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    • 3. 发明专利
    • Polymer electrolyte composition and polymer electrolyte membrane
    • 聚合物电解质组合物和聚合物电解质膜
    • JP2013047286A
    • 2013-03-07
    • JP2011184721
    • 2011-08-26
    • Sumitomo Chemical Co Ltd住友化学株式会社
    • ISHIYAMA TAKESHINAKAMURA DAISUKE
    • C08L101/12C08K5/36H01B1/06H01M4/86H01M8/02H01M8/10
    • Y02E60/521
    • PROBLEM TO BE SOLVED: To provide a polymer electrolyte composition which can be used to obtain a polymer electrolyte membrane enabling the achievement of a fuel cell having excellent long-term stability.SOLUTION: The polymer electrolyte composition contains a polymer electrolyte and at least one type selected from a group comprising a sulfur-containing aromatic compound [A] and the like. The sulfur-containing aromatic compound [A] is represented by formula (1), wherein Yrepresents a sulfur atom-containing divalent group; each of Cto Crepresents a carbon atom; ring Arrepresents a 4-50C aromatic ring containing Cand Cand optionally having a substituent; ring Arrepresents a 4-50C aromatic ring containing Cand Cand optionally having a substituent; each of the substituent, which Aroptionally has, and the substituent, which Aroptionally has, is a hydroxyl, a halogeno group, a cyano group, a carboxy group, a phosphono group, a sulfo group, a formyl group, a mercapto group, a methyl group or the like; and Xand Xare the same as or different from each other, and each of them represents a hydrogen atom, a hydroxyl, a halogeno group, a cyano group, a carboxy group, a phosphono group, a sulfo group, a formyl group, a mercapto group, a methyl group, a 4-20C aryl group optionally having a substituent, a 4-20C aryloxy group optionally having a substituent, 4-20C arylthio group optionally having a substituent, or the like.
    • 解决的问题:提供可用于获得能够实现具有优异的长期稳定性的燃料电池的聚合物电解质膜的聚合物电解质组合物。 解决方案:聚合物电解质组合物含有聚合物电解质和选自含硫芳族化合物[A]等的至少一种。 含硫芳族化合物[A]由式(1)表示,其中Y 1 表示含硫原子的二价基团; C 1 到C 4 中的每一个表示碳原子; 环Ar 01 表示包含C 1 和C 2 的4-50C芳环, 并且任选地具有取代基; 环Ar 02 表示含有C 3 和C 4 的4-50C芳环, 并且任选地具有取代基; 可选地具有任选具有的取代基,Ar 02 任选具有的取代基是羟基, 卤代基,氰基,羧基,膦酰基,磺基,甲酰基,巯基,甲基等; 并且X 1 和X 2 彼此相同或不同,并且它们各自表示氢原子, 羟基,卤代基,氰基,羧基,膦酰基,磺基,甲酰基,巯基,甲基,任选具有取代基的4-20C芳基,4-20C芳氧基 任选具有取代基的基团,任选具有取代基的4-20C芳硫基等。 版权所有(C)2013,JPO&INPIT
    • 6. 发明专利
    • Method for producing aromatic polymer and starting compound for the same
    • 用于生产芳族聚合物的方法和用于其的起始化合物
    • JP2009263634A
    • 2009-11-12
    • JP2009059216
    • 2009-03-12
    • Sumitomo Chemical Co Ltd住友化学株式会社
    • NAKAMURA DAISUKEYAMADA TAKASHIYASHIRO ARIHIRO
    • C08G65/40C08G75/04H01M8/02H01M8/10
    • C07F9/4021C07F9/404C07F9/4043C08G65/40C08G75/23C08L2205/05
    • PROBLEM TO BE SOLVED: To provide a method for producing an aromatic polymer with a small number of reaction processes. SOLUTION: This method for producing an aromatic polymer involves a polymerization step of polymerizing a monomer represented by a general formula (1) in the copresence of a base and a first transition metal salt, or a polymerization step of polymerizing a monomer represented by the general formula (1) in the presence of a base, wherein E 1 is a group represented by -(P(=O)(OR 1 )(OR 2 )) (R 1 represents a hydrogen atom, an inorganic cation or an organic cation; R 2 represents an alkyl group or an aryl group). In the general formula (1), the groups represented by X 1 and X 2 each independently represents a condensable reacting group; Ar 1 represents an aromatic group which may have a substituent. The group represented by E 1 represents an ion exchange group or an ion exchange precursor group; n represents an integer of 1 to 4. COPYRIGHT: (C)2010,JPO&INPIT
    • 待解决的问题:提供具有少量反应过程的芳族聚合物的制备方法。 解决方案:用于制备芳族聚合物的方法包括聚合步骤,在碱和第一过渡金属盐的共价下聚合由通式(1)表示的单体,或聚合单体的聚合步骤 在式(1)中,在存在碱的情况下,其中E 1 是由 - (P(= O)(OR 1 ) SP> 2 ))(R 1 表示氢原子,无机阳离子或有机阳离子; R SP 2表示烷基或芳基) 。 在通式(1)中,由X 1 和X 2 表示的基团各自独立地表示可冷凝的反应基团; Ar 1 表示可以具有取代基的芳香族基团。 由E 1表示的基团表示离子交换基团或离子交换前体基团; n表示1〜4的整数。(C)2010,JPO&INPIT
    • 7. 发明专利
    • Polymer electrolyte composition, polymer electrolyte membrane, catalyst composition, membrane-electrode assembly and polymer electrolyte fuel cell
    • 聚合物电解质组合物,聚合物电解质膜,催化剂组合物,膜电极组件和聚合物电解质燃料电池
    • JP2013173835A
    • 2013-09-05
    • JP2012038620
    • 2012-02-24
    • Sumitomo Chemical Co Ltd住友化学株式会社
    • NAKAMURA DAISUKEISHIYAMA TAKESHI
    • C08L65/00C08L71/10C08L81/06H01B1/06H01M4/86H01M8/02H01M8/10
    • Y02E60/521
    • PROBLEM TO BE SOLVED: To provide a polymer electrolyte composition achieving excellent fuel cell with prolonged stability; a polymer electrolyte membrane; a catalyst composition; a membrane-electrode assembly; and a polymer electrolyte fuel cell.SOLUTION: A polymer electrolyte composition includes a polymer electrolyte and a sulfur-containing polymer, where the sulfur-containing polymer has a first structural unit represented by formula (1) and a second structural unit represented by formula (2). In formulae, Arand Arare each an arylene group; Eis a direct bond, thio group, sulfinyl group or oxy group; Eis a thio group or sulfinyl group; Arand Arare each an arylene group; Eis a direct bond, thio group, sulfinyl group, oxy group or a group represented by formula (3); Yis a direct bond, oxy group, carbonyl group, sulfonyl group or a group represented by formula (3); Rand Rare each H, an alkyl group, alkoxy group, aryl group, aryloxy group or acyl group.
    • 要解决的问题:提供一种具有延长稳定性的优异燃料电池的聚合物电解质组合物; 聚合物电解质膜; 催化剂组合物; 膜 - 电极组件; 和聚合物电解质燃料电池。解决方案:聚合物电解质组合物包括聚合物电解质和含硫聚合物,其中含硫聚合物具有由式(1)表示的第一结构单元和由式(1)表示的第二结构单元 2)。 在公式中,Arand Arare各自为亚芳基; 直接键合,硫基,亚硫酰基或氧基; Eis是硫基或亚硫酰基; 阿兰Arare每个亚芳基; Eis是直接键,硫基,亚磺酰基,氧基或由式(3)表示的基团; Y是直接键,氧基,羰基,磺酰基或由式(3)表示的基团; 兰稀有每个H,烷基,烷氧基,芳基,芳氧基或酰基。
    • 9. 发明专利
    • Polymer, polymer electrolyte containing the same, and fuel cell obtained by using the electrolyte
    • 聚合物,含有该聚合物的聚合物电解质,以及使用电解质获得的燃料电池
    • JP2010150536A
    • 2010-07-08
    • JP2009268524
    • 2009-11-26
    • Sumitomo Chemical Co Ltd住友化学株式会社
    • YASHIRO ARIHIRONAKAMURA DAISUKESASAKI SHIGERU
    • C08G61/10H01B1/06H01M4/86H01M8/02H01M8/10
    • Y02E60/521
    • PROBLEM TO BE SOLVED: To provide a polymer from which a polymer electrolyte membrane which is excellent in radical resistance and proton conductivity is obtained. SOLUTION: The polymer has a main chain of a polyarylene structure substantially composed of a plurality of aromatic rings bonded to one another by direct bonding and a number-average molecular weight exceeding 10,000 in terms of polystyrene. A group shown by -(P(=O)(OR 1 )(OR 2 )) is directly bonded to a part or all of aromatic rings. The aromatic ring can be substituted by one or more groups selected from the group consisting of a fluorine atom, an optionally substituted 1-20C alkyl group, an optionally substituted 1-20C alkoxyl group, an optionally substituted 6-20C aryl group, an optionally substituted 6-20C aryloxy group, and an optionally substituted 2-20C acyl group. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供一种聚合物,其中获得了具有优异的自由基电阻和质子传导性的聚合物电解质膜。 解决方案:聚合物具有基本上由多个通过直接键合彼此结合的多个芳族环的聚亚芳基结构的主链和以聚苯乙烯换算的数均分子量超过10,000的聚合物。 - (P(= O)(OR 1 )(OR 2 ))所示的基团直接键合到芳环的一部分或全部。 芳环可以被一个或多个选自以下的基团取代:氟原子,任选取代的1-20C烷基,任选取代的1-20C烷氧基,任选取代的6-20C芳基,任选地 取代的6-20C芳氧基和任选取代的2-20C酰基。 版权所有(C)2010,JPO&INPIT