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    • 2. 发明申请
    • CONCENTRATED, STABLE FABRIC SOFTENING COMPOSITIONS INCLUDING CHELANTS
    • 浓缩的,稳定的织物组合物,包括香料
    • WO1997003172A1
    • 1997-01-30
    • PCT/US1996011572
    • 1996-07-11
    • THE PROCTER & GAMBLE COMPANYWAHL, Errol, HoffmanSEVERNS, John, CortWAITE, Scott, WilliamHARTMAN, Frederick, AnthonyDEMEYERE, Hugo, Jean, MarieDECLERCQ, Marc, JohanWARD, Alice, Marie
    • THE PROCTER & GAMBLE COMPANY
    • C11D03/33
    • D06M23/10C11D1/62C11D1/645C11D3/0015C11D3/2041C11D3/2044C11D3/2048C11D3/2093C11D3/33
    • Clear or translucent fabric softening compositions having a biodegradable fabric softening active and an added chelating agent are disclosed. The biodegradable fabric softening active preferably has formula (1), wherein each R substituent is hydrogen or a short chain C1-C6, preferably C1-C3 alkyl or hydroxyalkyl group, e.g., methyl (most preferred), ethyl, propyl, hydroxyethyl, and the like, benzyl, or mixtures thereof; each m is 2 or 3; each n is from 1 to about 4, preferably 2; each Y is -O-(O)C-, -(R)N-(O)C-, -C(O)-N(R)-, or -C(O)-O-, preferably -O-(O)C-; the sum of carbons in each R , plus one when Y is -O-(O)C- or -(R)N-(O)C-, is C6-C22, preferably C12-22, more preferably C14-C20, but no more than one R or YR sum being less than about 12 and then the other R or YR sum is at least about 16, with each R being a long chain C5-C21 (or C6-C22), preferably C9-C19 (or C9-C20), most preferably C11-C17 (or C12-C18), straight, branched, unsaturated or polyunsaturated alkyl, the average Iodine Value of the parent fatty acid of the R being from about 20 to about 140. The chelating agent is preferably diaminetriaminepentaacetic acid. The compositions display excellent clarity with a percentage haze in the transmission mode of a Hunter Color analysis of less than 90 %, preferably less than 50 %.
    • 公开了具有可生物降解织物软化活性物质和加入的螯合剂的透明或半透明织物柔软组合物。 生物可降解织物软化活性剂优选具有式(1),其中每个R取代基是氢或短链C1-C6,优选C1-C3烷基或羟烷基,例如甲基(最优选),乙基,丙基,羟乙基和 苄基或其混合物; 每个m为2或3; 每个n为1至约4,优选2; 每个Y是-O-(O)C - , - (R)N-(O)C - , - C(O)-N(R) - 或-C(O) (O)C-; 当Y是-O-(O)C-或 - (R)N-(O)C - )时,每个R 1中的碳的和加上一个,是C 6 -C 22,优选C 12-22,更优选C 14 -C 20,但不超过一个R 1或YR 1和小于约12,然后另一个R 1或YR 1和为至少约16,其中每个R 1为 长链C5-C21(或C6-C22),优选C9-C19(或C9-C20),最优选C11-C17(或C12-C18)直链,支链,不饱和或多不饱和烷基,平均碘值 R 1的母体脂肪酸为约20至约140.螯合剂优选为二胺三胺五乙酸。 该组合物显示出优异的透明度,在Hunter Color分析的透射模式中的雾度百分比小于90%,优选小于50%。
    • 3. 发明申请
    • PROCESS FOR THE PREPARATION OF FABRIC SOFTENING ACTIVES AND PRODUCTS EMPLOYING SAME
    • 制备织物活性剂和使用它们的产品的方法
    • WO1998003618A1
    • 1998-01-29
    • PCT/US1997011726
    • 1997-07-15
    • THE PROCTER & GAMBLE COMPANYWAHL, Errol, HoffmanWAITE, Scott, WilliamSEVERNS, John, CortHARTMAN, Frederick, Anthony
    • THE PROCTER & GAMBLE COMPANY
    • C11D01/62
    • C11D1/62C07C231/02
    • A process for the preparation of a biodegradable fabric softening active is provided. The process comprises the steps of: a) providing a source of triglyceride and reacting said source of triglyceride to form a mixture, said mixture comprising fatty acids having the formula R CO2H, fatty acid esters having the formula R CO2R", or mixtures thereof; wherein R is C1-C22 alkyl, C2-C22 alkenyl, and mixtures thereof; R" is C1-C4 alkyl, C2-C4 monohydroxyalkyl, C3-C4 dihydroxyalkyl; b) reacting said mixture from step (a) with one or more amines having formula (I) wherein R is C1-C6 alkyl, C1-C6 hydroxyalkyl, benzyl, or mixtures thereof; each Z is independently selected from the group consisting of -OH, -CHR'OH, -CH(OH)CH2OH, -NH2, and mixtures thereof, wherein R' is C1-C4 alkyl; m is an integer from 1 to 3; n is an integer from 1 to 4; to form a fabric softening active precursor mixture having formula (II) wherein R, R , m, and n are the same as above; Y has formula (III), (IV), (V) and (VI) or mixtures thereof; wherein R and R' are the same as above; and c) quaternizing said fabric softening active precursor mixture from step (b) by reacting said mixture with a quaternizing agent of the formula RX, wherein R is the same as defined in step (b) and X is a softener compatible anion, forming a fabric softening active having formula (VII) wherein R, R , X, Y, m, and n are the same as above; provided at least step (c) is carried out in the presence of a chelating agent selected from the group consisting of diethylenetriaminepentaacetic acid, ethylenediamine-N, N'-disuccinnic acid, and mixtures thereof. A process for forming a fabric softener premix and a fabric softening composition as well as products for all three processes is also provided.
    • 提供了一种制备可生物降解织物软化活性物质的方法。 该方法包括以下步骤:a)提供甘油三酸酯源并使所述甘油三酯源反应形成混合物,所述混合物包含具有式R 1 CO 2 H的脂肪酸,具有式R 1 CO 2 R的脂肪酸酯 “或其混合物;其中R 1是C 1 -C 22烷基,C 2 -C 22烯基及其混合物; R”是C 1 -C 4烷基,C 2 -C 4单羟基烷基,C 3 -C 4二羟基烷基; b)将来自步骤(a)的所述混合物与一种或多种具有式(I)的胺反应,其中R是C 1 -C 6烷基,C 1 -C 6羟基烷基,苄基或其混合物; 每个Z独立地选自-OH,-CHR'OH,-CH(OH)CH 2 OH,-NH 2及其混合物,其中R'是C 1 -C 4烷基; m为1〜3的整数; n是1至4的整数; 以形成具有式(II)的织物柔软活性前体混合物,其中R 1,R 1,m和n与上述相同; Y具有式(III),(IV),(V)和(VI)或其混合物; 其中R 1和R 3与上述相同; 和c)通过使所述混合物与式RX的季铵化剂反应将来自步骤(b)的所述织物柔软活性前体混合物季铵化,其中R与步骤(b)中所定义的相同,X是软化剂相容的阴离子,形成 具有式(VII)的织物柔软活性物,其中R,R 1,X,Y,m和n与上述相同; 提供至少步骤(c)在选自二亚乙基三胺五乙酸,乙二胺-N,N'-二琥珀酸及其混合物的螯合剂存在下进行。 还提供了用于形成织物柔软剂预混物和织物柔软组合物以及用于所有三种方法的产品的方法。
    • 8. 发明申请
    • CONCENTRATED FABRIC SOFTENING COMPOSITION
    • 浓缩织物组合物
    • WO1998017756A1
    • 1998-04-30
    • PCT/US1997018932
    • 1997-10-21
    • THE PROCTER & GAMBLE COMPANYWAHL, Errol, HoffmanTRINH, ToanOLER, Chad, James
    • THE PROCTER & GAMBLE COMPANY
    • C11D01/62
    • C11D17/046C11D1/40C11D1/528C11D1/62C11D3/0015C11D3/0084C11D3/2003C11D3/201C11D3/2017C11D3/2044C11D3/2048C11D3/2051C11D3/2055C11D3/2058C11D3/2068C11D3/43C11D17/041
    • Principal solvents, especially mono-ol and diol principal solvents, having a ClogP of from about 0.15 to about 0.64, preferably from about 0.25 to about 0.62, and more preferably from about 0.40 to about 0.60, are disclosed that have the ability to make clear aqueous fabric softener compositions containing relatively high concentrations of fabric softener actives having highly unsaturated hydrocarbon moieties or branched chains in two long-chain hydrophobic groups with specific cis/trans ratios and having long chain hydrocarbon groups with an IV of from about 70 to about 140 for the unsaturated groups corresponding to fatty acids with the same number of carbons and the same configuration, and the said principal solvents are used at levels of less than about 40 %. The fabric softener actives are preferably prepared in the presence of chelating agent and/or antioxidant, as disclosed herein. Such materials are new. Other solvents can be present. Premixes of the fabric softening actives, the principal solvents, and, optionally, other solvents are useful in the preparation of complete formulations by obviating/limiting the need for heating.
    • 公开了具有约0.15至约0.64,优选约0.25至约0.62,更优选约0.40至约0.60的ClogP的主要溶剂,特别是单醇和二醇主要溶剂,其具有澄清的能力 含有比较高浓度织物柔软剂活性物质的水性织物柔软剂组合物,其具有两个具有特定顺式/反式比例的长链疏水基团中具有高度不饱和烃部分或支链的长链烃基,IV为约70至约140, 对应于具有相同碳数和相同构型的脂肪酸的不饱和基团,并且所述主要溶剂的用量低于约40%。 织物柔软剂活性剂优选在本文公开的螯合剂和/或抗氧化剂存在下制备。 这些材料是新的。 可以存在其它溶剂。 织物软化活性物质的预混合物,主要溶剂和任选的其它溶剂可用于通过消除/限制加热的需要来制备完整的制剂。