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    • 4. 发明申请
    • OPTICAL DISK SUBSTRATE
    • 光盘基板
    • WO1997022649A1
    • 1997-06-26
    • PCT/JP1996003616
    • 1996-12-11
    • TEIJIN CHEMICALS, LTD.TOKUDA, Toshimasa
    • TEIJIN CHEMICALS, LTD.
    • C08G64/06
    • C08G64/06G11B7/2534
    • An optical disk substrate made from a polycarbonate resin prepared from at least one dihydric phenol selected from the group consisting of 2,2-bis(4-hydroxyphenyl)butane, 2,2-bis(4-hydroxyphenyl)-3-methylbutane, 2,2-bis(4-hydroxyphenyl)-4-methylpentane, and 2,2-bis(4-hydroxyphenyl)-3,3-dimethylbutane, the dihydric phenol amounting to 30 to 100 % by mole of the whole dihydric phenol component. The number of unacceptable surface irregularities of the substrate is 0 to 1, and the polycarbonate resin satisfies the requirements that (A) the specific viscosity measured as a solution of 0.7 g of the resin in 100 ml of methylene chloride at 20 DEG C is 0.2 to 0.4; (B) the number of insoluble particles measured as a solution of the polycarbonate resin in methylene chloride is not more than 25,000 per g of the polycarbonate resin in terms of the number of particles having an equivalent diameter of not less than 0.5 mu m and not more than 500 per g of the polycarbonate resin in terms of the number of particules having an equivalent diameter of not less than 1 mu m; and (C) the water absorption is not more than 0.2 % by weight. This substrate enables pits or grooves to be accurately transferred, is less likely to cause warpage derived from absorption of moisture, and has a high-density recording capacity. It has high functions suitable particularly for use as an optical disk substrate for video disks or the like.
    • 由由选自2,2-双(4-羟基苯基)丁烷,2,2-双(4-羟基苯基)-3-甲基丁烷,2 ,2-双(4-羟基苯基)-4-甲基戊烷和2,2-双(4-羟基苯基)-3,3-二甲基丁烷,二元酚为全部二元酚成分的30〜100摩尔%。 基板的不可接受的表面凹凸的数量为0〜1,聚碳酸酯树脂满足以下要求:(A)作为在20℃的二氯甲烷100ml中的0.7g树脂的溶液测定的比粘度为0.2 至0.4; (B)以聚碳酸酯树脂溶于二氯甲烷中的溶液测定的不溶性粒子的数量,以当量直径不小于0.5μm的粒子数为基准,不超过25,000 / g聚碳酸酯树脂 以每当量直径不小于1μm的颗粒数计,每克聚碳酸酯树脂多于500个; 和(C)吸水率不超过0.2重量%。 该基板能够精确地转印凹坑或凹槽,不太可能引起由吸湿引起的翘曲,并且具有高密度记录容量。 它具有很高的功能,特别适合用作视盘的光盘基片等。