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1. 发明专利

JPS594633A Diene type copolymeric composition and tire prepared using said composition in tread 失效
标题翻译：二苯乙烯类共聚物组合物和轮胎在TREAD中使用合成组合物
公开(公告)号：JPS594633A
公开(公告)日：1984-01-11
申请号：JP11473482
申请日：1982-06-30
申请人： Sumitomo Chem Co Ltd , Sumitomo Rubber Ind Ltd
发明人： YAMAMOTO KEISAKU , YOSHIDA MASASHI , OKAMOTO YASUSHI , IMAI AKIO , SEKI TOMOAKI , FURUKAWA HIROSHI , SAITOU YUUICHI
IPC分类号： C08L7/00 , B60C1/00 , B60C11/00 , C08L9/06 , C08L21/00
CPC分类号： Y02T10/862
摘要： PURPOSE: A composition, prepared by incorporating three types of copolymers of a specific vinyl aromatic compound and butadiene, having improved tear strength and tackiness without deteriorating the high wet skid resistance, low rolling resistance and processability, and useful for treads in tires.
CONSTITUTION: A diene type copolymeric composition prepared by incorporating three types of copolymers (A), (B) and (C) of a vinyl aromatic compound, preferably styrene, and butadiene to give 1W15wt% copolymer (C) in the total amount of the three copolymers and 70wt% or more copolymer (B) based on the total amount of the copolymers (A) and (B). The glass transition temperature of the resultant composition is -50°C or above. The copolymer (A) is a linear polymer having 1.0W4.0 intrinsic viscosity, and the copolymer (B) is a branched polymer in which the copolymer (A) is bonded with a trifunctional or tetrafunctional binder. The amount of the bonded vinyl aromatic compound in the copolymers (A) and (B) is 15W35wt%, and the amount 1,2-bonds in the bonded butadiene is 30W60mol%. The copolymer (C) is a linear or branched polymer having 0.1W0.8 intrinsic viscosity.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：通过结合三种类型的特定乙烯基芳族化合物和丁二烯的共聚物制备的组合物，其具有改善的撕裂强度和粘合性，而不会降低耐高湿滑性，低滚动阻力和加工性，并且可用于轮胎中的胎面。构成：通过将乙烯基芳族化合物，优选苯乙烯和丁二烯的三种类型的共聚物（A），（B）和（C）并入，得到1-15重量％的共聚物（C）的总量中制备的二烯型共聚物组合物的共聚物和70重量％以上的共聚物（B），基于共聚物（A）和（B）的总量。所得组合物的玻璃化转变温度为-50℃或更高。共聚物（A）是具有1.0-4.0特性粘度的线性聚合物，共聚物（B）是共聚物（A）与三官能或四官能粘合剂结合的支链聚合物。共聚物（A）和（B）中的键合乙烯基芳族化合物的量为15〜35重量％，结合丁二烯中的1,2-键的量为30〜60摩尔％。共聚物（C）是具有0.1-0.8特性粘度的直链或支链聚合物。

2. 发明专利

JPS57123237A Butadiene-isoprene copolymer composition 失效
标题翻译：丁二烯共聚物组合物
公开(公告)号：JPS57123237A
公开(公告)日：1982-07-31
申请号：JP1053781
申请日：1981-01-26
申请人： Sumitomo Rubber Ind Ltd
发明人： FURUKAWA HIROSHI , SAITOU YUUICHI , IMAI AKIO , YAMAMOTO KEISAKU , SEKI TOMOAKI , YOSHIDA MASASHI
IPC分类号： C08L7/00 , C08F36/00 , C08F236/08 , C08L9/00 , C08L21/00
摘要： PURPOSE: The titled composition with improved wet skid resistance and a dynamical heat evolving property, obtd. by use of a butadiene-isoprene copolymer of a specified or higher glass transition temp. and Mooney viscosity in a specified range as a rubber component.
CONSTITUTION: In the preparation of a butadiene-isoprene copolymer by the copolymn. of a butadiene monomer with an isoprene monomer in a non-polar hydrocarbon solvent, a catalyst system consisting of a combination of Li with a Lewis base is used as a polymn. catalyst. A copolymer of glass transition temp. ≥-50°C and molecular wt. such that the copolymer has Mooney viscosity of 20W120 at 121°C, is prepd. by adjusting a ratio of the added Lewis base to the Li and the polymn. temp. and a ratio of the added butadiene monomer to the added isoprene monomer, and the titled composition is prepd. by incorporating said copolymer as a rubber component.
COPYRIGHT: (C)1982,JPO&Japio
摘要翻译：目的：具有改进的抗湿滑性和动力演变性能的标题组合物。通过使用规定的或更高的玻璃化转变温度的丁二烯 - 异戊二烯共聚物。和作为橡胶组分的指定范围内的门尼粘度。构成：在共聚物中制备丁二烯 - 异戊二烯共聚物。的丁二烯单体与异戊二烯单体在非极性烃溶剂中的混合物，将由Li与路易斯碱的组合组成的催化剂体系用作聚合物。催化剂。玻璃化转变温度共聚物 > = -50℃，分子量使共聚物在121℃下的门尼粘度为20-120℃，制备。通过调节添加的路易斯碱与Li和聚合物的比例。温度和添加的丁二烯单体与所添加的异戊二烯单体的比例，并且标题化合物是制备的。通过引入所述共聚物作为橡胶组分。

3. 发明专利

JPS59170132A Rubber composition for tire 失效
标题翻译：轮胎橡胶组合物
公开(公告)号：JPS59170132A
公开(公告)日：1984-09-26
申请号：JP4572683
申请日：1983-03-17
申请人： Sumitomo Chem Co Ltd , Sumitomo Rubber Ind Ltd
发明人： FURUKAWA HIROSHI , SAITOU YUUICHI , YAMAMOTO KEISAKU , IMAI AKIO , YOSHIDA MASASHI , OKAMOTO YASUSHI , SEKI TOMOAKI
IPC分类号： C08L7/00 , C08L9/00 , C08L21/00
摘要： PURPOSE: To provide a rubber composition having high rolling resistance and wet-grip performance, also of good processability, comprising a specific butadiene or styrene-butadiene rubber prepared by solution polymerization.
CONSTITUTION: The objective composition comprising a butadiene or styrene- butadiene rubber prepared by solution polymerization, or, consisting mainly of an elastomer having a glass transition temperature ≥-50°C, with ≥70wt% molecular chains crosslinked through tri-or tetrafunctional bonding agent. Said rubber component should have an intrinsic viscosity of 1.0W6.0 (pref. 1.0W4.0) (measured in the form of toluene solution at 30°C). Said bonding agent is pref. of tetrafunctional type, e.g., silicon tetrachloride or tin tetrachloride. Incorporation of less than 30pts.wt. of natural or synthetic isoprene rubber based on 100pts.wt. of the total rubber component will result in highly balanced characteristics of the composition.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：提供具有高滚动阻力和湿抓地性能的橡胶组合物，还具有良好的加工性能，其包含通过溶液聚合制备的特定丁二烯或丁苯橡胶。构成：包含通过溶液聚合制备的丁二烯或苯乙烯 - 丁二烯橡胶的目标组合物，或者主要由具有玻璃化转变温度≥50℃的弹性体组成，具有> = 70重量％的分子链通过三元或四官能键合剂。所述橡胶组分的特性粘度应为1.0-6.0（优选1.0-4.0）（在30℃下以甲苯溶液的形式测量）。所述粘合剂是优选的。的四官能型，例如四氯化硅或四氯化锡。合并小于30pts.wt。的天然或合成异戊二烯橡胶，基于100pts.wt。的总橡胶组分将导致组合物的高度平衡的特性。

4. 发明专利

JPS594634A Branched copolymeric composition and tire prepared using said composition in tread 失效
标题翻译：在TREAD中使用合成组分制备的分支的共聚合组合物和轮胎
公开(公告)号：JPS594634A
公开(公告)日：1984-01-11
申请号：JP11473582
申请日：1982-06-30
申请人： Sumitomo Chem Co Ltd , Sumitomo Rubber Ind Ltd
发明人： YAMAMOTO KEISAKU , YOSHIDA MASASHI , OKAMOTO YASUSHI , IMAI AKIO , SEKI TOMOAKI , FURUKAWA HIROSHI , SAITOU YUUICHI
IPC分类号： C08L7/00 , B60C1/00 , B60C11/00 , C08L9/06 , C08L21/00
CPC分类号： Y02T10/862
摘要： PURPOSE: A composition, prepared by incorporating copolymers of a sepcific vinyl aromatic compound and butadiene, and having improved tear strength and tackiness without deteriorating the high wet skid resistance, low rolling resistance and processability, and useful for treads in tires.
CONSTITUTION: A branched copolymeric composition prepared by incorporating two types of copolymers (A) and (B) of a vinyl aromatic compound and butadinene within (30/70)W(95/5) weight ratio range between the copolymers (A) and (B). Preferably, the glass transition temperature of the resultant composition is -60°C or above, and the intrinsic viscosity is 1.3W4.0dl/g. The copolymers (A) and (B) are copolymers of the vinyl aromatic compound and butadiene containing 70wt% or more high polymer chain modified with a trifunctional or tetrafunctional binder. The copolymer (A) has 1.7W6.0dl/g intrinsic viscosity, and the copolymer (B) has 0.8W1.7dl/g intrinsic viscosity. The addition of 1W 10pts.wt. linear butadiene polymer having 0.1W0.8dl/g intrinsic viscosity, etc. to 100pts.wt. resultant composition further improves the tear strength and tackiness.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：通过引入分离的乙烯基芳族化合物和丁二烯的共聚物制备的组合物，并且具有改善的撕裂强度和粘合性，而不会降低耐湿滑性，低滚动阻力和加工性，并且可用于轮胎中的胎面。构成：通过在（30/70） - （95/5）重量比范围内将共聚物（A）和（A）和（B）之间的乙烯基芳族化合物和丁二烯的两种共聚物（A）和（B） B）。优选地，所得组合物的玻璃化转变温度为-60℃或更高，特性粘度为1.3-4.0dl / g。共聚物（A）和（B）是乙烯基芳族化合物和含有70重量％或更多的用三官能或四官能粘合剂改性的高分子链的丁二烯的共聚物。共聚物（A）的特性粘度为1.7-6.0dl / g，共聚物（B）的特性粘度为0.8-1.7dl / g。加入1〜10pts.wt。线性丁二烯聚合物具有0.1-0.8dl / g特性粘度等到100pts.wt。所得组合物进一步提高了撕裂强度和粘合性。

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