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    • 1. 发明专利
    • POLYESTER BOTTLE
    • JPH03200534A
    • 1991-09-02
    • JP34439789
    • 1989-12-28
    • TOYO BOSEKIYOSHINO KOGYOSHO CO LTD
    • ISAKA TSUTOMUMIKO TSUTOMUKUSHIDA HIDEOASAI SUNAOKOSHIO SHUICHI
    • B65C3/26B29C61/06B29K67/00B29K105/02B32B7/02
    • PURPOSE:To prevent a transparent part from being folded by a method wherein a specific heat-shrinkable polyester film is formed into a tubular label, at least one side of either or both ends of the label is put into print, so that the transparent part is given a specific dimension axially, and the transparent part is coated with a transparent organic high-molecular resin. CONSTITUTION:A heat-shrinkable polyester film 1 has a carry-over heat shrinkage percentage of 57-63%, a shrinkage stress of 1.0-1.8kg/mm and a heat shrinkage percentage of 15-33% at 65 deg.C. The label is formed into a tubular configuration and put into print 2, so that a transparent part formed at either or both ends of the label is given an axial width of at least 1.5mm, and a transparent coat layer 3 is formed on the transparent part. The resin intended for use in the coat layer, if capable of being coated on the film, is adequate for the purposes and, for example, nitrocellulose and polyamide resin may be used. In this manner the difference in shrinkage rate between the transparent part and the printing part is minimized, whereby the folding of the transparent part after the heat shrinkage can be prevented.
    • 9. 发明专利
    • DE69320280T2
    • 1999-03-18
    • DE69320280
    • 1993-09-02
    • HAYAKAWA RUBBERYOSHINO KOGYOSHO CO LTD
    • TANAKA BANNII HIROKIYAMADA KOSAKUKUSHIDA HIDEOMIYA TAKASHIKOSHIO SHUICHIHAYAKAWA TADASHI
    • B41M1/30C09D11/10B41M1/26
    • A printed thermoplastic resin product is provided by printing it with a specific radiation-curing ink composition and curing the printed ink with radiation to form a cured ink film thereon. The ink composition comprises a vehicle mixture containing: (A) an ingredient selected from the group consisting of a skeletal linear polyester oligomer having 1 to 10 double bonds in a molecule and a polymer of the oligomer, (B) an ingredient selected from the group consisting of a double bond-containing carboxylic acid wherein the acid has at least one acidic group which is capable of forming a water-soluble alkali metal salt in a molecule, a carboxylic ester of the acid and a carboxylic amide of the acid, (C) a double bond-containing polycarboxylic ester, having 2 to 10 acidic groups which are capable of forming an alkali metal salt which will swell with water absorption, (D) an ingredient selected from the group consisting of a fluorinated double bond-containing carboxylic ester wherein the fluorine component is oriented on the surface of a coplymer or polymer to give water-repellency, a block copolymer which comprises a surface-oriented and water-repellent fluorinated alkyl group-containing polymer segment and a (meth)acrylic polymer segment, and a block copolymer which comprises a surface-oriented and water-repellent siloxane group-containing polymer segment and a (meth)acrylic polymer segment, (E) a double bond-containing polycarboxylic ester, and (F) an ingredient selected from the group consisting of a double bond-containing monocarboxylic ester and its amide, wherein the acid value of the vehicle mixture is from 5 to 100.