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1. 发明申请

WO2010122115A3 UPGRADING LIGHT NAPHTAS FOR INCREASED OLEFINS PRODUCTION 审中-公开
标题翻译：升级光催化剂用于增加油脂生产
公开(公告)号：WO2010122115A3
公开(公告)日：2011-02-17
申请号：PCT/EP2010055370
申请日：2010-04-22
申请人： TOTAL PETROCHEMICALS RES FELUY , GONZALEZ JOSE CASTOR , MAZURELLE JEAN , VERMEIREN WALTER
发明人： GONZALEZ JOSE CASTOR , MAZURELLE JEAN , VERMEIREN WALTER
IPC分类号： C10G9/00 , C10G45/58 , C10G45/62 , C10G45/64 , C10G69/06 , C10G69/14
CPC分类号： C10G9/00 , C10G45/58 , C10G45/62 , C10G45/64 , C10G69/06 , C10G69/14 , C10G2300/1044 , C10G2300/4081 , C10G2300/807 , C10G2400/20
摘要： The present invention is a process to upgrade light naphthas comprising branched paraffins and their use as a feedstock in a steam cracking unit, said light naphthas consisting essentially of 90 to 100% by weight of hydrocarbons having at least 5 and up to 8 carbon atoms, said process comprising, a)optionally providing an isomerization zone recovered from the gasoline unit of an oil refinery, b)optionally providing a separation zone capable to treat an hydrocarbon stream comprising branched paraffins and normal paraffins to produce a first hydrocarbon stream having a reduced branched paraffins content and an enhanced normal paraffins content and a second hydrocarbon stream having an enhanced branched paraffins content and a reduced normal paraffins content, c)optionally providing a depentanizer, such that at least two of a), b) and c) are present, wherein, the light naphtha is sent to one of a), b) and c), streams are circulating between the various zones a), b) or c), a stream rich in normal paraffins is sent to the steam cracking unit.
摘要翻译：本发明是一种在蒸汽裂解装置中升级包含支链烷烃的轻石脑油及其作为原料的用途的方法，所述轻石脑油基本上由90至100重量％的具有至少5个和至多8个碳原子的烃，所述方法包括：a）任选地提供从炼油厂的汽油单元回收的异构化区，b）任选地提供能够处理包含支链烷烃和正链烷烃的烃流的分离区，以产生具有还原支化的第一烃流链烷烃含量和增强的正链烷烃含量和具有增强的支链链烷烃含量和降低的正链烷烃含量的第二烃流，c）任选地提供脱苯胺化剂，使得存在a），b）和c）中的至少两个，其中，轻石脑油被送到a），b）和c）中的一个，流在各个区域a），b）或c）之间循环，富含正常的链烷烃被送到蒸汽裂解装置。

2. 发明申请

WO2009092780A3 PROCESS FOR OBTAINING CATALYST COMPOSITES COMPRISING MEAPO AND THEIR USE IN CONVERSION OF ORGANICS TO OLEFINS 审中-公开
标题翻译：获得含有MEAPO的催化剂组合物及其在有机物转化成烯烃中的用途的方法
公开(公告)号：WO2009092780A3
公开(公告)日：2009-09-17
申请号：PCT/EP2009050756
申请日：2009-01-23
申请人： TOTAL PETROCHEMICALS RES FELUY , NESTERENKO NIKOLAI , VERMEIREN WALTER , VAN DONK SANDER
发明人： NESTERENKO NIKOLAI , VERMEIREN WALTER , VAN DONK SANDER
IPC分类号： B01J29/06 , B01J29/85 , C07C1/20
CPC分类号： C07C1/32 , B01J29/005 , B01J29/40 , B01J29/85 , B01J2229/186 , B01J2229/42 , C07C1/20 , C07C1/22 , C07C1/26 , Y02P30/42 , C07C11/02
摘要： The present invention is a catalyst composite comprising: - at least 0.5% by- weight of at least one metal salt, which is stable under XTO conditions and - at least 10% by weight of molecular sieves which comprise - 70% to 100% by weight of said molecular sieves of at least one small pore aluminosilicate or metalloaluminophosphate (MeAPO) molecular sieve and 0 to 30% by weight of said molecular sieves of at least one medium or large pore molecular sieve selected from one or more of crystalline silicoaluminates, silicoaluminophosphates or mesoporous silicoaluminates (co-catalyst) (A). MeAPO molecular sieves having CHA (SAPO-34) or AEI (SAPO-18) structure or mixture thereof are the most preferable. The present invention also relates to a process (hereunder referred as "XTO process") for making an olefin product from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock with the above catalyst. The present invention also relates to a "combined XTO and OCP process".
摘要翻译：本发明是一种催化剂复合材料，其包括：至少0.5重量％的至少一种金属盐，其在XTO条件下是稳定的，和至少10重量％的分子筛，其包含 - 70％至100％至少一种小孔硅铝酸盐或金属铝磷酸盐（MeAPO）分子筛的所述分子筛的重量和0至30重量％的所述分子筛至少一种选自一种或多种结晶硅铝酸盐，硅铝磷酸盐的中孔或大孔分子筛或介孔硅铝酸盐（助催化剂）（A）。具有CHA（SAPO-34）或AEI（SAPO-18）结构的MeAPO分子筛或其混合物是最优选的。本发明还涉及用含有上述催化剂的含氧卤化物或含硫有机原料制造烯烃产物的方法（以下称为“XTO法”）。本发明还涉及“组合的XTO和OCP方法”。

3. 发明申请

WO2011012440A3 A PROCESS FOR THE PRODUCTION OF BIO-NAPHTHA FROM COMPLEX MIXTURES OF NATURAL OCCURRING FATS & OILS 审中-公开
标题翻译：从天然油脂和油的复合混合物生产生物石墨的方法
公开(公告)号：WO2011012440A3
公开(公告)日：2011-07-21
申请号：PCT/EP2010060031
申请日：2010-07-13
申请人： TOTAL PETROCHEMICALS RES FELUY , VERMEIREN WALTER , BOUVART FRANCOIS , DUBUT NICOLAS
发明人： VERMEIREN WALTER , BOUVART FRANCOIS , DUBUT NICOLAS
IPC分类号： C11C3/12 , C10G3/00
CPC分类号： C10G3/40 , C10G3/45 , C10G3/46 , C10G3/49 , C10G3/50 , C10G2300/1007 , C10G2300/1014 , C10G2300/1018 , C10G2300/805 , C10G2300/807 , C10G2400/02 , C10G2400/20 , C10G2400/22 , C10G2400/30 , C11B3/06 , C11C1/10 , C11C3/10 , C11C3/123 , C11C3/126 , Y02E50/13 , Y02P30/20
摘要： Process for making a bio-diesel and a bio-naphtha and optionally bio-propane from a complex mixture of natural occurring fats & oils, wherein - said complex mixture is subjected to a refining treatment for removing the major part of the non- triglyceride and non-fatty acid components, thereby obtaining refined oils; - said refined oils are subjected to a fractionation step for obtaining: o an unsaturated or substantially unsaturated, liquid or substantially liquid triglyceride part (phase L); and o a saturated or substantially saturated, solid or substantially solid triglyceride part (phase S); and - said phase L is transformed into alkyl-esters as bio- diesel by a transesterification; - said phase S is transformed into linear or substantially linear paraffin's as the bio-naphtha : ° by an hydrodeoxygenation ° or from said phase S are obtained fatty acids that are transformed into linear or substantially linear paraffin's as the bio-naphtha by hydrodeoxygenation or decarboxylation of the free fatty acids or from said phase S are obtained fatty acids soaps that are transformed into linear or substantially linear paraffin's as the bio-naphtha by decarboxylation of the soaps.
摘要翻译：用于由天然存在的脂肪和油的复杂混合物制备生物柴油和生物石脑油以及任选的生物丙烷的方法，其中 - 对所述复合混合物进行精炼处理以除去非甘油三酯的主要部分，非脂肪酸组分，从而得到精制油; - 对所述精炼油进行分馏步骤，以获得：不饱和或基本上不饱和的液体或基本上液体的甘油三酸酯部分（相L）; 和饱和或基本上饱和的固体或基本上固体的甘油三酸酯部分（S相）。和 - 所述相L通过酯交换转化为生物柴油的烷基酯; - 所述相S被转化为线性或基本上线性的石蜡，其生物石脑油：通过加氢脱氧反应或从所述相S得到的脂肪酸，其通过加氢脱氧或脱羧转化成生物石脑油作为线性或基本线性的石蜡的游离脂肪酸或从所述相S获得的脂肪酸皂，其通过皂的脱羧转化成生物石脑油作为线性或基本上线性的石蜡。

4. 发明申请

WO2011073226A2 DEBOTTLENECKING OF A STEAM CRACKER UNIT TO ENHANCE PROPYLENE PRODUCTION 审中-公开
标题翻译：蒸汽破碎机单元的加固以增强丙烯生产
公开(公告)号：WO2011073226A2
公开(公告)日：2011-06-23
申请号：PCT/EP2010069694
申请日：2010-12-15
申请人： TOTAL PETROCHEMICALS RES FELUY , VERMEIREN WALTER , BOUVART FRANCOIS , CELIE INEKE , GARCIA WOLFGANG
发明人： VERMEIREN WALTER , BOUVART FRANCOIS , CELIE INEKE , GARCIA WOLFGANG
IPC分类号： C10G9/00 , C10G51/04 , C10G69/06
CPC分类号： C10G51/04 , C10G9/002 , C10G69/06 , C10G2300/807 , C10G2400/20 , C10G2400/26
摘要： The present invention is a method for debottlenecking an existing steam cracker unit of which the operation is modified from high severity to low severity operation, having a cracking zone and a fractionation zone, said fractionation zone comprising a gasoline stripper, a de-methaniser (I), a de-ethaniser (I), a de-propaniser (I) and a de-butaniser (I), said de-propaniser (I) receiving product from the bottom of the de-ethaniser (I) and optionally product from the bottom of the gasoline stripper (I), wherein said debottlenecking method comprises the steps of : a) adding a selective hydrogenation unit (II), b) adding a cracking reactor (II) comprising a catalyst selective towards light olefins in the outlet, c) adding a re-run column and a de-propaniser (II), d) sending a part or all of the bottoms stream of the gasoline stripper (I) to the selective hydrogenation unit (II) and subsequently to the cracking reactor (II) at conditions effective to produce an outlet with an olefin content of lower molecular weight than that of the inlet, e) sending a part of the bottoms stream of the de-ethaniser (I) to the de-propaniser (II), such as, not to overload the de-propaniser (I), f) optionally sending a part or all of the overhead raw C4 fraction of the de-butaniser (I) to the selective hydrogenation unit (II), g) sending the cracking reactor (II) outlet to the re-run column to produce a C6+ bottom stream and a C1-C5 overhead, sending said overhead to the de-propaniser (II) to produce a C1-C3 overhead and a C4+ bottom stream recycled in whole or in part to the selective hydrogenation unit (II), optionally withdrawing a part of said C4+ bottom stream.
摘要翻译：本发明是一种用于对现有蒸汽裂化装置进行脱瓶的方法，该装置的操作由高严重度到低严重性操作改变，具有裂化区和分馏区，所述分馏区包含汽提汽提塔，脱甲烷反应器），脱乙烷化酶（I），去propaniser（I）和脱丁烷（I），脱唾液酸酶（I）从脱乙烷（I）的底部接收产物，汽油汽提器（I）的底部，其中所述消除瓶颈方法包括以下步骤：a）加入选择性氢化单元（II），b）在出口中加入包含对轻质烯烃选择性的催化剂的裂化反应器（II） c）加入再运行的塔和去推进剂（II），d）将汽提汽提塔（I）的一部分或全部底部物流送入选择性加氢装置（II），随后将其送入裂解反应器 II）在有效产生具有烯烃含量的出口的条件下分子量低于入口的分子量，e）将去乙烷化器（I）的一部分底部物流送至去岐化器（II），例如不使去岐化剂（I）过载， f）任选将脱丁烷（I）的塔顶馏分C4馏分的一部分或全部送入选择氢化单元（II），g）将裂解反应器（II）出口送至再运行塔，以产生 C6 +底部流和C1-C5塔顶馏出物，将所述开销送到脱丙烷（II）以产生C1-C3塔顶馏出物，以及将全部或部分再循环至选择性加氢装置（II）的C4 +底部物流，任选地退出所述C4 +底部流的一部分。

5. 发明申请

WO2009016155A3 USE OF PHOSPHORUS MODIFIED MOLECULAR SIEVES IN CONVERSION OF ORGANICS TO OLEFINS 审中-公开
标题翻译：磷酸改性分子筛在有机物转化成烯烃中的应用
公开(公告)号：WO2009016155A3
公开(公告)日：2010-09-16
申请号：PCT/EP2008059885
申请日：2008-07-28
申请人： TOTAL PETROCHEMICALS RES FELUY , NESTERENKO NIKOLAI , VERMEIREN WALTER , MINOUX DELPHINE , VAN DONK SANDER
发明人： NESTERENKO NIKOLAI , VERMEIREN WALTER , MINOUX DELPHINE , VAN DONK SANDER
IPC分类号： C07C1/20 , C01B39/02 , C07C1/32 , C07C4/06 , C10G11/16
CPC分类号： C07C1/20 , B01J29/40 , B01J37/28 , B01J2229/18 , B01J2229/37 , C07C1/322 , C07C4/06 , C07C2529/85 , C10G2400/20 , Y02P30/42 , C07C11/02
摘要： The present invention relates to a process to make light olefins, in a combined XTO-OCP process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising : contacting said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the XTO reactor with a catalyst made of a P-modified zeolite (A) at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; separating said light olefins from said heavy hydrocarbon fraction; contacting said heavy hydrocarbon fraction in the OCP reactor with a catalyst made of a P-modified zeolite (A) at conditions effective to convert at least a portion of said heavy hydrocarbon fraction to light olefins; wherein said P-modified zeolite (A) is made by a process comprising in that order: selecting a zeolite (advantageously with Si/AI ratio between 4 and 500) among H+ or NH4 +-form of MFI, MEL, FER, MOR, clinoptilolite; introducing P at conditions effective to introduce advantageously at least 0.05 wt% of P; separation of the solid from the liquid if any; an optional washing step or an optional drying step or an optional drying step followed by a washing step; a calcination step.
摘要翻译：本发明涉及一种在组合的XTO-OCP方法中由含氧，含卤素或含硫有机原料制备轻质烯烃的方法，包括：将含氧的含卤素或含硫的在有效地转化至少一部分原料以形成包含轻质烯烃和重质烃馏分的XTO反应器流出物的条件下，在XTO反应器中的有机原料具有由P改性沸石（A）制成的催化剂; 将所述轻质烯烃与所述重质烃馏分分离; 在有效将至少一部分所述重质烃馏分转化为轻质烯烃的条件下，使所述OCP反应器中的所述重质烃馏分与由P-改性沸石（A）制成的催化剂接触; 其中所述P型改性沸石（A）通过以下方法制备：在MFI，MEL，FER，MOR，HNO 3的H +或NH 4 +形式中选择沸石（有利地具有4至500的Si / Al比）斜发沸石; 在有效引入至少0.05重量％的P的条件下引入P; 从液体中分离出固体物质; 任选的洗涤步骤或任选的干燥步骤或任选的干燥步骤，随后进行洗涤步骤; 煅烧步骤。

6. 发明申请

WO2009156436A3 PROCESS TO MAKE OLEFINS FROM ORGANICS 审中-公开
标题翻译：从有机物制备烯烃的方法
公开(公告)号：WO2009156436A3
公开(公告)日：2010-02-18
申请号：PCT/EP2009057890
申请日：2009-06-24
申请人： TOTAL PETROCHEMICALS RES FELUY , NESTERENKO NIKOLAI , VERMEIREN WALTER , GRASSO GIACOMO , VAN DONK SANDER , GARCIA WOLFGANG
发明人： NESTERENKO NIKOLAI , VERMEIREN WALTER , GRASSO GIACOMO , VAN DONK SANDER , GARCIA WOLFGANG
IPC分类号： C07C1/20 , B01J27/16 , B01J29/40 , B01J37/28 , C10G11/05
CPC分类号： C07C1/20 , B01J21/08 , B01J21/16 , B01J27/14 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/90 , B01J38/12 , B01J2229/16 , B01J2229/18 , B01J2229/36 , B01J2229/37 , C07C1/26 , C07C1/322 , C07C4/06 , C07C2529/40 , Y02P20/584 , Y02P30/42 , C07C11/02
摘要： The present invention relates to a process to make light olefins, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising : a0) providing a first portion and a second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock, a) providing a catalyst comprising zeolitic molecular sieves containing at least 10 membered ring pore openings or larger in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, optionally at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting the first portion of said oxygen-containing, halogenide- containing or sulphur-containing organic feedstock in the XTO reactor with the catalyst at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; d) separating said light olefins from said heavy hydrocarbon fraction; e) contacting said heavy hydrocarbon fraction and the second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the OC reactor with the catalyst at conditions effective to convert at least a portion of said heavy hydrocarbon fraction and oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to light olefins.
摘要翻译：本发明涉及一种在组合的XTO-OC方法中由含氧，含卤素或含硫有机原料制备轻质烯烃的方法，包括：a）提供所述氧气的第一部分和第二部分 a）提供包含在其微孔结构中含有至少10元环孔或更大孔沸石分子筛的催化剂，b）提供XTO反应区，OC反应区和催化剂再生区，所述催化剂在三个区域中循环，使得至少一部分再生催化剂通入OC反应区，任选地将OC反应区中的至少一部分催化剂通入XTO反应区域，并且XTO反应区中的至少一部分催化剂被传送到再生区; c）在有效地转化至少一部分原料以形成包含轻质烯烃的XTO反应器流出物的条件下，将XTO反应器中的含氧卤化物或含硫有机原料的第一部分与催化剂接触，重质烃馏分; d）从所述重质烃馏分中分离出所述轻质烯烃; e）在OC反应器中将所述重质烃部分和第二部分所述含氧卤化物或含硫有机原料与所述催化剂接触，所述条件有效地将至少一部分所述重质烃部分和氧 - 含卤素或含硫有机原料转化成轻质烯烃。

7. 发明申请

WO2009016153A3 PHOSPHORUS MODIFIED MOLECULAR SIEVES, THEIR USE IN CONVERSION OF ORGANICS TO OLEFINS 审中-公开
标题翻译：磷酸改性分子筛，它们在有机物转化成烯烃中的用途
公开(公告)号：WO2009016153A3
公开(公告)日：2010-04-29
申请号：PCT/EP2008059883
申请日：2008-07-28
申请人： TOTAL PETROCHEMICALS RES FELUY , NESTERENKO NIKOLAI , VERMEIREN WALTER , MINOUX DELPHINE , VAN DONK SANDER
发明人： NESTERENKO NIKOLAI , VERMEIREN WALTER , MINOUX DELPHINE , VAN DONK SANDER
IPC分类号： B01J29/85 , C01B39/02 , C07C1/20 , C07C2/08 , C07C11/02
CPC分类号： C07C1/322 , B01J29/40 , B01J29/85 , B01J2229/36 , B01J2229/37 , C01B39/026 , C07C1/20 , C07C1/22 , C07C1/26 , C07C2/06 , C07C4/06 , C07C7/04 , C07C2529/85 , C10G3/00 , C10G2300/202 , C10G2300/4081 , C10G2400/20 , Y02P20/52 , Y02P30/20 , Y02P30/42 , C07C11/02 , C07C11/06
摘要： The present invention is a phosphorous modified zeolite (A) made by a process comprising in that order: selecting a zeolite with low Si/AI ratio (advantageously lower than 30) among H+ or NH4 +-form of MFI, MEL, FER, MOR, clinoptilolite, said zeolite having been made preferably without direct addition of organic template; steaming at a temperature ranging from 400 to 870°C for 0.01-200h; leaching with an aqueous acid solution containing the source of P at conditions effective to remove a substantial part of Al from the zeolite and to introduce at least 0.3 wt% of P; separation of the solid from the liquid; an optional washing step or an optional drying step or an optional drying step followed by a washing step; a calcination step. The present invention also relates to a process (hereunder referred as 'XTO process') for making an olefin product from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock wherein said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock is contacted with the above catalyst (in the XTO reactor) under conditions effective to convert at least a portion of the oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to olefin products (the XTO reactor effluent). The present invention also relates to a process (hereunder referred as 'combined XTO and OCP process') to make light olefins from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising : contacting said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the XTO reactor with the above catalyst at conditions effective to convert at least a portion of the feedstock to form an XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; separating said light olefins from said heavy hydrocarbon fraction; contacting said heavy hydrocarbon fraction in the OCP reactor at conditions effective to convert at least a portion of said heavy hydrocarbon fraction to light olefins.
摘要翻译：本发明是通过以下方法制备的磷改性沸石（A）：在MFI，MEL，FER，MOR的H +或NH4 +形式中选择具有低Si / Al比（有利地低于30）的沸石，斜发沸石，所述沸石优选不直接添加有机模板; 在400〜870℃的温度范围内蒸煮0.01〜200h; 在有效从沸石中除去大部分Al并引入至少0.3wt％P的条件下，用含有P源的酸性水溶液浸出; 从液体中分离固体; 任选的洗涤步骤或任选的干燥步骤或任选的干燥步骤，随后进行洗涤步骤; 煅烧步骤。本发明还涉及从含氧，含卤素或含硫有机原料制备烯烃产物的方法（以下称为“XTO法”），其中所述含氧卤化物或含硫的在有效将至少一部分含氧，含卤素或含硫有机原料转化为烯烃产物（XTO反应器流出物）的条件下，有机原料与上述催化剂（在XTO反应器中）接触。本发明还涉及从含氧的含卤化物或含硫有机原料制备轻质烯烃的方法（以下称为“组合的XTO和OCP方法”），包括：使含有氧的含卤素的或含硫有机原料在具有上述催化剂的XTO反应器中，在有效地转化至少一部分原料以形成包含轻质烯烃和重质烃馏分的XTO反应器流出物的条件下; 将所述轻质烯烃与所述重质烃馏分分离; 在有效将至少一部分所述重质烃馏分转化为轻质烯烃的条件下使OCP反应器中的所述重质烃馏分接触。

8. 发明申请

WO2009156433A3 PROCESS TO MAKE OLEFINS FROM OXYGENATES 审中-公开
标题翻译：从氧化剂制备油脂的方法
公开(公告)号：WO2009156433A3
公开(公告)日：2010-02-18
申请号：PCT/EP2009057887
申请日：2009-06-24
申请人： TOTAL PETROCHEMICALS RES FELUY , NESTERENKO NIKOLAI , VERMEIREN WALTER , GRASSO GIACOMO , VAN DONK SANDER , GARCIA WOLFGANG
发明人： NESTERENKO NIKOLAI , VERMEIREN WALTER , GRASSO GIACOMO , VAN DONK SANDER , GARCIA WOLFGANG
IPC分类号： C07C1/20 , B01J29/40 , B01J37/28
CPC分类号： C07C1/22 , B01J21/08 , B01J21/16 , B01J27/14 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/90 , B01J37/10 , B01J38/12 , B01J2229/16 , B01J2229/186 , B01J2229/36 , C07C1/20 , C07C1/26 , C07C1/322 , C07C4/06 , C07C2529/40 , C10G3/44 , C10G3/49 , C10G3/62 , C10G9/00 , C10G55/04 , C10G2400/20 , Y02P20/584 , Y02P30/20 , Y02P30/42 , C07C11/02
摘要： The present invention relates to a process to make light olefins, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising : a) providing a catalyst comprising zeolitic molecular sieves containing 10 member and larger channels in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting said oxygen-containing, halogenide-containing or sulphur- containing organic feedstock in the XTO reactor with the catalyst at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; d) separating said light olefins from said heavy hydrocarbon fraction; e) contacting said heavy hydrocarbon fraction in the OC reactor with the catalyst at conditions effective to convert at least a portion of said heavy hydrocarbon fraction to light olefins.
摘要翻译：本发明涉及一种在组合的XTO-OC方法中由含氧的含卤素或含硫有机原料制备轻质烯烃的方法，包括：a）提供包含含有10个成员的沸石分子筛和在其微孔结构中较大的通道，b）提供XTO反应区，OC反应区和催化剂再生区，所述催化剂在三个区中循环，使得至少一部分再生催化剂通过OC反应区，将OC反应区中的至少一部分催化剂通入XTO反应区，并将XTO反应区中的至少一部分催化剂通入再生区; c）在有效地转化至少一部分原料以形成包含轻质烯烃和重质烃部分的XTO反应器流出物的条件下，将XTO反应器中的含氧，含卤素或含硫有机原料与催化剂接触 ; d）从所述重质烃馏分中分离出所述轻质烯烃; e）使OC反应器中的所述重质烃馏分与催化剂在有效将至少一部分所述重质烃馏分转化为轻质烯烃的条件下接触。

9. 发明申请

WO2009092781A2 PROCESS FOR OBTAINING MODIFIED MOLECULAR SIEVES 审中-公开
标题翻译：获得修饰分子筛的方法
公开(公告)号：WO2009092781A2
公开(公告)日：2009-07-30
申请号：PCT/EP2009050758
申请日：2009-01-23
申请人： TOTAL PETROCHEMICALS RES FELUY , NESTERENKO NIKOLAI , VERMEIREN WALTER , VAN DONK SANDER , MINOUX DELPHINE
发明人： NESTERENKO NIKOLAI , VERMEIREN WALTER , VAN DONK SANDER , MINOUX DELPHINE
IPC分类号： B01J27/16 , B01J29/06 , B01J29/40 , C07C1/20 , C07C4/06
CPC分类号： C07C1/20 , B01J27/16 , B01J29/06 , B01J29/061 , B01J29/40 , B01J29/405 , B01J37/0201 , B01J37/0207 , B01J37/024 , B01J37/28 , B01J2229/16 , B01J2229/186 , B01J2229/36 , B01J2229/37 , C07C4/06 , C07C2523/02 , C07C2527/14 , C07C2529/06 , C07C2529/40 , C07C2529/82 , C07C2529/85 , C08F110/02 , C10G2400/20 , Y02P30/42 , C07C11/02
摘要： The invention covers a process for obtaining an alkaline earth or rare earth metal-P-modified molecular sieve (M-P-modified molecular sieve) comprising the following steps: a), selecting at least one molecular sieve selected from one of: - a P-modified molecular sieve which contains at least 0.3 wt% of P obtained by dealuminating a molecular sieve in a steaming step, followed by a leaching step using an acid solution containing a source of P - a molecular sieve which is modified with P during step b) by dealuminating the molecular sieve in a steaming step, followed by a leaching step using an acid solution containing a source of P thereby introducing at least 0.3 wt % of P b). contacting said molecular sieve with an alkaline earth or rare earth metal-containing compound (M-containing compound) to introduce at least 0.05 wt% of the alkaline earth or rare earth metal to the molecular sieve. The invention also covers a catalyst composite comprising: a), at least 10 wt % of a M-P-modified molecular sieve comprising at least 0.05 % by weight of an alkaline earth or rare earth metal (M) and at least 0.3 wt% of P, b). optionally metal phosphate, c). optionally matrix material, and d). optionally binder. The catalyst of the invention can also be used in a process for making an olefin product from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock wherein said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock is contacted in the XTO reactor with the catalyst composite according to the invention under conditions effective to convert the oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to olefin products (the XTO reactor effluent). The catalyst composite of the invention can also be used in addition or alternatively in an OCP process.
摘要翻译：本发明包括获得碱土或稀土金属-P-改性分子筛（MP-改性分子筛）的方法，其包括以下步骤：a）选择至少一种选自以下物质之一的分子筛：-P- 其包含至少0.3重量％的通过在汽蒸步骤中将分子筛脱铝而获得的P，然后使用含有P的分子筛的酸溶液进行浸提步骤，所述分子筛在步骤b）期间用P改性，通过在汽蒸步骤中使分子筛脱铝，接着使用含有P源的酸溶液进行浸出步骤，由此引入至少0.3重量％的P b）。使所述分子筛与含碱土金属或稀土金属的化合物（含M化合物）接触以将至少0.05重量％的碱土金属或稀土金属引入分子筛中。本发明还包括催化剂复合物，其包含：a）至少10wt％的包含至少0.05重量％的碱土金属或稀土金属（M）和至少0.3重量％的P ，b）。任选地金属磷酸盐，c）。任选的基质材料，和d）。可选的粘合剂本发明的催化剂也可用于由含氧，含卤化物或含硫有机原料制备烯烃产物的方法，其中所述含氧，含卤化物或含硫有机原料与具有根据本发明的催化剂复合物的XTO反应器在有效将含氧，含卤化物或含硫有机原料转化成烯烃产物（XTO反应器流出物）的条件下进行。本发明的催化剂复合材料还可以另外或可选地用于OCP工艺中。

10. 发明申请

WO2009156435A3 PROCESS TO MAKE OLEFINS AND AROMATICS FROM ORGANICS 审中-公开
标题翻译：从有机物制备油脂和芳香油的工艺
公开(公告)号：WO2009156435A3
公开(公告)日：2010-02-18
申请号：PCT/EP2009057889
申请日：2009-06-24
申请人： TOTAL PETROCHEMICALS RES FELUY , NESTERENKO NIKOLAI , VERMEIREN WALTER , GRASSO GIACOMO , VAN DONK SANDER , GARCIA WOLFGANG
发明人： NESTERENKO NIKOLAI , VERMEIREN WALTER , GRASSO GIACOMO , VAN DONK SANDER , GARCIA WOLFGANG
IPC分类号： C07C1/20 , B01J29/40 , B01J37/28
CPC分类号： C07C1/20 , B01J21/08 , B01J21/16 , B01J27/14 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/90 , B01J38/12 , B01J2229/16 , B01J2229/18 , B01J2229/36 , B01J2229/37 , C07C1/26 , C07C1/322 , C07C2/864 , C07C4/06 , C07C2529/40 , Y02P20/584 , Y02P30/42 , C07C15/02 , C07C11/02
摘要： The present invention relates to a process to make light olefins and aromatics, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising : a0) providing a first portion and a second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock, a) providing a catalyst comprising zeolitic molecular sieves containing at least 10 membered ring pore openings or larger in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting the first portion of said oxygen-containing, halogenide- containing or sulphur-containing organic feedstock in the XTO reactor with the catalyst at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; d) separating said light olefins from said heavy hydrocarbon fraction; e) contacting said heavy hydrocarbon fraction and the second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the OC reactor with the catalyst at conditions effective to convert at least a portion of said heavy hydrocarbon fraction and oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to light olefins and aromatics.
摘要翻译：本发明涉及一种在组合的XTO-OC方法中由含氧，含卤素或含硫有机原料制备轻质烯烃和芳族化合物的方法，包括：a0）提供第一部分和第二部分所述含氧，含卤素或含硫有机原料，a）提供包含在其微孔结构中含有至少10元环孔孔或更大的沸石分子筛的催化剂，b）提供XTO反应区，OC反应区域和催化剂再生区，所述催化剂在三个区域中循环，使得至少一部分再生催化剂通过OC反应区，OC反应区中的至少一部分催化剂通过XTO 反应区和XTO反应区中的至少一部分催化剂通入再生区; c）在有效地转化至少一部分原料以形成包含轻质烯烃的XTO反应器流出物的条件下，将XTO反应器中的含氧卤化物或含硫有机原料的第一部分与催化剂接触，重质烃馏分; d）从所述重质烃馏分中分离出所述轻质烯烃; e）在OC反应器中将所述重质烃部分和第二部分所述含氧卤化物或含硫有机原料与所述催化剂接触，所述条件有效地将至少一部分所述重质烃部分和氧 - 含有卤化物或含硫有机原料至轻质烯烃和芳族化合物。

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