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    • 1. 发明授权
    • Ni-Fe magnetic alloy and method for producing thereof
    • 镍铁磁性合金及其制造方法
    • US5525164A
    • 1996-06-11
    • US400858
    • 1995-03-08
    • Tadashi InoueKiyoshi TsuruShinichi OkimotoNaokazu YamamuraTetsuo YamamotoHirohisa Haiji
    • Tadashi InoueKiyoshi TsuruShinichi OkimotoNaokazu YamamuraTetsuo YamamotoHirohisa Haiji
    • C22C19/03C22F1/00C22F1/10H01F1/147H01F1/00
    • H01F1/14708C22C19/03H01F1/14716
    • A Ni--Fe magnetic alloy consists essentially of:77 to 80 wt. % Ni, 3.5 to 5 wt. % Mo, 1.5 to 3 wt. % Cu, 0.1 to 1.1 wt. % Mn, 0.1 wt. % or less Cr, 0.003 wt. % or less S, 0.01 wt. % or less P, 0.005 wt. % or less O, 0.003 wt. % or less N, 0.02 wt. % or less C, 0.001 to 0.05 wt. % Al, 1 wt. % or less Si, 2.6-6 of the weight ratio of Ca to S, (Ca/S), and the balance being Fe and inevitable impurities, satisfies an equation of 3.2.ltoreq.(2.02.times.[Ni]-11.13.times.[Mo]-1.25.times.[Cu]-5.03.times.[Mn])/(2.13.times.[Fe]).ltoreq.3.8; and has a Mo segregation ratio defined by a seregration equation satisfying 5% or less, the seregration equation being .vertline.(Mo content in a segregation region-Mo average content)/(Mo average content).vertline..times.100%.A method for producing a magnetic Ni--Fe alloy comprises the steps of: a first heating step of heating an alloy ingot to 1200.degree. to 1300.degree. C. for 10 to 30 hrs; slabbing the heated ingot at a finishing temperature of 950.degree. C. or more to produce a slab; a second heating step of heating the slab at 1150.degree. to 1270.degree. C. for 1 to 5 hrs; and hot rolling the heated slab at a finishing temperature 950.degree. C. or more.
    • Ni-Fe磁性合金主要由以下组成:77〜80wt。 %Ni,3.5〜5wt。 %Mo,1.5〜3wt。 %Cu,0.1〜1.1wt。 %Mn,0.1wt。 %以下Cr,0.003重量% %以下S,0.01重量% %以下P,0.005重量% %以下O,0.003重量% %以下N,0.02重量% %以下C,0.001〜0.05重量% %Al,1wt。 %以下的Si,2.6〜6(Ca / S)的重量比(Ca / S),余量为Fe和不可避免的杂质,满足3.2的方程式(2.02×[Ni] -11.13×[ Mo] -1.25x [Cu] -5.03x [Mn])/(2.13x [Fe])= 3.8; 并且具有由满足5%以下的对数方程定义的Mo偏析比,所述对数方程为|(偏析区中的Mo含量-Mo平均含量)/(Mo平均含量)| x100%。 一种磁性Ni-Fe合金的制造方法,其特征在于,包括以下步骤:将合金锭加热到1200〜1300℃进行10〜30小时的第一加热工序; 在950℃或更高的终轧温度下对加热的锭进行烧结以制造板坯; 第二加热步骤,在1150℃至1270℃下加热板坯1至5小时; 并在最终温度950℃或更高温度下热轧加热的板坯。
    • 2. 发明授权
    • Ni-Fe magnetic alloy and method for producing thereof
    • 镍铁磁性合金及其制造方法
    • US5669989A
    • 1997-09-23
    • US547705
    • 1995-10-19
    • Tadashi InoueKiyoshi TsuruShinichi OkimotoNaokazu YamamuraTetsuo YamamotoHirohisa Haiji
    • Tadashi InoueKiyoshi TsuruShinichi OkimotoNaokazu YamamuraTetsuo YamamotoHirohisa Haiji
    • C22C19/03C22F1/00C22F1/10H01F1/147H01F1/04
    • H01F1/14708C22C19/03H01F1/14716
    • A Ni--Fe magnetic alloy consists essentially of: 77 to 80 wt. % Ni, 3.5 to 5 wt. % Mo, 1.5 to 3 wt. % Cu, 0.1 to 1.1 wt. % Mn, 0.1 wt. % or less Cr, 0.003 wt. % or less S, 0.01 wt. % or less P, 0.005 wt. % or less 0, 0.003 wt. % or less N, 0.02 wt. % or less C, 0.001 to 0.05 wt. % Al, 1 wt. % or less Si, 2.6-6 of the weight ratio of Ca to S, (Ca/S), and the balance being Fe and inevitable impurities, satisfies an equation of 3.2.ltoreq.(2.02.times.�Ni!-11.13.times.�Mo!-1.25.times.�Cu!-5.03.times.�Mn!)/(2.13.times.�Fe!).ltoreq.3.8; and has a Mo segregation ratio defined by a seregration equation satisfying 5% or less, the seregration equation being .vertline.(Mo content in a segregation region-Mo average content)/(Mo average content).vertline..times.100%. A method for producing a magnetic Ni--Fe alloy comprises the steps of: a first heating step of heating an alloy ingot to 1200.degree. to 1300.degree. C. for 10 to 30 hrs; slabbing the heated ingot at a finishing temperature of 950.degree. C. or more to produce a slab; a second heating step of heating the slab at 1150.degree. to 1270.degree. C. for 1 to 5 hrs; and hot rolling the heated slab at a finishing temperature 950.degree. C. or more.
    • Ni-Fe磁性合金主要由以下组成:77〜80wt。 %Ni,3.5〜5wt。 %Mo,1.5〜3wt。 %Cu,0.1〜1.1wt。 %Mn,0.1wt。 %以下Cr,0.003重量% %以下S,0.01重量% %以下P,0.005重量% %以下0,0.003重量% %以下N,0.02重量% %以下C,0.001〜0.05重量% %Al,1wt。 %以下的Si,2.6〜6(Ca / S)的重量比(Ca / S),余量为Fe和不可避免的杂质,满足3.2的方程式(2.02×[Ni] -11.13×[ Mo] -1.25x [Cu] -5.03x [Mn])/(2.13x [Fe])= 3.8; 并且具有由满足5%以下的对数方程定义的Mo偏析比,所述对数方程为|(偏析区中的Mo含量-Mo平均含量)/(Mo平均含量)| x100%。 一种磁性Ni-Fe合金的制造方法,其特征在于,包括以下步骤:将合金锭加热到1200〜1300℃进行10〜30小时的第一加热工序; 在950℃或更高的终轧温度下对加热的锭进行烧结以制造板坯; 第二加热步骤,在1150℃至1270℃下加热板坯1至5小时; 并在最终温度950℃或更高温度下热轧加热的板坯。
    • 3. 发明授权
    • NI-FE magnetic alloy and method for producing thereof
    • NI-FE磁性合金及其制造方法
    • US5500057A
    • 1996-03-19
    • US130369
    • 1993-10-01
    • Tadashi InoueKiyoshi TsuruShinichi OkimotoNaokazu YamamuraTetsuo YamamotoHirohisa Haiji
    • Tadashi InoueKiyoshi TsuruShinichi OkimotoNaokazu YamamuraTetsuo YamamotoHirohisa Haiji
    • C22C19/03C22F1/00C22F1/10H01F1/147H01F1/04
    • H01F1/14708C22C19/03H01F1/14716
    • A Ni-Fe magnetic alloy consists essentially of:77 to 80 wt. % Ni, 3.5 to 5 wt. % Mo, 1.5 to 3 wt. % Cu, 0.1 to 1.1 wt. % Mn, 0.1 wt. % or less Cr, 0.003 wt. % or less S, 0.01 wt. % or less P, 0.005 wt. % or less 0, 0.003 wt. % or less N, 0.02 wt. % or less C, 0.001 to 0.05 wt. % Al, 1 wt. % or less Si, 2.6-6 of the weight ratio of Ca to S, (Ca/S), and the balance being Fe and inevitable impurities, satisfies an equation of 3.2.ltoreq.(2.02.times.[Ni]-11.13.times.[Mo]-1.25.times.[Cu]-5.03.times.[Mn])/ (2.13.times.[Fe]).ltoreq.3.8; and has a Mo segregation ratio defined by a seregration equation satisfying 5% or less, the seregration equation being .vertline.(Mo content in a segregation region-Mo average content)/ (Mo average content).vertline..times.100%.A method for producing a magnetic Ni-Fe alloy comprises the steps of: a first heating step of heating an alloy ingot to 1200.degree. to 1300.degree. C. for 10 to 30 hrs; slabbing the heated ingot at a finishing temperature of 950.degree. C. or more to produce a slab; a second heating step of heating the slab at 1150.degree. to 1270.degree. C. for 1 to 5 hrs: and hot rolling the heated slab at a finishing temperature 950.degree. C. or more.
    • Ni-Fe磁性合金主要由以下组成:77〜80wt。 %Ni,3.5〜5wt。 %Mo,1.5〜3wt。 %Cu,0.1〜1.1wt。 %Mn,0.1wt。 %以下Cr,0.003重量% %以下S,0.01重量% %以下P,0.005重量% %以下0,0.003重量% %以下N,0.02重量% %以下C,0.001〜0.05重量% %Al,1wt。 %以下的Si,2.6〜6(Ca / S)的重量比(Ca / S),余量为Fe和不可避免的杂质,满足3.2的方程式(2.02×[Ni] -11.13×[ Mo] -1.25x [Cu] -5.03x [Mn])/(2.13x [Fe])= 3.8; 并且具有由满足5%以下的对数方程定义的Mo偏析比,所述对数方程为|(偏析区中的Mo含量-Mo平均含量)/(Mo平均含量)| x100%。 一种磁性Ni-Fe合金的制造方法,其特征在于,包括以下步骤:将合金锭加热到1200〜1300℃进行10〜30小时的第一加热工序; 在950℃或更高的终轧温度下对加热的锭进行烧结以制造板坯; 第二加热步骤,在1150℃〜1270℃下加热板坯1〜5小时,并在950℃以上的终轧温度下热轧。
    • 5. 发明授权
    • Method of producing an alloy sheet for a shadow mask
    • 荫罩用合金薄片的制造方法
    • US5637161A
    • 1997-06-10
    • US429252
    • 1995-04-25
    • Tadashi InoueKiyoshi TsuruMichihito HiasaTomoyoshi Okita
    • Tadashi InoueKiyoshi TsuruMichihito HiasaTomoyoshi Okita
    • C21D8/02C22C38/08H01J9/14C21D6/00
    • C21D8/0205C22C38/08H01J9/142C21D2201/05C21D8/0236H01J2229/0733
    • A method for manufacturing an alloy sheet for a shadow mask is provided which includes: (i) annealing a hot-rolled sheet containing Fe and Ni at a temperature of 910.degree. to 990.degree. C.; (ii) cold-rolling the annealed hot-rolled sheet from step (i) to produce a cold-rolled sheet; (iii) crystallization annealing of the cold-rolled sheet from step (ii); (iv) cold-rolling the annealed cold rolled sheet from step (iii); (v) finish recrystallization annealing step of the cold-rolled sheet of step (iv); (vi) finish cold-rolling of the sheet from step (v) at a cold-rolling reduction ratio R (%) satisfying the following equations: 16.ltoreq.R.ltoreq.75 and 6.38 D-133.9.ltoreq.R.ltoreq.6.38 D-51.0 wherein D is the average austenite grain size in .mu.m; (vii) softening annealing the sheet from step (vi) at a temperature of 720.degree. to 790.degree. C. for 2 to 40 minutes before press-forming and at conditions of temperature T in .degree.C. and time t in minutes which satisfy the following equation:T.gtoreq.-53.8 log t+806.
    • 提供一种用于制造荫罩用合金薄片的方法,该方法包括:(i)在910-990℃的温度下退火含有Fe和Ni的热轧薄板; (ii)将来自步骤(i)的退火的热轧板冷轧以制造冷轧板; (iii)来自步骤(ii)的冷轧板的结晶退火; (iv)将来自步骤(iii)的退火冷轧板冷轧; (v)步骤(iv)的冷轧板的最终再结晶退火工序; (vi)以满足以下等式的冷轧减速比R(%)从步骤(v)中对板进行最终冷轧:16 / = - 53.8 log t + 806。
    • 6. 发明授权
    • Thin Fe-Ni alloy sheet for shadow mask
    • 用于荫罩的薄Fe-Ni合金薄板
    • US5628841A
    • 1997-05-13
    • US184840
    • 1994-01-21
    • Tadashi InoueKiyoshi TsuruTomoyoshi OkitaMichihito Hiasa
    • Tadashi InoueKiyoshi TsuruTomoyoshi OkitaMichihito Hiasa
    • C21D8/02C22C38/08H01J9/14H01J29/07H01F1/04
    • H01J9/142C21D8/0205C22C38/08H01J29/07C21D2201/05C21D8/0236H01J2229/0733
    • A thin Fe--Ni alloy sheet for shadow mask consists essentially of Ni of 34 to 38 wt. %, Si of 0.05 wt. % or less, B of 0.0005 wt. % or less, O of 0.002 wt. % or less and N of 0.0015% or less, the balance being Fe and inevitable impurities; said alloy sheet after annealing before press-forming having 0.2% proof stress of 28.5 kgf/mm.sup.2 or less; and a degree of {211} plane on a surface of said alloy sheet being 16% or less. And further modified similar alloy sheets are also provided.Further, a method for producing a thin Fe--Ni alloy sheet for shadow mask comprises the steps of: (a) hot-rolling of a slab into a hot-rolled alloy strip; (b) hot-rolled sheet annealing of the hot-rolled strip at 910 to 990.degree. C.; (c) cold-rolling of the annealed hot-rolled strip into a cold-rolled strip; (d) recrystallization annealing of the cold-rolled strip; (e) finish cold-rolling of the recrystallization annealed strip at a finish cold reduction ratio in response to austenite grain size D(D.mu.m) yieleded by the recrystallization annealing, the finish cold reducration ratio(R) being within a region enclosed by a range of R of 16 to 75 and a range of D of 6.38D-133.9.ltoreq.R.ltoreq.6.38D-51.0 and (f) annealing of the finish cold-rolled strip on conditions of a temperature of 720.degree. to 790.degree. C., a time of 2 to 40 min. and T.gtoreq.-53.8 logt+806, where T(.degree.C.) is the temperature of the annealing. And further modified similar methods are also provided.
    • 用于荫罩的薄Fe-Ni合金板基本上由34至38重量%的Ni组成。 %,Si为0.05wt。 %以下,B为0.0005重量% %以下,O为0.002重量% %以下,N为0.0015%以下,余量为Fe和不可避免的杂质; 压制成形后的退火后的合金板的0.2%的屈服应力为28.5kgf / mm 2以下; 并且所述合金板的表面上的{211}面的程度为16%以下。 还提供了进一步改进的类似合金片材。 此外,用于制造用于荫罩的薄Fe-Ni合金薄板的方法包括以下步骤:(a)将板坯热轧成热轧合金带; (b)在910〜990℃的热轧带材的热轧板退火。 (c)将退火的热轧带材冷轧成冷轧带材; (d)冷轧带材的再结晶退火; (e)根据通过再结晶退火所生成的奥氏体晶粒尺寸D(D mu m),精加工冷轧后的再结晶退火钢带进行冷轧,最终冷却还原率(R)在由 R的范围为16〜75,D范围为6.38D-133.9 / = - 53.8 logt + 806,其中T(℃)是退火的温度。 并提供了进一步修改的类似方法。
    • 7. 发明授权
    • Alloy sheet for shadow mask
    • 荫罩合金板
    • US5620535A
    • 1997-04-15
    • US160399
    • 1993-12-01
    • Tadashi InoueKiyoshi TsuruMichihito HiasaTomoyoshi Okita
    • Tadashi InoueKiyoshi TsuruMichihito HiasaTomoyoshi Okita
    • C21D8/02C22C38/08H01J9/14H01F1/04
    • C21D8/0205C22C38/08H01J9/142C21D2201/05C21D8/0236H01J2229/0733
    • An alloy sheet for making a shadow mask consists essentially of 34 to 38 wt. % Ni, 0.07 wt. % or less Si, 0.002 wt. % or less B, 0.002 wt. % or less O, less than 0.002 wt. % N and the balance being Fe and inevitable impurities;said alloy sheet after annealing before press-forming having 0.2% proof stress of 28 kgf/mm.sup.2 or less; anda gathering degree of {211} plane being 16% or less.A method for manufacturing an alloy sheet comprises:a finish cold-rolling step of cold-rolling the cold-rolled sheet at a cold-rolling reduction ratio in response to an average austenite grain size D (.mu.m), the reduction ratio of final cold-rolling R (%) satisfying the equations below;16.ltoreq.R.ltoreq.75,6.38D-133.9.ltoreq.R.ltoreq.6.38D-51.0a softening annealing step of annealing said cold rolled sheet in a temperature range of 720.degree. to 790.degree. C. for 2 to 40 min. before press-forming and on conditions satisfying the equation below;T.gtoreq.-53.8 log t+806,where T(.degree. C.) is the temperature and t (min.) is the time of the annealing.
    • 用于制造荫罩的合金薄板基本上由34至38wt。 %Ni,0.07重量% %以下Si,0.002重量% %以下B,0.002重量% %以下O,小于0.002重量% %N,余量为Fe和不可避免的杂质; 所述合金板在压制成形之后的退火之后具有28kgf / mm2以下的0.2%的弹性极限应力; {211}飞机的集体度为16%以下。 一种合金板的制造方法,其特征在于,包括:根据平均奥氏体晶粒尺寸D(μm)以冷轧压下率冷轧所述冷轧板的最终冷轧工序,最终的 冷轧R(%)满足以下等式; 16 / = - 53.8log t + 806,其中T(℃)为温度,t(min。)为退火时间。
    • 9. 发明授权
    • Method of manufacturing an alloy sheet
    • 合金板的制造方法
    • US5522953A
    • 1996-06-04
    • US398567
    • 1995-03-03
    • Tadashi InoueKiyoshi TsuruTomoyoshi OkitaMichihito Hiasa
    • Tadashi InoueKiyoshi TsuruTomoyoshi OkitaMichihito Hiasa
    • C21D8/02C22C38/08H01J9/14H01J29/07
    • H01J29/07C21D8/0205C22C38/08H01J9/142C21D2201/05C21D8/0236H01J2229/0733
    • A method for manufacturing an alloy sheet comprising the steps of: (a) hot-rolling a slab containing Fe, Ni and Cr into a hot-rolled strip; (b) annealing the hot-rolled strip at a temperature of 810.degree. to 890.degree. C.; (c) cold-rolling the annealed hot-rolled strip at a reduction ratio of 81 to 94% into a cold-rolled sheet; (d) recrystallization annealing of the cold-rolled sheet; (e) finish cold-rolling the cold-rolled sheet subjected to the recrystallization annealing at a reduction ratio of 14 to 29%; (f) stress relief annealing of the cold-rolled sheet subjected to the finish cold-rolling; and (g) annealing, before press-forming. The cold-rolled sheet subjected to the stress relief annealing at a temperature of 740.degree. to 900.degree. C. for 2 to 40 minutes and satisfying the following equation: T.ltoreq.-123 logt+937, where T is a temperature (.degree.C.) and t is a time (minutes) for the annealing.
    • 一种制造合金薄板的方法,包括以下步骤:(a)将含有Fe,Ni和Cr的板坯热轧成热轧带材; (b)在810℃至890℃的温度下退火该热轧带材; (c)将退火后的热轧带材以81〜94%的压下率冷轧成冷轧板材; (d)冷轧板的再结晶退火; (e)以14〜29%的压下比进行再结晶退火的冷轧板的冷轧, (f)经过精冷轧的冷轧板的应力消除退火; 和(g)在压制成形之前进行退火。 冷轧板在740〜900℃的温度下进行2〜40分钟的应力消除退火,满足以下公式:T = 123logt + 937,其中T为温度 C.),t是退火的时间(分钟)。
    • 10. 发明授权
    • Method for manufacturing thin Fe--Ni alloy sheet for shadow mask
    • 用于制造用于荫罩的薄Fe-Ni合金薄板的方法
    • US5520755A
    • 1996-05-28
    • US342109
    • 1994-11-18
    • Tadashi InoueKiyoshi TsuruTomoyoshi OkitaMichihito Hiasa
    • Tadashi InoueKiyoshi TsuruTomoyoshi OkitaMichihito Hiasa
    • C21D8/02C22C38/08H01J9/14H01J29/07
    • H01J9/142C21D8/0205C22C38/08H01J29/07C21D2201/05C21D8/0236H01J2229/0733
    • A thin Fe--Ni alloy sheet for shadow mask consists essentially of Ni of 34 to 38 wt. %, Si of 0.05 wt. % or less, B of 0.0005 wt. % or less, O of 0.002 wt. % or less and N of 0.0015% or less, the balance being Fe and inevitable impurities; said alloy sheet after annealing before press-forming having 0.2% proof stress of 28.5 kgf/mm.sup.2 or less; and a degree of {211} plane on a surface of said alloy sheet being 16% or less. And further modified similar alloy sheets are also provided.Further, a method for producing a thin Fe--Ni alloy sheet for shadow mask comprises the steps of: (a) hot-rolling of a slab into a hot-rolled alloy strip; (b) hot-rolled sheet annealing of the hot-rolled strip at 910.degree. to 990.degree. C.; (c) cold-rolling of the annealed hot-rolled strip into a cold-rolled strip; (d) recrystallization annealing of the cold-rolled strip; (e) finish cold-rolling of the recrystallization annealed strip at a finish cold reduction ratio in response to austenite grain size D(D.mu.m) yielded by the recrystallization annealing, the finish cold reducration ratio(R) being within a region enclosed by a range of R of 16 to 75 and a range of D of 6.38D-133.9.ltoreq.R.ltoreq.6.38D-51.0 and (f) annealing of the finish cold-rolled strip on conditions of a temperature of 720.degree. to 790.degree. C., a time of 2 to 40 min. and T.gtoreq.-53.8 logt+806, where T(.degree.C.) is the temperature of the annealing. And further modified similar methods are also provided.
    • 用于荫罩的薄Fe-Ni合金板基本上由34至38重量%的Ni组成。 %,Si为0.05wt。 %以下,B为0.0005重量% %以下,O为0.002重量% %以下,N为0.0015%以下,余量为Fe和不可避免的杂质; 压制成形后的退火后的合金板的0.2%的屈服应力为28.5kgf / mm 2以下; 并且所述合金板的表面上的{211}面的程度为16%以下。 还提供了进一步改进的类似合金片材。 此外,用于制造用于荫罩的薄Fe-Ni合金薄板的方法包括以下步骤:(a)将板坯热轧成热轧合金带; (b)在910〜990℃的热轧带钢的热轧板退火。 (c)将退火的热轧带材冷轧成冷轧带材; (d)冷轧带材的再结晶退火; (e)根据再结晶退火产生的奥氏体晶粒尺寸D(D mu),精冷冷轧后的再结晶退火钢带进行冷轧,精冷还原率(R)在由 R的范围为16〜75,D范围为6.38D-133.9 / = - 53.8 logt + 806,其中T(℃)是退火的温度。 并提供了进一步修改的类似方法。