca, 0.1 to 10% of Sn, 0.005 to 2% of P, and 0.02 to 7% of Si.
    • 本发明提供一种耐腐蚀性高的浸镀热镀锌钢材,其由Zn基热浸镀钢材组成,通过添加的元素实现镀层本身的较高的耐腐蚀性,并通过镀层牺牲铁金属的牺牲保护,或 不含添加元素形成金属间化合物的劣化的可加工性,即耐腐蚀性高的镀锌钢材,其特征在于,含有Zn:35质量%以上,优选为40质量%以上的合金镀层, 含有通过差示扫描量热法测定的热容量为1J / g以上的非平衡相。 此外,以体积%计为5%以上,优选为50%以上是非晶相。 合金层可以以质量%计含有Mg:1〜60%,Al:0.07〜59%,还可以含有选自Cr,Mn,Fe,Co,Ni和Cu中的一种或多种元素,总计0.1 〜10%,另外可以含有0.1〜10%的La,0.1〜10%的Ce,0.1〜10%的Ca,0.1〜10%的Sn,0.005〜2%的P,以及 0.02〜7%的Si。