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1. 发明申请

WO2014108647A3 METHOD FOR PURIFYING THE CO2 CONTAINED IN AN ETHYLENE STREAM RESULTING FROM THE DEHYDRATION OF ETHANOL 审中-公开
标题翻译：净化乙醇脱水产生的乙烯流中含有的二氧化碳的方法
公开(公告)号：WO2014108647A3
公开(公告)日：2014-11-27
申请号：PCT/FR2014050043
申请日：2014-01-10
申请人： IFP ENERGIES NOUVELLES , TOTAL RES & TECHNOLOGY FELUY
发明人： COUPARD VINCENT , PLENNEVAUX THOMAS , FLEURIER STÉPHANIE , VERMEIREN WALTER , MINOUX DELPHINE , DE SMEDT PHILIP , ADAM CINDY , NESTERENKO NICOLAI
IPC分类号： C07C1/24
CPC分类号： C07C1/24 , C07C11/04
摘要： The invention concerns a method for producing ethylene from an ethanol feedstock comprising at least the following steps: a) A step of dehydration so as to produce at least one ethylene effluent, and at least one water effluent, b) A step of partial condensation of said ethylene effluent, c) A step of phase separation of said partially condensed ethylene effluent so as to produce a gaseous effluent and a liquid effluent, d) A step of compressing said gaseous effluent resulting from step b) so as to produce a compressed gaseous effluent, e) A step of washing by bringing said compressed gaseous effluent into contact with washing water recycled according to step h) so as to produce a washed gaseous effluent and a waste water effluent, f) A step of absorption by bringing said washed gaseous effluent into contact with at least one absorbent solution so as to produce a purified gaseous effluent, g) A step of distilling said waste water effluent resulting from step e) along with said water effluent resulting from said dehydration step so as to produce at least a gas distillate, a liquid distillate, a purified water effluent, and a distillation residue. h) A step of recycling at least a portion of said purified water effluent resulting from step g) upstream from washing step e), said portion then being referred to as washing water.
摘要翻译：本发明涉及一种由乙醇原料生产乙烯的方法，所述方法至少包括以下步骤：a）脱水步骤以产生至少一种乙烯流出物和至少一种水流出物，b）部分冷凝所述乙烯流出物，c）使所述部分冷凝的乙烯流出物相分离以产生气态流出物和液体流出物的步骤，d）压缩步骤b）产生的所述气态流出物以产生压缩气体 e）通过使所述压缩的气体流出物与根据步骤h）再循环的洗涤水接触以产生洗涤过的气体流出物和废水流出物来洗涤的步骤，f）通过使所述洗涤过的气体流出物与至少一种吸收剂溶液接触以产生纯化的气体流出物，g）将步骤e）产生的所述废水流出物与所述水一起蒸馏的步骤ef 从所述脱水步骤产生的流体，以产生至少一种气体馏出物，液体馏出物，净化水流出物和蒸馏残余物。 h）将从洗涤步骤e）上游的步骤g）得到的至少一部分所述净化水流出物进行再循环的步骤，然后将所述部分称为洗涤水。

2. 发明专利

ES2868140T3 Procedimiento de conversión de al menos un alcohol en olefinas ligeras 未知
公开(公告)号：ES2868140T3
公开(公告)日：2021-10-21
申请号：ES12738463
申请日：2012-07-25
申请人： TOTAL RES & TECHNOLOGY FELUY , IFP ENERGIES NOW
发明人： NESTERENKO NIKOLAI , MINOUX DELPHINE , ADAM CINDY , DATH JEAN-PIERRE , LOPEZ JOSEPH , EUZEN PATRICK
IPC分类号： B01J29/40 , B01J29/85 , B01J37/10 , B01J37/28 , C07C1/20
摘要： Procedimiento de conversión de al menos un alcohol en olefinas ligeras en un procedimiento de deshidratación para producir una olefina que tiene el mismo número de átomos de carbono que el alcohol usando un catalizador que comprende una zeolita modificada con fósforo y que se produce mediante un procedimiento que comprende las siguientes etapas, en este orden, a) proporcionar una zeolita que comprende al menos un anillo de diez miembros en la estructura, opcionalmente, vaporizar dicha zeolita, b) mezclar dicha zeolita de la etapa a) con al menos un componente seleccionado de entre uno o más aglutinantes y aditivos de conformación, a continuación, conformar dicha mezcla, c) opcionalmente, realizar un intercambio iónico, d) vaporizar el catalizador conformado, opcionalmente antes de la etapa c), e) introducir fósforo en el catalizador para introducir al menos un 0,1% en peso de fósforo, realizándose dicha introducción mediante impregnación o deposición química de vapor, f) opcionalmente, introducir un metal alcalinotérreo o de tierras raras en forma de óxido, opcionalmente, simultáneamente con la etapa e), g) opcionalmente, lavar el catalizador, h) opcionalmente, calcinar el catalizador, i) vaporizar el catalizador, a la que se hace referencia también como etapa de equilibrado.

4. 发明专利

EA026722B1 СПОСОБ ПОЛУЧЕНИЯ КАТАЛИЗАТОРА НА ОСНОВЕ МОДИФИЦИРОВАННОГО ФОСФОРОМ ЦЕОЛИТА И ПРИМЕНЕНИЕ ТАКОГО КАТАЛИЗАТОРА 未知
公开(公告)号：EA026722B1
公开(公告)日：2017-05-31
申请号：EA201490358
申请日：2012-07-25
申请人： TOTAL RES & TECHNOLOGY FELUY
发明人： NESTERENKO NIKOLAI , MINOUX DELPHINE , ADAM CINDY , DATH JEAN-PIERRE
IPC分类号： B01J29/40 , B01J29/85 , B01J37/10 , B01J37/28 , C07C1/20
摘要： Заявляемоеизобретениев первомвариантереализацииотноситсяк способуполучениякатализаторанаосновемодифицированногофосфоромцеолита, включающемуследующиестадиив указаннойпоследовательности: а) обеспечитьцеолит, вструктурукотороговходитхотябыоднодесятичленноекольцо; b) обработатьуказанныйцеолитпаром, с) ввестив цеолитпоменьшеймере 0,1 мас.% фосфора, применяясухуюимпрегнациюилипарофазноехимическоеосаждение, d) смешатьцеолит, указанныйнастадиис), какминимумс однимизсвязующихкомпонентови структуронаправляющихагентов; е) сформоватьполученнуюсмесь; i) обработатьмодифицированныйфосфоромцеолитпаром - стадия, называемаятакжеприведениемв равновесноесостояние. Вовторомвариантереализациифосформожетбытьвведёнлюбымспособом, инастадии i) показательинтенсивностипарообработки (X) составляетпоменьшеймере 2. Вовторомвариантереализациимодифицированныйфосфоромцеолитподвергаютобработкепаромпритемпературевыше 625°С, преимущественнов диапазонеот 700 до 800°С. Настоящееизобретениетакжеотноситсяк применениюуказанногокатализаторадлядегидратацииспиртов, крекингаолефиновс выделениемболеелёгкихолефинов, вконверсииМТОи алкилированииароматическихуглеводородовспиртамис олефинамии/илиспиртами.

5. 发明专利

ES2603029T3 Deshidratación e isomerización del esqueleto simultáneas del isobutanol sobre catalizadores ácidos 未知
公开(公告)号：ES2603029T3
公开(公告)日：2017-02-23
申请号：ES11708283
申请日：2011-03-15
申请人： TOTAL RES & TECHNOLOGY FELUY
发明人： ADAM CINDY , MINOUX DELPHINE , NESTERENKO NIKOLAI , VAN DONK SANDER , DATH JEAN-PIERRE
IPC分类号： C07C1/24 , B01J29/06 , B01J29/40 , B01J29/85 , C07C5/25 , C07C5/27 , C07C11/00 , C07C11/08 , C07C11/09
摘要： Procedimiento de deshidratación e isomerización del esqueleto simultáneas del isobutanol para preparar las olefinas correspondientes, que tienen el mismo número de carbonos y que consisten esencialmente en una mezcla de n-butenos e isobuteno, comprendiendo dicho procedimiento: a) introducir en un reactor una corriente (A) que comprende isobutanol, opcionalmente agua, opcionalmente un componente inerte, b) poner en contacto dicha corriente con un catalizador en dicho reactor en condiciones eficaces para deshidratar e isomerizar el esqueleto de al menos una porción del isobutanol a fin de preparar una mezcla de n-butenos e isobuteno, c) recuperar de dicho reactor una corriente (B), eliminar el agua, el componente inerte, si lo hubiera, y el isobutanol sin convertir, si lo hubiera, para obtener una mezcla de n-butenos e isobuteno, en el que, la WHSV del isobutanol es de al menos 1 h-1 y el catalizador es capaz de efectuar simultáneamente la deshidratación y la isomerización del esqueleto del buteno y es un silicato cristalino del grupo FER, MWW, EUO, MFS, ZSM-48, MTT, MFI, MEL o TON con Si/Al superior a 10, o un silicato cristalino desaluminado del grupo FER, MWW, EUO, MFS, ZSM-48, MTT, MFI, MEL o TON con Si/Al superior a 10, o un silicato cristalino modificado con fósforo del grupo FER, MWW, EUO, MFS, ZSM-48, MTT, MFI, MEL o TON con Si/Al superior a 10, o un tamiz molecular de silicoaluminonafosfato del grupo AEL, o una alúmina de silicato, zirconato, titanato o fluorada.

6. 发明专利

DK2547638T3 SAMTIDIG DEHYDRERING OG SKELETISOMERISERING AF ISOBUTANOL PÅ SYREKATALYSATORER 未知
公开(公告)号：DK2547638T3
公开(公告)日：2016-12-12
申请号：DK11708283
申请日：2011-03-15
申请人： TOTAL RES & TECHNOLOGY FELUY
发明人： ADAM CINDY , MINOUX DELPHINE , VAN DONK SANDER , DATH JEAN-PIERRE , NESTERENKO NIKOLAI
IPC分类号： C07C1/24 , B01J29/06 , B01J29/40 , B01J29/85 , C07C5/25 , C07C5/27 , C07C11/00 , C07C11/08 , C07C11/09

7. 发明专利

CA2791218C SIMULTANEOUS DEHYDRATION AND SKELETAL ISOMERISATION OF ISOBUTANOL ON ACID CATALYSTS 未知
公开(公告)号：CA2791218C
公开(公告)日：2014-11-25
申请号：CA2791218
申请日：2011-03-15
申请人： TOTAL RES & TECHNOLOGY FELUY
发明人： ADAM CINDY , MINOUX DELPHINE , NESTERENKO NIKOLAI , VAN DONK SANDER , DATH JEAN-PIERRE
IPC分类号： C07C1/24 , B01J29/06 , B01J29/40 , B01J29/85 , C07C11/00 , C07C11/08 , C07C11/09
摘要： The present invention (in a first embodiment) relates to a process for the simu ltaneou s dehyd ration and skeletal isomerisation of isobuta nol to ma ke substantially corresponding olefins, having the same number of carbons and consisting essentially of a mixture of n-butenes and iso-butene, said process comprising: a) introducing in a reactor a stream (A) comprising isobutanol, optionally water, optionally an inert component, b) contacting said stream with a catalyst in said reactor at conditions effective to dehydrate and skeletal isomerise at least a portion of the isobutanol to make a mixture of n-butenes and iso-butene, c) recovering from said reactor a stream (B), removing water, the inert component if any and unconverted isobutanol if any to get a mixture of n-butenes and iso-butene, Wherein, the WHSV of the isobutanol is at least 1 h-1 or the temperature is from 200°C to 600°C and the catalyst is capable to make simultaneously the dehydration and skeletal isomerization of butene. The catalyst is a crystalline silicate of the group FER, MWW, EUO, MFS, ZSM-48, MTT, MFI, MEL or TON having Si/AI higher than 10, or a dealuminated crystalline silicate of the group FER, MWW, EUO, MFS, ZSM- 48, MTT, MFI, MEL or TON having Si/AI higher than 10, or a phosphorus modified crystalline silicate of the group FER, MWW, EUO, MFS, ZSM-48, MTT, MFI, MEL or TON having Si/AI higher than 10, or a silicoaluminaphosphate molecular sieve of the group AEL, or a silicated, zirconated or titanated or fluorinated alumina. Advantageously the stream (B) is fractionated in a step d) to produce a n-butenes stream (N) and to remove the essential part of isobutene optionally recycled with stream (A) to the dehydration/isomerization reactor of step b).

8. 发明专利

CO6960529A2 Catalizador que comprende una zeolita modificada con fósforo y que tiene parcialmente una estructura alpo 未知
公开(公告)号：CO6960529A2
公开(公告)日：2014-05-30
申请号：CO14042038
申请日：2014-02-27
申请人： TOTAL RES & TECHNOLOGY FELUY
发明人： NESTERENKO NIKOLAI , MINOUX DELPHINE , ADAM CINDY , DATH JEAN PIERRE
IPC分类号： B01J37/28

9. 发明专利

CA2842388A1 METHOD FOR MAKING A CATALYST COMPRISING A PHOSPHORUS MODIFIED ZEOLITE AND USE OF SAID ZEOLITE 未知
公开(公告)号：CA2842388A1
公开(公告)日：2013-02-07
申请号：CA2842388
申请日：2012-07-25
申请人： TOTAL RES & TECHNOLOGY FELUY
发明人： NESTERENKO NIKOLAI , MINOUX DELPHINE , ADAM CINDY , DATH JEAN-PIERRE
IPC分类号： B01J29/40 , B01J29/85 , B01J37/10 , B01J37/28 , C07C1/20
摘要： The present invention relates, in a first embodiment, to a method to make a phosphorus modified zeolite comprising the following steps in this order, a) providing a zeolite comprising at least one ten members ring in the structure, optionally steaming said zeolite, b) mixing said zeolite of step a) with at least a component selected among one or more binders and shaping additives, then shaping said mixture, c) optionally making a ion-exchange, d) optionally steaming the shaped catalyst, optionally before step c), at least among said steaming of step d) and the steaming of step a) one is mandatory, e) introducing phosphorus on the catalyst to introduce at least 0.1 wt% of phosphorus, said introduction being made by dry impregnation or chemical vapor deposition, f) introducing a metal, optionally simultaneously with step e), g) optionally washing the catalyst, h) optionally calcinating the catalyst, i) steaming the catalyst, also referred to as the equilibration step. In a second embodiment phosphorus can be introduced by any means and at step i) the steaming severity (X) is at least about 2. In said second embodiment the catalyst is advantageously steamed at a temperature above 625°C, preferably in the range 700 to 800°C. The metal of step f) is advantageously Calcium. The present invention also relates to the use said catalyst in the alcohol dehydration, the olefin cracking to make lighter olefins, the MTO and the alkylation of aromatics by alcohols with olefins and/or alcohols.

10. 发明专利

AU2011269098A1 Dehydration of alcohols on poisoned acidic catalysts 未知
公开(公告)号：AU2011269098A1
公开(公告)日：2013-01-10
申请号：AU2011269098
申请日：2011-06-20
申请人： TOTAL RES & TECHNOLOGY FELUY
发明人： MINOUX DELPHINE , ADAM CINDY , NESTERENKO NIKOLAI , VAN DONK SANDER , DATH JEAN-PIERRE , VERMEIREN WALTER
IPC分类号： C07C1/24 , C07C11/04
摘要： The present invention is a process for the dehydration of an alcohol having at least 2 carbon atoms to make the corresponding olefin, comprising: a) introducing in a reactor a stream (A) comprising at least an alcohol, optionally water, optionally an inert component, b) contacting said stream with an acidic catalyst in said reactor at conditions effective to dehydrate at least a portion of the alcohol to make an olefin, c) recovering from said reactor a stream (B) comprising : the inert component and at least an olefin, water and optionally unconverted alcohol, d) optionally fractionating the stream (B) to recover the unconverted alcohol and recycling said unconverted alcohol to the reactor of step a), e) optionally fractionating the stream (B) to recover the inert component, water and the olefin and optionally recycling said inert component and optionally a part of the water to the reactor of step a), wherein, f) an effective amount of a component capable to neutralize a part of the catalyst active site is introduced in stream (A) or directly in the dehydration reactor and g) optionally the temperature of the dehydration reactor is adjusted to increase the alcohol conversion or the olefin yield or both. In another embodiment at step f) an effective amount of a component capable to increase the selectivity for the desired corresponding olefin is introduced in stream (A) or directly in the dehydration reactor. The component introcuced at step f) can be chosen from the group consisting of ammonia, organic ammonium salts, hydrazine, nitriles, amines (including pyridines, pyrrols, pyrrolydones and pyrrolidines), amides, imines, di-imines, imides, cyanates, isocyanates, nitrites and nitroso compounds, aldehydes, ketones, carboxylic esters, and their corresponding thio-compounds (thiols, sulphides, disulfides).

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