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1. 发明专利

JPH04371232A PRODUCTION OF CARRIER FOR CATALYST FOR PURIFICATION OF EXHAUST GAS 失效
公开(公告)号：JPH04371232A
公开(公告)日：1992-12-24
申请号：JP17593791
申请日：1991-06-20
申请人： TOYOTA CENTRAL RES & DEV , TOYOTA MOTOR CORP , TOSOH CORP
发明人： SUZUKI TADASHI , KIMURA MAREO , KONDO SHIRO , ADACHI MARIKO , ISHIBASHI KAZUNOBU , MATSUMOTO SHINICHI , OKANIWA HIROSHI , SEKIZAWA KAZUHIKO
IPC分类号： B01D53/94 , B01J29/06
摘要： PURPOSE:To improve the heat resistance and durability of a zeolite carrier used for a catalyst for purification of exhaust gas. CONSTITUTION:Coarse crystalline zeolite of >=2mum particle diameter having >=20 molar ratio of SiO2, to Al2O3 is prepd. and pulverized to produce a zeolite carrier contg. >=10wt.% fine particles of 0.1-2mum particle diameter. This zeolite carrier is suitable for use as the carrier of a catalyst for removal of NO from exhaust gas contg. excess oxygen.

2. 发明公开

EP2857356A4 SILICOALUMINOPHOSPHATE, METHOD FOR PRODUCING SAME, AND SOLID ACID CATALYST COMPRISING SAME 有权
标题翻译：硅片，方法其生产和固体酸催化剂，该催化剂
公开(公告)号：EP2857356A4
公开(公告)日：2016-01-06
申请号：EP13794531
申请日：2013-05-23
申请人： TOSOH CORP
发明人： OKANIWA HIROSHI , AOYAMA HIDEKAZU
IPC分类号： C01B37/08 , C01B39/54
CPC分类号： C01B39/54 , B01J29/80 , B01J29/85 , B01J35/023 , B01J37/08 , C01B39/023

3. 发明专利

JP2004105298A Treating method for organic chlorine compound 审中-公开
公开(公告)号：JP2004105298A
公开(公告)日：2004-04-08
申请号：JP2002268989
申请日：2002-09-13
申请人： Tosoh Corp , 東ソー株式会社
发明人： OKANIWA HIROSHI , AMAN SHUNJI
IPC分类号： A62D3/34 , A62D3/37 , A62D101/22 , A62D101/28 , B09B3/00 , B09C1/02 , B09C1/08 , C07B35/06 , C07D319/24 , A62D3/00
摘要： PROBLEM TO BE SOLVED: To provide a treating method for an organic chlorine compound which is industrially advantageous by reducing harmful effects of a highly toxic organic chlorine compound such as dioxins, polychlorinated biphenyls or substances containing toxic organic chlorine compounds such as chlorobenzenes used as precursors of these toxic substances (flying ash, soil, bottom sediment, or the like) at an ordinary temperature without heating.
SOLUTION: The organic chlorine compound is treated by bringing the substance containing the organic chlorine compound into contact with an alkaline metal compound and an aliphatic alcohol compound.
COPYRIGHT: (C)2004,JPO

4. 发明专利

JPH11290691A DIMERIZATION CATALYST COMPOSITION OF OLEFIN AND OLEFIN DIMERIZATION 失效
公开(公告)号：JPH11290691A
公开(公告)日：1999-10-26
申请号：JP10453198
申请日：1998-04-15
申请人： TOSOH CORP
发明人： WATANABE MASATO , OKANIWA HIROSHI , KOIE YASUYUKI
IPC分类号： B01J23/755 , B01J31/28 , C07C2/24 , C07C11/02
摘要： PROBLEM TO BE SOLVED: To obtains a catalyst composition to be used for producing commercially useful 8C or more olefins with high activity and highly selectively and to provide a method for manufacturing the catalyst composition. SOLUTION: A >=4C olefin dimerization catalyst composition is used which comprises a zero valency nickel compound, a trivalent organic phosphorus compound, a fluorinated sulfonic acid and a fluorinated alcohol. In particular, the dimerization catalyst composition is used which comprises, for example, bis(cycloocta-1,5-diene) nickel, phosphine, trifluoromethane sulfonic acid and 2,2,2-trifluoroethanol.

5. 发明专利

JPH0360412A PRODUCTION OF CRYSTALLINE ALUMINOPHOSPHATE 失效
公开(公告)号：JPH0360412A
公开(公告)日：1991-03-15
申请号：JP19253789
申请日：1989-07-27
申请人： TOSOH CORP
发明人： OKANIWA HIROSHI , INAOKA WATARU , NISHIMURA TORU
IPC分类号： C01B25/36
摘要： PURPOSE:To obtain a molecular sieve having a prescribed X-ray diffraction pattern as powder and a porous structure having uniform pore size by holding a mixture contg. a phosphoric acid source, an alumina source and ethylpropylamine in prescribed ratios at a prescribed temp. CONSTITUTION:A phosphoric acid source and an alumina source are mixed with water and ethylpropylamine or diethylamine or further mixed with a hydroxy ion source so as to satisfy molar ratios of P2O5/Al2O3=(0.8-1.5), H2O/Al2 O3=(20-100) R/Al2O3 >=0.05 [R is C2H5NHC3H7 or (C2H5)2NH], OH /Al2O3>=0, (OH +R)/Al2O3 +0.7R)/Al2O3>=0.47. The resulting mixture is held at 110-200 deg.C and crystalline aluminophosphate represented by a formula Al2O3, 1+ or -0.2P2O5 and having an X-ray diffraction pattern shown in the table as powder is obtd.

6. 发明专利

JPH02129015A PRODUCTION OF CELLULAR CRYSTALLINE SILICATE 失效
公开(公告)号：JPH02129015A
公开(公告)日：1990-05-17
申请号：JP27937088
申请日：1988-11-07
申请人： TOSOH CORP
发明人： OKANIWA HIROSHI , KASAHARA MOTOJI
IPC分类号： B01J20/18 , C01B37/02 , C01B39/04
摘要： PURPOSE:To enable production of a silicate resembling ZSM-48 from a raw material with hardly any danger by mixing a tetramethylammonium ion source with a silicon, Al, OH sources and water and keeping the prepared reaction mixture at a specific temperature. CONSTITUTION:A tetramethylammonium ion source is mixed with a silicon, aluminum, hydroxy ion sources and water to prepare a reaction mixture having the following composition expressed in terms of molar ratios of oxides. >=50 SiO2/Al2O3, 0.04-0.10 OH /SiO2, 15-60 H2O/SiO2 and 0.05-1.0 TMA /SiO2 (TMA is tetramethylammonium ion). The resultant reaction mixture is then kept at 100-200 deg.C temperature to afford a cellular crystalline silicate having a powder X-ray diffraction pattern including spacings shown in the table. There is no upper limit in values of the above-mentioned SiO2/Al2O3. That is a silicate resembling ZSM-48 without containing aluminum can be synthesized.

7. 发明专利

JPS63260809A CRYSTALLINE BOROALUMINOSILICATE AND PRODUCTION THEREOF 失效
公开(公告)号：JPS63260809A
公开(公告)日：1988-10-27
申请号：JP22533287
申请日：1987-09-10
申请人： TOSOH CORP
发明人： OKANIWA HIROSHI , KASAHARA SENJI
IPC分类号： B01J20/20 , B01J20/02 , B01J29/86 , C01B35/10 , C01B39/04 , C01B39/12
摘要： PURPOSE:To obtain the titled substance having fine pore diameter and excellent adsorption characteristics and catalytic characteristics and useful as a molecular sieve, adsorbent, catalyst component, etc., by mixing an organic cation source, an Si source, an Al source, a B source, an alkali ion source, etc., and water and crystallizing the obtained reaction mixture at a specific temperature. CONSTITUTION:An organic cation source (e.g. tetramethylammonium chloride), an Si source (e.g. amorphous silica), an Al source (e.g. alumina sol), a B source (e.g. boric acid or its salt) and one or more alkali ion sources selected from alkali or alkaline earth metal ion source, NH4 ion source, etc., (e.g. NaOH) are added to water and uniformly mixed to obtain a reaction mixture having a molar composition of formula I (R is organic cation; M' is alkali ion; n' is atomic valence of M'). The mixture is crystallized by maintaining at 100-250 deg.C for 2-200hr preferably under atmospheric pressure and the objective porous substance is separated and recovered from the product. The obtained substance exhibits a powder X-ray diffraction pattern shown in the Table II (W, M, S and VS represent 'weak', 'middle', 'strong' and 'very strong', respectively) in unbaked state and has a chemical composition of formula III (0 =15; M is cation; n is atomic valence of M) in an anhydrous state.

8. 发明专利

JP2014114203A Silicoaluminophosphate salt and method for producing the same 有权
标题翻译：硅烷基磷酸盐及其制备方法
公开(公告)号：JP2014114203A
公开(公告)日：2014-06-26
申请号：JP2013170641
申请日：2013-08-20
申请人： Tosoh Corp , 東ソー株式会社
发明人： OKANIWA HIROSHI , TOKUNAGA KEISUKE , AOYAMA HIDEKAZU , NAGAI YOSHIKAZU , YOSHIMITSU MITSUAKI
IPC分类号： C01B39/54 , B01D53/94 , B01J29/85 , F01N3/10 , F01N3/28
摘要： PROBLEM TO BE SOLVED: To provide a SAPO-47 which gives a catalyst having a high catalytic activity, especially a high catalytic activity at low temperatures and a method for producing the same.SOLUTION: There is provided a SAPO-47 having an average crystal particle diameter of less than 5 μm and an Si/Al molar ratio of less than 0.23. Additionally, in the SAPO-47, the amount of solid acid after a hydration treatment with respect to the amount of solid acid before a hydration treatment is preferably 40% or more. This SAPO-47 can be produced by a production method having a crystallization process in which a mixture containing alkylethylenediamine is crystallized.
摘要翻译：要解决的问题：提供一种SAPO-47，其提供具有高催化活性，特别是在低温下的高催化活性的催化剂及其制备方法。解决方案：提供具有平均晶体的SAPO-47 粒径小于5μm，Si / Al摩尔比小于0.23。此外，在SAPO-47中，水合处理后的固体酸相对于水合处理前的固体酸的量优选为40％以上。该SAPO-47可以通过结晶方法的制造方法制造，其中含有烷基乙二胺的混合物结晶。

9. 发明专利

JP2003340289A Photocatalyst composition 审中-公开
标题翻译：光催化组合物
公开(公告)号：JP2003340289A
公开(公告)日：2003-12-02
申请号：JP2002158095
申请日：2002-05-30
申请人： Tosoh Corp , 東ソー株式会社
发明人： OKANIWA HIROSHI
IPC分类号： B01D53/86 , B01J27/24 , B01J35/02 , B01J37/04
摘要： PROBLEM TO BE SOLVED: To obtain a photocatalyst composition having high photocatalytic activity by visible light as well as by ultraviolet rays. SOLUTION: A titanium oxide type visible light responsive photocatalyst such as a metal-doped type titanium oxide into which a metal such as chromium or vanadium is introduced, an oxygen deficient type titanium oxide modified by plasma method, anion-doped titanium oxide into which anions such as nitrogen or sulfur are introduced and a photocatalyst such as titanium oxide, zinc oxide or strontium titanate having a specific surface area higher than that of the visible light responsive photocatalyst are contained in a weight ratio of 5:95-99:1 to obtain the photocatalyst composition. This composition is dispersed in a solvent such as water or an alcohol to prepare a coating agent. This coating argent is formed on the surface of an article. The high photocatalytic activity can be developed indoors or outdoors. COPYRIGHT: (C)2004,JPO
摘要翻译：要解决的问题：获得可见光和紫外线具有高光催化活性的光催化剂组合物。解决方案：引入金属如铬或钒的金属掺杂型氧化钛的氧化钛型可见光响应性光催化剂，通过等离子体法改性的缺氧型氧化钛，阴离子掺杂二氧化钛导入阴离子如氮或硫的光催化剂，比表面积高于可见光响应光催化剂的钛氧化物，氧化锌或钛酸锶等光催化剂的重量比为5：95〜99： 1，得到光催化剂组合物。将该组合物分散在溶剂如水或醇中以制备涂布剂。该涂层基体形成在制品的表面上。高光催化活性可在室内或户外进行。版权所有（C）2004，JPO

10. 发明专利

JP2576151B2 失效
公开(公告)号：JP2576151B2
公开(公告)日：1997-01-29
申请号：JP27823687
申请日：1987-11-05
申请人： TOSOH CORP
发明人： OKANIWA HIROSHI , KASAHARA SENJI
IPC分类号： C01B33/20 , B01J21/06 , B01J29/70 , C01B39/04 , C01B39/06 , C01B39/08

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