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1. 发明申请

WO2009147522A1 METHOD FOR GLYCOSYLATING AND SEPARATING PLANT FIBER MATERIAL 审中-公开
标题翻译：用于糖化和分离植物纤维材料的方法
公开(公告)号：WO2009147522A1
公开(公告)日：2009-12-10
申请号：PCT/IB2009005927
申请日：2009-06-02
申请人： TOYOTA MOTOR CO LTD , TAKESHIMA SHINICHI , KIKUCHI TAKESHI
发明人： TAKESHIMA SHINICHI , KIKUCHI TAKESHI
IPC分类号： C13K1/02
CPC分类号： C13K1/02
摘要： The invention relates to a method for hydrolyzing a plant fiber material and producing and separating a saccharide including glucose. The method of the invention includes a hydrolysis process of using a cluster acid catalyst in a pseudo-molten state to hydrolyze cellulose contained in the plant fiber material and produce glucose. In the hydrolysis process, the cluster acid catalyst and a first amount of the plant fiber material that increases a viscosity of the cluster acid catalyst in a pseudo-molten state when added to the cluster acid catalyst in a pseudo-molten state are heated and mixed, and a second amount of the plant fiber material is then further added when the decrease in viscosity of the heated mixture occurs.
摘要翻译：本发明涉及水解植物纤维材料并生产和分离包括葡萄糖的糖类的方法。本发明的方法包括使用假熔融状态的簇酸催化剂水解纤维素中所含的纤维素并产生葡萄糖的水解方法。在水解过程中，将加入到熔融状态的聚氨酯催化剂中的模拟熔融状态下的聚氨酯酸催化剂的粘度增加的簇酸催化剂和第一量的植物纤维材料加热混合然后当加热的混合物的粘度降低时，进一步添加第二量的植物纤维材料。

2. 发明申请

WO2009147521A8 METHOD FOR GLYCOSYLATING AND SEPARATING PLANT FIBER MATERIAL 审中-公开
标题翻译：用于糖化和分离植物纤维材料的方法
公开(公告)号：WO2009147521A8
公开(公告)日：2010-11-25
申请号：PCT/IB2009005920
申请日：2009-06-02
申请人： TOYOTA MOTOR CO LTD , TAKESHIMA SHINICHI , KIKUCHI TAKESHI
发明人： TAKESHIMA SHINICHI , KIKUCHI TAKESHI
IPC分类号： C13K1/02
CPC分类号： C13K1/02
摘要： The invention relates to a method for hydrolyzing the plant fiber material to produce and separate a saccharide including glucose. The method includes a hydrolysis process of hydrolyzing cellulose contained in the plant fiber material and producing glucose in a first organic solvent having a cluster acid catalyst dissolved therein.
摘要翻译：本发明涉及水解植物纤维材料以产生和分离包含葡萄糖的糖的方法。该方法包括水解含有植物纤维材料中的纤维素并在其中溶解有簇酸催化剂的第一有机溶剂中产生葡萄糖的水解方法。

3. 发明申请

WO2008132605A9 PLANT-FIBER-MATERIAL TRANSFORMATION METHOD 审中-公开
标题翻译：植物纤维材料转化方法
公开(公告)号：WO2008132605A9
公开(公告)日：2008-12-18
申请号：PCT/IB2008001528
申请日：2008-04-25
申请人： TOYOTA MOTOR CO LTD , TAKESHIMA SHINICHI , KOYAMA AKIO
发明人： TAKESHIMA SHINICHI , KOYAMA AKIO
IPC分类号： C13K1/02 , C13K1/04
CPC分类号： C13K1/02 , C13K1/04
摘要： Cellulose contained in plant fiber material is hydrolyzed with the use of a pseudo-molten cluster acid as a hydrolysis catalyst to produce saccharide, most of which is glucose. After the glucose is produced, the saccharide is precipitated with the use of an organic solvent, and the saccharide including a solidified saccharide during the hydrolysis and the precipitated saccharide is separated from residues' and the cluster acid.
摘要翻译：植物纤维材料中所含的纤维素通过使用假熔融簇酸作为水解催化剂水解，生成糖，其中大部分是葡萄糖。葡萄糖生成后，使用有机溶剂使糖析出，水解过程中包含固化糖的糖类和析出的糖类与残基和簇酸分离。

4. 发明申请

WO2009147523A8 METHOD FOR GLYCOSYLATING AND SEPARATING PLANT FIBER MATERIAL 审中-公开
标题翻译：用于糖化和分离植物纤维材料的方法
公开(公告)号：WO2009147523A8
公开(公告)日：2010-11-25
申请号：PCT/IB2009005928
申请日：2009-06-02
申请人： TOYOTA MOTOR CO LTD , TAKESHIMA SHINICHI , KIKUCHI TAKESHI
发明人： TAKESHIMA SHINICHI , KIKUCHI TAKESHI
IPC分类号： C13K1/02
CPC分类号： C13K1/02
摘要： The invention relates to a method for hydrolyzing a plant fiber material to produce and separate a saccharide including glucose. The method includes a hydrolysis process of using a cluster acid catalyst in a pseudo-molten state to hydrolyze cellulose contained in the plant fiber material, and produce glucose. The cluster acid catalyst is subjected to a clustering enhancing treatment by which clustering of the cluster acid catalyst in a crystalline state is enhanced.
摘要翻译：本发明涉及一种用于水解植物纤维材料以产生和分离包括葡萄糖的糖的方法。该方法包括在假熔融状态下使用簇酸催化剂水解纤维素中所含的纤维素并产生葡萄糖的水解方法。聚簇酸催化剂进行聚簇增强处理，通过该聚集增强处理，晶体状态的聚集酸催化剂的聚集得到增强。

5. 发明专利

ES2555866T3 Procedimiento de producción de hidrógeno 未知
公开(公告)号：ES2555866T3
公开(公告)日：2016-01-11
申请号：ES11811168
申请日：2011-12-07
申请人： TOYOTA MOTOR CO LTD
发明人： TAKESHIMA SHINICHI , NAKAMURA NORIHIKO
IPC分类号： C01B3/06 , C01B17/50
摘要： Procedimiento de producción de hidrógeno que comprende separar el agua en hidrógeno y oxígeno, en el que el procedimiento comprende la descomposición de ácido sulfúrico en agua, dióxido de azufre y oxígeno a través de una reacción representada por la fórmula (X1) siguiente utilizando energía térmica solar, la reacción representada por la fórmula (X1) siguiente incluye unas reacciones elementales representadas por las fórmulas (X1-1) y (X1-2) siguientes, por lo menos una parte de la reacción elemental de la fórmula (X1-1) siguiente se lleva a cabo utilizando energía solar térmica, por lo menos una parte de la reacción elemental de la fórmula (X1-2) siguiente se lleva a cabo utilizando energía térmica adicional proporcionada por la combustión de hidrógeno añadido en un recipiente de reacción utilizado para llevar a cabo las reacciones elementales de la fórmula (X1-1) y/o la fórmula (X1-2), y el equilibrio de reacción representado por la fórmula (X1-2) siguiente se desplaza al lado de producción de dióxido de azufre por reacción del hidrógeno añadido restante tras la combustión y del oxígeno generado por la conversión de SO3 a SO2, y en el que la temperatura de calentamiento mediante dicha energía térmica adicional es superior en 10ºC o más a la temperatura de calentamiento mediante la energía térmica solar, y por lo menos una parte de dicha energía térmica adicional se genera en el recipiente de reacción utilizado para llevar a cabo las reacciones elementales de la fórmula (X1-1) y/o la fórmula (X1-2), y la reacción del hidrógeno añadido restante tras la combustión y del oxígeno generado por la conversión de SO3 a SO2 se produce en el recipiente de reacción utilizado para llevar a cabo la reacción elemental de la fórmula (X1-2): (X1) H2SO4 → H2O + SO2 + 1/2O2 (X1-1) H2SO4 → H2O + SO3 (X1-2) SO3 → SO2 + 1/2O2

6. 发明专利

AU2011350411B2 Catalyst for decomposition of sulfur trioxide and hydrogen production process 未知
公开(公告)号：AU2011350411B2
公开(公告)日：2014-08-07
申请号：AU2011350411
申请日：2011-12-27
申请人： UNIV KUMAMOTO NAT UNIV CORP , TOYOTA MOTOR CO LTD
发明人： TAKESHIMA SHINICHI , MACHIDA MASATO
IPC分类号： B01J23/22 , B01J23/847 , B01J35/10 , B01J37/02 , C01B3/06
摘要： To provide a sulfur trioxide decomposition catalyst, particularly, a sulfur trioxide decomposition catalyst capable of lowering the temperature required when producing hydrogen by an S-I cycle process. A sulfur trioxide decomposition catalyst comprising a composite oxide of vanadium and at least one metal selected from the group consisting of transition metal and rare earth elements is provided. Also, a sulfur dioxide production process comprising decomposing sulfur trioxide into sulfur dioxide and oxygen by using the sulfur trioxide decomposition catalyst above, is provided. Furthermore, a hydrogen production process, wherein the reaction of decomposing sulfur trioxide into sulfur dioxide and oxygen by an S-I cycle process is performed by the above-described sulfur dioxide production process, is provided.

7. 发明专利

AU2011350411A1 Catalyst for decomposition of sulfur trioxide and hydrogen production process 未知
公开(公告)号：AU2011350411A1
公开(公告)日：2013-07-04
申请号：AU2011350411
申请日：2011-12-27
申请人： UNIV KUMAMOTO NAT UNIV CORP , TOYOTA MOTOR CO LTD
发明人： TAKESHIMA SHINICHI , MACHIDA MASATO
IPC分类号： B01J23/22 , B01J23/847 , B01J35/10 , B01J37/02 , C01B3/06
摘要： To provide a sulfur trioxide decomposition catalyst, particularly, a sulfur trioxide decomposition catalyst capable of lowering the temperature required when producing hydrogen by an S-I cycle process. A sulfur trioxide decomposition catalyst comprising a composite oxide of vanadium and at least one metal selected from the group consisting of transition metal and rare earth elements is provided. Also, a sulfur dioxide production process comprising decomposing sulfur trioxide into sulfur dioxide and oxygen by using the sulfur trioxide decomposition catalyst above, is provided. Furthermore, a hydrogen production process, wherein the reaction of decomposing sulfur trioxide into sulfur dioxide and oxygen by an S-I cycle process is performed by the above-described sulfur dioxide production process, is provided.

8. 发明专利

CA2697449C METHOD OF SACCHARIFICATION AND SEPARATION FOR PLANT FIBER MATERIALS 未知
公开(公告)号：CA2697449C
公开(公告)日：2012-10-23
申请号：CA2697449
申请日：2008-08-29
申请人： TOYOTA MOTOR CO LTD
发明人： TAKESHIMA SHINICHI , KIKUCHI TAKESHI
IPC分类号： C13K1/02 , B01D11/02 , B09B3/00 , C07H1/08
摘要： The present invention is to provide a high-purity aqueous saccharide solution by increasing the collection rate of cluster acid which is a hydrolysis catalyst for cellulose in saccharification and separation for cellulose using a cluster acid catalyst. A method of saccharification and separation for plant fiber materials of the present invention comprises: a hydrolysis step of hydrolyzing cellulose contained in the plant fiber materials using a cluster acid catalyst in a pseudo-molten state to produce saccharide, most of which is glucose; a first separation step of separating a mixture containing an aqueous saccharide solution in which at least a portion of the saccharide produced in the hydrolysis step is dissolved, a cluster acid organic solvent solution in which the cluster acid catalyst is dissolved, and residues into a solid content containing the residues and a liquid content containing the aqueous saccharide solution and the cluster acid organic solvent solution; and a second separation step of dehydrating the liquid content, which contains the aqueous saccharide solution and the cluster acid organic solvent solution and is separated in the first separation step, by a dehydration means capable of absorbing water through chemical absorption to deposit the saccharide in the aqueous saccharide solution, and separating a solid content containing the saccharide from a liquid content containing the cluster acid catalyst and the organic solvent.

9. 发明专利

DE602006014805D1 BRENNKRAFTMOTORSTEUERVORRICHTUNG UND ABGASREINIGUNGSVERFAHREN 未知
公开(公告)号：DE602006014805D1
公开(公告)日：2010-07-22
申请号：DE602006014805
申请日：2006-03-17
申请人： TOYOTA MOTOR CO LTD
发明人： ITO HIROSHI , HAYASHI KOTARO , YAMASHITA TETSUYA , TAKESHIMA SHINICHI
IPC分类号： F02D41/08 , F01M1/16 , F01N3/02 , F01N3/24 , F02D41/12 , F02D45/00

10. 发明专利

DE69326217T3 未知
公开(公告)号：DE69326217T3
公开(公告)日：2009-11-12
申请号：DE69326217
申请日：1993-06-10
申请人： TOYOTA MOTOR CO LTD
发明人： TAKESHIMA SHINICHI , TANAKA TOSHIAKI , IGUCHI SATOSHI , ARAKI YASUSHI , HIROTA SHINYA , ODA TOMOHIRO , MURAKAMI FUMITADA
IPC分类号： F01N3/28 , B01D53/04 , B01D53/34 , B01D53/86 , B01D53/94 , B01J23/58 , F01N3/08 , F01N3/20 , F01N3/24 , F01N9/00 , F01N13/02 , F02B1/04 , F02D41/02 , F02D41/14
摘要： An NOx absorbing agent (17) is disposed inside an exhaust gas passage of a combustion engine. This NOx absorbing agent (17) absorbs NOx when the air/fuel ratio of exhaust gas flowing thereinto is lean, and discharges NOx which it has absorbed when the air/fuel ratio of exhaust gas flowing thereinto becomes rich. The amount of NOx absorbed in the NOx absorbing agent (17) is estimated from the engine load and the number of revolutions of the engine, and when this estimated NOx amount becomes the maximum NOx absorbing capacity of the NOx absorbing agent (17), the air/fuel ratio of exhaust gas flowing into the NOx absorbing agent (17) is made rich.

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