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1. 发明申请

US20090188240A1 APPARATUS FOR PURIFICATION OF EXHAUST GAS AND METHOD FOR PURIFICATION OF EXHAUST GAS USING THE SAME 审中-公开
标题翻译：用于净化排气的装置和使用其排出的排气的方法
公开(公告)号：US20090188240A1
公开(公告)日：2009-07-30
申请号：US12300654
申请日：2007-06-11
申请人： Tadashi Suzuki , Naoki Takahashi , Ichiro Hachisuka
发明人： Tadashi Suzuki , Naoki Takahashi , Ichiro Hachisuka
IPC分类号： F01N9/00 , F01N3/10
CPC分类号： F01N3/206 , B01D53/9445 , B01D53/9459 , B01D53/9477 , B01D2251/102 , B01D2251/11 , B01D2255/20738 , B01D2255/20753 , B01J23/002 , B01J23/894 , B01J37/0242 , B01J2523/00 , F01N3/021 , F01N3/0814 , F01N3/0842 , F01N3/0885 , F01N3/32 , F01N9/00 , F01N13/009 , F01N13/0093 , F01N2560/025 , F01N2560/06 , F01N2610/04 , F01N2610/08 , F01N2610/146 , F01N2900/08 , Y02A50/2324 , Y02T10/22 , Y02T10/47 , B01J2523/3706 , B01J2523/3712 , B01J2523/3718 , B01J2523/48
摘要： An apparatus for purification of exhaust gas comprises: an exhaust gas pipe (2) connected to an internal combustion engine (1); an upstream catalyst (3) arranged at the upstream side of an exhaust gas passage inside the exhaust gas pipe (2); a downstream catalyst (4) which is arranged at the downstream side of the exhaust gas passage inside the exhaust gas pipe (2), and on which nickel and/or iron is supported; and oxidizing gas supply means (5) which is connected to the exhaust gas pipe (2) between the upstream catalyst (3) and the downstream catalyst (4), and which supplies oxidizing gas into the exhaust gas pipe (2).
摘要翻译：废气净化装置包括：与内燃机（1）连接的排气管（2）; 上游催化剂（3），其布置在所述排气管（2）内的废气通道的上游侧; 下游催化剂（4），其布置在排气管（2）内的排气通道的下游侧，并且其上支撑有镍和/或铁; 以及与上游催化剂（3）和下游催化剂（4）之间的排气管（2）连接并将氧化气体供给到排气管（2）中的氧化气体供给装置（5）。

2. 发明申请

US20090137387A1 Catalyst for purifying exhaust gas 有权
标题翻译：废气净化催化剂
公开(公告)号：US20090137387A1
公开(公告)日：2009-05-28
申请号：US12227523
申请日：2007-06-05
申请人： Michihiko Takeuchi , Hirotaka Ori , Takeru Yoshida , Kazunobu Ishibashi , Ichiro Hachisuka
发明人： Michihiko Takeuchi , Hirotaka Ori , Takeru Yoshida , Kazunobu Ishibashi , Ichiro Hachisuka
IPC分类号： B01J23/10 , B01J23/44 , B01J23/40 , B01J23/42
CPC分类号： B01J37/0234 , B01D53/945 , B01D2255/1021 , B01D2255/1023 , B01D2255/1026 , B01D2255/2065 , B01D2255/2068 , B01D2255/9022 , B01D2255/908 , B01J23/63 , B01J37/0244 , F01N2510/0682 , F01N2570/24 , Y02T10/22
摘要： The present invention provides an exhaust gas purification catalyst comprising a base material, and a two or more layered catalyst coating layer, formed on the base material, wherein the two or more layers have upper and lower layers, and wherein the upper layer contains a large amount of noble metal per liter of the base material more than that of the lower layer, and the lower layer contains a large amount of an oxygen storage/release material per liter of the base material more than that of the upper layer. This exhaust gas purification catalyst has more excellent H2S purifying performance than conventional catalysts while maintaining purifying performance against NOx and the other exhaust gas components.
摘要翻译：本发明提供了一种排气净化催化剂，其包含基材和形成在基材上的两层以上的层叠催化剂被覆层，其中两层以上具有上层和下层，并且其中上层含有大的贵金属的量比每一基底材料多于下层的贵金属，下层含有比上层更多的每升基材的大量的储氧/释放材料。这种废气净化催化剂具有比常规催化剂更优异的H 2 S净化性能，同时保持对NOx和其它废气组分的净化性能。

3. 发明授权

US07816300B2 Catalyst for purifying exhaust gas 有权
标题翻译：废气净化催化剂
公开(公告)号：US07816300B2
公开(公告)日：2010-10-19
申请号：US12227523
申请日：2007-06-05
申请人： Michihiko Takeuchi , Hirotaka Ori , Takeru Yoshida , Kazunobu Ishibashi , Ichiro Hachisuka
发明人： Michihiko Takeuchi , Hirotaka Ori , Takeru Yoshida , Kazunobu Ishibashi , Ichiro Hachisuka
IPC分类号： B01J23/40 , B01J23/10 , B01D53/94
CPC分类号： B01J37/0234 , B01D53/945 , B01D2255/1021 , B01D2255/1023 , B01D2255/1026 , B01D2255/2065 , B01D2255/2068 , B01D2255/9022 , B01D2255/908 , B01J23/63 , B01J37/0244 , F01N2510/0682 , F01N2570/24 , Y02T10/22
摘要： The present invention provides an exhaust gas purification catalyst comprising a base material, and a two or more layered catalyst coating layer, formed on the base material, wherein the two or more layers have upper and lower layers, and wherein the upper layer contains a large amount of noble metal per liter of the base material more than that of the lower layer, and the lower layer contains a large amount of an oxygen storage/release material per liter of the base material more than that of the upper layer. This exhaust gas purification catalyst has more excellent H2S purifying performance than conventional catalysts while maintaining purifying performance against NOx and the other exhaust gas components.
摘要翻译：本发明提供了一种排气净化催化剂，其包含基材和形成在基材上的两层以上的层叠催化剂被覆层，其中两层以上具有上层和下层，并且其中上层含有大的贵金属的量比每一基底材料多于下层的贵金属，下层含有比上层更多的每升基材的大量的储氧/释放材料。这种废气净化催化剂具有比常规催化剂更优异的H 2 S净化性能，同时保持对NOx和其它废气组分的净化性能。

4. 发明申请

US20090269253A1 HYDROGEN SULFIDE PRODUCTION-SUPPRESSING MEMBER AND EXHAUST GAS-PURIFYING CATALYST 审中-公开
标题翻译：硫化氢生产抑制部件和排气净化催化剂
公开(公告)号：US20090269253A1
公开(公告)日：2009-10-29
申请号：US12159995
申请日：2007-01-10
申请人： Ichiro Hachisuka
发明人： Ichiro Hachisuka
IPC分类号： B01D53/48
CPC分类号： B01D53/945 , B01D53/8615 , B01D2255/206 , B01D2257/304 , B01J21/063 , B01J21/066 , B01J23/10 , B01J23/63 , B01J35/0006 , B01J35/04 , B01J37/0215 , F01N3/0807 , F01N3/085 , F01N13/0097 , F01N2370/02 , F01N2510/06 , F01N2510/0682 , Y02A50/2324 , Y02T10/20 , Y02T10/22
摘要： Disclosed herein is a hydrogen sulfide production-suppressing member, comprising: a sulfur-adsorbing portion 2 comprising an oxide comprising at least ceria, the sulfur-adsorbing portion 2 being disposed upstream side of an exhaust gas; and a sulfur-releasing portion 3 being disposed downstream side of the sulfur-adsorbing portion 2 and having surface acidity higher than that of the sulfur-adsorbing portion 2. SOx adsorbed on the sulfur-adsorbing portion is released in a high-temperature zone, but the released SOx, is difficult to adsorb on the sulfur-releasing portion 3, and thus is not adsorbed again. Thus, the production of H2S is suppressed without using environmental loading substances such as nickel.
摘要翻译：本发明公开了一种硫化氢生成抑制部件，其特征在于，包括：硫吸附部2，其含有至少包含二氧化铈的氧化物，所述硫吸附部2设置在废气的上游侧; 硫磺吸附部2的下游侧具有硫磺释放部3，表面酸度高于硫吸附部2.硫吸附部上的SOx在高温区域被释放，但释放的SO x难以吸附在硫释放部3上，因此不再被吸附。因此，不使用镍等环境负荷物质来抑制H 2 S的生成。

5. 发明授权

US07229947B2 Catalyst for hydrogen generation and catalyst for purifying of exhaust gas 失效
标题翻译：用于氢气生成的催化剂和用于净化废气的催化剂
公开(公告)号：US07229947B2
公开(公告)日：2007-06-12
申请号：US10468417
申请日：2002-02-04
申请人： Naoyuki Hara , Ichiro Hachisuka
发明人： Naoyuki Hara , Ichiro Hachisuka
IPC分类号： B01J23/00
CPC分类号： F01N3/0842 , B01D53/8628 , B01D53/9422 , B01D2255/20707 , B01D2255/20715 , B01D2255/2092 , B01J21/04 , B01J21/063 , B01J21/066 , B01J23/40 , B01J23/464 , B01J23/58 , B01J35/0006 , B01J37/03 , C01B3/40 , C01B2203/1064 , C01B2203/1082 , F01N3/0814 , Y02P20/52
摘要： An NOx sorption-and-reduction type catalyst is made which includes a hydrogen generating catalyst in which Rh is loaded on a support including an Al2O3—ZrO2 composite oxide. Since the Al2O3—ZrO2 composite oxide exhibits a basicity lower than ZrO2, SOx are less likely to approach so that it is possible to suppress the sulfur poisoning of Rh. Moreover, the Al2O3—ZrO2 composite oxide exhibits higher heat resistance than ZrO2, and it has a function of improving the steam reforming reaction activity of Rh in the same manner as ZrO2. Therefore, the post-durability NOx purifying ability of the NOx sorption-and-reduction type catalyst is improved.
摘要翻译：制备了一种NO x吸附还原型催化剂，其包括产氢催化剂，其中Rh负载在包含Al 2 O 3的载体上， / SUB-2复合氧化物。由于Al 2 O 3 -ZrO 2复合氧化物显示的碱度低于ZrO 2 N 2，SO 3 > x 不太可能接近，从而可以抑制Rh的硫中毒。此外，Al 2 O 3 - ZrO 2复合氧化物表现出比ZrO 2 N更高的耐热性，并且具有以与ZrO 2 2相同的方式改善Rh的蒸气重整反应活性的功能。因此，提高了NO x吸附还原型催化剂的耐久后NO x的纯化能力。

6. 发明授权

US07220702B2 Exhaust gas purification catalyst 失效
标题翻译：废气净化催化剂
公开(公告)号：US07220702B2
公开(公告)日：2007-05-22
申请号：US10468354
申请日：2002-02-04
申请人： Naoyuki Hara , Ichiro Hachisuka
发明人： Naoyuki Hara , Ichiro Hachisuka
IPC分类号： B01J23/00 , B01J21/00 , B01J20/00
CPC分类号： F01N3/0842 , B01D53/8628 , B01D53/9422 , B01D2255/20707 , B01D2255/20715 , B01D2255/2092 , B01J21/04 , B01J21/063 , B01J21/066 , B01J23/40 , B01J23/464 , B01J23/58 , B01J35/0006 , B01J37/03 , C01B3/40 , C01B2203/1064 , C01B2203/1082 , F01N3/0814 , Y02P20/52
摘要： A noble metal and an NOx sorption member are loaded on a support which includes composite particles having a structure including a core portion in which ZrO2 is a major component and a superficial portion formed on a surface of the core portion and including an oxide, whose basicity is lower than ZrO2, more than the core portion. The composite particles exhibit a high basicity at the inside and a low basicity on the surface by Al2O3 or TiO2 which exists more in the surface. Accordingly, the sulfur-poisoning resistance is improved, and, at the same time, the post-durability NOx purifying ability is improved.
摘要翻译：将贵金属和NO x吸附构件负载在载体上，该载体包括复合颗粒，该复合颗粒具有包含其中ZrO 2 2主要成分和表面的主要组分的核心部分的结构形成在芯部表面上并且包含比核心部分更碱性低于ZrO 2 2 O的氧化物的部分。复合颗粒在内部表现出高的碱性，并且通过Al 2 N 3 O 3或TiO 2在表面上表现出低碱度，其存在于表面。因此，耐硫中毒性提高，同时提高了耐久后的NO x2纯化能力。

7. 发明授权

US07056859B2 Catalyst for purifying exhaust gases 失效
标题翻译：废气净化催化剂
公开(公告)号：US07056859B2
公开(公告)日：2006-06-06
申请号：US10389919
申请日：2003-03-18
申请人： Ichiro Hachisuka
发明人： Ichiro Hachisuka
IPC分类号： B01J23/00
CPC分类号： B01D53/945 , B01D53/86 , B01D2255/102 , B01D2255/902 , B01D2255/91 , B01D2257/404 , B01D2257/502 , B01D2257/702 , B01J23/58 , B01J23/6527 , B01J27/1856 , B01J35/002 , B01J37/0242 , B01J37/0244 , Y02T10/22
摘要： A catalyst for purifying exhaust gases which can suppress an active ingredient, such as an alkali metal, which reacts with a substrate from moving to the substrate, thereby preventing a decrease in strength such as thermal shock resistance of the substrate. In production, first, a first oxide layer composed mainly of an oxide which has a high reactability with the active ingredient is formed on the substrate. Next, a second oxide layer composed mainly of an oxide which has a low reactability with the active ingredient is formed on the first oxide layer. Then, a catalyst layer loaded at least with a noble metal and the active ingredient is formed on the second oxide layer. This second oxide layer suppresses transfer of the active ingredient and some active ingredient which has passed through the second oxide layer is caught by the first oxide layer owing to its reaction.
摘要翻译：一种用于净化废气的催化剂，其能够抑制与基板反应的活性成分（例如碱金属）移动到基板，从而防止基板的耐热冲击性等强度的降低。在制造中，首先，在基板上形成主要由与活性成分反应性高的氧化物构成的第一氧化物层。接着，在第一氧化物层上形成有与活性成分反应性低的主要由氧化物构成的第二氧化物层。然后，在第二氧化物层上形成至少载有贵金属和活性成分的催化剂层。该第二氧化物层抑制活性成分的转移，并且通过第二氧化物层的一些活性成分由于其反应而被第一氧化物层捕获。

8. 发明授权

US06461579B1 Catalyst for purifying exhaust gas and exhaust gas purifying method 失效
标题翻译：废气净化催化剂和废气净化方法
公开(公告)号：US06461579B1
公开(公告)日：2002-10-08
申请号：US09555384
申请日：2000-07-21
申请人： Ichiro Hachisuka , Yasuo Ikeda
发明人： Ichiro Hachisuka , Yasuo Ikeda
IPC分类号： B01D5394
CPC分类号： B01D53/945 , B01D53/8628 , B01J23/002 , B01J23/464 , B01J23/58 , B01J23/63 , B01J35/0006 , B01J35/023 , B01J37/0248 , B01J2523/00 , Y02T10/22 , B01J2523/11 , B01J2523/13 , B01J2523/23 , B01J2523/25 , B01J2523/31 , B01J2523/47 , B01J2523/48 , B01J2523/822 , B01J2523/828 , B01J2523/3706
摘要： A catalyst for purifying exhaust of an internal combustion engine is prepared by mixing first powders in which at least Pt is loaded on a first support and second powders in which at least Rh is loaded on a second support and loading NOx occluding material, for example an alkaline-earth metal, alkali metal or rare-earth metal, at least on the first support. In such catalyst, the second support is made of a stabilized zirconia stabilized by alkaline-earth metal or rare-earth element. The second support, having been become alkaline by the alkaline-earth metal or the rare-earth element, is excellent in absorbing performance of the steam (H2O), so that the steam reforming reaction by Rh advances sufficiently. Therefore, the created hydrogen greatly contributes to the reduction of NOx and to the sulfur poisoning prevention of the NOx occluding material. Also, the oxidizing ability of Pt is maintained high, Rh sufficiently exhibits the steam reforming reaction activity and the sulfur poisoning of NOx occluding material is restrained. An exhaust gas from an internal combustion engine is combusted where mixed gas of rich atmosphere containing excessive fuel is supplied to mixed gas of lean atmosphere containing excessive oxygen like a pulse. The exhaust gas is then introduced to the catalyst wherein the exhaust gas is purified.
摘要翻译：用于净化内燃机的排气的催化剂是通过混合其中至少将Pt装载在第一载体上的第一种粉末和其中至少将Rh装载在第二载体上的第二种粉末和装载NO x吸留材料，例如碱土金属，碱金属或稀土金属，至少在第一载体上。在这种催化剂中，第二载体由稳定的由碱土金属或稀土元素稳定的氧化锆制成。通过碱土金属或稀土元素变成碱性的第二载体具有优异的蒸气（H 2 O）吸收性能，使得Rh的蒸汽重整反应充分进行。因此，所产生的氢气大大有助于NOx的还原和防止NOx吸留材料的硫中毒。此外，Pt的氧化能力保持较高，Rh充分显示出蒸汽重整反应活性，并且抑制了NOx吸留材料的硫中毒。在含有过量燃料的富含气体的混合气体被供给到含有过量的氧气的稀薄气体的混合气体中的情况下，来自内燃机的废气燃烧。然后将废气引入催化剂，其中净化废气。

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