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    • 1. 发明授权
    • Process for the production of polymeric polyols
    • 生产聚合多元醇的方法
    • US5292803A
    • 1994-03-08
    • US957008
    • 1992-10-06
    • Tadayuki OhmaeHisao TanakaSumio HaraKenzo Chikanari
    • Tadayuki OhmaeHisao TanakaSumio HaraKenzo Chikanari
    • C08F8/00
    • C08F8/00
    • There is disclosed a process for the production of polymeric polyols, which comprises the steps of:partially or completely saponifying a heterogeous two-phase mixture of (a) a heated molten liquid containing an ethylene-saturated carboxylic acid vinyl ester copolymer having a number average molecular weight of from 800 to 5000 and a saturated carboxylic acid vinyl ester content of from 1 to 50% by weight, and (b) an aliphatic alcohol, in the presence of an alkali catalyst, while removing a saturated carboxylic acid alkyl ester byproduct from the reaction system;then removing the residual aliphatic alcohol from the reaction system; andsupplying an alkylene oxide to effect an alkylene oxide-addition reaction, optionally after further supplying the alkali catalyst.
    • 公开了一种制备聚合多元醇的方法,其包括以下步骤:部分或完全皂化(a)加热的含有数均分子量的乙烯饱和羧酸乙烯基酯共聚物的熔融液体的异质混合物 分子量为800〜5000,饱和羧酸乙烯基酯含量为1〜50重量%,(b)脂肪醇,在碱催化剂存在下,同时除去饱和羧酸烷基酯副产物, 反应体系; 然后从反应体系中除去残留的脂族醇; 并提供烯化氧以进行烯化氧加成反应,任选地在进一步供给碱催化剂之后。