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    • 6. 发明申请
    • Method of preparing metal catalyst and electrode including the same
    • 制备金属催化剂和包括其的电极的方法
    • US20070184335A1
    • 2007-08-09
    • US11703131
    • 2007-02-07
    • Suk-gi HongDuck-young YooJung-ock ParkWoo-sung Jeon
    • Suk-gi HongDuck-young YooJung-ock ParkWoo-sung Jeon
    • H01M4/86B05D5/12B01J23/00H01M4/88H01M4/00
    • H01M4/90H01M4/8657H01M4/8663H01M4/8857H01M4/8882H01M4/926H01M2008/1095
    • A method of preparing a metal catalyst including a conductive catalyst material and a coating layer formed of a water repellent material on the surface of the conductive catalyst material includes: obtaining a water repellent material solution by mixing a water repellent material and a first solvent; obtaining a conductive catalyst solution by mixing a conductive catalyst material and a first solvent; mixing the water repellent material solution and the conductive catalyst solution; casting the result onto a supporter, drying the cast result and then separating a metal catalyst in a solid state from the supporter; and pulverizing and sieving the product. Also provided are a metal catalyst prepared using the method, an electrode including the metal catalyst, a method of preparing the electrode, and a fuel cell employing the electrode. A metal catalyst including a coating layer formed of a water repellent material on the surface of a conductive catalyst particle can be obtained by using the method of preparing a metal catalyst. Such a metal catalyst does not sink into a liquid electrolyte since hydrophobicity is efficiently distributed around the conductive catalyst particle. Also, the distribution and movement of the liquid electrolyte, such as phosphoric acid, around the metal catalyst can be controlled. A fuel cell employing the metal catalyst has excellent efficiency and overall performance.
    • 在导电性催化剂材料的表面上制备包括导电催化剂材料和由防水材料形成的涂层的金属催化剂的方法包括:通过混合防水材料和第一溶剂获得防水材料溶液; 通过混合导电催化剂材料和第一溶剂获得导电催化剂溶液; 混合防水材料溶液和导电催化剂溶液; 将结果浇注到支持体上,干燥铸造结果,然后将固体状态的金属催化剂与载体分离; 并对产品进行粉碎和筛分。 还提供了使用该方法制备的金属催化剂,包括金属催化剂的电极,制备电极的方法和使用该电极的燃料电池。 通过使用金属催化剂的制备方法,可以得到在导电性催化剂粒子的表面上由斥水材料形成的涂层的金属催化剂。 这种金属催化剂不会沉入液体电解质中,因为疏水性有效地分布在导电催化剂颗粒周围。 此外,可以控制金属催化剂周围的液体电解质如磷酸的分布和移动。 使用金属催化剂的燃料电池具有优异的效率和整体性能。
    • 10. 发明授权
    • Binder for electrode of fuel cell, electrode for fuel cell including the binder, method of manufacturing the electrode, and fuel cell using the electrode
    • 燃料电池用电极用粘合剂,包括粘合剂的燃料电池用电极,电极的制造方法以及使用该电极的燃料电池
    • US08501370B2
    • 2013-08-06
    • US11846050
    • 2007-08-28
    • Myung-jin LeeSuk-gi HongMyung-dong Cho
    • Myung-jin LeeSuk-gi HongMyung-dong Cho
    • H01M4/02H01M4/36
    • H01M8/0239H01M4/8668H01M4/8828H01M4/8882H01M8/0234H01M8/0245H01M8/1007H01M2008/1095Y02P70/56Y10T29/49115
    • A binder for an electrode of a fuel cell is a basic polymer including a nitrogen-containing functional group and a proton conductive polymer having a phosphoric acid impregnation capacity of 200 wt % or less. An electrode for a fuel cell includes the binder and a catalyst, and a fuel cell includes the electrode. The electrode is manufactured by mixing the binder, a catalyst, and a solvent; and coating the mixture on a carbon support and heat-treating the coated mixture. The binder has excellent proton conductivity by having a phosphoric acid impregnation capacity of 200 wt % or less, and has improved durability without membrane damage and micro-structural changes due to swelling, which occurs when PBI is used as a binder. Accordingly, an electrode including the binder has improved phosphoric acid retention capacity, and increased wetting velocity. Thus, a fuel cell having improved efficiency can be manufactured due to the improved proton conductivity and durability of the electrode.
    • 用于燃料电池的电极的粘合剂是包含含氮官能团和磷酸浸渍能力为200重量%以下的质子传导性聚合物的碱性聚合物。 用于燃料电池的电极包括粘合剂和催化剂,燃料电池包括电极。 电极通过混合粘合剂,催化剂和溶剂来制造; 并将混合物涂覆在碳载体上并对涂覆的混合物进行热处理。 粘合剂通过具有200重量%以下的磷酸浸渍能力而具有优异的质子传导性,并且具有改善的耐久性,而不会由于PBI作为粘合剂而发生膜损伤和由于溶胀引起的微观结构变化。 因此,包括粘合剂的电极具有改善的磷酸保留能力和增加的润湿速度。 因此,由于电极的质子传导性和耐久性得到改善,所以可以制造效率提高的燃料电池。