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1. 发明专利

DE60315391D1 未知
公开(公告)号：DE60315391D1
公开(公告)日：2007-09-20
申请号：DE60315391
申请日：2003-09-24
申请人： TOSOH CORP
发明人： KAGAWA TAKUMI , KAMBARA TAKESHI , SAKKA HIDEO , YANASE MANABU
IPC分类号： C07D303/32 , C07B53/00 , C07C45/63 , C07C45/65 , C07C45/72 , C07C49/16 , C07C49/163 , C07C49/167 , C07C49/794 , C07C49/798 , C07C49/80 , C07C49/813 , C07C49/82 , C07C49/83 , C07D303/48
摘要： An optically active substituted (2S,3R)-epoxyenone derivative (I), is new. Optically active substituted (2S,3R)-epoxyenone derivative of formula (I) is new. [Image] R 1>methyl, ethyl or 3-10C alkyl; and R 2>optionally substituted phenyl or tert-butyl. Independent claims are also included for: (a) method (M) for preparation of (I) involving: asymmetrically oxidizing an enone of formula R 1>-CH=CH-C(=O)-R 2>(II); (b) an optically active (2R,3S)-epoxyester of formula (III); (c) method (M1) for preparation of (III) involving: oxidizing (I) with an oxidizing agent; (d) method (M2) for preparation of an optically active (2S,3R)-2,3-epoxypropionic acid of formula (IV) having a substituent at 3-position involving hydrolyzing (III); (e) 3-halogenopropan-1-one derivative of formula R 1>-CH(X)-CH 2-C(=O)-R 2>(V); (f) method (M3) for preparation of (V) involving reacting a beta -hydroxyketone derivative of formula R 1>-CH(OH)CH 2-C(=O)-R 2>(VI) with a hydrogen halide or hydrogen halide acid; (g) method (M4) for preparation of (II) involving treating (V) with a base; (h) method (M5) for preparation of an optically active 2,3-epoxy-3-cyclohexylpropionic acid or its ester involving: reacting an enzyme having an ability to asymmetrically hydrolyze an ester bond, to a mixture of (2R,3S)-2,3-epoxy-3-cyclohexylpropionate and a (2R,3S)-2,3-epoxy-3-cyclohexylpropionate, of the 2,3-epoxy-3-cyclohexylpropionate of formula (VII) for stereoselective hydrolysis, followed by separation and purification. [Image] X : halo; A : optionally substituted cyclohexyl; and R 3>ester.

2. 发明专利

DE3888473D1 未知
公开(公告)号：DE3888473D1
公开(公告)日：1994-04-21
申请号：DE3888473
申请日：1988-12-06
申请人： TOSOH CORP
发明人： MATSUBA TAKAO , KUBO MASASHIGE , KAGAWA TAKUMI , OYAMA KIYOTAKA , KAWABATA KOJI
IPC分类号： C07D209/48 , C08K5/41 , C08K5/34

3. 发明专利

NL1005508A1 未知
公开(公告)号：NL1005508A1
公开(公告)日：1997-09-17
申请号：NL1005508
申请日：1997-03-12
申请人： TOSOH CORP
发明人： KAGAWA TAKUMI , KONDO NORIHISA , KASAI NORIYUKI , SAKKA HIDEO
IPC分类号： C07C39/367 , C07C43/23 , C08K5/00 , C08K5/136 , C07C37/62 , C07D303/26 , C08K5/06 , C08K5/15 , C09K21/08
摘要： Brominated p-cumylphenol represented by the formula (1) described hereinafter and derivative thereof represented by the formula (2) described hereinabove, process for the preparation of the same, and flame-retardant resin compositions containing the same, are disclosed. Those compounds are useful flame retardant, and can be blended with various thermosetting resins or thermoplastic resins to obtain flame retardant resin compositions.

4. 发明专利

DE60233919D1 未知
公开(公告)号：DE60233919D1
公开(公告)日：2009-11-19
申请号：DE60233919
申请日：2002-08-16
申请人： TOSOH CORP
发明人： KAGAWA TAKUMI , SAKKA HIDEO
IPC分类号： B01J20/291 , C07D207/452 , B01D15/08 , B01J20/281 , C07D207/44 , C07D207/448 , C08F2/44 , C08F4/46 , C08F22/40 , G01N30/88
摘要： A separating agent that serves as an optical resolution agent is composed of a novel, useful optically active polymer of the following formula (3) or (4). The separating agent is obtained through anionic polymerization of a novel maleimide and serves to separate optically active compounds.

5. 发明专利

DE60129608T2 未知
公开(公告)号：DE60129608T2
公开(公告)日：2008-05-21
申请号：DE60129608
申请日：2001-02-22
申请人： TOSOH CORP
发明人： INANAGA JUNJI , KAGAWA TAKUMI
IPC分类号： B01J31/12 , B01J23/10 , B01J31/18 , B01J31/22 , B01J31/24 , C07B53/00 , C07D301/19 , C07D303/32
摘要： A complex catalyst for asymmetric epoxidation of enones, which comprises: (A) an optically active binaphthol, (B) lanthanum triisopropoxide, (C) triphenylphosphine oxide, and (D) tert-butyl hydroperoxide, wherein (A) the binaphthol is from 1 to 3 mols, (C) the triphenylphosphine oxide is from 0.1 to 10 mols, and (D) the tert-butyl hydroperoxide is from 1 to 20 mols, per mol of (B) the lanthanum triisopropoxide.

6. 发明专利

DE60315391T2 未知
公开(公告)号：DE60315391T2
公开(公告)日：2008-04-17
申请号：DE60315391
申请日：2003-09-24
申请人： TOSOH CORP
发明人： KAGAWA TAKUMI , KAMBARA TAKESHI , SAKKA HIDEO , YANASE MANABU
IPC分类号： C07D303/32 , C07B53/00 , C07C45/63 , C07C45/65 , C07C45/72 , C07C49/16 , C07C49/163 , C07C49/167 , C07C49/794 , C07C49/798 , C07C49/80 , C07C49/813 , C07C49/82 , C07C49/83 , C07D303/48
摘要： An optically active substituted (2S,3R)-epoxyenone derivative (I), is new. Optically active substituted (2S,3R)-epoxyenone derivative of formula (I) is new. [Image] R 1>methyl, ethyl or 3-10C alkyl; and R 2>optionally substituted phenyl or tert-butyl. Independent claims are also included for: (a) method (M) for preparation of (I) involving: asymmetrically oxidizing an enone of formula R 1>-CH=CH-C(=O)-R 2>(II); (b) an optically active (2R,3S)-epoxyester of formula (III); (c) method (M1) for preparation of (III) involving: oxidizing (I) with an oxidizing agent; (d) method (M2) for preparation of an optically active (2S,3R)-2,3-epoxypropionic acid of formula (IV) having a substituent at 3-position involving hydrolyzing (III); (e) 3-halogenopropan-1-one derivative of formula R 1>-CH(X)-CH 2-C(=O)-R 2>(V); (f) method (M3) for preparation of (V) involving reacting a beta -hydroxyketone derivative of formula R 1>-CH(OH)CH 2-C(=O)-R 2>(VI) with a hydrogen halide or hydrogen halide acid; (g) method (M4) for preparation of (II) involving treating (V) with a base; (h) method (M5) for preparation of an optically active 2,3-epoxy-3-cyclohexylpropionic acid or its ester involving: reacting an enzyme having an ability to asymmetrically hydrolyze an ester bond, to a mixture of (2R,3S)-2,3-epoxy-3-cyclohexylpropionate and a (2R,3S)-2,3-epoxy-3-cyclohexylpropionate, of the 2,3-epoxy-3-cyclohexylpropionate of formula (VII) for stereoselective hydrolysis, followed by separation and purification. [Image] X : halo; A : optionally substituted cyclohexyl; and R 3>ester.

7. 发明专利

DE3888473T2 未知
公开(公告)号：DE3888473T2
公开(公告)日：1994-07-07
申请号：DE3888473
申请日：1988-12-06
申请人： TOSOH CORP
发明人： MATSUBA TAKAO , KUBO MASASHIGE , KAGAWA TAKUMI , OYAMA KIYOTAKA , KAWABATA KOJI
IPC分类号： C07D209/48 , C08K5/41 , C08K5/34

8. 发明专利

DE60116383T2 未知
公开(公告)号：DE60116383T2
公开(公告)日：2006-07-13
申请号：DE60116383
申请日：2001-02-22
申请人： TOSOH CORP
发明人： INANAGA JUNJI , KAGAWA TAKUMI
IPC分类号： B01J31/12 , B01J23/10 , B01J31/18 , B01J31/22 , B01J31/24 , C07B53/00 , C07D301/19 , C07D303/32
摘要： A complex catalyst for asymmetric epoxidation of enones, which comprises: (A) an optically active binaphthol, (B) lanthanum triisopropoxide, (C) triphenylphosphine oxide, and (D) tert-butyl hydroperoxide, wherein (A) the binaphthol is from 1 to 3 mols, (C) the triphenylphosphine oxide is from 0.1 to 10 mols, and (D) the tert-butyl hydroperoxide is from 1 to 20 mols, per mol of (B) the lanthanum triisopropoxide.

9. 发明专利

DE60120005D1 未知
公开(公告)号：DE60120005D1
公开(公告)日：2006-07-06
申请号：DE60120005
申请日：2001-02-22
申请人： TOSOH CORP
发明人： INANAGA JUNJI , KAGAWA TAKUMI
IPC分类号： B01J31/12 , B01J23/10 , B01J31/18 , B01J31/22 , B01J31/24 , C07B53/00 , C07D301/19 , C07D303/32
摘要： A complex catalyst for asymmetric epoxidation of enones, which comprises: (A) an optically active binaphthol, (B) lanthanum triisopropoxide, (C) triphenylphosphine oxide, and (D) tert-butyl hydroperoxide, wherein (A) the binaphthol is from 1 to 3 mols, (C) the triphenylphosphine oxide is from 0.1 to 10 mols, and (D) the tert-butyl hydroperoxide is from 1 to 20 mols, per mol of (B) the lanthanum triisopropoxide.

10. 发明专利

NL1005508C2 未知
公开(公告)号：NL1005508C2
公开(公告)日：1999-06-09
申请号：NL1005508
申请日：1997-03-12
申请人： TOSOH CORP
发明人： KAGAWA TAKUMI , KONDO NORIHISA , KASAI NORIYUKI , SAKKA HIDEO
IPC分类号： C07C39/367 , C07C43/23 , C08K5/00 , C08K5/136 , C07C37/62 , C07D303/26 , C08K5/06 , C08K5/15 , C09K21/08
摘要： Brominated p-cumylphenol represented by the formula (1) described hereinafter and derivative thereof represented by the formula (2) described hereinabove, process for the preparation of the same, and flame-retardant resin compositions containing the same, are disclosed. Those compounds are useful flame retardant, and can be blended with various thermosetting resins or thermoplastic resins to obtain flame retardant resin compositions.

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