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1. 发明授权

KR840001600B1 홋트-멜트형 접착제 조성물 失效
公开(公告)号：KR840001600B1
公开(公告)日：1984-10-11
申请号：KR810000651
申请日：1981-02-27
申请人： TAKEDA CHEMICAL INDUSTRIES LTD
发明人： NAKABAYASHI MASAMITSU , DOURA FUMIHIRO , TATSUMI TETSUJIRO , MIYAMOTO REIJI
IPC分类号： C09J133/04 , C08L23/06 , C09J133/06 , C09J3/14

2. 发明授权

US3877969A Coated glass bottles 失效
标题翻译：涂层玻璃瓶
公开(公告)号：US3877969A
公开(公告)日：1975-04-15
申请号：US36250273
申请日：1973-05-21
申请人： TAKEDA CHEMICAL INDUSTRIES LTD
发明人： TATSUMI TETSUJIRO , MIYAMOTO REIJI , MATSUI YUTAKA , KAZAMA SEIJI , TAKEMURA TADAO , KANAYAMA HIKOYOSHI
IPC分类号： B65D23/08 , C03C17/32 , C03C17/34 , B32B17/10
CPC分类号： C03C17/3405 , B65D23/0814 , C03C17/322 , Y10S215/06 , Y10T428/1321 , Y10T428/265 , Y10T428/31576 , Y10T428/31587 , Y10T428/31601 , Y10T428/31649
摘要： Glass bottles, suitable as containers for drinks, such as, beer and fruit juices, are coated first with an olefine copolymer containing hydroxyl or both hydroxyl and carboxyl groups in its molecule, and then with a thermoplastic polyurethane. The so coated bottles break less easily than conventional glass bottles, show less tendency to scatter when they are broken, and are not easily scratched.
摘要翻译：适合作为饮料容器（例如啤酒和果汁）的玻璃瓶首先用分子中含有羟基或羟基和羧基的烯烃共聚物，然后用热塑性聚氨酯涂覆。如此涂层的瓶子比常规玻璃瓶容易破裂，破碎时显示较少的散射倾向，并且不易划伤。

3. 发明授权

US3889031A Coated glass bottles 失效
标题翻译：涂层玻璃瓶
公开(公告)号：US3889031A
公开(公告)日：1975-06-10
申请号：US30124572
申请日：1972-10-26
申请人： TAKEDA CHEMICAL INDUSTRIES LTD
发明人： TATSUMI TESTUJIRO , MIYAMOTO REIJI , MATSUI YUTAKA , KAZAMA SEIJI , TAKEMURA TADAO , KANAYAMA HIKOYOSHI
IPC分类号： B65D23/08 , C03C17/32 , C03C17/34 , C08G18/62 , B41M1/18 , B44C3/02 , B44D1/02
CPC分类号： B65D23/0814 , C03C17/322 , C03C17/3405 , C08G18/6204 , C08G18/6212 , Y10S215/06 , Y10T428/1321 , Y10T428/24975 , Y10T428/31587 , Y10T428/31649
摘要： Glass bottles having their surface initially coated with an olefine copolymer containing OH groups or OH and COOH groups and then coated with a polyisocyanate or mixture of a polyisocyanate and a polyol or thermoplastic polyurethane, such coated bottles exhibiting resistance to breakage.

4. 发明专利

DE3132300A1 未知
公开(公告)号：DE3132300A1
公开(公告)日：1982-04-15
申请号：DE3132300
申请日：1981-08-17
申请人： TAKEDA CHEMICAL INDUSTRIES LTD
发明人： GOTO JUGO , MOCHIZUKI KAZUTAKA , KUBOTA TSUTOMU , MIYAMOTO REIJI
IPC分类号： C09D5/03 , C08G18/10 , C08G18/40 , C08G18/42 , C08G18/62 , C08G18/80 , C09D5/46 , C09D175/04 , C09D3/72 , C09D5/40 , C09D5/42

5. 发明专利

CA1015617A COATED GLASS BOTTLES 未知
公开(公告)号：CA1015617A
公开(公告)日：1977-08-16
申请号：CA171846
申请日：1973-05-18
申请人： TAKEDA CHEMICAL INDUSTRIES LTD , MITSUI POLYCHEMICALS LTD
发明人： TATSUMI TETSUJIRO , MIYAMOTO REIJI , MATSUI YUTAKA , KAZAMA SEIJI , TAKEMURA TADAO , KANAYAMA HIKOYOSHI
IPC分类号： B65D23/08 , C03C17/32 , C03C17/34
摘要： Glass bottles, suitable as containers for drinks, such as, beer and fruit juices, are coated first with an olefine copolymer containing hydroxyl or both hydroxyl and carboxyl groups in its molecule, and then with a thermoplastic polyurethane. The so coated bottles break less easily than conventional glass bottles, show less tendency to scatter when they are broken, and are not easily scratched.

6. 发明专利

CA971839A COATED GLASS BOTTLES 未知
公开(公告)号：CA971839A
公开(公告)日：1975-07-29
申请号：CA157242
申请日：1972-11-23
申请人： TAKEDA CHEMICAL INDUSTRIES LTD , MITSUI POLYCHEMICALS LTD
发明人： TATSUMI TETSUJIRO , MIYAMOTO REIJI , KANAYAMA HIKOYOSHI , MATSUI YUTAKA , KAZAMA SEIJI , TAKEMURA TADAO
IPC分类号： B65D23/08 , C03C17/32 , C03C17/34 , C08G18/62
摘要： 1363360 Coated glass containers TAKEDA YAKUHIN KOGYO KK and MITSUI POLYCHEMICALS CO Ltd 10 Nov 1972 [24 Nov 1971] 52114/72 Heading B2E A glass container, especially a bottle, is coated first with an olefin copolymer containing OH and/or COOH groups in its molecule and then with a polyisocyanate or a mixture thereof with a polyol or a thermoplastic polyurethane. The olefin copolymer may be one containing repeating units of (a) -CH 2 -CHR 1 - where R 1 is H or C 1-2 alkyl, (b) -CH 2 -CR 2 X 1 where R 2 is H or CH 3 and X 1 is -OH, -COOH or -COO(CH 2 ) 1-3 OH and (c) -CH 2 -CR 2 X 2 - where X 3 is -OCOR 3 or -COOR 4 (in which R 3 and R 4 are C 1-4 alkyl) and usually has a melt index of 0.5 to 1000 g/10 min. It may particularly be a copolymer of a C 2-4 α-olefin with acrylic or methacrylic acid or a hydroxy -C 1-4 - alkyl acrylate or methacrylate or the hydrolysed product of a copolymer of a C 2-4 α-olefin and vinyl acetate, propionate or butyrate or a methacrylic or acrylic acid C 1-4 alkyl ester, the degree of hydrolysis being 5-100 mole per cent. If the copolymer contains -COOH groups, it may be in the metal salt (or ionomeric) state. The olefin copolymer is applied as a powder by fluidised bed or electrostatic techniques or as a solution by dipping. The polyisocyanate may be tolylene diisocyanate, w, w 1 -diisocyano dimethylbenzene, dicyclohexylmethane diisocyanate or w, w 1 - diisocyano dimethylcyclohexane, or a polyurethane polyisocyanate prepared by reacting an excess of one of these diisocyanates with a polyol containing 2-8 OH groups per molecule and having a molecular weight of 60 to 2000. The polyisocyanate or mixture thereof is applied as a solution by dipping. The coatings reduce the breakage of the bottles by impact without a decrease in transparency of the bottles.

7. 发明专利

DE2709451A1 未知
公开(公告)号：DE2709451A1
公开(公告)日：1977-09-22
申请号：DE2709451
申请日：1977-03-04
申请人： TAKEDA CHEMICAL INDUSTRIES LTD , MITSUI POLYCHEMICALS LTD
发明人： TATSUMI TETSUJIRO , MIYAMOTO REIJI , NARASAKI SHIRO , ICHIHARA CHIBA , KAZAMA SEIJI , TANAKA MICHIO
IPC分类号： B65D23/08 , C03C17/32 , C08G18/62 , B05D7/26
摘要： Glass bottles, suitable as containers for drinks, such as beer and fruit juice, are coated with a single layer of a thermally cured material formed of a powdery composition comprising a mixture of (i) a blocked organic polyisocyanate and (ii) a hydrolyzed ethylene-vinyl ester copolymer and/or a carboxyl-modified version of said hydrolyzed copolymer. The coated bottles are highly effective in the prevention of scattering of glass fragments in the event of breakage and excellent in clarity, alkali resistance, abrasion resistance, scratch resistance and weathering quality.

8. 发明专利

DE3104967A1 未知
公开(公告)号：DE3104967A1
公开(公告)日：1981-11-19
申请号：DE3104967
申请日：1981-02-12
申请人： TAKEDA CHEMICAL INDUSTRIES LTD , MITSUI POLYCHEMICALS LTD
发明人： NAKABAYASHI MASAMITSU , DOURA FUMIHIRO , MIYAMOTO REIJI , TATSUMI TETSUJIRO
IPC分类号： C08L23/00 , C08L23/26 , C08L29/04 , C08L51/00 , C08L51/02 , C08L101/00 , C09J123/26 , C09J129/04 , C09J151/00 , C09J3/14 , C09J5/06
摘要： A hot-melt adhesive composition containing (i) a first component consisting of (a) 20 to 100 weight percent of a hydrolyzed ethylene-vinyl acetate copolymer whose vinyl acetate unit content is in the range of 5 to 50 weight percent and its hydrolysis degree is at least 50 percent and/or a carboxyl-containing product obtained by grafting said copolymer with a carboxyl-containing unsaturated compound or anhydride thereof and (b) 0 to 80 weight percent of a resin compatible with said copolymer and/or said carboxyl-containing product and (ii) a second component which is a tackifying resin, the proportion of said first component being not less than 20 weight percent and that of said second component being not less than 20 weight percent, both based on said two components, and said composition optionally may further contain (iii) a wax as a third component is highly improved in adhesivity as compared with the hitherto known hot-melt adhesive compositions.

9. 发明专利

CA1091513A COATED GLASS BOTTLES 未知
公开(公告)号：CA1091513A
公开(公告)日：1980-12-16
申请号：CA273502
申请日：1977-03-08
申请人： TAKEDA CHEMICAL INDUSTRIES LTD , MITSUI POLYCHEMICALS LTD
发明人： TATSUMI TETSUJIRO , MIYAMOTO REIJI , NARASAKI SHIRO , KAZAMA SEIJI , TANAKA MICHIO
IPC分类号： B65D23/08 , C03C17/32 , C08G18/62 , B32B17/10
摘要： COATED GLASS BOTTLES of the disclosure Glass bottles, suitable as containers for drinks, such as beer and fruit juice, are coated with a single layer of a thermally cured material formed of a powdery composition comprising a mixture of (i) a blocked organic polyisocyanate and (ii) a hydrolyzed ethylene-vinyl ester copolymer and/or a carboxyl-modified version of said hydrolyzed copolymer. The coated bottles are highly effective in the prevention of scattering of glass fragments in the event of breakage and excellent in clarity, alkali resistance, abrasion resistance, scratch resistance and weathering quality.

10. 发明专利

CA1167196A POLYURETHANE COMPOSITION FOR POWDER COATING 未知
公开(公告)号：CA1167196A
公开(公告)日：1984-05-08
申请号：CA384008
申请日：1981-08-17
申请人： TAKEDA CHEMICAL INDUSTRIES LTD
发明人： GOTO JUGO , MOCHIZUKI KAZUTAKA , KUBOTA TSUTOMU , MIYAMOTO REIJI
IPC分类号： C09D5/03 , C08G18/10 , C08G18/40 , C08G18/42 , C08G18/62 , C08G18/80 , C09D5/46 , C09D175/04
摘要： A polyurethane based composition for powder coating uses, which comprises a combination of an organic polyisocyanate compound and a hydroxylcontaining compound, the hydroxyl-containing compound being (A) A hydroxyl-containing polymer, or its carboxyl-modified product, obtained by hydrolyzing a copolymer of a vinyl ester of a saturated monocarboxylic acid and other polymerizable vinyl monomers, and ( B) A polyester polyol of softening point of not lower than 40.degree.C containing not less than 30 weight % of cyclohexylene or cyclohexenylene group or spiro rings. The composition provides coating films exhibiting exceedingly improved hardness, heat resistance, toughness and transparency as compared with the conventional polyolefin based powder coatings.

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