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    • 8. 发明申请
    • BULK POLYMER COMPOSITES
    • 散装聚合物复合材料
    • WO2013090610A1
    • 2013-06-20
    • PCT/US2012/069556
    • 2012-12-13
    • THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
    • PEI, QibingCHEN, Qi
    • C08F2/00C08F20/10C08J3/00C09K11/06G01T1/20
    • C09K11/06C08F2/02C08F2/44C08F2/50C08F20/10C08F212/08C09K11/025C09K2211/1416H05B33/14H05B33/20
    • A method for the synthesis and use of transparent bulk conjugated polymers prepared from liquid monomers via bulk polymerization. The liquid monomer contains pi-electron conjugated moieties and polymerizable moieties. The monomer solution may also have functionalizing additives such as a luminescence additive that includes organic dyes, luminescent molecules, fluorescent compounds, phosphorescent compounds, and luminescent quantum dots. The monomer solution may also have sensitizing additives such as high-energy photo sensitizing compounds, nanoparticles of compounds containing atoms with atomic numbers greater than 52 and neutron sensitizing additives. The monomer solution is polymerized by heating to an elevated temperature with or without addition of an initiator. Alternatively, the monomer is polymerized by photo-induced polymerization. A photoinitiator may be employed to initiate the photopolymerization. Scintillation materials with significant light yields are illustrated.
    • 一种通过本体聚合合成和使用由液体单体制备的透明体共轭聚合物的方法。 液体单体含有π-电子共轭部分和可聚合部分。 单体溶液还可以具有官能化添加剂,例如包括有机染料,发光分子,荧光化合物,磷光化合物和发光量子点的发光添加剂。 单体溶液还可以具有敏化添加剂,例如高能光敏化合物,含有原子数大于52的原子的化合物的纳米颗粒和中子增感添加剂。 通过加入或不添加引发剂将单体溶液加热至高温而聚合。 或者,通过光诱导聚合使单体聚合。 可以使用光引发剂来引发光聚合。 示出了具有显着的光收率的闪烁材料。