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    • 8. 发明授权
    • Heat resisting low expansion zirconyl phosphate-zircon composite
    • 耐热低膨胀型磷酸锆锆石复合材料
    • US4883781A
    • 1989-11-28
    • US94743
    • 1987-09-09
    • Keiichiro WatanabeTsuneaki Ohashi
    • Keiichiro WatanabeTsuneaki Ohashi
    • C04B35/447C04B35/48
    • C04B35/481C04B35/447
    • Heat resisting low expansion zirconyl phosphate-zircon composite bodies are disclosed, which contain zirconyl phosphate and zircon as a main crystalline phase and a secondary crystalline phase, respectively. The heat resisting low expansion zirconyl phosphate-zircon composite bodies have a coefficient of thermal expansion in a temperature range from room temperature to 1,400.degree. C. being not more than 30.times.10-7/.degree. C. and a melting point being not less than 1,600.degree. C. The composite bodies have a chemical composition essentially consisting of 58.2 to 65.4% by weight of ZrO.sub.2, 17.4 to 37.1% by weight of P.sub.2 O.sub.5, and 1.5 to 19.0% by weight of SiO.sub.2. The heat resisting low expansion zirconyl phosphate-zircon composite bodies optionally contain MgO and Al.sub.2 O.sub.3 in a total amount of not more than 2.5% by weight or 0.1 to 4% by weight of Nb.sub.2 O.sub.5. A process for producing such zirconyl phosphate-zircon composite bodies is also disclosed.
    • 公开了耐热低膨胀性磷酸锆锆石复合体,其分别含有磷酸锆和锆石作为主结晶相和二次结晶相。 耐热低膨胀型磷酸锆锆锆复合体的体系在室温〜1400℃的温度范围内的热膨胀系数为30×10 -7 /℃以下,熔点为1600℃以上 复合体具有基本上由58.2至65.4重量%的ZrO 2,17.4至37.1重量%的P 2 O 5和1.5至19.0重量%的SiO 2组成的化学组成。 耐热低膨胀性磷酸锆锆锆复合体任意地含有MgO和Al 2 O 3,其总量不超过2.5重量%或0.1〜4重量%的Nb 2 O 5。 还公开了一种制备这种磷酸锆锆石复合体的方法。