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    • 8. 发明申请
    • PYRIDAZINE DERIVATIVES
    • 吡啶衍生物
    • WO2008049585A1
    • 2008-05-02
    • PCT/EP2007/009189
    • 2007-10-23
    • SYNGENTA PARTICIPATIONS AGTRAH, StephanLAMBERTH, ClemensWENDEBORN, Sebastian
    • TRAH, StephanLAMBERTH, ClemensWENDEBORN, Sebastian
    • C07D237/08C07D237/12C07D237/14C07D237/18C07D237/04C07D405/04C07D409/04C07D401/04C07D403/04C07D413/04C07D417/04C07D401/12C07D409/12C07D307/60
    • C07D237/14A01N43/58C07D237/08C07D237/12C07D307/60C07D307/79C07D401/04C07D401/12C07D403/04C07D405/04C07D405/12C07D407/04C07D409/04C07D409/12C07D413/04C07D417/04
    • The present invention relates to novel pyridazine derivatives of formula (I) as active ingredients which have microbiocidal activity, in particular fungicidal activity: wherein R 1 is hydrogen, C 1 -C 6 alkyl, C 1 -C 8 haloalkyl or C 3 -C 6 cycloalkyl; R 2 is cycloalkyl, cycloalkylalkyl, halocycloalkyl, cycloalkoxy, halocycloalkoxy, cycloalkylalkoxy, halocycloalkylalkoxy, alkoxyalkyl, cycloalkoxyalkoxyalkyl, haloalkoxyalkyl, trialkylsilyl, alkylthioalkyl, haloalkylthioalkyl, cycloalkylthio, halocycloalkylthio, cycloalkylalkylthio, halocycloalkylalkylthio, alkylsulfinylalkyl, alkylsulfonylalkyl, alkylsulfinyl, haloalkylsulfinyl, alkylsulfonyl, haloalkylsulfonyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, optionally substituted arylsulfonyl, optionally substituted aryloxy, optionally substituted heteroaryloxy, optionally substituted arylthio, optionally substituted heteroarylthio; or R 2 together with an adjacent carbon atom forms an optionally substituted fused ring; R 3 is an optionally substituted aryl; R 4 is hydrogen, halogen, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 1 -C 8 alkoxy, C 1 -C 6 haloalkoxy, hydroxy or cyano; and n is a whole number from 1 to 4; or an agrochemically usable salt form thereof.
    • 本发明涉及式(I)的新颖哒嗪衍生物作为具有杀微生物活性,特别是杀真菌活性的活性成分:其中R 1是氢,C 1 -C C 1 -C 6烷基,C 1 -C 8卤代烷基或C 3 -C 6烷基, 环烷基; R 2是环烷基,环烷基烷基,卤代环烷基,环烷氧基,卤代环烷氧基,环烷基烷氧基,卤代环烷基烷氧基,烷氧基烷基,环烷氧基烷氧基烷基,卤代烷氧基烷基,三烷基甲硅烷基,烷硫基烷基,卤代烷硫基烷基,环烷硫基,卤代环烷基硫基,环烷基烷硫基,卤代环烷基烷硫基,烷基亚磺酰基烷基, 卤代烷基亚磺酰基,烷基磺酰基,卤代烷基磺酰基,C 2 -C 6亚烷基,C 2 -C 6 - 炔基,任选取代的 芳基磺酰基,任选取代的芳氧基,任选取代的杂芳氧基,任选取代的芳硫基,任选取代的杂芳硫基; 或R 2与相邻碳原子一起形成任选取代的稠合环; R 3是任选取代的芳基; R 4是氢,卤素,C 1 -C 6烷基,C 1 -C 6烷基,C 1 -C 6烷基,C 1 -C 6烷基,C 1 -C 6 - 卤代烷基,C 1 -C 8烷氧基,C 1 -C 6卤代烷氧基,羟基或 氰基; n为1〜4的整数; 或其农业化学上可用的盐形式。
    • 9. 发明申请
    • DIHALO-ALLYLOXY-PHENOL DERIVATIVES HAVING PESTICIDAL ACTIVITY
    • 具有杀虫活性的二氢 - 全氟代苯酚衍生物
    • WO2004052816A1
    • 2004-06-24
    • PCT/EP2003/014009
    • 2003-12-10
    • SYNGENTA PARTICIPATIONS AGZAMBACH, WernerRENOLD, PeterHALL, Roger, GrahamTRAH, Stephan
    • ZAMBACH, WernerRENOLD, PeterHALL, Roger, GrahamTRAH, Stephan
    • C07C43/225
    • A01N37/34C07C43/225C07C43/23C07C43/315C07C45/29C07C45/71C07C49/255C07C69/76C07C205/32C07C251/40C07C255/37C07C255/41C07C271/16C07C2601/02C07D213/57C07D261/08C07D307/54C07D307/81C07D333/24C07C49/84
    • Compounds of formula (I), wherein A 1 and A 2 are each independently of the other a bond or a C 1 -C 6 alkylene bridge; A 3 is a C 1 -C 6 alkylene bridge; X 1 and X 2 are each independently of the other fluorine, chlorine or bromine; Y is O, NR 7 , S, SO or SO 2 ; R 1 , R 2 and R 3 are each independently of the others, for example, H, halogen, OH, SH, CN, nitro, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 1 -C 6 alkylcarbonyl or C 2 -C 6 alkenyl; Q is O, NR 5 , S, SO or SO 2 ; W is, for example, O, NR 5 or SO; T is for example, a bond, O or NR 5 ; D is CH or N; R 4 is, for example, H, halogen, OH, SH, CN or nitro; R 5 and R 7 are, for example, H, C 1 -C 6 alkyl or C 1 -C 3 haloalkyl; k is 1, 2, 3 or 4; m is 1 or 2; R 10 is a radical which contains O, N or S; R 11 is, for example, H, C 1 -C 12 alkyl or a radical which contains from one to three hetero atoms selected from O, N and S; or R 11 together with R 12 is a bond; R 12 is, for example, H, C 1 -C 6 alkyl, halo-C 1 -C 6 alkyl or C 1 -C 6 alkoxy-C 1 -C 6 -alkyl; and, where applicable, their possible E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free from or in salt form, a process for the preparation of those compounds and their use, pesticidal compositions in which the active ingredient has been selected from those compounds or an agrochemically acceptable salt thereof; a process for the preparation of those compositions and their use, plant propagation material treated with those compositions, and a method of controlling pests.
    • 式(I)化合物,其中A1和A2各自独立地为一个键或C1-C6亚烷基桥; A3是C1-C6亚烷基桥; X1和X2各自独立地为氟,氯或溴; Y是O,NR7,S,SO或SO2; R 1,R 2和R 3各自独立地为H,卤素,OH,SH,CN,硝基,C 1 -C 6烷基,C 1 -C 6卤代烷基,C 1 -C 6烷基羰基或C 2 -C 6烯基; Q是O,NR5,S,SO或SO2; W是例如O,NR5或SO; T为例如O或NR5的键; D是CH或N; R4是例如H,卤素,OH,SH,CN或硝基; R5和R7是例如H,C1-C6烷基或C1-C3卤代烷基; k为1,2,3或4; m为1或2; R10是含有O,N或S的基团; R 11是例如H,C 1 -C 12烷基或含有1至3个选自O,N和S的杂原子的基团; 或R11与R12一起为键; R 12是例如H,C 1 -C 6烷基,卤代-C 1 -C 6烷基或C 1 -C 6烷氧基-C 1 -C 6 - 烷基; 在适用情况下,它们可能的E / Z异构体,E / Z异构体混合物和/或互变异构体在每种情况下不含或以盐形式,制备这些化合物的方法及其用途,其中 从这些化合物或其农业化学上可接受的盐中选择活性成分; 制备这些组合物及其用途的方法,用这些组合物处理的植物繁殖材料以及防治害虫的方法。