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    • 2. 发明授权
    • Thermally sensitive recording medium
    • 热敏记录介质
    • US06432874B1
    • 2002-08-13
    • US09572088
    • 2000-05-17
    • Tadakazu FukuchiKaoru HamadaKunio TakebayashiHidenori OgawaYoshimi MidorikawaReiko SatoYoshihide Kimura
    • Tadakazu FukuchiKaoru HamadaKunio TakebayashiHidenori OgawaYoshimi MidorikawaReiko SatoYoshihide Kimura
    • B41M540
    • B41M5/44B41M5/30
    • A thermally sensitive recording paper having a recording surface which when a postage stamp or a revenue stamp is adhered to the recording surface requires at least ten cycles of a removal test procedure to remove at least one third of the adhered surface of the stamp from the recording surface of the thermally sensitive recording paper, wherein the removal test procedure comprises adhering the postage stamp or revenue stamp to the recording surface of the thermally sensitive recording paper, hanging the recording paper over an iron bar of about 8 mm diameter with the postage stamp or revenue stamp on an outer surface of the recording paper, adjusting the recording paper such that equal lengths are on either side of the iron bar, attaching to one end of the thermally sensitive recording paper a weight of about 500 g, holding the other end of the thermally sensitive recording paper by hand and carrying out a pull down ant put back cycle motion of the hand to move the postage stamp or revenue stamp over the iron bar until at least a portion of the postage stamp or revenue stamp is removed from the surface of the recording paper.
    • 一种具有记录表面的热敏记录纸,当邮票或收入印记附着在记录表面上时,需要至少十个循环的去除测试程序,以从记录中去除印模的粘附表面的至少三分之一 热敏记录纸的表面,其中去除测试程序包括将邮票或收入印章粘贴到热敏记录纸的记录表面上,将该记录纸用约8mm直径的铁棒用邮资戳或 记录纸的外表面上的收入印章,调整记录纸,使得相同的长度在铁棒的任一侧上,附着在热敏记录纸的一端,重量约为500g,保持另一端 手感热敏记录纸,并执行拉下蚂蚁放回手的循环运动,以移动邮票或邮寄 场地邮票在铁条上,直到从记录纸的表面移除至少一部分邮票或收据。
    • 3. 发明授权
    • Thermally sensitive recording medium
    • 热敏记录介质
    • US06303540B1
    • 2001-10-16
    • US09431052
    • 1999-11-01
    • Tadakazu FukuchiKaoru HamadaYuji TsuzukiYoshihide KimuraTomoaki NagaiYutaka Wakita
    • Tadakazu FukuchiKaoru HamadaYuji TsuzukiYoshihide KimuraTomoaki NagaiYutaka Wakita
    • B41M530
    • B41M5/3336B41M5/3375
    • A thermally sensitive recording medium which has thermally sensitive recording layer containing colorless or pale colored basic leuco dye and organic color developer as main components on a substrate, wherein said thermally sensitive recording layer contains diphenylsulfone bridgeable type compound represented by general formula (1) and at least one compound represented by general formula (1). In general formula (2), X and Y can be different and indicates a saturated or an unsaturated liner or grafted hydrocarbon group of carbon number 1-12 which can possess ether bond, or indicates wherein R indicates a methylene group or an ethylene group, T indicates a hydrogen atom or an alkyl group of carbon number 1-4, and R1-R6 independently indicate a halogen atom, an alkyl group of carbon number 1-6, or an alkenyl group, further, m, n, p, q, r, t indicate an integer number of 0-4 and when are bigger than 2, R1-R6 can be different, and a is an integer of 0-10. In general formula (2), R7 represents an alkyl group of carbon number 1-6 or an electron attracting group, u is an integer of 0-2.
    • 一种热敏记录介质,其具有含有无色或浅色基础无色染料和有机彩色显影剂作为主要成分的热敏记录层,其中所述热敏记录层含有通式(1)表示的二苯砜桥连型化合物, 至少一种由通式(1)表示的化合物。在通式(2)中,X和Y可以不同,表示可以具有醚键的碳数1-12的饱和或不饱和的内衬或接枝烃基,或表示在 R表示亚甲基或亚乙基,T表示氢原子或碳数为1-4的烷基,R1-R6独立地表示卤素原子,碳原子数为1-6的烷基或烯基 此外,m,n,p,q,r,t表示0-4的整数,当大于2时,R1-R6可以不同,a是0-10的整数。在通式( 2),R7表示 碳数1-6的烷基或吸电子基团,u为0-2的整数。
    • 4. 发明授权
    • Multi chromatic thermally sensitive recording medium
    • 多色热敏记录介质
    • US06579828B1
    • 2003-06-17
    • US09680928
    • 2000-10-10
    • Kaoru HamadaTadakazu FukuchiYoshimi MidorikawaYoshihide Kimura
    • Kaoru HamadaTadakazu FukuchiYoshimi MidorikawaYoshihide Kimura
    • B41M530
    • B41M5/3333B41M5/3331
    • A multi chromatic thermally sensitive recording medium comprising, a higher temperature color developing layer containing dye precursor and an organic color developer that reacts with said dye precursor and develops color by heating, and at least one lower temperature color developing layer that develops different color from that of said higher temperature color developing layer and develops color by lower temperature than the color developing temperature of said higher temperature color developing layer laminated in order on a substrate, wherein an organic color developer contained in said higher temperature color developing layer contains said diphenylsulfone bridgeable type compound represented by general formula (1) and/or said 3-{[(phenylamine)carbonyl]amino}benzenesulfoneamide compound represented by general formula (2), wherein, X and Y can be different and indicates a saturate or an unsaturated liner or grafted hydrocarbon group of carbon number 1 to 12 which can possess an ether bond, or wherein R indicates a methylene group or an ethylene group, T indicates a hydrogen atom or an alkyl group of carbon number 1 to 4, and R1 to R6 independently indicate a halogen atom, an alkyl group of carbon number 1 to 6 or an alkenyl group, further m, n, p, q, r, t indicate an integer number of 0 to 4 and when are bigger than 2, R1 to R6 can be different and a is an integer of 0 to 10.
    • 一种多色热敏记录介质,包括:含有染料前体的高温彩色显影层和与所述染料前体反应并通过加热显色的有机彩色显影剂;以及至少一种与该色素前体形成不同颜色的低温彩色显影层 的所述高温彩色显影层,并且通过比在所述高温彩色显影层的彩色显影温度更低的温度显影出颜色,所述显色温度依次层压在基板上,其中所述高温彩色显影层中所含的有机彩色显影剂含有所述二苯砜可桥接型 由通式(1)表示的化合物和/或由通式(2)表示的所述3 - {[(苯基胺)羰基]氨基}苯磺酰胺化合物,其中X和Y可以不同,表示饱和或不饱和的内衬或 碳原子数1〜12的可接受烃基的接枝烃基 R键,或其中R表示亚甲基或亚乙基,T表示氢原子或碳数1〜4的烷基,R1〜R6独立地表示卤素原子,碳原子数为1〜6的烷基或 烯基,另外m,n,p,q,r,t表示0〜4的整数,当大于2时,R 1〜R 6可以不同,a为0〜10的整数。
    • 5. 发明授权
    • Thermal recording material
    • 热敏记录材料
    • US06407036B1
    • 2002-06-18
    • US09674299
    • 2000-10-31
    • Yoshimi MidorikawaNaomi SumikawaYuji TsuzukiTomoniri SekineKaoru HamadaYoshihide Kimura
    • Yoshimi MidorikawaNaomi SumikawaYuji TsuzukiTomoniri SekineKaoru HamadaYoshihide Kimura
    • B41M530
    • B41M5/3336B41M5/3375
    • A thermal recording sheet which is satisfactory in sensitivity in color development, background heat resistance, and background color, is free from powdering, and has excellent image retention. The sheet comprises supporting and formed thereon a thermal color development layer containing as main components a colorless or light-colored basic dye and an organic color developer, and is characterized in that the thermal color development layer contains at least one dihydroxydiphenyl sulfone compound represented by general formula (1) as the organic color developer, and further contains either at least one saturated fatty acid monoamide represented by general formula (2) in an amount of 1.5 to 5 parts per part of the organic color developer or a combination of at least one saturated fatty acid monoamide represented by general formula (2) and at least one diphenyl sulfone derivative represented by the general formula (3). In said formulas, R1 and R2 each represents C1-8 alkyl, alkenyl, or halogeno; and a and b each is an integer of 0 to 3; R3 represents C11-21 alkyl; and R4 to R9 each represents hydrogen, alkyl, halogeno, nitro, alkoxy, cyano, or allyloxy.
    • 在显色性,背景耐热性和背景颜色方面的感光度令人满意的热敏记录片材没有粉化,并且具有优异的图像保留性。 该片材包括在其上形成含有无色或浅色碱性染料和有机彩色显影剂作为主要成分的热显色层,其特征在于,热显色层含有至少一种二氢二苯基砜化合物 式(1)表示的化合物,并且还含有至少一种由通式(2)表示的饱和脂肪酸单酰胺,其用量为每份有机彩色显影剂1.5至5份或至少一种 由通式(2)表示的饱和脂肪酸单酰胺和由通式(3)表示的至少一种二苯砜衍生物。 在所述式中,R 1和R 2各自表示C 1-8烷基,烯基或卤素; a和b各自为0〜3的整数; R 3表示C 11-21烷基; 并且R 4至R 9各自表示氢,烷基,卤代,硝基,烷氧基,氰基或烯丙氧基。