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1. 发明申请

WO2006005066A2 NANOTUBULAR SOLID OXIDE FUEL CELL 审中-公开
标题翻译：纳米固体氧化物燃料电池
公开(公告)号：WO2006005066A2
公开(公告)日：2006-01-12
申请号：PCT/US2005/023767
申请日：2005-06-30
申请人： THE BOARD OF TRUSTEES OF THE LELAND STANFORD JUNIOR UNIVERSITY , CHA, Suk-Won , BENT, Stacey , HOLME, Tim , JIANG, Xirong , PRINZ, Friedrich, B. , SAITO, Yuji
发明人： CHA, Suk-Won , BENT, Stacey , HOLME, Tim , JIANG, Xirong , PRINZ, Friedrich, B. , SAITO, Yuji
IPC分类号： H01M8/02 , H01M4/90 , H01M8/10 , H01M4/92 , B05D5/12 , H01M4/88
CPC分类号： H01M8/122 , B01J35/04 , H01M4/8636 , H01M4/8647 , H01M4/8814 , H01M4/8867 , H01M4/8871 , H01M4/9033 , H01M4/905 , H01M4/9091 , H01M4/928 , H01M8/004 , H01M8/1213 , H01M8/124 , H01M8/1286 , H01M8/243 , H01M8/2435 , Y02P70/56
摘要： A membrane electrode assembly (MEA) having a nano-tubular patterned structure and having solid (instead of porous) electrode layers is provided. Increased mechanical strength is provided by the use of solid electrode layers. The electrode layers are sufficiently thin to permit the flow of reactants to the electrolyte. The nano-tubular pattern includes multiple closed-end tubes and increase the reaction area to volume ratio of the MEA. The nano-tubular pattern also serves to increase mechanical strength, especially in a preferred honey-comb like arrangement of the closed-end tubes. A catalyst is preferably disposed on the anode and cathode surfaces of the MEA, and is preferably in the form of separated catalyst islands in order to increase reaction area. MEAs according to the invention can be fabricated by layer deposition on a patterned template. Atomic layer deposition is a preferred deposition technique.
摘要翻译：提供具有纳米管状图案结构并具有固体（代替多孔）电极层的膜电极组件（MEA）。通过使用固体电极层提供增加的机械强度。电极层足够薄以允许反应物流向电解质。纳米管状图案包括多个封闭端管，并增加MEA的反应面积与体积比。纳米管状图案还用于增加机械强度，特别是在封闭端管优选的蜂巢状布置中。催化剂优选设置在MEA的阳极和阴极表面上，并且优选为分离的催化剂岛的形式，以增加反应面积。根据本发明的MEA可以通过在图案化模板上的层沉积来制造。原子层沉积是优选的沉积技术。

2. 发明申请

WO2009058388A3 LAYER-STRUCTURED FUEL CELL CATALYSTS AND CURRENT COLLECTORS 审中-公开
公开(公告)号：WO2009058388A3
公开(公告)日：2009-05-07
申请号：PCT/US2008/012417
申请日：2008-10-31
申请人： THE BOARD OF TRUSTEES OF THE LELAND STANFORD JUNIOR UNIVERSITY , HONDA MOTOR CO. LTD , JIANG, Xirong , TIAN, Xu , PRINZ, Friedrich, B. , BENT, Stacey, F. , SHIM, Joon, Hyung , SUGAWARA, Masayuki , HUANG, Hong
发明人： JIANG, Xirong , TIAN, Xu , PRINZ, Friedrich, B. , BENT, Stacey, F. , SHIM, Joon, Hyung , SUGAWARA, Masayuki , HUANG, Hong
IPC分类号： H01M4/86 , H01M4/88 , H01M8/10 , H01M8/12
摘要： A method of fabricating a layer-structured catalysts at the electrode/electrolyte interface of a fuel cell is provided. The method includes providing a substrate, depositing an electrolyte layer on the substrate, depositing a catalyst bonding layer to the electrolyte layer, depositing a catalyst layer to the catalyst bonding layer, and depositing a microstructure stabilizing layer to the catalyst layer, where the bonding layer improves adhesion of the catalyst onto the electrolyte. The catalyst and a current collector is a porous catalyst and a fully dense current collector, or a fully dense catalyst and a fully dense current collector structure layer. A nano-island catalyst and current collector structure layer is deposited over the catalyst and current collector or over the bonding layer, which is deposited over the electrolyte layer. The fuel cell can be hydrogen-fueled solid oxide, solid oxide with hydrocarbons, solid sensor, solid acid, polymer electrolyte or direct methanol.

3. 发明申请

WO2008136882A2 FABRICATION METHOD OF SIZE-CONTROLLED, SPATIALLY DISTRIBUTED NANOSTRUCTURES BY ATOMIC LAYER DEPOSITION 审中-公开
标题翻译：原子层沉积制备尺寸可控，空间分布的纳米结构的方法
公开(公告)号：WO2008136882A2
公开(公告)日：2008-11-13
申请号：PCT/US2008/002105
申请日：2008-02-14
申请人： THE BOARD OF TRUSTEES OF THE LELAND STANFORD JUNIOR UNIVERSITY , HONDA MOTOR CO., LTD , BENT, Stacey, F. , CHEN, Rong , JIANG, Xirong , SAITO, Yuji
发明人： BENT, Stacey, F. , CHEN, Rong , JIANG, Xirong , SAITO, Yuji
IPC分类号： H01L29/02 , H01L29/06
CPC分类号： C23C16/04 , C23C16/45525
摘要： A method of growing spatially-separated and size-controlled particles on substrate surfaces is provided. The method utilizes chemical modification of the substrate surface, an atomic layer deposition (ALD) system, providing a modified layer to the substrate surface and providing an ALD material for nanoparticle deposition. The method induces a Volmer-Weber growth method, where islands of the nanoparticles are formed on the surface. The modified layer controls a number of nucleation sites on the surface, where controlling the number of ALD cycles limits an amount of deposited the material for discrete the nanoparticles. The modified layer can include self-assembled monolayers, modified hydrophobicity of the surface, H-terminated surfaces, and varying functional groups within the modified layer, where thermally attached alkenes, photochemically attached alkenes, thermally attached alkynes or photochemically attached alkynes are attached to the H-terminated surfaces, and the density of the nucleation sites of the nanoparticles are thereby managed.
摘要翻译：提供了在衬底表面上生长空间分离和尺寸控制的颗粒的方法。该方法利用衬底表面的化学改性，原子层沉积（ALD）系统，向衬底表面提供改性层并提供用于纳米颗粒沉积的ALD材料。该方法诱导Volmer-Weber生长方法，其中纳米颗粒的岛在表面上形成。改性层控制表面上的许多成核位点，其中控制ALD循环次数限制了用于离散纳米颗粒的材料的沉积量。改性层可以包括自组装单层，表面的改性疏水性，H-封端表面和改性层内的不同官能团，其中热连接的烯烃，光化学连接的烯烃，热连接的炔烃或光化学连接的炔烃连接到 H-终止的表面，以及纳米颗粒的成核位点的密度由此被管理。

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