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    • 1. 发明授权
    • High density metal boride-based ceramic sintered body
    • 高密度金属硼化物陶瓷烧结体
    • US5036028A
    • 1991-07-30
    • US511816
    • 1990-04-18
    • Tadahiko WatanabeTsuyoshi DoutsuKazuhisa ShobuYukio Kai
    • Tadahiko WatanabeTsuyoshi DoutsuKazuhisa ShobuYukio Kai
    • C04B35/58
    • C04B35/5805C04B35/58064C04B35/58071C04B35/58078C04B35/645
    • A high density metal-boride based ceramic sintered body consists essentially of component (A) at least one of TiB.sub.2, ZrB.sub.2, CrB.sub.2, HfB.sub.2, VB.sub.2, TaB.sub.2, NbB.sub.2, MnB.sub.2, MoB.sub.2, YB.sub.2, AlB.sub.2, MgB.sub.2, CrB, VB, TaB, NbB, MoB, HfB, YB, ZrB, HfB, TiB, MnB, W.sub.2 B.sub.5 and Mo.sub.2 B.sub.5, componet (B) 0.1 wt. %-10 wt. % based on the total amount of a metal binder comprising at least one of cobalt boride, nickel boride and iron boride, and component (C) 0.1 wt. %-10 wt. % based on the total amount of at least one of a double carbide comprising Ti, Zr, W and C, ZrCN, HfCN, or a double carbo-nitride comprising Ti, Zr, Hf and C, N.The sintered body is not easily oxidized and has extremely few pores and high shock resistance even using a fine grain raw material powder because component (C) has an oxygen removing effect during sintering.
    • 高密度金属硼化物系陶瓷烧结体主要由TiB 2,ZrB 2,CrB 2,HfB 2,VB 2,TaB 2,NbB 2,MnB 2,MoB 2,YB 2,AlB 2,MgB 2,CrB,VB,TaB ,NbB,MoB,HfB,YB,ZrB,HfB,TiB,MnB,W2B5和Mo2B5,组分(B)0.1wt。 %-10wt。 基于包含钴硼化物,硼化镍和硼化物中的至少一种的金属粘合剂的总量的%,和组分(C)0.1重量% %-10wt。 基于包含Ti,Zr,W和C,ZrCN,HfCN或包含Ti,Zr,Hf和C,N的双碳氮化物中的至少一种的总量的%。烧结体不容易 氧化,并且即使使用细粒原料粉末也具有极少的孔和高抗冲击性,因为组分(C)在烧结期间具有除氧效果。