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1. 发明授权

US06699405B2 Polymerizable liquid crystals 失效
标题翻译：可聚合液晶
公开(公告)号：US06699405B2
公开(公告)日：2004-03-02
申请号：US09824022
申请日：2001-04-03
申请人： Frank Prechtl , Robert Parker , Peter Schuhmacher , Norbert Schneider , Sylke Haremza , Hans-Werner Schmidt , Gerold Schmitt
发明人： Frank Prechtl , Robert Parker , Peter Schuhmacher , Norbert Schneider , Sylke Haremza , Hans-Werner Schmidt , Gerold Schmitt
IPC分类号： C09K1920
CPC分类号： C09K19/2007 , C09K19/00 , C09K19/38 , C09K2019/0448 , Y10T428/10
摘要： Disclosed are polymerizable liquid-crystalline compounds of the general formula (I) where A1 and A2 are identical or different and are each a crosslinkable group; the radicals X are identical or different and are each a single bond, —O—, —S—, —C═N—, —O—CO—, —CO—O—, —O—CO—O—, —CO—NR—, —NR—CO—, —NR—, —O—CO—NR, —NR—CO—O—, —CH2—O— or —NR—CO—NR, in which R is H or C1-C4-alkyl; and M is a mesogenic group, a process for their preparation and their use for preparing cholesteric phases.
摘要翻译：公开了通式（I）的可聚合液晶化合物，其中A 1和A 2相同或不同，并且各自为可交联基团; 基团X相同或不同，并且各自为单键，-O - ， - S - ， - C = N - ， - O-CO-，-CO-O-，-O-CO-O-，-CO -NR-，-NR-CO-，-NR-，-O-CO-NR，-NR-CO-O-，-CH2-O-或-NR-CO-NR，其中R是H或C1- C4-烷基; M是介晶基团，其制备方法及其用于制备胆甾型相。

2. 发明授权

US06793986B2 Polymerizable liquid crystals 失效
公开(公告)号：US06793986B2
公开(公告)日：2004-09-21
申请号：US10678111
申请日：2003-10-06
申请人： Frank Prechtl , Robert Parker , Peter Schuhmacher , Norbert Schneider , Sylke Haremza , Hans-Werner Schmidt , Gerold Schmitt
发明人： Frank Prechtl , Robert Parker , Peter Schuhmacher , Norbert Schneider , Sylke Haremza , Hans-Werner Schmidt , Gerold Schmitt
IPC分类号： C09K1900
CPC分类号： C09K19/2007 , C09K19/00 , C09K19/38 , C09K2019/0448 , Y10T428/10
摘要： Disclosed are polymerizable liquid-crystalline compounds of the general formula (I) where A1 and A2 are identical or different and are each a crosslinkable group; the radicals X are identical or different and are each a single bond, —O—, —S—, —C═N—, —O—CO—, —CO—O—, —O—CO—O—, —CO—NR—, —NR—CO—, —NR—, —O—CO—NR, —NR—CO—O—, —CH2—O— or —NR—CO—NR, in which R is H or C1-C4-alkyl; and M is a mesogenic group, a process for their preparation and their use for preparing cholesteric phases.

3. 发明授权

US06712992B2 Liquid-crystalline composition of matter 失效
标题翻译：物质的液晶组成
公开(公告)号：US06712992B2
公开(公告)日：2004-03-30
申请号：US09864314
申请日：2001-05-25
申请人： Frank Prechtl , Sylke Haremza , Frank Meyer , Robert Parker , Kathrin Kürschner , Peter Schuhmacher , Hans-Werner Schmidt , Gerold Schmitt , Reiner Giesa
发明人： Frank Prechtl , Sylke Haremza , Frank Meyer , Robert Parker , Kathrin Kürschner , Peter Schuhmacher , Hans-Werner Schmidt , Gerold Schmitt , Reiner Giesa
IPC分类号： C09K1906
CPC分类号： C09K19/38 , C09B67/0098 , C09D5/00 , C09K19/00 , Y10T428/10
摘要： Liquid-crystalline compositions containing, as components, A) at least one compound of the formula I Z1—Y1—A1—Y3—M—Y4—A2—Y2—Z2 (I), where Z1 and Z2 are each a reactive group, Y1 to Y4 are each a linking unit, A1 and A2 are each a spacer and M is a mesogenic group, B) at least one reactive compound selected from b1) vinyl or allyl ethers, b2) vinyl or allyl esters of saturated or unsaturated carboxylic acids, b3) methacrylic or acrylic esters of monofunctional or polyfunctional alcohols, b4) polyester (meth)acrylates, b5) vinylaromatics or vinylheteroaromatics, and b6) compounds of the general formula II CH2═CH—NR2—R1 (II), in which R1 and R2 are as defined in detail in the description, and C) if desired further additives.
摘要翻译：含有A）至少一种式I的化合物（其中Z 1和Z 2）各自为反应性基团，Y 1至Y 4各自为连接单元的液晶组合物，A b）至少一种选自b1）乙烯基或烯丙基醚的反应性化合物，b2）饱和或不饱和羧酸的乙烯基或烯丙基酯，b3） b4）聚酯（甲基）丙烯酸酯，b5）乙烯基芳香族化合物或乙烯基芳族化合物，和b6）通式IIin的化合物，其中R 1和R 2如在描述，和C）如果需要，其他添加剂。

4. 发明申请

US20090209679A1 CORE-SHELL FLOW IMPROVER 审中-公开
标题翻译：核心流程改进
公开(公告)号：US20090209679A1
公开(公告)日：2009-08-20
申请号：US12031290
申请日：2008-02-14
申请人： Wayne R. Dreher , Kenneth W. Smith , Stuart N. Milligan , Timothy L. Burden , William F. Harris , Ray L. Johnston , Wolfgang Klesse , Gerold Schmitt , John Wey
发明人： Wayne R. Dreher , Kenneth W. Smith , Stuart N. Milligan , Timothy L. Burden , William F. Harris , Ray L. Johnston , Wolfgang Klesse , Gerold Schmitt , John Wey
IPC分类号： B05D5/08 , C08F118/02 , C08F16/12 , C08F210/00 , C08F222/10 , C08F226/06 , C08F14/06 , C08F20/44 , C08F222/04 , C08F222/38
CPC分类号： C08F265/06 , C08F2/002 , C08F2/22 , C08F265/04 , C08L51/003 , F17D1/17 , C08L2666/02
摘要： A flow improver comprising a plurality of core-shell particles that can be formed by emulsion polymerization. The core of the core-shell particles can include a drag reducing polymer, while the shell of the particles can include repeat units of a hydrophobic compound and an amphiphilic compound. The flow improver can demonstrate increased pumping stability over conventionally prepared latex flow improvers.
摘要翻译：一种流动改进剂，其包含可以通过乳液聚合形成的多个核 - 壳颗粒。核 - 壳颗粒的核心可以包括减阻聚合物，而颗粒的壳可以包括疏水化合物和两亲化合物的重复单元。流动改进剂可以显示出比常规制备的胶乳流动改进剂提高的泵送稳定性。

5. 发明授权

US08168736B2 Emulsion polymer comprising activators, process for preparation thereof and use thereof in two-component or multicomponent systems 有权
标题翻译：包含活化剂的乳液聚合物，其制备方法及其在双组分或多组分体系中的用途
公开(公告)号：US08168736B2
公开(公告)日：2012-05-01
申请号：US12668450
申请日：2008-06-27
申请人： Gerold Schmitt , Wolfgang Klesse , Joachim Knebel
发明人： Gerold Schmitt , Wolfgang Klesse , Joachim Knebel
IPC分类号： C08F220/10
CPC分类号： C08F265/06 , C08F285/00 , C09D151/003 , C09J151/003
摘要： The invention describes anemulsion polymer which can be obtained by polymerization of a mixture comprising a) from 5 to 99.9% by weight of one or more monomers having a solubility in water of 2% by weight at 20° C.; and e) 0.1-95% by weight of at least one activator, with the components a) to e) adding up to 100% by weight of the polymerizable constituents of the mixture, and is characterized in that e1) the activator is a compound of the Formula I, where the radicals R1 to R7 and X have the meanings given in the description; and in that e2) the activator e) is incorporated via covalent bonds into the emulsion polymer. The emulsion polymer makes it possible to form core-shell polymers having a protected activator fixed to the polymer and can be used particularly advantageously for controlling the pot life of two-component or multicomponent systems, for example in adhesives, pourable resins, floor coatings, compositions for reactive pegs, dental compositions or sealing compositions.
摘要翻译：本发明描述了一种乳液聚合物，其可以通过聚合包含a）5至99.9重量％的一种或多种在20℃下具有<2重量％的水溶性的单体的混合物而获得，并且选自由单官能（甲基）丙烯酸酯单体，苯乙烯和乙烯基酯组成的组; b）0至70重量％的可与单体a）共聚的一种或多种单体; c）0至20重量％的一种或多种双重或多重的乙烯基不饱和化合物; d）0至20重量％的在20℃下具有> 2重量％水溶性的一种或多种极性单体; 和e）0.1-95重量％的至少一种活化剂，组分a）至e）加入至多100重量％的混合物的可聚合组分，其特征在于e1）活化剂是化合物其中基团R 1至R 7和X具有在说明书中给出的含义; 并且在该e2）中，活化剂e）通过共价键并入乳液聚合物中。乳液聚合物使得可以形成具有固定在聚合物上的保护的活化剂的核 - 壳聚合物，并且可以特别有利地用于控制双组分或多组分体系的适用期，例如在粘合剂，可倾倒树脂，地板涂料，反应栓，牙科组合物或密封组合物的组合物。

6. 发明申请

US20110319514A1 COMPOSITION COMPRISING AS THE AQUEOUS DISPERSION PREFERABLY (METH)ACRYLATE POLYMERS CONTAINING BENZOPHENONE IN A MIXTURE WITH (METH)ACRYLATE POLYMERS DIFFERENT THEREFROM AND THE USE OF SAID COMPOSITION 失效
标题翻译：作为含有（甲基）丙烯酸酯聚合物的混合物中含有苯甲酸酯（甲基）丙烯酸酯聚合物的优选（甲基）丙烯酸酯聚合物的组合物和不同组合物的使用
公开(公告)号：US20110319514A1
公开(公告)日：2011-12-29
申请号：US13201889
申请日：2010-03-02
申请人： Christine Maria Breiner , Mario Gomez Andreu , Gerold Schmitt , Wolfgang Klesse
发明人： Christine Maria Breiner , Mario Gomez Andreu , Gerold Schmitt , Wolfgang Klesse
IPC分类号： C09D129/12 , C08J3/28
CPC分类号： C04B41/009 , C04B41/483 , C04B41/63 , C04B2111/60 , C08L33/12 , C08L2205/02 , C09D133/12 , C04B28/02 , C08L2666/04
摘要： The invention describes a composition comprising, in the form of aqueous dispersion, A) for every 100 parts by weight of a, or of a plurality of, (meth)acrylate polymer(s); B) from 1-400 parts by weight of a, or of a plurality of, (meth)acrylate polymer(s), which contain(s) a compound of the formula (I) copolymerized, where the (meth)acrylate polymer(s) B) differ from the (meth)acrylate polymers specified in A), where these are obtainable by emulsion polymerization of a mixture comprising a) from 0.1 to 99.9 percent by weight of at least one compound of the formula (I), preferably of a benzophenone (meth)acrylate, in which the definitions of the moieties are those given in the description; and b) from 99.9 to 0.1% by weight of a, or of a plurality of, ethylenically unsaturated monomer(s) which differ(s) from a) and which is/are copolymerizable with a), where components a) and b) together give 100% by weight of the polymerizable constituents of the mixture; and where the parts by weight of A) and B) are based on the solids content of the polymers A) or B) in the aqueous dispersion. Dispersions of this type are UV-curable and have excellent suitability for the production of coatings of any type, in particular for coating of mineral substrates, such as concrete. The dispersions of the invention are also advantageous for blending with known dispersions and improve their properties, in particular in respect of their curing profile.
摘要翻译：本发明描述了一种组合物，其包含水分散体的形式，A）每100重量份的一种或多种（甲基）丙烯酸酯聚合物; B）1-400重量份的一种或多种（甲基）丙烯酸酯聚合物，其含有（s）共聚的式（I）化合物，其中（甲基）丙烯酸酯聚合物（ s）B）与A）中规定的（甲基）丙烯酸酯聚合物不同，其中这些可通过将混合物乳液聚合而获得，所述混合物包含a）0.1至99.9重量％的至少一种式（I）化合物，优选的二苯甲酮（甲基）丙烯酸酯，其中部分的定义是在说明书中给出的那些; 和b）99.9重量％至0.1重量％的a）或多个不同于a）的烯键式不饱和单体，并且其可与a）共聚，其中组分a）和b）一起提供100重量％的混合物的可聚合组分; 并且其中A）和B）的重量份数基于水分散体中聚合物A）或B）的固体含量。这种类型的分散体是可UV固化的，并且对于任何类型的涂料的生产具有优异的适用性，特别是用于矿物基材例如混凝土的涂层。本发明的分散体也有利于与已知的分散体共混并改进其性能，特别是在其固化分布方面。

7. 发明申请

US20100286331A1 TWO OR MORE-COMPONENT SYSTEM CURED BY A REDOX INITIATOR SYSTEM WITH CONTROLLABLE WORKING LIFE, AND THE USE THEREOF 审中-公开
标题翻译：两个或多个组件系统由具有可控制工作寿命的反射器系统固化，以及其使用
公开(公告)号：US20100286331A1
公开(公告)日：2010-11-11
申请号：US12668157
申请日：2008-06-27
申请人： Gerold Schmitt , Wolfgang Klesse , Joachim Knebel
发明人： Gerold Schmitt , Wolfgang Klesse , Joachim Knebel
IPC分类号： C09J133/12 , C09J133/10
CPC分类号： C08F257/02 , C08F4/40 , C08F263/00 , C08F263/04 , C08F265/04 , C08F265/06 , C08F285/00 , C08F291/00 , C08L51/003 , C08L2666/02 , C09D151/003 , C09J151/003 , A61K6/0023 , C08L33/08 , C08L33/10 , C08L33/12 , C08L25/08
摘要： Two-component or multicomponent system which cures by means of a redox initiator system and has a controllable pot life and comprises A) 0.8-69.94% by weight of an emulsion polymer which can be obtained by polymerization of a mixture; B) 30-99.14% by weight of one or more ethylenically unsaturated monomers; C) 0.05-10% by weight of peroxides; and if appropriate further constituents; characterized in that the component A) and the component C) are stored together and at least one constituent of the component B) is stored together from the components A) and C), with the separately stored constituent of the component B) being selected so that the ability of this constituent of the component B) to swell the polymer A) is sufficiently high for the polymer-fixed activator e) of the polymer A) to be able to react with the component C).
摘要翻译：双组分或多组分系统，其通过氧化还原引发剂体系固化并具有可控的适用期，并且包含A）0.8-69.94重量％的可通过混合物聚合获得的乳液聚合物; B）30-99.14重量％的一种或多种烯属不饱和单体; C）0.05-10重量％的过氧化物; 并酌情进一步组成; 其特征在于组分A）和组分C）一起存储在一起，并且组分B）的至少一种组分从组分A）和C）一起储存，组分B）的单独存储的组分被选择为组分B）的这种组分使聚合物A）溶胀的能力对于聚合物A）的聚合物固定的活化剂e）能够与组分C）反应是足够高的。

8. 发明申请

US20100210784A1 EMULSION POLYMER COMPRISING ACTIVATORS, PROCESS FOR PREPARATION THEREOF AND USE THEREOF IN TWO-COMPONENT OR MULTICOMPONENT SYSTEMS 审中-公开
标题翻译：包含活化剂的乳液聚合物，其制备方法及其在双组分或多组分体系中的应用
公开(公告)号：US20100210784A1
公开(公告)日：2010-08-19
申请号：US12668677
申请日：2008-06-27
申请人： Gerold Schmitt , Wolfgang Klesse , Joachim Knebel , Volker Kerscher
发明人： Gerold Schmitt , Wolfgang Klesse , Joachim Knebel , Volker Kerscher
IPC分类号： C08L33/10
CPC分类号： C08F220/14 , C08F220/34 , C08F265/06 , C08F285/00 , C09D151/003 , C09J151/003
摘要： Emulsion polymer which can be obtained by polymerization of a mixture. The emulsion polymer of the invention makes it possible to provide two-component or multicomponent systems which cure by means of a redox initiator system and have a controllable pot life, in which use is preferably made of two monomers which swell the emulsion polymer to different extents and of which that having a sufficient swelling action is stored separately from the emulsion polymer, preferably together with a peroxide in an organic solvent, until the system is used. The system is used in adhesives, pourable resins, floor coatings and other reactive coatings, sealing compositions, impregnation compositions, embedding compositions, compositions for producing artificial marble and other artificial stones, compositions for reactive pegs, dental compositions, porous plastic moulds for ceramic objects or in unsaturated polyester resins and vinyl ester resins.
摘要翻译：可通过混合物聚合得到的乳液聚合物。本发明的乳液聚合物使得可以提供通过氧化还原引发剂体系固化并具有可控的适用期的双组分或多组分体系，其中优选使用将乳液聚合物溶胀到不同程度的两种单体并且其具有足够溶胀作用的物质与乳液聚合物分开储存，优选与有机溶剂中的过氧化物一起储存，直到使用该系统。该系统用于粘合剂，可倾倒树脂，地板涂料和其它反应性涂料，密封组合物，浸渍组合物，包埋组合物，用于生产人造大理石和其它人造石的组合物，用于活性栓的组合物，牙科组合物，用于陶瓷物体的多孔塑料模具或在不饱和聚酯树脂和乙烯基酯树脂中。

9. 发明授权

US08389659B2 Emulsion polymers, aqueous dispersions and method for producing the same 失效
标题翻译：乳液聚合物，水分散体及其制备方法
公开(公告)号：US08389659B2
公开(公告)日：2013-03-05
申请号：US12678160
申请日：2008-10-06
申请人： Christine Breiner , Joachim Knebel , Gerold Schmitt , Dieter Tessmer
发明人： Christine Breiner , Joachim Knebel , Gerold Schmitt , Dieter Tessmer
IPC分类号： C08F118/02 , C08L75/04 , C08L33/10 , B32B5/16
CPC分类号： C08F220/18 , C08F220/06 , C08F220/26 , C08F220/68 , Y10T428/2982
摘要： The present invention relates to an emulsion polymer comprising at least one (meth)acrylate segment which comprises 1% to 30% by weight of units derived from (meth)acrylates which in the alkyl radical have at least one double bond and 8 to 40 carbon atoms, 0.1% to 10% by weight of units derived from monomers containing acid groups, and 50% to 98.9% by weight of units derived from (meth)acrylates having 1 to 6 carbon atoms in the alkyl radical, based in each case on the weight of the (meth)acrylate segment, the emulsion polymer having a particle radius of at least 50 nm.
摘要翻译：本发明涉及包含至少一种（甲基）丙烯酸酯部分的乳液聚合物，其包含1至30重量％的衍生自（甲基）丙烯酸酯的单元，其在烷基中具有至少一个双键和8至40个碳原子，0.1重量％至10重量％的衍生自含有酸基团的单体的单元和50重量％至98.9重量％的衍生自在烷基中具有1至6个碳原子的（甲基）丙烯酸酯的单元，（甲基）丙烯酸酯链段的重量，乳液聚合物的粒子半径至少为50nm。

10. 发明申请

US20100280205A1 PROCESS FOR PREPARING (METH)ACRYLATES 有权
标题翻译：制备（甲基）丙烯酸酯的方法
公开(公告)号：US20100280205A1
公开(公告)日：2010-11-04
申请号：US12745703
申请日：2008-09-29
申请人： Joachim Knebel , Ralf Merbach , Guido Protzmann , Klaus Gottmann , John Hirsh , Gerold Schmitt , Dieter Tessmer , Wilhelm Karnbrock , Wolfgang Klesse , Volker Kerscher
发明人： Joachim Knebel , Ralf Merbach , Guido Protzmann , Klaus Gottmann , John Hirsh , Gerold Schmitt , Dieter Tessmer , Wilhelm Karnbrock , Wolfgang Klesse , Volker Kerscher
IPC分类号： C08F120/12 , C07C69/54
CPC分类号： C07C67/03 , C08F20/18 , C08F120/12 , C07C69/54
摘要： Process for preparing (meth)acrylates of the formula (I) CH2═C(R1)—CO—O—R2 (I) in which R1 is hydrogen or methyl and R2 is a saturated or unsaturated, linear or branched, aliphatic or cyclic alkyl radical having 6 to 22 carbon atoms, or a (C6-C14)-aryl-(C1-C8)-alkyl radical; by reacting a (meth)acrylate of the formula II CH2═C(R1)—CO—OR3 (II) with an alcohol of the formula (III) HO—R2 (III) in the presence of an amount of a suitable catalyst which catalyses the reaction and of an amount of a phenolic polymerization inhibitor or a combination of two or more phenolic polymerization inhibitors which is sufficient to inhibit undesired polymerization; the reaction being undertaken with input or introduction into the reaction mixture resulting from the reaction of an amount of oxygen or of an oxygenous gas mixture sufficient to inhibit undesired polymerization, and the process is characterized in that the specific total oxygen input is less than or equal to 1.0 l/kg, measured in litres of oxygen per kilogram of (meth)acrylate of the formula (I), where the volume of oxygen introduced is calculated at a temperature of 25° C. and a pressure of 101 325 pascal. The resulting (meth)acrylates can surprisingly be processed to particularly high molecular weight emulsion polymers which are, for example, outstandingly suitable for use as flow resistance reducers in mineral oil extraction.
摘要翻译：制备式（I）的（甲基）丙烯酸酯的方法，其中R 1是氢或甲基，R 2是饱和或不饱和的，直链或支链的脂族或环状的具有6至22个碳原子的烷基或（C 6 -C 14） - 芳基 - （C 1 -C 8） - 烷基; 通过使式II CH 2 = C（R 1）-CO-OR 3（II）的（甲基）丙烯酸酯与式（III）的醇HO-R 2（III）在一定量的合适的催化剂存在下反应，催化反应和一定量的酚聚合抑制剂或两种或多种酚聚合抑制剂的组合，其足以抑制不期望的聚合; 反应是通过输入或引入反应混合物中进行的，所述反应混合物是由一定量的氧气或足够抑制不期望的聚合的氧气混合物的反应而产生的，并且该方法的特征在于特定的总氧气输入量小于或等于至1.0l / kg，以公斤式（I）的（甲基）丙烯酸酯计，氧气的导入量在25℃，压力为101 325帕斯卡时计算。所得到的（甲基）丙烯酸酯可以令人惊奇地加工成特别高分子量的乳液聚合物，例如非常适合用作矿物油提取中的阻流剂。

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