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    • 1. 发明申请
    • TREATMENT OF RECYCLING GAS FOR DIRECT THERMOCHEMICAL CONVERSION OF HIGH MOLECULAR WEIGHT ORGANIC SUBSTANCES INTO LOW VISCOSITY LIQUID RAW MATERIALS, COMBUSTIBLES AND FUELS
    • 有机物质在分子高液态低ROH和燃料气路中气体处理直接热化学转化
    • WO2009130046A3
    • 2010-01-14
    • PCT/EP2009003023
    • 2009-04-24
    • TECH WERKE LUDWIGSHAFEN AGBERGER UWEWILLNER THOMASVANSELOW WALTER
    • BERGER UWEWILLNER THOMASVANSELOW WALTER
    • C10G1/00C10G1/06C10G1/10
    • C10G1/002C10G1/065C10G1/10C10G2300/1011C10G2300/202Y02P30/20
    • The invention relates to a method for the direct thermochemical conversion of high molecular weight organic starting products into low molecular weight organic products that are liquid with a low viscosity at ambient temperature and can be combusted. Said method consists of the following steps: (1) the starting product, at least one reducing gas and slow-evaporating product fractions are provided in a reactor, (2) the provided starting material is rapidly heated to a reaction temperature, (3) said starting material is converted using the temperature, the reducing effect of the gas and autocatalytical effects of the product fractions in vaporous reaction products and reaction gas, (4) the reaction gas is separated by means of condensation by evacuating the condensed reaction products, said separated reaction gas comprising a mixture of hydrogen, methane and other hydrocarbons and carbon monoxide and carbon dioxide. Said claimed method is characterised by other additional steps: (5) the separated reaction gas is conditioned by discharging at least one part of the gas mixture and optionally, introducing hydrogen, said conditioning followed by (6) re-injecting the conditioned reaction gas into the reactor for simultaneously producing a hydrating, reducing and stripping effect for converting the starting material. According to the invention, the amount of active gas fractions and its part in the total flow of the reaction gas can be modified in an advantageous manner, thus increasing the effectiveness of the method and leading to an improvement of the target product quality and yield with total lower production costs. The invention also relates to a method for carrying out the claimed method.
    • 本发明涉及一种用于高分子量有机起始原料在低分子量的有机物,其存在在室温下为低粘度的流体,并且可燃的直接热化学转化的方法,包括以下步骤:(1)提供起始原料,至少一种还原在反应器中气体和低挥发性的产物馏分 ,(2)所提供的原料的冲击加热至反应温度,(3)服用以蒸气反应产物和反应气体产物组分的气体和自催化效应的还原作用的温度的优点的原料的转化,(4)通过冷凝并除去的分离反应气体 冷凝的反应产物,其中包括氢,甲烷和其他烃的混合物以及一氧化碳和二氧化碳,其特征在于,作为进一步的横移被分离的反应气体 由气体混合物的至少一部分的放电的装置和任选的另外的氢气入口的装置,随后(6)再循环调节反应气体到反应器中用于同时生产一种氢化的ensschritte分离的反应气体的(5)调节,减少和对转化剥离效果 离析物被提供。 根据本发明的方法,有效的气体成分和它们的反应气体的总流量的比例的量因此可以以有利的方式修改,从而导致增加了过程的效率,以及到目标产品的质量和产量的降低整体工艺成本的改进。 本发明还涉及一种用于实施本发明方法的装置。
    • 7. 发明专利
    • TREATMENT OF RECYCLING GAS FOR DIRECT THERMOCHEMICAL CONVERSION OF HIGH MOLECULAR WEIGHT ORGANIC SUBSTANCES INTO LOW VISCOSITY LIQUID RAW MATERIALS, COMBUSTIBLES AND FUELS
    • CA2721239C
    • 2015-04-21
    • CA2721239
    • 2009-04-24
    • TECH WERKE LUDWIGSHAFEN AG
    • BERGER UWEWILLNER THOMASVANSELOW WALTER
    • C10G1/00C10G1/06C10G1/10
    • The invention relates to a method for the direct thermochemical conversi-on of high molecular weight organic starting products into low molecular weight organic products that are liquid with a low viscosity at ambient temperature and can be combus-ted. Said method consists of the following steps: (1) the starting product, at least one re-ducing gas and slow-evaporating product fractions are provided in a reactor, (2) the provided starting material is rapidly heated to a reaction temperature, (3) said starting mate-rial is converted using the temperature, the reducing effect of the gas and autocatalytical effects of the product fractions in vaporous reaction products and reaction gas, (4) the re-action gas is separated by means of condensation by evacuating the condensed reaction products, said separated reaction gas comprising a mixture of hydrogen, methane and other hydrocarbons and carbon monoxide and carbon dioxide. Said claimed method is characterised by other additional steps: (5) the separated reaction gas is conditioned by discharging at least one part of the gas mixture and optionally, introducing hydrogen, said conditioning followed by (6) re-injecting the conditioned reaction gas into the reac-tor for simultaneously producing a hydrating, reducing and stripping effect for converting the starting material. According to the invention, the amount of active gas fractions and its part in the total flow of the reaction gas can be modified in an advantageous manner, thus increasing the effectiveness of the method and leading to an improvement of the tar-get product quality and yield with total lower production costs. The invention also relates to a method for carrying out the claimed method.
    • 8. 发明专利
    • Tratamiento de gas de reciclaje para la transformación termoquímica directa de sustancias orgánicas de alto peso molecular en materias primas, combustibles y carburantes líquidos de baja viscosidad
    • ES2524260T3
    • 2014-12-04
    • ES09735165
    • 2009-04-24
    • TECH WERKE LUDWIGSHAFEN AG
    • BERGER UWEWILLNER THOMASVANSELOW WALTER
    • C10G1/00C10G1/06C10G1/10
    • Procedimiento para la transformación termoquímica directa de al menos un reactante orgánico de alto peso molecular en productos orgánicos de bajo peso molecular que están presentes a temperatura ambiente como líquidos de baja viscosidad y son combustibles, aplicándose como reactante sustancias y/o mezclas de sustancias que contienen carbono de macromoléculas de cadena larga y/o reticuladas, en forma de materias primas renovables así como sustancias residuales y de desecho, que presenta las etapas de procedimiento: - facilitación del reactante, fracciones de producto difícilmente volátiles y al menos un gas reductor en un reactor, - calentamiento brusco del reactante en el intervalo de segundos a la temperatura de reacción de 200 ºC a 600 ºC, - transformación del reactante a la temperatura de reacción con aprovechamiento de la acción reductora del gas y/o efectos autocatalíticos de las fracciones de producto en productos de reacción en forma de vapor y gas de reacción, - separación del gas de reacción mediante condensación con evacuación de los productos de reacción condensados, comprendiendo el gas de reacción separado a) en caso de reactantes que contienen oxígeno, hidrógeno, metano así como eventualmente otros hidrocarburos, monóxido de carbono y dióxido de carbono y b) en caso de reactantes sin oxígeno, hidrógeno, metano y eventualmente otros hidrocarburos, - acondicionamiento del gas de reacción separado mediante exclusión de al menos una parte de la mezcla de gases y de forma adicional mediante aporte de hidrógeno y/u otra sustancia reductora, en particular en forma de monóxido de carbono o tetralina, - reconducción del gas de reacción acondicionado al reactor para la generación simultánea de un efecto reductor, en particular de hidrogenación, para la transformación del reactante y/o un efecto de arrastre para la descarga del producto, comprimiéndose y precalentándose el gas de reacción acondicionado antes de su reconducción al reactor.