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    • 1. 发明专利
    • Method for producing propylene oxide
    • 生产丙烯氧化物的方法
    • JP2013116924A
    • 2013-06-13
    • JP2013057934
    • 2013-03-21
    • Sumitomo Chemical Co Ltd住友化学株式会社
    • KAWABATA TOMONORIYAMAMOTO MORIOKITAURA TAKEAKIKNAPP CARLOS
    • C07D301/08C07D303/04
    • Y02P20/52
    • PROBLEM TO BE SOLVED: To provide a method to inhibit runaway reaction due to a highly active catalyst at the start-up of a fixed-bed type propylene oxide reactor.SOLUTION: This method for starting a fixed-bed type propylene oxide reactor containing a metallic catalyst carried on a carrier comprises following steps of: (a) heating the reactor at a temperature lower by 5-55°C than that in normal operation conditions; (b) passing a propylene-containing gas on the catalyst in the reactor at a flow rate of 5-40% of designed flow rate value; (c) adding an organic chlorine compound to the gas passing on the catalyst; (d) adding oxygen to the gas passing on the catalyst, and raising the reactor temperature and gas flow rate to the operating conditions.
    • 要解决的问题:提供一种在固定床型环氧丙烷反应器启动时抑制由于高活性催化剂引起的失控反应的方法。 解决方案:用于启动承载在载体上的含有金属催化剂的固定床型环氧丙烷反应器的方法包括以下步骤:(a)在比常温下低5-55℃的温度下加热反应器 操作条件; (b)以设计流量值的5-40%的流量将含丙烯气体在反应器中的催化剂上通过; (c)向通过催化剂的气体中加入有机氯化合物; (d)向通过催化剂的气体加入氧气,并将反应器温度和气体流量提高到操作条件。 版权所有(C)2013,JPO&INPIT
    • 5. 发明专利
    • Method for producing hydroxy compound
    • 生产羟基化合物的方法
    • JP2008308468A
    • 2008-12-25
    • JP2007159908
    • 2007-06-18
    • Sumitomo Chemical Co Ltd住友化学株式会社
    • UI TOSHIAKISUZUTA TETSUYAKNAPP CARLOS
    • C07C37/02B01J29/46C07B61/00C07C39/04
    • Y02P20/52
    • PROBLEM TO BE SOLVED: To provide a method for producing a hydroxy compound by hydrolyzing a chlorohydrocarbon compound in the presence of a catalyst containing nickel supported on a metallosilicate, and exhibiting excellent characteristics to prevent the lowering of the catalytic performance at the start of the production process and develop high catalytic activity in stationary operation. SOLUTION: The reaction is started at ≤405°C and then the temperature is elevated. The starting temperature of reaction is defined by the temperature to start the coexistence of the chlorohydrocarbon and steam on the catalyst, and the temperature is ≤405°C, preferably 300-400°C. Too high reaction temperature results in the lowering of the catalytic performance in the case of making only the chlorohydrocarbon into contact with the catalyst in the absence of steam at the start of the reaction, and too low temperature fails in sufficient development of the catalytic performance and sometimes causes the lowering of the conversion of the chlorohydrocarbon. COPYRIGHT: (C)2009,JPO&INPIT
    • 待解决的问题:提供一种通过在含有负载在金属硅酸盐上的镍的催化剂存在下水解氯代烃化合物来制备羟基化合物的方法,并且具有优异的特性以防止起始时催化性能的降低 的生产过程,并在稳定运行中发挥高催化活性。

      解决方案:反应在≤405℃开始,然后升温。 反应的起始温度由开始氯代烃和蒸汽在催化剂上共存的温度限定,温度≤405℃,优选300-400℃。 反应温度过高导致在反应开始时在不存在蒸汽的情况下仅使氯烃与催化剂接触的情况下催化性能降低,并且过低的温度不能充分发挥催化性能, 有时会降低氯代烃的转化率。 版权所有(C)2009,JPO&INPIT

    • 6. 发明专利
    • Method for preparing catalyst for hydrolysis reaction and catalyst for hydrolysis reaction
    • 水解反应催化剂制备方法及水解反应催化剂
    • JP2008126123A
    • 2008-06-05
    • JP2006312527
    • 2006-11-20
    • Sumitomo Chemical Co Ltd住友化学株式会社
    • KNAPP CARLOSUI TOSHIAKI
    • B01J29/46B01J37/02C07B61/00C07C37/02C07C39/04
    • Y02P20/52
    • PROBLEM TO BE SOLVED: To provide a catalyst for a hydrolysis reaction, in detail having some characteristics with respect to a method for the catalyst for the hydrolysis reaction and the catalyst for the hydrolysis reaction. SOLUTION: The method for preparing the catalyst for the hydrolysis reaction has the process of immersing metallosilicate into a solution dissolving nickel acetate and/or nickel formate. An Si/Me atomic ratio is preferably five or more as metallosilicate and the metallosilicate may be a crystal silicate comprising silica dioxide substantially containing no Me components (wherein Me is one or more of kinds metal elements selected from Al, Cu, Ga, Fe, B, Zn, Cr, Be, Co, La, Ge, Ti, Zr, Hf, V, Ni, Sb, Bi, Nb and the like). COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:为了提供水解反应的催化剂,具体地涉及用于水解反应的催化剂的方法和水解反应的催化剂的一些特性。 解决方案:制备用于水解反应的催化剂的方法具有将金属硅酸盐浸入溶解有乙酸镍和/或甲酸镍的溶液中的方法。 作为金属硅酸盐,Si / Me原子比优选为5以上,金属硅酸盐可以是包含基本上不含Me成分的二氧化硅的结晶硅酸盐(其中Me是选自Al,Cu,Ga,Fe中的一种或多种金属元素, B,Zn,Cr,Be,Co,La,Ge,Ti,Zr,Hf,V,Ni,Sb,Bi,Nb等)。 版权所有(C)2008,JPO&INPIT
    • 7. 发明专利
    • Catalyst for hydrolysis reaction and its manufacturing method
    • 水解反应催化剂及其制备方法
    • JP2007253007A
    • 2007-10-04
    • JP2006078277
    • 2006-03-22
    • Sumitomo Chemical Co Ltd住友化学株式会社
    • SUGITA KEISUKEKNAPP CARLOSUI TOSHIAKI
    • B01J29/46B01J37/02C07B61/00C07C37/02C07C39/04
    • Y02P20/52
    • PROBLEM TO BE SOLVED: To provide a catalyst for a hydrolysis reaction, which has such an excellent characteristic that the desired hydrolysis reaction can be performed in high yield and with high selectivity and its selectivity is not deteriorated even when hydrochloric acid is used as a raw material and the hydrolysis reaction is continued for ≥50 hours and to provide a method for manufacturing the catalyst for the hydrolysis reaction. SOLUTION: The catalyst for the hydrolysis reaction is obtained by bringing metallosilicate into contact with copper sulfate, in the concrete, by impregnating metallosilicate with a copper sulfate-dissolved solution. Cupric sulfate such as CuSO 4 and CuSO 4 -5H 2 O can be used as the copper sulfate. This catalyst is used suitably in such a reaction that a hydroxyl group is substituted for the chlorine of a chlorinated hydrocarbon compound. A reaction that chlorobenzene is converted into phenol can be exemplified as a concrete example of the hydrolysis reaction. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:为了提供具有这样优异特性的水解反应催化剂,即可以高产率和高选择性进行所需的水解反应,即使使用盐酸也不会降低其选择性 作为原料,并且水解反应持续≥50小时,并提供制备用于水解反应的催化剂的方法。 解决方案:通过使金属硅酸盐与硫酸铜接触,在混凝土中通过用硫酸铜溶液浸渍金属硅酸盐来获得水解反应的催化剂。 可以使用硫酸铜如CuSO 4 SB 3和CuSO 4 SBB-5H SB 2作为硫酸铜。 该催化剂适当地用于羟基取代氯代烃化合物的氯的反应。 作为水解反应的具体实例,可以举出氯苯转化为苯酚的反应。 版权所有(C)2008,JPO&INPIT
    • 9. 发明专利
    • Method for producing propylene oxide
    • 生产丙烯氧化物的方法
    • JP2013126978A
    • 2013-06-27
    • JP2012255218
    • 2012-11-21
    • Sumitomo Chemical Co Ltd住友化学株式会社
    • KAWABATA TOMONORIYAMAMOTO MORIOKITAURA TAKEAKIKNAPP CARLOS
    • C07D301/08C07D303/04
    • Y02P20/52
    • PROBLEM TO BE SOLVED: To provide a method for producing propylene oxide, which minimizes the loss to a purge gas of propylene, and improves the yield in a propylene oxide production process.SOLUTION: The method includes: (a) mixing propylene 102, high-purity oxygen 101 and balance gas 103 with recycle gas 110 to form a reaction gas mixture; (b) feeding the reaction mixture to a reactor 120 packed with a catalyst, and making an effluent 125 flow out from the reactor; (c) sending the effluent from the reactor to a recovery column 140 and forming a gas flow 148 having no propylene oxide; (d) sending the gas flow 148 having no propylene oxide to a diffusion column 130 to remove carbon dioxide 135; (e) purging 115 a part 138 of a gas flow having no carbon dioxide, and recycling a remaining gas flow as the recycle gas; (f) compressing the recycle gas again; and (g) regulating the flow amount of the purge gas to effectively reduce the concentration of argon.
    • 要解决的问题:提供一种生产环氧丙烷的方法,其使丙烯吹扫气体的损失最小化,并且提高了环氧丙烷生产过程中的产率。 解决方案:该方法包括:(a)将丙烯102,高纯度氧101和余量气体103与循环气体110混合以形成反应气体混合物; (b)将反应混合物进料到装有催化剂的反应器120中,并使流出物125从反应器中流出; (c)将流出物从反应器送到回收塔140并形成不具有环氧丙烷的气流148; (d)将不含环氧丙烷的气流148送到扩散塔130以除去二氧化碳135; (e)清除115没有二氧化碳的气流的部分138,并循环剩余的气流作为循环气体; (f)再次压缩再循环气体; 和(g)调节净化气体的流量以有效地降低氩气的浓度。 版权所有(C)2013,JPO&INPIT
    • 10. 发明专利
    • Method for measuring propylene oxide selectivity
    • 测量丙烯选择性的方法
    • JP2013082692A
    • 2013-05-09
    • JP2012198402
    • 2012-09-10
    • Sumitomo Chemical Co Ltd住友化学株式会社
    • KAWABATA TOMONORIYAMAMOTO MORIOKITAURA TAKEAKIKNAPP CARLOS
    • C07D301/08C07B61/00C07D303/04
    • PROBLEM TO BE SOLVED: To provide a method for measuring a precise propylene oxide selectivity and a method for optimizing the propylene oxide selectivity to maintain an optimum reaction condition.SOLUTION: In the production method of propylene oxide in which a reactant gas flow containing propylene and oxygen is supplied to a reaction tower containing a catalyst and a generated gas flow containing propylene oxide is discharged from the reaction tower, the method for measuring propylene oxide selectivity includes the steps of: (I) determining at least two concentrations of propylene, oxygen, propylene oxide, carbon and water in the reactant gas by measuring absorption rates of infrared ray or near infrared ray in the reactant gas flow or the sample of the reactant gas flow and analyzing a composition of the reactant gas flow ; (II) determining the concentration of the compound from the measurement of absorption rates of infrared ray or near infrared ray; and (III) calculating the propylene oxide selectivity from the concentrations obtained in the step (I) and the step (II).
    • 要解决的问题:提供测量精确的环氧丙烷选择性的方法和优化环氧丙烷选择性以保持最佳反应条件的方法。 解决方案:在将含有丙烯和氧气的反应物气体流供应到含有催化剂的反应塔和含有环氧丙烷的产生气流的环氧丙烷的制备方法中,从反应塔排出测量方法 环氧丙烷选择性包括以下步骤:(I)通过测量反应气体流或样品中的红外线或近红外线的吸收速率来测定反应气体中的丙烯,氧气,环氧丙烷,碳和水中的至少两个浓度 的反应气流,分析反应气流的组成; (II)从测量红外线或近红外线的吸收率确定化合物的浓度; 和(III)从步骤(I)和步骤(II)中获得的浓度计算环氧丙烷选择性。 版权所有(C)2013,JPO&INPIT