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1. 发明公开

EP0902093A1 Iron manufacturing 失效
标题翻译： Herstellung von Eisen
公开(公告)号：EP0902093A1
公开(公告)日：1999-03-17
申请号：EP98305838.9
申请日：1998-07-22
申请人： THE BOC GROUP, INC.
发明人： Saxena, Neeraj , Sweeney, Paul Alfred , Kapoor, Akhilesh
IPC分类号： C21B13/00
CPC分类号： C21B13/0006 , C21B2100/282 , C21B2100/284 , C21B2100/42 , C21B2100/62 , C21B2100/66 , Y02P10/136 , Y02P10/216
摘要： Iron ore is reduced to molten iron by introducing the ore into a reactor (A) while combusting coal with pure oxygen in the reactor (A). The molten iron phase (60), which forms at the bottom of the reactor (A), is stirred by injecting carbon monoxide into the molten iron (60). In a preferred embodiment, finely pulverized iron ore is injected with pure oxygen tangentially into a cyclone section (2) of the furnace (A) situated on top of a converter section (4), thereby causing melting and preliminary reduction of the ore to take place in the cyclone section (2). Primary reduction of the iron oxide occurs in the converter section (4) of the furnace.
摘要翻译：通过在反应器（A）中用纯氧燃烧煤而将矿石引入反应器（A）中将铁矿石还原成铁水。在反应器（A）的底部形成的铁水相（60）通过将一氧化碳注入铁水（60）来搅拌。在一个优选实施例中，将精细粉碎的铁矿石切向地注入位于转炉段（4）顶部的炉（A）的旋风分段（2）中，从而使矿石熔化和初步还原放在旋风部分（2）。氧化铁的一次还原发生在炉的转炉部分（4）中。

2. 发明公开

EP0583981A3 Hydrogen and carbon monoxide production by partial oxidation of hydrocarbon feed 失效
标题翻译：通过部分氧化氢进料的氢和一氧化碳生产
公开(公告)号：EP0583981A3
公开(公告)日：1994-09-14
申请号：EP93306512.0
申请日：1993-08-18
申请人： THE BOC GROUP, INC.
发明人： Kapoor, Akhilesh , Krishnamurthy, Ramachandran , Maclean, Donald
IPC分类号： C01B3/56 , C01B31/18
CPC分类号： F25J3/0271 , C01B3/36 , C01B3/56 , C01B32/40 , C01B2203/043 , C01B2203/047 , C01B2203/0475 , C01B2203/048 , C01B2203/0495 , F25J3/0223 , F25J3/0233 , F25J3/0261 , F25J2205/30 , F25J2245/02
摘要： Synthesis gas comprising hydrogen, water, carbon monoxide, carbon dioxide, and hydrocarbons is produced by contacting a gasified hydrocarbon feedstock and an oxidant in a partial oxidation reactor under at least 95% carbon monoxide selective, low hydrocarbon conversion conditions wherein the temperature, pressure, and flow rate conditions in the reactor yield synthesis gas having less than about 2% carbon dioxide. After being cooled, The synthesis gas is separated into high purity hydrogen, high purity carbon monoxide and a hydrogen-carbon monoxide gas mixture by pressure swing adsorption followed by cryogenic distillation or by two or more pressure swing adsorption steps.

3. 发明公开

EP1101522A1 Pressure swing adsorption process 有权
标题翻译： Druckwechseladsorptionsverfahren
公开(公告)号：EP1101522A1
公开(公告)日：2001-05-23
申请号：EP99309075.2
申请日：1999-11-15
申请人： THE BOC GROUP, INC.
发明人： Chen, Yudong , Kapoor, Akhilesh , Hamprasad, Narayanan
IPC分类号： B01D53/047 , B01D53/053
CPC分类号： B01D53/047 , B01D53/0476 , B01D53/053 , B01D2253/104 , B01D2253/108 , B01D2253/25 , B01D2256/16 , B01D2256/22 , B01D2256/245 , B01D2257/502 , B01D2257/504 , B01D2259/40022 , B01D2259/40033 , B01D2259/40049 , B01D2259/40052 , B01D2259/40075 , B01D2259/40079 , Y02C10/08 , Y02C20/20
摘要： High purity strongly adsorbed gas, e.g. carbon monoxide, is separated from a gas mixture containing one or more other gas components, e.g. hydrogen, carbon dioxide, methane, nitrogen and possibly other impurities, by a two-phase pressure swing adsorption process comprising the following steps:

(a) passing the feed gas mixture at superatmospheric pressure through an adsorbent which selectively adsorbs the carbon monoxide from the feed gas mixture, thereby producing a first carbon monoxide depleted gas stream (Figure 2, step 2);
(b) depressurising the adsorbent thereby producing a carbon monoxide enriched gas steam (Figure 2, step 6);
(c) purging the adsorbent with carbon monoxide enriched stream from step (b), thereby producing a first purge effluent (Figure 2, step (9));
(d) purging the adsorbent with carbon monoxide product, thereby producing a second purge effluent (Figure 2, step 10);
(e) depressurising the adsorbent, thereby producing the carbon monoxide product (Figure 2, step 11).
摘要翻译：高纯度强吸附气体，例如一氧化碳与含有一种或多种其它气体组分的气体混合物分离，例如，氢气，二氧化碳，甲烷，氮气和可能的其他杂质，通过两相变压吸附方法，包括以下步骤：（a）使进料气体混合物在超大气压下通过选自吸附一氧化碳的吸附剂气体混合物，从而产生第一贫乏一氧化碳气流（图2，步骤2）; （b）使吸附剂减压，从而产生富含一氧化碳的气体蒸汽（图2，步骤6）; （c）用来自步骤（b）的富含一氧化碳的料流清洗吸附剂，从而产生第一清洗流出物（图2，步骤（9））; （d）用一氧化碳产物清洗吸附剂，从而产生第二清洗流出物（图2，步骤10）; （e）使吸附剂减压，从而产生一氧化碳产物（图2，步骤11）。

4. 发明公开

EP0684066A2 Method of recovering a light element from a dilute feed 失效
标题翻译： Verfahren zurZurückgewinnungeines leichten Elementes aus einemverdünntenRohgas。
公开(公告)号：EP0684066A2
公开(公告)日：1995-11-29
申请号：EP95302293.6
申请日：1995-04-06
申请人： THE BOC GROUP, INC.
发明人： Kapoor, Akhilesh , Krishnamurthy, Ramachandran
IPC分类号： B01D53/22 , B01D53/047 , C01B3/50 , C01B23/00
CPC分类号： C01B23/0094 , B01D53/047 , B01D53/229 , B01D2253/108 , B01D2256/16 , B01D2256/18 , B01D2257/102 , B01D2257/504 , B01D2257/7022 , B01D2257/80 , B01D2258/06 , B01D2259/416 , C01B3/501 , C01B3/56 , C01B2203/0405 , C01B2203/043 , C01B2203/0465 , C01B2203/047 , C01B2203/0475 , C01B2203/048 , C01B2203/0495 , C01B2210/0012 , C01B2210/0014 , C01B2210/0031 , C10L3/101 , C10L2290/06 , C10L2290/10 , C10L2290/46 , C10L2290/542 , C10L2290/548 , Y02C10/08 , Y02C10/10 , Y02P20/152
摘要： A method of recovering a light element comprising hydrogen or helium from a high pressure feed stream. The feed stream comprises the light element in a concentration of less than 30% by volume and also, hydrocarbons and trace heavy contaminants. Methane and nitrogen may be in the high pressure feed stream if derived from a natural gas source. The trace heavy contaminants are removed from the high pressure feed stream through absorption in one or more beds of activated carbon and the feed stream, still at high pressure, is passed through a membrane unit having a membrane design to allow permeation of the light element while rejection of the hydrocarbons, possibly methane, and nitrogen. The membrane unit produces a process stream enriched to somewhere above 40% in the light elements and a mass flow rate that is only a fraction of the mass flow rate of the feed stream. The process stream is then compressed and subjected to a pressure swing adsorption process utilizing one or more adsorbents to least absorb the hydrocarbons to produce a product stream highly enriched in the light element or 98% enriched and above. Since the mass flow rate of the process stream is very low, very little energy need be expended in compressing the process stream as compared with prior art processes using cryogenic rectification. Additionally, since the waste stream is rejected at pressure, if the pressure is high enough, it can simply be returned to a source of the feed stream without recompression or if not being supplied at a requisite high pressure, it can be recompressed with a blower and then returned to the supply.
摘要翻译：从高压进料流中回收包含氢或氦的轻元素的方法。进料流包含浓度小于30体积％的轻质元素，以及烃和痕量重的污染物。如果源自天然气源，甲烷和氮气可能在高压进料流中。通过在一个或多个活性炭床中的吸收从高压进料流中除去痕量重的污染物，并且仍然在高压下的进料流通过具有膜设计的膜单元以允许轻元素的渗透同时排除烃，可能是甲烷和氮气。膜单元产生在轻元素中富集到40％以上的工艺流，并且质量流量仅为进料流质量流量的一部分。然后将工艺流压缩并进行利用一种或多种吸附剂的变压吸附方法以最少吸收烃以产生高度富集在轻元素中的产物流或富含98％以上的产物流。由于工艺流的质量流速非常低，与使用低温精馏的现有技术方法相比，在压缩流程中需要很少的能量消耗。此外，由于废物流在压力下被排出，如果压力足够高，则可以简单地将其返回到进料流源而不进行再压缩，或者如果在必要的高压下不被供给，则可以用鼓风机然后回到供应。

5. 发明公开

EP0684066A3 Method of recovering a light element from a dilute feed 失效
标题翻译：一种用于回收从稀释粗气体的光元件的方法。
公开(公告)号：EP0684066A3
公开(公告)日：1996-05-22
申请号：EP95302293.6
申请日：1995-04-06
申请人： THE BOC GROUP, INC.
发明人： Kapoor, Akhilesh , Krishnamurthy, Ramachandran
IPC分类号： B01D53/22 , B01D53/047 , C01B3/50 , C01B23/00
CPC分类号： C01B23/0094 , B01D53/047 , B01D53/229 , B01D2253/108 , B01D2256/16 , B01D2256/18 , B01D2257/102 , B01D2257/504 , B01D2257/7022 , B01D2257/80 , B01D2258/06 , B01D2259/416 , C01B3/501 , C01B3/56 , C01B2203/0405 , C01B2203/043 , C01B2203/0465 , C01B2203/047 , C01B2203/0475 , C01B2203/048 , C01B2203/0495 , C01B2210/0012 , C01B2210/0014 , C01B2210/0031 , C10L3/101 , C10L2290/06 , C10L2290/10 , C10L2290/46 , C10L2290/542 , C10L2290/548 , Y02C10/08 , Y02C10/10 , Y02P20/152
摘要： A method of recovering a light element comprising hydrogen or helium from a high pressure feed stream. The feed stream comprises the light element in a concentration of less than 30% by volume and also, hydrocarbons and trace heavy contaminants. Methane and nitrogen may be in the high pressure feed stream if derived from a natural gas source. The trace heavy contaminants are removed from the high pressure feed stream through absorption in one or more beds of activated carbon and the feed stream, still at high pressure, is passed through a membrane unit having a membrane design to allow permeation of the light element while rejection of the hydrocarbons, possibly methane, and nitrogen. The membrane unit produces a process stream enriched to somewhere above 40% in the light elements and a mass flow rate that is only a fraction of the mass flow rate of the feed stream. The process stream is then compressed and subjected to a pressure swing adsorption process utilizing one or more adsorbents to least absorb the hydrocarbons to produce a product stream highly enriched in the light element or 98% enriched and above. Since the mass flow rate of the process stream is very low, very little energy need be expended in compressing the process stream as compared with prior art processes using cryogenic rectification. Additionally, since the waste stream is rejected at pressure, if the pressure is high enough, it can simply be returned to a source of the feed stream without recompression or if not being supplied at a requisite high pressure, it can be recompressed with a blower and then returned to the supply.

6. 发明公开

EP0643013A1 Production of hydrogen and carbon monoxide for oxyfuel furnace off-gas 失效
标题翻译：产量从氧气 - 燃料炉的废气的氢气和一氧化碳。
公开(公告)号：EP0643013A1
公开(公告)日：1995-03-15
申请号：EP94305906.3
申请日：1994-08-10
申请人： THE BOC GROUP, INC.
发明人： Kapoor, Akhilesh , Tamhankar, Satish , Krishnamurthy, Ramachandran
IPC分类号： C01B3/34
CPC分类号： C01B3/34 , C01B3/38 , C01B3/48 , C01B3/56 , C01B2203/0211 , C01B2203/0233 , C01B2203/0255 , C01B2203/0261 , C01B2203/0283 , C01B2203/043 , C01B2203/045 , C01B2203/046 , C01B2203/0465 , C01B2203/047 , C01B2203/0475 , C01B2203/0811 , C01B2203/0844 , C01B2203/0883 , C01B2203/1047 , C01B2203/1058 , C01B2203/1064 , C01B2203/107 , C01B2203/1076 , C01B2203/1235 , C01B2203/1241 , C01B2203/1258 , C01B2203/127 , C01B2203/146 , C01B2203/148 , F25J3/0223 , F25J3/0252 , F25J3/0261 , F25J3/04527 , F25J3/04533 , F25J3/04539 , F25J2245/02
摘要： Hot exhaust gases (from oxygen-based hydrocarbon-fire) furnace A made up predominantly of steam and carbon dioxide are used for reforming in reformer C a hydrocarbonaceous substance in the presence or absence of oxygen to produce carbon monoxide and hydrogen. Additional hydrogen can be produced by subjecting the carbon monoxide produced in the reaction to the water gas shift reaction.
摘要翻译：热废气（从基于氧的烃类火灾）炉A由主要蒸汽和二氧化碳的使用在C重整氢重整在存在或不存在氧，以产生一氧化碳和烃类物质。额外的氢可以通过使在所述反应中的水煤气变换反应中产生的一氧化碳来制备。

7. 发明公开

EP0583981A2 Hydrogen and carbon monoxide production by partial oxidation of hydrocarbon feed 失效
标题翻译：生产氢和一氧化碳的烃类的部分氧化。
公开(公告)号：EP0583981A2
公开(公告)日：1994-02-23
申请号：EP93306512.0
申请日：1993-08-18
申请人： THE BOC GROUP, INC.
发明人： Kapoor, Akhilesh , Krishnamurthy, Ramachandran , Maclean, Donald
IPC分类号： C01B3/56 , C01B31/18
CPC分类号： F25J3/0271 , C01B3/36 , C01B3/56 , C01B32/40 , C01B2203/043 , C01B2203/047 , C01B2203/0475 , C01B2203/048 , C01B2203/0495 , F25J3/0223 , F25J3/0233 , F25J3/0261 , F25J2205/30 , F25J2245/02
摘要： Synthesis gas comprising hydrogen, water, carbon monoxide, carbon dioxide, and hydrocarbons is produced by contacting a gasified hydrocarbon feedstock and an oxidant in a partial oxidation reactor under at least 95% carbon monoxide selective, low hydrocarbon conversion conditions wherein the temperature, pressure, and flow rate conditions in the reactor yield synthesis gas having less than about 2% carbon dioxide. After being cooled, The synthesis gas is separated into high purity hydrogen, high purity carbon monoxide and a hydrogen-carbon monoxide gas mixture by pressure swing adsorption followed by cryogenic distillation or by two or more pressure swing adsorption steps.
摘要翻译：合成气包含氢气，水，一氧化碳，二氧化碳和烃类是由接触气化烃原料生产和部分氧化反应器对氧化剂具有至少95％的一氧化碳的选择性，低的烃转化条件worin的温度，压力下，和流速条件具有小于约2％的二氧化碳较少反应器产率的合成气英寸冷却后，合成气被分离成高纯度氢，高纯度一氧化碳和通过变压吸附氢 - 一氧化碳气体混合物，然后通过低温蒸馏或通过两个或更多个变压吸附步骤。

8. 发明公开

EP1022045A3 Multiple equalization pressure swing adsorption process. 审中-公开
标题翻译：与vielstufigem压力平衡变压吸附方法
公开(公告)号：EP1022045A3
公开(公告)日：2002-10-16
申请号：EP00300292.0
申请日：2000-01-17
申请人： THE BOC GROUP, INC.
发明人： Kapoor, Akhilesh , Chen, YuDong , Davies, Simon Paul , Kumar, Ravi , Thorogood, Robert M.
IPC分类号： B01D53/047
CPC分类号： B01D53/047 , B01D2256/10 , B01D2256/16 , B01D2256/20 , B01D2256/22 , B01D2257/502 , B01D2259/4003 , B01D2259/40037 , B01D2259/40039 , B01D2259/40041 , B01D2259/40045 , B01D2259/40052 , B01D2259/40067 , B01D2259/40069 , B01D2259/40071 , B01D2259/40075 , B01D2259/40079
摘要： The strongly adsorbed component of a gas mixture is produced in enhanced purity and yield by novel PSA cycles. The basic steps of the cycles include an adsorption vessel prepressurisation step (R), a cocurrent nonadsorbed gas production step (A), a cocurrent purge step with strongly adsorbed gas product (P) and a countercurrent depressurisation step (E) which produces the strongly adsorbed gas product that is used in the cocurrent purge step. In addition to the basic steps, a first depressurisation equalization step (EDI) precedes or follows the cocurrent purge step (P) and a corresponding first pressurisation equalization step (EPI) follows the countercurrent depressurisation step (E). The cycle optionally includes one or two further depressurisation equalization steps before the cocurrent purge step and one or two corresponding pressurisation equalization steps after the first pressurisation equalization step.

9. 发明公开

EP1022044A3 High pressure purge pressure swing adsorption process 审中-公开
标题翻译：用高压清洗变压吸附方法
公开(公告)号：EP1022044A3
公开(公告)日：2002-10-16
申请号：EP00300291.2
申请日：2000-01-17
申请人： THE BOC GROUP, INC.
发明人： Kapoor, Akhilesh , Chen, YuDong , Davies, Simon Paul , Kumar, Ravi , Thorogood, Robert M.
IPC分类号： B01D53/047
CPC分类号： B01D53/047 , B01D2256/10 , B01D2256/16 , B01D2256/20 , B01D2256/22 , B01D2257/502 , B01D2259/4003 , B01D2259/40037 , B01D2259/40041 , B01D2259/40045 , B01D2259/40047 , B01D2259/40052 , B01D2259/40066 , B01D2259/40067 , B01D2259/40069 , B01D2259/40073 , B01D2259/40075 , B01D2259/40079
摘要： A high pressure purge step (HPP) is incorporated into the cycle of a PSA process designed for the recovery of strongly adsorbed product gas from a gas mixture. The basic steps of the PSA cycle are: (a) pressurising an adsorption zone to a selected adsorption pressure (R); (b) cocurrently introducing the gas mixture into the adsorption zone at the selected pressure while cocurrently removing purge effluent therefrom (A); (c) purging the adsorption zone by cocurrently introducing thereinto part of a second component-enriched gas produced in step (d), while cocurrently removing purge effluent therefrom (P); and (d) depressurising the adsorption zone by countercurrently removing gas therefrom, thereby producing second component-enriched gas (E). The high pressure purge stream is obtained by compressing the low pressure cocurrent purge step (P) that preceds the countercurrent depressurisation or evacuation step (E). The high pressure purge step (HPP) is included in the cycle following the adsorption step (A) of the process.

10. 发明授权

EP0583981B1 Hydrogen and carbon monoxide production by partial oxidation of hydrocarbon feed 失效
标题翻译：生产氢和一氧化碳的烃类的部分氧化
公开(公告)号：EP0583981B1
公开(公告)日：1997-03-12
申请号：EP93306512.0
申请日：1993-08-18
申请人： THE BOC GROUP, INC.
发明人： Kapoor, Akhilesh , Krishnamurthy, Ramachandran , Maclean, Donald
IPC分类号： C01B3/56 , C01B31/18
CPC分类号： F25J3/0271 , C01B3/36 , C01B3/56 , C01B32/40 , C01B2203/043 , C01B2203/047 , C01B2203/0475 , C01B2203/048 , C01B2203/0495 , F25J3/0223 , F25J3/0233 , F25J3/0261 , F25J2205/30 , F25J2245/02
摘要： Synthesis gas comprising hydrogen, water, carbon monoxide, carbon dioxide, and hydrocarbons is produced by contacting a gasified hydrocarbon feedstock and an oxidant in a partial oxidation reactor under at least 95% carbon monoxide selective, low hydrocarbon conversion conditions wherein the temperature, pressure, and flow rate conditions in the reactor yield synthesis gas having less than about 2% carbon dioxide. After being cooled, The synthesis gas is separated into high purity hydrogen, high purity carbon monoxide and a hydrogen-carbon monoxide gas mixture by pressure swing adsorption followed by cryogenic distillation or by two or more pressure swing adsorption steps.

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