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1. 发明授权

US4597856A Process for fluidized catalytic cracking of heavy oils and production of hydrogen 失效
标题翻译：重油流化催化裂化和氢气生产工艺
公开(公告)号：US4597856A
公开(公告)日：1986-07-01
申请号：US661750
申请日：1984-10-17
申请人： Susumu Yoshioka , Nobuo Matsuo , Nobuyasu Meguri , Tadashi Murakami , Yasushi Ishibashi , Kenichi Matsuda , Teruo Suzuka , Satoshi Fukase , Hidetaka Ohse
发明人： Susumu Yoshioka , Nobuo Matsuo , Nobuyasu Meguri , Tadashi Murakami , Yasushi Ishibashi , Kenichi Matsuda , Teruo Suzuka , Satoshi Fukase , Hidetaka Ohse
IPC分类号： C10G11/20 , C01B3/10 , C01B3/30 , C01B3/40 , C01B3/44 , C10G47/02
CPC分类号： C01B3/44 , C01B3/40 , Y02E60/36 , Y02P20/52
摘要： A process for fluidized catalytic cracking of heavy oils and production of hydrogen is described, comprising contacting steam and heavy oils with fluidized catalyst particles containing reduced iron at high temperatures, wherein a fluidized bed is formed such that the catalyst particles are fed from the bottom and withdrawn from the top of the fluidized bed and the fluidized bed is provided with a means for retarding the mixing rate of the catalyst particles in the vertical direction, to thereby generate a temperature difference between zones of the fluidized bed above and below said means, and use the upper zone for cracking of heavy oils and the lower zone for production of hydrogen. Catalyst particles withdrawn from the fluidized bed may be regenerated and recycled. Thus, light oils and hydrogen can be produced in high yields.
摘要翻译：描述了重油的流化催化裂化和氢气生产的方法，包括使蒸汽和重油与高温下含有还原铁的流化催化剂颗粒接触，其中形成流化床，使得催化剂颗粒从底部进料，从流化床顶部排出并且流化床设置有用于延迟催化剂颗粒在垂直方向上的混合速率的装置，从而在所述装置上方和下方产生流化床的区域之间的温差，以及使用上部区域用于重油的裂化和用于生产氢的下部区域。从流化床排出的催化剂颗粒可以被再生和再循环。因此，可以高产率生产轻油和氢。

2. 发明授权

US4399023A Process for simultaneously cracking heavy hydrocarbons into light oils and producing hydrogen 失效
标题翻译：将重质烃同时裂解成轻油并生产氢的方法
公开(公告)号：US4399023A
公开(公告)日：1983-08-16
申请号：US348540
申请日：1982-02-12
申请人： Teruo Suzuka , Yukio Inoue , Shirou Aizawa , Yasushi Ishibashi , Hidetaka Ohse
发明人： Teruo Suzuka , Yukio Inoue , Shirou Aizawa , Yasushi Ishibashi , Hidetaka Ohse
IPC分类号： C01B3/32 , B01J23/00 , B01J23/745 , B01J23/94 , C01B3/10 , C10G11/00 , C10G11/02 , C10G11/04 , C10G11/14 , C10G11/18 , C10J3/54
CPC分类号： C10G11/14 , B01J23/94 , C10G11/18 , Y02E60/36
摘要： A process for simultaneously cracking heavy hydrocarbons to form light oil and producing hydrogen is described, which comprises (1) a first step wherein steam and heavy hydrocarbons are simultaneously contacted with a catalyst in a reduced state, containing iron in the form of iron oxide, to produce hydrogen, cracked gases and cracked light oils, to convert the reduced-state catalyst into an oxidized-state catalyst, and to deposit coke on the catalyst, (2) a second step wherein the oxidized-state catalyst with coke deposited thereon is contacted with an oxygen-containing gas to partially combust the coke on the catalyst, to convert the oxidized-state catalyst into a reduced-state catalyst, and to fix a sulfur compound contained in the coke as iron sulfide with a part of the reduced-state catalyst; and (3) a third step wherein catalyst obtained from the first step, the major portion of the catalyst being recycled between the first step and second step, is contacted with an oxygen-containing gas at a temperature of from 600.degree. to 1,000.degree. C. to effect roasting and gasification of iron sulfide in the catalyst.
摘要翻译：描述了同时裂化重质烃以形成轻油并产生氢气的方法，其包括（1）第一步骤，其中蒸汽和重质烃同时与还原状态的催化剂接触，所述催化剂含有氧化铁形式的铁，产生氢气，裂化气体和裂解轻油，将还原态催化剂转化为氧化态催化剂，并将焦炭沉积在催化剂上，（2）第二步，其中沉积有焦炭的氧化态催化剂为与含氧气体接触以部分地燃烧催化剂上的焦炭，将氧化态催化剂转化为还原态催化剂，并将包含在焦炭中的硫化合物与硫化铁固定在一起，状态催化剂; 和（3）第三步骤，其中从第一步骤获得的催化剂在第一步骤和第二步骤之间循环的主要部分与含氧气体在600-1000℃的温度下接触在催化剂中进行硫化铁的焙烧和气化。

3. 发明授权

US4643813A Process for producing alkanesulfonic acids 失效
标题翻译：烷基磺酸的制备方法
公开(公告)号：US4643813A
公开(公告)日：1987-02-17
申请号：US775295
申请日：1985-09-12
申请人： Yasukazu Sato , Kenichi Matsuda , Hiromi Ozaki , Teruo Suzuka , Mamoru Yamane
发明人： Yasukazu Sato , Kenichi Matsuda , Hiromi Ozaki , Teruo Suzuka , Mamoru Yamane
IPC分类号： C07C303/14 , C07C309/04 , C07C3/24
CPC分类号： C07C303/14
摘要： A process for producing an alkanesulfonic acid is described, which comprises causing sulfur dioxide and oxygen to act on a saturated hydrocarbon under illumination with light in a substantially water-free reaction system, wherein photo-sulfoxidation of the saturated hydrocarbon is performed as a reaction mixture in the reaction system is held in contact with sodium sulfite.
摘要翻译：描述了一种制备链烷磺酸的方法，其包括在基本上无水的反应体系中用光照射下使二氧化硫和氧作用在饱和烃上，其中饱和烃的光 - 亚砜氧化作为反应混合物在反应体系中与亚硫酸钠接触。

4. 发明授权

US4421635A Process for simultaneously cracking heavy hydrocarbons into light oils and producing hydrogen 失效
标题翻译：将重质烃同时裂解成轻油并生产氢的方法
公开(公告)号：US4421635A
公开(公告)日：1983-12-20
申请号：US348542
申请日：1982-02-12
申请人： Tadashi Murakami , Teruo Suzuka , Yukio Inoue , Shirou Aizawa
发明人： Tadashi Murakami , Teruo Suzuka , Yukio Inoue , Shirou Aizawa
IPC分类号： C10G11/04 , B01J23/00 , B01J23/74 , B01J23/94 , C01B3/10 , C01B3/38 , C10G11/00 , C10G11/14 , C10G11/18 , C10G47/04
CPC分类号： C10G11/18 , B01J23/94 , C10G11/14 , Y02E60/36 , Y02P30/446
摘要： A process for simultaneously cracking a heavy hydrocarbons to form light oil and producing hydrogen is described, which comprises (1) a first step wherein steam and heavy hydrocarbons are simultaneously contacted with a catalyst in a reduced state, containing iron in the form of iron oxide, to produce hydrogen, cracked gases and cracked light oils, to convert the reduced-state catalyst into an oxidized-state catalyst, and to deposit coke on the catalyst, (2) a second step wherein the oxidized-state catalyst with coke deposited thereon is contacted with an oxygen-containing gas to partially combust the coke on the catalyst, to convert the oxidized-state catalyst into a reduced-state catalyst, and to fix a sulfur compound contained in the coke as iron sulfide with a part of the reduced-state catalyst; and (3) a third step wherein catalyst obtained from the second step, the major portion of the catalyst being recycled between the first step and second step, is contacted with an oxygen-containing gas at a temperature of from 600.degree. to 1,000.degree. C. to effect roasting and gasification of iron sulfide in the catalyst.
摘要翻译：描述了同时裂化重质烃以形成轻油并产生氢的方法，其包括（1）第一步骤，其中蒸汽和重质烃同时与还原状态的催化剂接触，所述催化剂含有氧化铁形式的铁产生氢气，裂化气体和裂解轻油，将还原态催化剂转化为氧化态催化剂，并将焦炭沉积在催化剂上，（2）第二步，其中沉积有焦炭的氧化态催化剂与含氧气体接触以部分地燃烧催化剂上的焦炭，将氧化态催化剂转化为还原态催化剂，并将包含在焦炭中的硫化合物固定为硫化铁与部分还原剂状态催化剂和（3）第三步骤，其中从第二步骤获得的催化剂在第一步骤和第二步骤之间循环的主要部分与含氧气体在600至1000℃的温度下接触在催化剂中进行硫化铁的焙烧和气化。

5. 发明授权

US4115324A Catalyst for treating heavy oils 失效
标题翻译：用于处理重油的催化剂
公开(公告)号：US4115324A
公开(公告)日：1978-09-19
申请号：US805355
申请日：1977-06-10
申请人： Hiromi Ozaki , Mamoru Yamane , Yoshihito Satomi , Teruo Suzuka , Toshinobu Miyake , Mizuho Hirato
发明人： Hiromi Ozaki , Mamoru Yamane , Yoshihito Satomi , Teruo Suzuka , Toshinobu Miyake , Mizuho Hirato
IPC分类号： B01J23/755 , C10G11/02 , B01J29/10 , B01J23/40 , B01J23/74 , B01J29/20
CPC分类号： B01J23/755 , C10G11/02
摘要： A catalyst suitable for cracking heavy oils can be obtained by baking nickel-containing ore at a temperature between about 850.degree. C and about 1200.degree. C.
摘要翻译：适用于裂解重油的催化剂可以通过在约850℃至约1200℃的温度下焙烧含镍矿石来获得。

6. 发明授权

US4224140A Process for producing cracked distillate and hydrogen from heavy oil 失效
标题翻译：从重油生产裂化馏出物和氢气的方法
公开(公告)号：US4224140A
公开(公告)日：1980-09-23
申请号：US22385
申请日：1979-03-21
申请人： Kuniaki Fujimori , Yoshihito Satomi , Teruo Suzuka , Shirou Aizawa
发明人： Kuniaki Fujimori , Yoshihito Satomi , Teruo Suzuka , Shirou Aizawa
IPC分类号： C01B3/10 , B01J23/745 , B01J37/00 , C10G11/04 , C10G11/18 , C01B1/08 , C10G13/02 , C10G34/00
CPC分类号： C10G11/04 , B01J23/745 , B01J37/0018 , C10G11/18 , Y02E60/36
摘要： A process for producing a cracked distillate and hydrogen from a heavy oil which comprises cracking the heavy oil in the presence of laterite or a laterite-containing catalyst while simultaneously depositing coke on said laterite or laterite-containing catalysts, reducing the laterite or laterite-containing catalyst on which the coke is deposited, and forming a hydrogen-rich gas by contacting the reduced laterite or laterite-containing catalyst with steam.
摘要翻译：一种从重油中生产裂化馏出物和氢的方法，包括在红土或含红土的催化剂存在下裂化重油，同时在所述红土或含红土的催化剂上沉积焦炭，还原红土或含红土的催化剂在其上沉积焦炭的催化剂，并且通过使还原的红土或含红土的催化剂与蒸汽接触而形成富氢气体。

7. 发明授权

US4325812A Process for cracking heavy hydrocarbons into light oils and producing hydrogen 失效
标题翻译：将重质烃裂解成轻油并生产氢的方法
公开(公告)号：US4325812A
公开(公告)日：1982-04-20
申请号：US191617
申请日：1980-09-29
申请人： Kuniaki Fujimori , Teruo Suzuka , Yukio Inoue , Shirou Aizawa
发明人： Kuniaki Fujimori , Teruo Suzuka , Yukio Inoue , Shirou Aizawa
IPC分类号： B01J23/745 , B01J23/94 , C01B3/10 , C01B3/26 , C01B3/38 , C01B3/40 , C10G11/02 , C10G11/04 , C10G11/18 , C10G11/20 , C10G47/32
CPC分类号： C10G11/18 , B01J23/745 , B01J23/94 , C01B3/26 , C01B3/40 , C10G11/02 , C10G11/04 , C10G47/32 , C01B2203/04 , C01B2203/0415 , C01B2203/043 , C01B2203/046 , C01B2203/048 , C01B2203/1047 , C01B2203/1052 , C01B2203/1247 , C01B2203/147 , C01B2203/148 , Y02E60/36 , Y02P20/52 , Y02P20/584
摘要： A process is described for cracking a heavy hydrocarbon to form a light oil and for producing hydrogen by the use of a catalyst containing at least 30 wt % Fe which comprises a first step wherein steam and heavy hydrocarbon are simultaneously contacted with the catalyst in a reduced state to produce hydrogen, cracked gases, and a cracked light oil, to oxidize the reduced-state catalyst, and to deposit coke on the catalyst; and a second step wherein the oxidized-state catalyst on which said coke is deposited is contacted with an oxygen-containing gas insufficient for achieving complete combustion of the coke, to thereby partially combust the coke and regenerate the catalyst to a reduced state.
摘要翻译：描述了一种通过使用含有至少30重量％Fe的催化剂来裂解重质烃以形成轻质油并产生氢的方法，该催化剂包含第一步骤，其中蒸汽和重质烃同时与还原的催化剂接触产生氢气，裂解气体和裂解轻油，以氧化还原态催化剂，并将焦炭沉积在催化剂上; 和第二步骤，其中沉积有所述焦炭的氧化态催化剂与不足以实现焦炭完全燃烧的含氧气体接触，从而部分燃烧焦炭并将催化剂再生为还原状态。

8. 发明授权

US4298460A Process for processing sulfur-containing heavy oil 失效
标题翻译：含硫重油加工工艺
公开(公告)号：US4298460A
公开(公告)日：1981-11-03
申请号：US133082
申请日：1980-03-24
申请人： Kuniaki Fujimori , Teruo Suzuka , Yukio Inoue , Shirou Aizawa
发明人： Kuniaki Fujimori , Teruo Suzuka , Yukio Inoue , Shirou Aizawa
IPC分类号： B01J23/745 , B01J23/94 , C01B3/22 , C10G11/02 , C10G11/18
CPC分类号： B01J23/745 , B01J23/94 , C10G11/02 , C10G11/18
摘要： A process for processing a sulfur-containing heavy oil, which comprises:in a first zone, catalytically cracking a sulfur-containing heavy oil in the presence of fluidized catalyst particles containing about 30 to 60 wt % Fe to thereby convert the heavy oil to a light oil, deposit sulfur-containing coke on the catalyst particles, and partially fixing the decomposed sulfur compounds with the reduced iron contained in the catalyst particles as iron sulfide;in a second zone, contacting the catalyst from the first zone with an oxygen containing gas in an amount less than that theoretically required to thereby partially combust the coke on the catalyst, reduce the iron in the catalyst, and fix the sulfur compounds contained in the coke as iron sulfide; andin a third zone, contacting the reduced catalyst from the second zone with steam in a fluidized manner to produce hydrogen and hydrogen sulfide and to convert the reduced iron and iron sulfide in the catalyst to iron oxides, with the iron oxide-containing catalyst obtained in the third zone being recirculated into the second zone to be reduced and a part of the reduced-state catalyst obtained in the second zone being recirculated into the first zone.
摘要翻译：一种处理含硫重油的方法，其包括：在第一区域中，在含有约30至60重量％Fe的流化催化剂颗粒存在下，将含硫重油催化裂化，从而将重油转化为轻油，在催化剂颗粒上沉积含硫焦炭，并用硫化铁将催化剂颗粒中所含的还原铁部分固定在分解的硫化合物上; 在第二区域中，将来自第一区域的催化剂与含氧气体接触的量小于理论上所需的量，从而部分燃烧催化剂上的焦炭，减少催化剂中的铁，并固定在焦炭为硫化铁; 并且在第三区域中，使来自第二区域的还原催化剂以蒸气以流化方式接触以产生氢气和硫化氢，并将催化剂中还原的铁和硫化铁转化为氧化铁，得到含氧化铁的催化剂在第三区域中被再循环到第二区域以被还原，并且在第二区域中获得的部分还原态催化剂被再循环到第一区域中。

9. 发明授权

US4308173A Catalyst for cracking heavy hydrocarbons 失效
标题翻译：用于裂解重质烃的催化剂
公开(公告)号：US4308173A
公开(公告)日：1981-12-29
申请号：US132955
申请日：1980-03-24
申请人： Kuniaki Fujimori , Teruo Suzuka , Yukio Inoue , Shirou Aizawa
发明人： Kuniaki Fujimori , Teruo Suzuka , Yukio Inoue , Shirou Aizawa
IPC分类号： B01J23/755 , B01J23/78 , C01B3/06 , C01B3/10 , C10G11/00 , C10G11/02 , C10G11/18 , B01J23/74
CPC分类号： C10G11/18 , B01J23/755 , C01B3/063 , C01B3/10 , C10G11/02 , Y02E60/36
摘要： A catalyst is described for use in a process for oxidizing and/or cracking a heavy hydrocarbon under fluidizing conditions in the presence of the catalyst, including simultaneously or subsequently reducing iron oxides in said catalyst and then reacting the reduced oxidation-state iron with steam to produce hydrogen, said catalyst consisting essentially of from 30 to 60 wt % Fe, 0.1 to 10 wt % Ni, and 10 wt % or less SiO.sub.2, and having a specific surface area of from 0.1 to 30 m.sup.2 /g and an apparent specific gravity of from 2.5 to 4.0.
摘要翻译：描述了催化剂用于在催化剂存在下在流化条件下氧化和/或裂解重质烃的方法，包括同时或随后还原所述催化剂中的氧化铁，然后使还原的氧化态铁与蒸汽反应，所述催化剂基本上由30-60重量％的Fe，0.1-10重量％的Ni和10重量％的SiO 2组成，比表面积为0.1-30m 2 / g，表观比重从2.5到4.0。

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