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    • 1. 发明授权
    • Modified zinc oxide particles
    • 改性氧化锌颗粒
    • US08747804B2
    • 2014-06-10
    • US13054636
    • 2009-07-14
    • Andrey KarpovHartmut HibstSimon SchambonyRichard RiggsSylke Haremza
    • Andrey KarpovHartmut HibstSimon SchambonyRichard RiggsSylke Haremza
    • C01G9/02
    • C09C1/043C01G9/02C01P2002/84
    • Process for the preparation of modified ZnO particles in which a zinc salt and a base are mixed in a polar solvent and, if appropriate after the precipitation of a precipitation product, the polar solvent is removed and a residue is obtained, where the residue is taken up in a nonpolar solvent, surface-active substances are added, optionally further effect substances are added and then the modified ZnO particles are separated off from further by-products. Materials such as plastics, coatings or paints comprising modified ZnO particles. Methods for the incorporation of modified ZnO particles into materials, where the modified ZnO particles are incorporated into the materials in the form of dispersions or suspensions. Use of modified ZnO particles for protecting material against the effect of light, heat, oxygen or free radicals, as catalysts, for semiconductive films or cosmetic applications.
    • 制备其中将锌盐和碱在极性溶剂中混合的改性ZnO颗粒的制备方法,并且如果适当,在析出产物沉淀后,除去极性溶剂,得到残留物,其中残留物被 在非极性溶剂中加入表面活性物质,任选地添加另外的效果物质,然后将改性的ZnO颗粒与进一步的副产物分离。 诸如塑料,涂料或包含改性ZnO颗粒的涂料的材料。 将改性的ZnO颗粒引入到材料中的方法,其中将改性的ZnO颗粒以分散体或悬浮液的形式引入材料中。 使用改性ZnO颗粒来保护材料免受光,热,氧或自由基作为半导体膜或化妆品应用的催化剂的影响。
    • 4. 发明申请
    • STABILISERS FOR INANIMATE ORGANIC MATERIALS
    • 用于有机材料的稳定剂
    • US20110214590A1
    • 2011-09-08
    • US13060705
    • 2009-08-14
    • Alban GlaserSylke HaremzaSimon Schambony
    • Alban GlaserSylke HaremzaSimon Schambony
    • C09D7/12C08K5/3435C07D401/12C07D401/04C07D211/56
    • C07D211/94
    • The present invention relates to the use of sterically hindered amines comprising one or more groups of the general formula (I) to stabilize inanimate organic material, more particularly plastics or coating materials, where R1 and R2 each independently, alike or different, are H, C1-C20 alkyl, C3-C15 cycloalkyl, aryl, hetaryl or a heterocycle, R4, R5, R6, and R7 each independently, alike or different, are C1-C20 alkyl, or R4 and R6 or R5 and R7 together are a tetramethylene or pentamethylene group, and R3 is aryl or hetaryl. The invention further relates to methods of stabilizing inanimate organic material, especially plastics or coating materials. Additionally provided by the invention are selected sterically hindered amines comprising one or more groups of the general formula (I). Additionally provided by the invention are materials that comprise selected sterically hindered amines.
    • 本发明涉及包含一个或多个通式(I)的基团的空间位阻胺的用途,用于稳定无生命的有机材料,更特别的是塑料或涂料,其中R 1和R 2各自独立地或不同地是H, C 1 -C 20烷基,C 3 -C 15环烷基,芳基,杂芳基或杂环,R 4,R 5,R 6和R 7各自独立地为不同或不同的是C 1 -C 20烷基,或R 4和R 6或R 5和R 7一起是四亚甲基 或五亚甲基,R 3为芳基或杂芳基。 本发明还涉及稳定无生命的有机材料,特别是塑料或涂料的方法。 本发明另外提供的是包含一个或多个通式(I)的基团的空间位阻胺。 本发明另外提供的是包含选定的空间位阻胺的材料。
    • 7. 发明授权
    • Use of polymeric reaction product
    • US07008990B2
    • 2006-03-07
    • US10311378
    • 2001-06-13
    • Roman Benedikt RaetherSusanne Brinkmann-RengelSylke Haremza
    • Roman Benedikt RaetherSusanne Brinkmann-RengelSylke Haremza
    • C08K3/20
    • C08K3/20C08F293/00
    • A reaction product (A) which can be prepared by reaction, under free radical conditions, of at least one monomer (a) capable of free radical reaction, in the presence of at least one free radical initiator and of a radical of the formula (III) where R1 to R3, in each case independently of one another, are hydrogen, methyl or a radical-stabilizing and/or bulky group selected from an unsubstituted or substituted, linear or branched alkyl of two or more carbon atoms, cycloalkyl, alcohol, ether, polyether, amine, aralkyl radical, a substituted or unsubstituted aromatic, heterocyclic or olefinic hydrocarbon, a halogen atom, a substituted or unsubstituted, linear or branched alkenyl or alkynyl group, —C(O)R5, —C(O)OR5, —CR5R6—O—R7, —O—C(O)R5, —CN, —O—CN, —S—CN, —O—C═NR5, —S—C═NR5, —O—CR5R6—CR7R8NR9R10, —N═C═O, —C═NR5, —CR5R6-Hal, —C(S)R5, —CR5R6—P(O)R7R8, —CR5R6—PR7R8, —CR5R6—NR7R8, —CR5R6(OR7)(OR8), —CR5R6(OR7)(NR8), —CR5R6(NR7)(NR8), an anhydride, acetal or ketal group, —SO2R5, an amidine group, —NR5C(S)NR6, —NR5C(S)—OR6, —N═C═S, —NO2, —C═N—OH, —N(R5)═NR6, —PR5R6R7, —OSiR5R6R7 or —SiR5R6R7, where R5 to R10, independently of one another in each case, are defined in the same way as R1 to R4, or two of the radicals R1 to R4 form a C4- to C7-ring which in turn may be substituted or unsubstituted and, if required, may contain one or more heteroatoms, with the proviso that at least two of the radicals R1 to R3 are a radical-stabilizing and/or bulky group as defined above, has various uses.