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1. 发明授权

US06380294B1 COMPOSITIONS OF INTERPOLYMERS OF &agr;-OLEFIN MONOMERS WITH ONE OR MORE VINYL OR VINYLIDENE AROMATIC MONOMERS AND/OR ONE OR MORE HINDERED ALIPHATIC OR CYCLOALIPHATIC VINYL OR VINYLIDENE MONOMERS BLENDED WITH A CONDUCTIVE ADDITIVE 失效
标题翻译： α-烯烃单体与一种或多种乙烯基或乙烯基芳族单体和/或一种或多种引诱剂或环己基乙烯基或乙烯基单体与导电添加剂混合的嵌段共聚物的组合物
公开(公告)号：US06380294B1
公开(公告)日：2002-04-30
申请号：US09173381
申请日：1998-10-15
申请人： Susan J. Babinec , Mechelle A. Blanchard , Martin J. Guest , Brian W. Walther , Bharat I. Chaudhary , Russell P. Barry
发明人： Susan J. Babinec , Mechelle A. Blanchard , Martin J. Guest , Brian W. Walther , Bharat I. Chaudhary , Russell P. Barry
IPC分类号： C08K308
CPC分类号： C08L23/02 , C08K3/08 , C08K7/02 , C08L23/04 , C08L23/0815 , C08L23/0838 , C08L23/10 , C08L2201/04 , C08L2203/20 , C08L2205/02 , C08L25/00 , C08L2666/04
摘要： A blend of polymeric materials comprising (A) of from about 1 to about 99.99 weight percent based on the combined weights of Components A, B and C of at least one substantially random interpolymer; and wherein said interpolymer; (1) contains of from about 0.5 to about 65 mole percent of polymer units derived from; (a) at least one vinyl or vinylidene aromatic monomer, or (b) at least one hindered aliphatic or cycloaliphatic vinyl or vinylidene monomer, or (c) a combination of at least one vinyl or vinylidene aromatic monomer and at least one hindered aliphatic or cycloaliphatic vinyl or vinylidene monomer; (2) contains of from about 35 to about 99.5 mole percent of polymer units derived from at least one aliphatic &agr;-olefin having from 2 to 20 carbon atoms; (3) has a molecular weight (Mn) greater than about 1,000; (4) has a melt index (I2) of from about 0.01 to about 1,000; (5) has a molecular weight distribution (Mw/Mn) of from about 1.5 to about 20; and (B) of from about 99 to about 0.01 weight percent based on the combined weights of Components A, B, and C of one or more conductive additives and/or one or more additives with high magnetic permeability ; and (C) of from 0 to about 98.99 weight percent based on the combined weights of Components A, B, and C of one or more polymers other than A.
摘要翻译：聚合材料的混合物，其包含（A）约1至约99.99重量％，基于组分A，B和C的至少一种基本上无规的互聚物的组合重量; 并且其中所述互聚物;（1）含有约0.5至约65摩尔％的衍生自（a）至少一种乙烯基或亚乙烯基芳族单体的聚合物单元，或（b）至少一个受阻脂族或脂环族乙烯基或亚乙烯基单体，或（c）至少一种乙烯基或亚乙烯基芳族单体和至少一种受阻的脂族或脂环族乙烯基或亚乙烯基单体的组合;（2）含有约35至约99.5摩尔％的至少衍生的聚合物单元一种具有2至20个碳原子的脂族α-烯烃;（3）具有大于约1,000的分子量（Mn）;（4）具有约0.01至约1,000的熔体指数（I 2）;（5）具有分子量分布（Mw / Mn）为约1.5至约20; 和（B）为约99至约0.01重量％，基于组分A，B和C的一种或多种导电添加剂和/或一种或多种具有高磁导率的添加剂的组合重量; 和（C）为0至约98.99重量％，基于除A以外的一种或多种聚合物的组分A，B和C的组合重量。

2. 发明授权

US10072146B2 Compositions, methods of making the same, and articles prepared from the same 有权
公开(公告)号：US10072146B2
公开(公告)日：2018-09-11
申请号：US13991545
申请日：2011-12-29
申请人： Xiaosong Wu , Jose M. Rego , Kim L. Walton , Brian W. Walther , Michael D. Read
发明人： Xiaosong Wu , Jose M. Rego , Kim L. Walton , Brian W. Walther , Michael D. Read
IPC分类号： C08L47/00 , C08L23/16 , C08L23/10
CPC分类号： C08L47/00 , C08L23/10 , C08L23/16 , Y10T428/139
摘要： A composition comprising at least the following components: (A) a first composition comprising the following: i) a first interpolymer comprising, in polymerized form, ethylene, an α-olefin, and a nonconjugated polyene; ii) a second interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; and wherein the first composition has an MWD less than, or equal to, 3.5, a Mooney Viscosity (ML (1+4 @125° C.)) greater than, or equal to, 80, and an [(ML(1+4 @125° C.))/Mw(conv)]*1000 greater than 0.429 mole/g; (B) a thermoplastic polymer; and (C) a vulcanization agent is provided. A crosslinked composition made by heating one or more of the inventive compositions is also provided. Articles made from one or more of the inventive compositions are also provided.

3. 发明授权

US08563658B2 Block composites in thermoplastic vulcanizate applications 有权
标题翻译：热塑性硫化胶应用中的复合材料
公开(公告)号：US08563658B2
公开(公告)日：2013-10-22
申请号：US13499862
申请日：2010-10-01
申请人： Kim L. Walton , Brian W. Walther , Robert T. Johnston , Jose M. Rego , Xiaosong (Sharon) Wu
发明人： Kim L. Walton , Brian W. Walther , Robert T. Johnston , Jose M. Rego , Xiaosong (Sharon) Wu
IPC分类号： C08L53/00
CPC分类号： C08L23/16 , C08L23/10 , C08L53/00 , C08L2666/02
摘要： Embodiments of the invention provide block composites and their use in thermoplastic vulcanizate compounds.
摘要翻译：本发明的实施方案提供了嵌段复合材料及其在热塑性硫化胶料中的应用。

4. 发明申请

US20120208962A1 BLOCK COMPOSITES IN THERMOPLASTIC VULCANIZATE APPLICATIONS 有权
标题翻译：热塑性弹性体应用中的块状复合材料
公开(公告)号：US20120208962A1
公开(公告)日：2012-08-16
申请号：US13499862
申请日：2010-10-01
申请人： Kim L. Walton , Brian W. Walther , Robert T. Johnston , Jose M. Rego , Xiaosong Sharon Wu
发明人： Kim L. Walton , Brian W. Walther , Robert T. Johnston , Jose M. Rego , Xiaosong Sharon Wu
IPC分类号： C08L53/00
CPC分类号： C08L23/16 , C08L23/10 , C08L53/00 , C08L2666/02
摘要： Embodiments of the invention provide block composites and their use in thermoplastic vulcanizate compounds.
摘要翻译：本发明的实施方案提供了嵌段复合材料及其在热塑性硫化胶料中的应用。

5. 发明申请

US20110152437A1 Functionalized Ethylene/a-Olefin Interpolymer Compositions 有权
标题翻译：官能化乙烯/α-烯烃互聚物组合物
公开(公告)号：US20110152437A1
公开(公告)日：2011-06-23
申请号：US13031406
申请日：2011-02-21
申请人： William J. Harris , John D. Weaver , Brian W. Walther , Stephen F. Hahn , Yunwa W. Cheung , Pankaj Gupta , Thoi H. Ho , Kenneth N. Reichek , Selim Yalvac , Teresa P. Karjala , Benjamin R. Rozenblat , Cynthia L. Rickey
发明人： William J. Harris , John D. Weaver , Brian W. Walther , Stephen F. Hahn , Yunwa W. Cheung , Pankaj Gupta , Thoi H. Ho , Kenneth N. Reichek , Selim Yalvac , Teresa P. Karjala , Benjamin R. Rozenblat , Cynthia L. Rickey
IPC分类号： C08L53/00 , C08F255/02 , C08F8/14 , C08F8/00
CPC分类号： C08F297/086 , C08F210/16 , C08F295/00 , C08F297/083 , C08L23/08 , C08F210/14 , C08F2500/03 , C08F2500/20 , C08F2500/12 , C08F2500/11 , C08F2500/21
摘要： The invention relates to functionalized interpolymers derived from base olefin interpolymers, which are prepared by polymerizing one or more monomers or mixtures of monomers, such as ethylene and one or more comonomers, to form an interpolymer products having unique physical properties. The functionalized olefin interpolymers contain two or more differing regions or segments (blocks), resulting in unique processing and physical properties.
摘要翻译：本发明涉及衍生自基础烯烃互聚物的官能化互聚物，其通过聚合一种或多种单体或单体混合物如乙烯和一种或多种共聚单体而制备，以形成具有独特物理性质的互聚物产物。官能化的烯烃互聚物含有两个或多个不同的区域或链段（嵌段），产生独特的加工和物理性能。

6. 发明申请

US20100086798A1 Gloss Resins and Method for Making Same 有权
标题翻译：光泽树脂及其制作方法
公开(公告)号：US20100086798A1
公开(公告)日：2010-04-08
申请号：US12571689
申请日：2009-10-01
申请人： Todd A. Hogan , Malcolm F. Finlayson , Brian W. Walther
发明人： Todd A. Hogan , Malcolm F. Finlayson , Brian W. Walther
IPC分类号： B32B27/08 , C08L23/14
CPC分类号： C08L53/02 , B28B5/02 , B32B27/32 , C08F8/30 , C08F8/34 , C08J11/06 , C08L9/00 , C08L21/00 , C08L23/14 , C08L23/142 , C08L23/286 , C08L53/025 , Y02P20/582 , Y10T428/31913 , C08F210/06 , C08L2666/02 , C08L2666/04
摘要： The present disclosure is directed to polymeric compositions which form gloss resins suitable for thermoforming applications. The polymeric compositions include a reaction product composed of a clarified random propylene/α-olefin copolymer, a coupling agent, and optionally an elastomer. Methods for adjusting the melt flow rate of the gloss resin are also disclosed. Adjustment of the gloss resin melt flow rate advantageously enables scrap thermoplastic material containing the gloss resin to be recycled in a thermoforming operation.
摘要翻译：本公开涉及形成适于热成型应用的光泽树脂的聚合物组合物。聚合物组合物包括由澄清的无规丙烯/α-烯烃共聚物，偶联剂和任选的弹性体组成的反应产物。还公开了调节光泽树脂的熔体流动速率的方法。光泽树脂熔体流动速率的调整有利地使含有光泽树脂的废塑料材料在热成型操作中被再循环。

7. 发明授权

US06365658B1 Polymer compositions 失效
标题翻译：聚合物组合物
公开(公告)号：US06365658B1
公开(公告)日：2002-04-02
申请号：US09374098
申请日：1999-08-12
申请人： Jerker B. L. Kjellqvist , Brian W. Walther , Wenbin Liang , Roland Karlsson
发明人： Jerker B. L. Kjellqvist , Brian W. Walther , Wenbin Liang , Roland Karlsson
IPC分类号： C08K506
CPC分类号： B32B27/08 , B32B27/20 , B32B27/32 , B32B2437/02 , B32B2439/60 , B32B2471/00 , B32B2479/00 , B32B2509/00 , B32B2605/08 , B32B2605/12 , C08J5/18 , C08J2323/08 , C08L23/04 , C08L23/08 , C08L23/0815 , C08L23/0838 , C08L23/10 , C08L27/12 , C08L83/04 , C08L2205/02 , C08L2314/06 , C08L2666/04
摘要： A polymer composition comprising, based on the total weight of A), B), C) and D), A) from about 10 to 89.99 percent of a substantially random interpolymer comprising in polymerized form i) from about 35 to about 89.5 mole percent of one or more &agr;-olefin monomers and ii) from about 65 to about 10.5 mole percent of one or more vinyl or vinylidene aromatic monomers and/or one or more sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene monomers, and optionally iii) other polymerizable ethylenically unsaturated monomer(s); B) from about 10 to about 75 percent of one or more polyolefins selected from the group consisting of I) propylene polymers and II) high density polyethylenes; and C) from 0.01 to about 10 percent of a non-ionic lubricant; and D) from 0 to about 60 percent of a substantially random interpolymer comprising in polymerized form i) from about 50 to about 99.5 mole percent of one or more &agr;-olefin monomers and ii) from about 50 to about 0.5 mole percent of one or more vinyl or vinylidene aromatic monomers and/or one or more sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene monomers, and optionally iii) other polymerizable ethylenically unsaturated monomer(s) with the proviso that the molar percentage of the one or more &agr;-olefin monomers in the substantially random interpolymer D) is at least about 10 mole percent higher than the molar percentage of the one or more &agr;-olefin monomers in the substantially random interpolymer A).
摘要翻译：一种聚合物组合物，其包含基于A），B），C）和D）的总重量，A）约10至89.99％的基本上无规共聚体，其包含聚合形式，i）约35至约89.5摩尔％的一种或多种α-烯烃单体，和ii）约65至约10.5摩尔％的一种或多种乙烯基或亚乙烯基芳族单体和/或一种或多种空间位阻脂族或脂环族乙烯基或亚乙烯基单体，和任选地iii）其它可聚合的烯属不饱和单体; B）约10至约75％的一种或多种选自I）丙烯聚合物和II）高密度聚乙烯的聚烯烃; 和C）0.01至约10％的非离子润滑剂; 和D）0至约60％的基本上无规共聚体，其包含聚合形式，i）约50-约99.5摩尔％的一种或多种α-烯烃单体和ii）约50-约0.5摩尔％的一种或多种乙烯基或亚乙烯基芳族单体和/或一种或多种空间位阻脂族或脂环族乙烯基或亚乙烯基单体，以及任选地iii）其它可聚合的烯键式不饱和单体，条件是一个或多个α-烯烃单体的摩尔百分数基本上无规的互聚物D）比基本无规共聚体A）中的一种或多种α-烯烃单体的摩尔百分比高至少约10摩尔％。

8. 发明授权

US5905097A High-strength breathable films of block copolymer lattices 失效
标题翻译：高强度透气膜的嵌段共聚物晶格
公开(公告)号：US5905097A
公开(公告)日：1999-05-18
申请号：US713974
申请日：1996-09-12
申请人： Brian W. Walther
发明人： Brian W. Walther
IPC分类号： B29C41/00 , B29C71/02 , B29D7/01 , C08J3/03 , C08J5/18 , C08L53/02 , C08L9/00 , C08J9/00
CPC分类号： B29C41/003 , B29D7/01 , C08J3/03 , C08J5/18 , C08L53/02 , C08L53/025 , B29C71/02 , B29K2009/06 , B29K2096/04 , B29K2105/0064 , C08J2353/02
摘要： The invention is a film having a discontinuous phase of open and closed cells and a continuous organic phase comprising:(a) one or more block copolymer(s) corresponding to the Formula I:A--B--X.sub.m --(B--A).sub.n (I)wherein each A is a polymer block derived comprising one or more monovinylidene aromatic monomers, each B is a polymer block derived from one or more conjugated dienes, X is the remnant of a multifunctional coupling agent, m is 0 or 1, and n is an integer from 1 to 5, each A polymer block has a weight average molecular weight from 4,000 to 20,000 Daltons, each B polymer block has a weight average molecular weight from 20,000 to 100,000 Daltons, wherein the block copolymers are optionally hydrogenated; and(b) optionally, an extender which is compatible with the B polymer block, and wherein the organic phase contains from about 5 to about 30 percent by weight of units derived from monovinylidene aromatic monomers and the effective phase volume of the A polymer block in the organic phase is from about 5 to about 20 percent.Also claimed is a process for the preparation of such articles.
摘要翻译：本发明是具有开闭细胞和闭孔的连续相的连续有机相的膜，其包含：（a）对应于式I的一种或多种嵌段共聚物：AB-Xm-（BA）n（I）其中每个A是衍生自一种或多种单亚乙烯基芳族单体的聚合物嵌段，每个B是衍生自一种或多种共轭二烯的聚合物嵌段，X是多官能偶联剂的残余物，m是0或1，n是整数 1至5，每个A聚合物嵌段的重均分子量为4,000至20,000道尔顿，每个B聚合物嵌段的重均分子量为20,000至100,000道尔顿，其中嵌段共聚物任选被氢化; 和（b）任选的与B聚合物嵌段相容的增量剂，其中有机相含有约5-约30重量％的衍生自单亚乙烯基芳族单体的单元和A聚合物嵌段的有效相体积有机相为约5至约20％。还要求的是制备这种制品的过程。

9. 发明授权

US4794145A Process for metallating nonconjugated diene-containing ethylene polymers and graft polymers prepared therefrom 失效
标题翻译：用于金属化非共轭二烯的乙烯聚合物和由其制备的接枝聚合物的方法
公开(公告)号：US4794145A
公开(公告)日：1988-12-27
申请号：US109332
申请日：1987-10-16
申请人： Gary K. Lund , Raymond L. Laakso, Jr. , Calvin P. Esneault , Brian W. Walther
发明人： Gary K. Lund , Raymond L. Laakso, Jr. , Calvin P. Esneault , Brian W. Walther
IPC分类号： C08F8/42 , C08F255/06 , C08F255/00
CPC分类号： C08F8/42
摘要： A process is provided for metallating ethylene polymers which have polymerized therein a minor amount of nonconjugated diene. Metallation is accomplished with a blend of three metallating reagents: (a) an alkyllithium compound; (b) a potassium alkoxide; and (c) a chelating tertiary diamine. The metallated polymers so prepared may be reacted with one or more anionically polymerizable monomers to form graft polymers or with a reagent such as carbon dioxide to form a functionalized polymer. When the anionically polymerizable monomer has two or more polymerizable sites, the metallated polymer is reacted with a modifying compound such as alpha-methylstyrene before it is reacted with the monomer(s). Certain of the graft polymers behave as thermoplastic elastomers whereas others are thermoplastic. The blend of metallating reagents may be used with any polymer having partial or complete unsaturation.
摘要翻译：提供了一种金属化乙烯聚合物的方法，其中聚合有少量非共轭二烯。金属化是用三种金属化试剂的混合物完成的：（a）烷基锂化合物; （b）醇钾; 和（c）螯合叔胺。如此制备的金属化聚合物可以与一种或多种阴离子可聚合单体反应以形成接枝聚合物或与诸如二氧化碳的试剂形成官能化聚合物。当阴离子聚合单体具有两个或更多个可聚合位点时，金属化聚合物在与单体反应之前与诸如α-甲基苯乙烯的改性化合物反应。某些接枝聚合物表现为热塑性弹性体，而另一些则是热塑性弹性体。金属化试剂的混合物可以与具有部分或完全不饱和度的任何聚合物一起使用。

10. 发明授权

US08603639B2 Gloss resins and method for making same 有权
标题翻译：光泽树脂及其制造方法
公开(公告)号：US08603639B2
公开(公告)日：2013-12-10
申请号：US12571689
申请日：2009-10-01
申请人： Todd A. Hogan , Malcolm F. Finlayson , Brian W. Walther
发明人： Todd A. Hogan , Malcolm F. Finlayson , Brian W. Walther
IPC分类号： B32B27/08
CPC分类号： C08L53/02 , B28B5/02 , B32B27/32 , C08F8/30 , C08F8/34 , C08J11/06 , C08L9/00 , C08L21/00 , C08L23/14 , C08L23/142 , C08L23/286 , C08L53/025 , Y02P20/582 , Y10T428/31913 , C08F210/06 , C08L2666/02 , C08L2666/04
摘要： The present disclosure is directed to polymeric compositions which form gloss resins suitable for thermoforming applications. The polymeric compositions include a reaction product composed of a clarified random propylene/α-olefin copolymer, a coupling agent, and optionally an elastomer. Methods for adjusting the melt flow rate of the gloss resin are also disclosed. Adjustment of the gloss resin melt flow rate advantageously enables scrap thermoplastic material containing the gloss resin to be recycled in a thermoforming operation.
摘要翻译：本公开涉及形成适于热成型应用的光泽树脂的聚合物组合物。聚合物组合物包括由澄清的无规丙烯/α-烯烃共聚物，偶联剂和任选的弹性体组成的反应产物。还公开了调节光泽树脂的熔体流动速率的方法。光泽树脂熔体流动速率的调整有利地使含有光泽树脂的废塑料材料在热成型操作中被再循环。

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