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1. 发明授权

US07297652B2 Method of preparing a nanoporous nickel phosphate molecular sieve 失效
标题翻译：制备纳米多孔镍磷酸盐分子筛的方法
公开(公告)号：US07297652B2
公开(公告)日：2007-11-20
申请号：US10875962
申请日：2004-06-25
申请人： Sung Hwa Jhung , Jong-San Chang , Sang-Eon Park , Anthony K. Cheetham
发明人： Sung Hwa Jhung , Jong-San Chang , Sang-Eon Park , Anthony K. Cheetham
IPC分类号： B01J29/04 , B01J29/82
CPC分类号： B01J20/2808 , B01J20/0225 , B01J20/0259 , B01J20/041 , B01J20/226 , B01J20/3078 , B01J29/82 , C01B3/001 , C01B37/002 , Y02E60/324
摘要： The present invention relates to a process for preparing nanoporous VSB-5 molecular sieves, and more particularly, to a process for preparing nanoporous VSB-5 molecular sieves useful as a hydrogen storage material, a catalyst, a catalyst supporter and an adsorbent, performed in such a manner that low-cost inorganic base or monoamine instead of a template essential in the conventional process is, as a pH modifier, incorporated into raw materials comprised of nickel and phosphorous compounds and crystallized to give VSB-5 molecular sieves in an economical and efficient manner.
摘要翻译：本发明涉及一种制备纳米多孔VSB-5分子筛的方法，更具体地说，涉及制备用作储氢材料的纳米多孔VSB-5分子筛的方法，催化剂，催化剂载体和吸附剂，其在这样的方式是将常规方法中所需的低成本无机碱或单胺替代模板作为pH调节剂掺入由镍和磷化合物组成的原料中并结晶化得到VSB-5分子筛的经济和有效的方式。

2. 发明授权

US07235508B2 Metal-incorporated nanoporous nickel phosphate molecular sieve and its preparation method 有权
标题翻译：金属纳米多孔磷酸镍分子筛及其制备方法
公开(公告)号：US07235508B2
公开(公告)日：2007-06-26
申请号：US10916512
申请日：2004-08-12
申请人： Sung Hwa Jhung , Jong-San Chang , Sang-Eon Park , Anthony K. Cheetham
发明人： Sung Hwa Jhung , Jong-San Chang , Sang-Eon Park , Anthony K. Cheetham
IPC分类号： B01J29/04 , B01J29/82
CPC分类号： C01B37/002 , B01J20/186 , B01J20/3078 , B01J29/82 , C01B3/001 , Y02E60/327 , Y02E60/328
摘要： The present invention relates to a composition of metal-incorporated VSB-5 molecular sieve with nanopores and its preparation method, in particular, to a composition of a metal-incorporated VSB-5 molecular sieve with a framework of VSB-5 molecular sieve comprising nickel, phosphorous, oxygen and metal, which is useful in various fields such as a hydrogen storage material, an optical and electric/electronic material, a sensor, a catalyst, a catalyst supporter and an adsorbent, and its preparation method performed in such a manner that a specific metal component is added in a predetermined mole ratio to a reaction mixture comprised of nickel and phosphorous compounds and the resultant mixture is crystallized in the presence of inorganic or organic base as a pH modifier to yield a metal-incorporated VSB-5 molecular sieves in an economical and efficient manner.
摘要翻译：本发明涉及具有纳米孔的掺入金属的VSB-5分子筛的组合物及其制备方法，特别涉及具有包含镍的VSB-5分子筛骨架的金属掺入的VSB-5分子筛的组合物，磷，氧和金属，其可用于各种领域，例如储氢材料，光学和电气/电子材料，传感器，催化剂，催化剂载体和吸附剂，及其制备方法将特定的金属组分以与镍和磷化合物组成的反应混合物以预定的摩尔比加入，所得混合物在无机或有机碱的存在下作为pH调节剂结晶，得到金属掺入的VSB-5分子以经济高效的方式筛选。

3. 发明申请

US20050043169A1 Metal-incorporated nanoporous VSB-5 molecular sieve and its preparation method 有权
标题翻译：金属纳米多孔VSB-5分子筛及其制备方法
公开(公告)号：US20050043169A1
公开(公告)日：2005-02-24
申请号：US10916512
申请日：2004-08-12
申请人： Sung Hwa Jhung , Jong-San Chang , Sang-Eon Park , A.K. Cheetham
发明人： Sung Hwa Jhung , Jong-San Chang , Sang-Eon Park , A.K. Cheetham
IPC分类号： C01B39/54 , B01J20/02 , B01J29/82 , C01B3/00 , C01B37/00 , B01J29/04
CPC分类号： C01B37/002 , B01J20/186 , B01J20/3078 , B01J29/82 , C01B3/001 , Y02E60/327 , Y02E60/328
摘要： The present invention relates to a composition of metal-incorporated VSB-5 molecular sieve with nanopores and its preparation method, in particular, to a composition of a metal-incorporated VSB-5 molecular sieve with a framework of VSB-5 molecular sieve comprising nickel, phosphorous, oxygen and metal, which is useful in various fields such as a hydrogen storage material, an optical and electric/electronic material, a sensor, a catalyst, a catalyst supporter and an adsorbent, and its preparation method performed in such a manner that a specific metal component is added in a predetermined mole ratio to a reaction mixture comprised of nickel and phosphorous compounds and the resultant mixture is crystallized in the presence of inorganic or organic base as a pH modifier to yield a metal-incorporated VSB-5 molecular sieves in an economical and efficient manner.
摘要翻译：本发明涉及具有纳米孔的掺入金属的VSB-5分子筛的组合物及其制备方法，特别涉及具有包含镍的VSB-5分子筛骨架的金属掺入的VSB-5分子筛的组合物，磷，氧和金属，其可用于各种领域，例如储氢材料，光学和电气/电子材料，传感器，催化剂，催化剂载体和吸附剂，及其制备方法将特定的金属组分以与镍和磷化合物组成的反应混合物以预定的摩尔比加入，所得混合物在无机或有机碱的存在下作为pH调节剂结晶，得到金属掺入的VSB-5分子以经济高效的方式筛选。

4. 发明申请

US20090263621A1 POROUS ORGANIC-INORGANIC HYBRID MATERIALS AND ADSORBENT COMPRISING THE SAME 有权
标题翻译：多孔有机无机混合材料和包含其的吸附剂
公开(公告)号：US20090263621A1
公开(公告)日：2009-10-22
申请号：US12484090
申请日：2009-06-12
申请人： Jong-San Chang , Young Kyu Hwang , Sung Hwa Jhung , Do-Young Hong , You-Kyung Seo
发明人： Jong-San Chang , Young Kyu Hwang , Sung Hwa Jhung , Do-Young Hong , You-Kyung Seo
IPC分类号： B32B3/12 , B32B1/00 , B32B3/26 , B32B3/10 , C07F15/00 , C07F11/00 , C07F9/00 , C07F1/00 , C07F3/00 , C07F5/06 , C07F7/02
CPC分类号： B01J20/28033 , B01D53/28 , B01J20/226 , B01J20/28007 , B01J2220/68 , B32B3/26 , B82Y30/00 , C07F11/005 , C07F15/025 , Y10T428/24149 , Y10T428/249953 , Y10T428/2982 , Y10T442/10
摘要： The present invention relates to an adsorbent using the porous organic-inorganic hybrid material(s) containing iron having a large surface area and a high pore volume, in particular, a water adsorbent. Also, it relates to an adsorbent that can be used in humidifiers, dehumidifiers, coolers/heaters, a refrigerating machine or an air conditioner, etc., which can easily absorb or desorb at 100° C. and below, and has a great adsorption amount per weight of the adsorbent.Also, the present invention relates to a novel preparation method of porous organic-inorganic hybrid material(s), in particular, a preparation method characterized by not using hydrofluoric acid, porous organic-inorganic hybrid material(s) prepared by said preparation method, and a use as an adsorbent thereof.
摘要翻译：本发明涉及使用含有大的表面积和高孔体积的铁，特别是水吸附剂的多孔有机 - 无机混合材料的吸附剂。另外，本发明涉及一种能够在100℃以下容易吸收或解吸的加湿器，除湿器，冷却器/加热器，制冷机或空调机等中使用的吸附剂，具有很大的吸附性吸附剂重量的量。另外，本发明涉及一种多孔有机 - 无机混合材料的新型制备方法，特别是不使用氢氟酸的制备方法，通过所述制备方法制备的多孔有机 - 无机杂化材料，以及作为其吸附剂的用途。

5. 发明申请

US20070014715A1 Method and apparatus for the preparation of porous materials and mixed metal oxides 审中-公开
标题翻译：用于制备多孔材料和混合金属氧化物的方法和装置
公开(公告)号：US20070014715A1
公开(公告)日：2007-01-18
申请号：US11485008
申请日：2006-07-12
申请人： Jong-San Chang , Sung-Hwa Jhung , Young-Kyu Hwang , Jin-Soo Hwang
发明人： Jong-San Chang , Sung-Hwa Jhung , Young-Kyu Hwang , Jin-Soo Hwang
IPC分类号： C01G23/00
CPC分类号： C01G23/006 , C01B37/02 , C01B39/00 , C01B39/40 , C01B39/54 , C01G53/04 , C01P2002/34 , C01P2002/72 , C01P2006/12
摘要： Disclosed herein is a method for the preparation of porous materials, which can be used not only for a catalyst, an adsorbent, a catalytic support, ion exchange and gas storage, but also for adsorbent of guest molecules due to nanometer spaces (nanospaces), and of mixed metal oxides which are used as functional ceramic materials. More particularly, disclosed is a method for the preparation of porous materials and mixed metal oxides, in which microwave energy is used as a heating source, and a tube free of connection portions is used as a reactor, and the pressure within the reactor is controlled by measuring the pressure of gas remaining after the separation of solid and liquid, so that the method has increased operational stability and reproducibility, makes the control of residence time easy, and can achieve an increase in productivity. Also, disclosed is an apparatus for the continuous preparation of porous materials and mixed metal oxides, which can perform the preparation method.
摘要翻译：本文公开了一种制备多孔材料的方法，其不仅可用于催化剂，吸附剂，催化载体，离子交换和气体储存，而且可用于由于纳米空间（纳米空间）引起的客体分子的吸附剂，和用作功能陶瓷材料的混合金属氧化物。更具体地，公开了一种制备多孔材料和混合金属氧化物的方法，其中使用微波能量作为加热源，并且使用不具有连接部分的管作为反应器，并且控制反应器内的压力通过测量分离固体和液体后残留的气体压力，使得该方法具有增加的操作稳定性和再现性，使得停留时间的控制变得容易，并且可以实现生产率的提高。此外，还公开了可以进行制备方法的连续制备多孔材料和混合金属氧化物的装置。

6. 发明授权

US08980128B2 Adsorbent for water adsorption and desorption 有权
标题翻译：用于吸附和解吸附吸附剂
公开(公告)号：US08980128B2
公开(公告)日：2015-03-17
申请号：US13155907
申请日：2011-06-08
申请人： Jong-San Chang , Sung-Hwa Jhung , Young-Kyu Hwang
发明人： Jong-San Chang , Sung-Hwa Jhung , Young-Kyu Hwang
IPC分类号： C09K3/00 , B01J20/22 , B01J20/02 , B01J20/28 , B01J20/30 , B01J20/32 , C07F11/00 , B01D53/26 , B01D53/28
CPC分类号： B01J20/226 , B01D53/263 , B01D53/28 , B01D2253/204 , B01D2253/304 , B01D2253/306 , B01D2253/308 , B01D2253/311 , B01J20/02 , B01J20/0214 , B01J20/0218 , B01J20/0229 , B01J20/28033 , B01J20/28066 , B01J20/28076 , B01J20/2808 , B01J20/30 , B01J20/3078 , B01J20/3085 , B01J20/3204 , B01J20/3208 , B01J20/3236 , B01J20/3242 , B01J20/3248 , B01J20/3255 , B01J2220/68 , C07F11/005
摘要： The present invention relates to methods for absorbing and/or desorbing water by contacting water with hybrid inorganic-organic material having high surface area, and pores with the size of molecules or nanometers. More specifically, the water adsorbent has facile adsorption-desorption even below 100° C., having high adsorption capacity, and having high desorption capacity when it is heated up to the temperature below 100° C. The adsorbent of the present invention can be applied to a humidifier, dehumidifier, cooler and heater. The present invention also relates to a technology to control humidity using the adsorbent.
摘要翻译：本发明涉及通过使水与具有高表面积的混合无机 - 有机材料和分子或纳米尺寸的孔接触来吸收和/或解吸水的方法。更具体地，水吸附剂即使在100℃以下也具有容易的吸附 - 解吸，具有高吸附能力，并且当其被加热到低于100℃的温度时具有高的解吸能力。本发明的吸附剂可以应用加湿器，除湿机，冷却器和加热器。本发明还涉及使用吸附剂控制湿度的技术。

7. 发明授权

US08569193B2 Preparation of surface functionalized porous organic-inorganic hybrid materials or mesoporous materials with coordinatively unsaturated metal sites and catalytic applications thereof 有权
标题翻译：制备具有配位不饱和金属部位的表面官能化多孔有机 - 无机杂化材料或介孔材料及其催化应用
公开(公告)号：US08569193B2
公开(公告)日：2013-10-29
申请号：US12600997
申请日：2007-12-11
申请人： Jong-San Chang , Young Kyu Hwang , Sung Hwa Jhung , Do-Young Hong , You-Kyung Seo , Gerard Ferey , Christian Serre
发明人： Jong-San Chang , Young Kyu Hwang , Sung Hwa Jhung , Do-Young Hong , You-Kyung Seo , Gerard Ferey , Christian Serre
IPC分类号： B01J31/00
CPC分类号： B01J31/1691 , B01J31/069 , B01J2531/18 , B01J2531/824
摘要： Disclosed herein is a method of surface-functionalizing a porous organic-inorganic hybrid material or a organic-inorganic mesoporous material, in which organic substances, inorganic substances, ionic liquids and organic-inorganic hybrid substances are selectively functionalized on the coordinatively unsaturated metal sites of a porous organic-inorganic hybrid material or organic-inorganic mesoporous material, and thus the porous organic-inorganic hybrid material can be used for adsorbents, gas storage devices, sensors, membranes, functional thin films, catalysts, catalytic supports, and the like, and the applications of the surface-functionalized porous organic-inorganic hybrid material prepared using the method to catalytic reactions.
摘要翻译：本文公开了一种表面官能化多孔有机 - 无机杂化材料或有机 - 无机介孔材料的方法，其中有机物质，无机物质，离子液体和有机 - 无机杂化物质在配位不饱和金属位置上选择性地官能化多孔有机 - 无机混合材料或有机 - 无机介孔材料，因此多孔有机 - 无机混合材料可用于吸附剂，储气装置，传感器，膜，功能薄膜，催化剂，催化载体等，以及使用该方法制备的表面官能化多孔有机 - 无机杂化材料在催化反应中的应用。

8. 发明授权

US08168813B2 Porous organic-inorganic hybrid materials and adsorbent comprising the same 有权
标题翻译：多孔有机 - 无机杂化材料和包含其的吸附剂
公开(公告)号：US08168813B2
公开(公告)日：2012-05-01
申请号：US12484090
申请日：2009-06-12
申请人： Jong-San Chang , Young Kyu Hwang , Sung Hwa Jhung , Do-Young Hong , You-Kyung Seo
发明人： Jong-San Chang , Young Kyu Hwang , Sung Hwa Jhung , Do-Young Hong , You-Kyung Seo
IPC分类号： C07F15/00 , B32B3/12
CPC分类号： B01J20/28033 , B01D53/28 , B01J20/226 , B01J20/28007 , B01J2220/68 , B32B3/26 , B82Y30/00 , C07F11/005 , C07F15/025 , Y10T428/24149 , Y10T428/249953 , Y10T428/2982 , Y10T442/10
摘要： The present invention relates to an adsorbent using the porous organic-inorganic hybrid material(s) containing iron having a large surface area and a high pore volume, in particular, a water adsorbent. Also, it relates to an adsorbent that can be used in humidifiers, dehumidifiers, coolers/heaters, a refrigerating machine or an air conditioner, etc., which can easily absorb or desorb at 100° C. and below, and has a great adsorption amount per weight of the adsorbent.Also, the present invention relates to a novel preparation method of porous organic-inorganic hybrid material(s), in particular, a preparation method characterized by not using hydrofluoric acid, porous organic-inorganic hybrid material(s) prepared by said preparation method, and a use as an adsorbent thereof.
摘要翻译：本发明涉及使用含有大的表面积和高孔体积的铁，特别是水吸附剂的多孔有机 - 无机混合材料的吸附剂。另外，本发明涉及一种能够在100℃以下容易吸收或解吸的加湿器，除湿器，冷却器/加热器，制冷机或空调机等中使用的吸附剂，具有很大的吸附性吸附剂重量的量。另外，本发明涉及一种多孔有机 - 无机混合材料的新型制备方法，特别是不使用氢氟酸的制备方法，通过所述制备方法制备的多孔有机 - 无机杂化材料，以及作为其吸附剂的用途。

9. 发明授权

US07855299B2 Preparation method of porous organic inorganic hybrid materials 有权
标题翻译：多孔有机无机杂化材料的制备方法
公开(公告)号：US07855299B2
公开(公告)日：2010-12-21
申请号：US12278556
申请日：2007-02-07
申请人： Sung-Hwa Jhung , Jong-San Chang , Young-Kyu Hwang , Christian Serre , Gerard Ferey
发明人： Sung-Hwa Jhung , Jong-San Chang , Young-Kyu Hwang , Christian Serre , Gerard Ferey
IPC分类号： C07F9/00 , C07F11/00 , C07F15/00
CPC分类号： C07F11/005 , B01J20/226 , B01J20/30 , B01J31/1691 , B01J31/2239 , B01J2531/62
摘要： The present invention relates to a synthesis method of porous hybrid inorganic-organic materials that can be applied for adsorbents, gas storages, sensors, membranes, functional thin films, catalysts, catalyst supports, encapsulating guest molecules and separation of molecules by the pore structures. More specifically, the present invention relates to the synthesis method of nanocrystalline porous hybrid inorganic-organic materials.
摘要翻译：本发明涉及可用于吸附剂，气体储存器，传感器，膜，功能薄膜，催化剂，催化剂载体，包封客体分子和通过孔结构分离分子的多孔混合无机 - 有机材料的合成方法。更具体地说，本发明涉及纳米晶体多孔混合无机 - 有机材料的合成方法。

10. 发明授权

US08173827B2 Method for preparing porous organic-inorganic hybrid materials, porous organic-inorganic hybrid materials obtained by the method and catalytic uses of the materials 有权
标题翻译：制备多孔有机 - 无机杂化材料的方法，通过该方法获得的多孔有机 - 无机杂化材料和材料的催化应用
公开(公告)号：US08173827B2
公开(公告)日：2012-05-08
申请号：US12473048
申请日：2009-05-27
申请人： Jong-San Chang , Young Kyu Hwang , Sung Hwa Jhung , Do-Young Hong , You-Kyung Seo , Gerard Ferey , Christian Serre
发明人： Jong-San Chang , Young Kyu Hwang , Sung Hwa Jhung , Do-Young Hong , You-Kyung Seo , Gerard Ferey , Christian Serre
IPC分类号： C07F9/00
CPC分类号： B01J31/1691 , B01J31/069 , B01J37/346 , B01J2231/4205 , B01J2231/70 , B01J2231/72 , B01J2531/56 , B01J2531/62 , B01J2531/842 , C07C1/26 , C07F15/025 , C07C15/14
摘要： The present invention relates to a method for preparing iron-containing porous organic-inorganic hybrid materials where the organic compound ligand is bonded to a central metal and has a large surface area and pores of molecular size or nano size, by irradiating microwaves instead of heat treatments such as the conventional electric heating, etc. as the heat source of the hydrothermal or solvothermal synthesis reaction, after reacting a metal or metal salt and organic compound to form crystal nuclei by a predetermined pre-treatment operation in the presence of a solvent.In another aspect, a method of the present invention further comprises the step of purifying the obtained porous organic-inorganic hybrid materials by treating them with inorganic salt. In particular, a method of the present invention is characterized by not using a hydrofluoric acid.
摘要翻译：本发明涉及一种制备含铁多孔有机 - 无机杂化材料的方法，其中有机化合物配体通过照射微波代替热而结合到中心金属并具有大的表面积和分子尺寸或纳米尺寸的孔在常规电加热等作为水热或溶剂热合成反应的热源的处理之后，在溶剂存在下，通过预定的预处理操作使金属或金属盐与有机化合物反应形成晶核。另一方面，本发明的方法还包括用无机盐处理得到的多孔有机 - 无机杂化材料的步骤。特别地，本发明的方法的特征在于不使用氢氟酸。

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