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    • 4. 发明授权
    • Synthesis of carbon nanotubes filled with palladium nanoparticles using arc discharge in solution
    • 在溶液中使用电弧放电合成填充有钯纳米颗粒的碳纳米管
    • US07438885B1
    • 2008-10-21
    • US10891570
    • 2004-07-15
    • Sudipta SealSuresh C. KuiryDebasis BeraMeyya MeyyappanMatthew Luke McCutchen
    • Sudipta SealSuresh C. KuiryDebasis BeraMeyya MeyyappanMatthew Luke McCutchen
    • D01F9/12
    • B82Y40/00B82Y30/00C01B32/16C01B2202/02C01B2202/06C01B2202/36Y10S977/846
    • A novel method for simultaneously forming and filling and decorating carbon nanotubes with palladium nanoparticles is disclosed. Synthesis involves preparing a palladium chloride (PdCl2) solution in a container, having two graphite electrodes, then immersing the graphite electrode assembly, into the PdCl2 solution; connecting the graphite electrodes to a direct current power supply; bringing the electrodes into contact with each other to strike an arc; separating the electrodes to sustain the arc inside the solution; putting the container with electrode assembly in a water-cooled bath; and collecting Pd-nanoparticles encapsulated in carbon nanotubes and carbon nanotubes decorated with Pd-nanoparticles. The temperature at the site of the arc-discharge is greater than 3000° C. At these temperatures, the palladium is ionized into nanoparticles and the graphite electrodes generate layers of graphene (carbon), which roll away from the anode and encapsulate or entrap the Pd-nanoparticles. The unique nanotube structures have significant commercial potential as gas sensors or as a means for hydrogen storage.
    • 公开了一种用钯纳米颗粒同时形成和填充和装饰碳纳米管的新方法。 合成包括在容器中制备氯化钯(PdCl 2/2)溶液,其具有两个石墨电极,然后将石墨电极组件浸入到PdCl 2溶液中; 将石墨电极连接到直流电源; 使电极彼此接触以产生电弧; 分离电极以维持溶液内的电弧; 将容器与电极组件放在水冷浴中; 并收集封装在碳纳米管中的Pd-纳米颗粒和用Pd-纳米颗粒装饰的碳纳米管。 电弧放电现场的温度大于3000℃。在这些温度下,钯离子化成纳米颗粒,石墨电极产生石墨烯层(碳),其从阳极卷起并封闭或截留 钯纳米粒子。 独特的纳米管结构作为气体传感器或作为氢存储的手段具有显着的商业潜力。
    • 5. 发明授权
    • Advanced catalyst system prepared from a whiskered aluminum-containing metallic alloy substrate
    • 先进的催化剂体系由含铝的金属合金基材制成
    • US08247034B2
    • 2012-08-21
    • US13224848
    • 2011-09-02
    • Weifeng FeiSuresh C. KuirySudipta Seal
    • Weifeng FeiSuresh C. KuirySudipta Seal
    • B05D3/02
    • C30B29/62B22F2998/00C30B1/02B22F1/004B22F1/02
    • A method for whisker formation on the surface of aluminum-containing metallic alloy fibers and substrates provides a support structure for many technical, medical and pharmaceutical applications. The novel surface modification of metallic alloy fibers and other metallic substrates involves heating the fiber or substrate in air at temperatures ranging from approximately 800° C. to approximately 1000° C. for a period of time ranging from approximately 10 hours to approximately 100 hours to form whiskers. The use of a metal oxide coating with large ions, such as zirconium oxide, allows the formation of alumina whiskers while preserving the structural integrity of the metallic alloy substrate. Uses of the present invention include, but are not limited to an advanced catalyst support, a highly efficient filter medium, a support for implants and the like.
    • 在含铝金属合金纤维和基材的表面上形成晶须的方法为许多技术,医疗和制药应用提供了支撑结构。 金属合金纤维和其它金属基底的新型表面改性涉及将空气中的纤维或基底在约800℃至约1000℃的温度范围内加热约10小时至约100小时的时间, 形成晶须 使用具有大离子的金属氧化物涂层,例如氧化锆,允许形成氧化铝晶须,同时保持金属合金基底的结构完整性。 本发明的用途包括但不限于高级催化剂载体,高效过滤介质,用于植入物的载体等。
    • 6. 发明申请
    • Synthesis of carbon nanotubes filled with palladium nanoparticles using arc discharge in solution
    • 在溶液中使用电弧放电合成填充有钯纳米颗粒的碳纳米管
    • US20090072192A1
    • 2009-03-19
    • US12229683
    • 2008-08-26
    • Sudipta SealDebasis BeraSuresh C. KuiryMeyya MeyyappanMatthew Luke McCutchen
    • Sudipta SealDebasis BeraSuresh C. KuiryMeyya MeyyappanMatthew Luke McCutchen
    • C09K3/00
    • B82Y40/00B82Y30/00C01B32/16C01B2202/02C01B2202/06C01B2202/36Y10S977/846
    • A novel method for simultaneously forming and filling and decorating carbon nanotubes with palladium nanoparticles is disclosed. Synthesis involves preparing a palladium chloride (PdCl2) solution in a container, having two graphite electrodes, then immersing the graphite electrode assembly, into the PdCl2 solution; connecting the graphite electrodes to a direct current power supply; bringing the electrodes into contact with each other to strike an arc; separating the electrodes to sustain the arc inside the solution; putting the container with electrode assembly in a water-cooled bath; and collecting Pd-nanoparticles encapsulated in carbon nanotubes and carbon nanotubes decorated with Pd-nanoparticles. The temperature at the site of the arc-discharge is greater than 3000° C. At these temperatures, the palladium is ionized into nanoparticles and the graphite electrodes generate layers of graphene (carbon), which roll away from the anode and encapsulate or entrap the Pd-nanoparticles. The unique nanotube structures have significant commercial potential as gas sensors or as a means for hydrogen storage.
    • 公开了一种用钯纳米颗粒同时形成和填充和装饰碳纳米管的新方法。 合成包括在容器中制备氯化钯(PdCl 2)溶液,其具有两个石墨电极,然后将石墨电极组件浸入PdCl 2溶液中; 将石墨电极连接到直流电源; 使电极彼此接触以产生电弧; 分离电极以维持溶液内的电弧; 将容器与电极组件放在水冷浴中; 并收集封装在碳纳米管中的Pd-纳米颗粒和用Pd-纳米颗粒装饰的碳纳米管。 电弧放电现场的温度大于3000℃。在这些温度下,钯离子化成纳米颗粒,石墨电极产生石墨烯层(碳),其从阳极卷起并封闭或截留 钯纳米粒子。 独特的纳米管结构作为气体传感器或作为氢存储的手段具有显着的商业潜力。
    • 7. 发明申请
    • Method for Whisker Formation on Metallic Fibers and Substrates
    • 金属纤维和基体上晶须形成的方法
    • US20120227869A1
    • 2012-09-13
    • US13475547
    • 2012-05-18
    • Weifeng FeiSuresh C. KuirySudipta Seal
    • Weifeng FeiSuresh C. KuirySudipta Seal
    • C23C8/10
    • C30B29/62B22F2998/00C30B1/02B22F1/004B22F1/02
    • A method for whisker formation on the surface of aluminum-containing metallic alloy fibers and substrates provides a support structure for many technical, medical and pharmaceutical applications. The novel surface modification of metallic alloy fibers and other metallic substrates involves heating the fiber or substrate in air at temperatures ranging from approximately 800° C. to approximately 1000° C. for a period of time ranging from approximately 10 hours to approximately 100 hours to form whiskers. The use of a metal oxide coating with large ions, such as zirconium oxide, allows the formation of alumina whiskers while preserving the structural integrity of the metallic alloy substrate. Uses of the present invention include, but are not limited to an advanced catalyst support, a highly efficient filter medium, a support for implants and the like.
    • 在含铝金属合金纤维和基材的表面上形成晶须的方法为许多技术,医疗和制药应用提供了支撑结构。 金属合金纤维和其它金属基底的新型表面改性涉及将空气中的纤维或基底在约800℃至约1000℃的温度范围内加热约10小时至约100小时的时间, 形成晶须 使用具有大离子的金属氧化物涂层,例如氧化锆,允许形成氧化铝晶须,同时保持金属合金基底的结构完整性。 本发明的用途包括但不限于高级催化剂载体,高效过滤介质,用于植入物的载体等。
    • 8. 发明授权
    • Method for whisker formation on metallic fibers and substrates
    • 在金属纤维和基材上形成晶须的方法
    • US08084096B1
    • 2011-12-27
    • US11135987
    • 2005-05-24
    • Weifeng FeiSuresh C. KuirySudipta Seal
    • Weifeng FeiSuresh C. KuirySudipta Seal
    • B05D3/02
    • C30B29/62B22F2998/00C30B1/02B22F1/004B22F1/02
    • A method for whisker formation on the surface of aluminum-containing metallic alloy fibers and substrates provides a support structure for many technical, medical and pharmaceutical applications. The novel surface modification of metallic alloy fibers and other metallic substrates involves heating the fiber or substrate in air at temperatures ranging from approximately 800° C. to approximately 1000° C. for a period of time ranging from approximately 10 hours to approximately 100 hours to form whiskers. The use of a metal oxide coating with large ions, such as zirconium oxide, allows the formation of alumina whiskers while preserving the structural integrity of the metallic alloy substrate. Uses of the present invention include, but are not limited to an advanced catalyst support, a highly efficient filter medium, a support for implants and the like.
    • 在含铝金属合金纤维和基材的表面上形成晶须的方法为许多技术,医疗和制药应用提供了支撑结构。 金属合金纤维和其它金属基底的新型表面改性涉及将空气中的纤维或基底在约800℃至约1000℃的温度范围内加热约10小时至约100小时的时间, 形成晶须 使用具有大离子的金属氧化物涂层,例如氧化锆,允许形成氧化铝晶须,同时保持金属合金基底的结构完整性。 本发明的用途包括但不限于高级催化剂载体,高效过滤介质,用于植入物的载体等。
    • 9. 发明授权
    • In-situ synthesis of carbon nanotubes filled with metallic nanoparticles using arc discharge in solution
    • 在溶液中使用电弧放电填充金属纳米粒子的碳纳米管的原位合成
    • US07968072B2
    • 2011-06-28
    • US12229683
    • 2008-08-26
    • Sudipta SealDebasis BeraSuresh C. KuiryMeyya MeyyappanMatthew Luke McCutchen
    • Sudipta SealDebasis BeraSuresh C. KuiryMeyya MeyyappanMatthew Luke McCutchen
    • B82B3/00
    • B82Y40/00B82Y30/00C01B32/16C01B2202/02C01B2202/06C01B2202/36Y10S977/846
    • A novel method for simultaneously forming and filling and decorating carbon nanotubes with palladium nanoparticles is disclosed. Synthesis involves preparing a palladium chloride (PdCl2) solution in a container, having two graphite electrodes, then immersing the graphite electrode assembly, into the PdCl2 solution; connecting the graphite electrodes to a direct current power supply; bringing the electrodes into contact with each other to strike an arc; separating the electrodes to sustain the arc inside the solution; putting the container with electrode assembly in a water-cooled bath; and collecting Pd-nanoparticles encapsulated in carbon nanotubes and carbon nanotubes decorated with Pd-nanoparticles. The temperature at the site of the arc-discharge is greater than 3000° C. At these temperatures, the palladium is ionized into nanoparticles and the graphite electrodes generate layers of graphene (carbon), which roll away from the anode and encapsulate or entrap the Pd-nanoparticles. The unique nanotube structures have significant commercial potential as gas sensors or as a means for hydrogen storage.
    • 公开了一种用钯纳米颗粒同时形成和填充和装饰碳纳米管的新方法。 合成包括在容器中制备氯化钯(PdCl 2)溶液,其具有两个石墨电极,然后将石墨电极组件浸入PdCl 2溶液中; 将石墨电极连接到直流电源; 使电极彼此接触以产生电弧; 分离电极以维持溶液内的电弧; 将容器与电极组件放在水冷浴中; 并收集封装在碳纳米管中的Pd-纳米颗粒和用Pd-纳米颗粒装饰的碳纳米管。 电弧放电现场的温度大于3000℃。在这些温度下,钯离子化成纳米颗粒,石墨电极产生石墨烯层(碳),其从阳极卷起并封闭或截留 钯纳米粒子。 独特的纳米管结构作为气体传感器或作为氢存储的手段具有显着的商业潜力。
    • 10. 发明授权
    • Method for whisker formation on metallic fibers and substrates
    • 在金属纤维和基材上形成晶须的方法
    • US08591996B2
    • 2013-11-26
    • US13475547
    • 2012-05-18
    • Weifeng FeiSuresh C. KuirySudipta Seal
    • Weifeng FeiSuresh C. KuirySudipta Seal
    • B05D3/02
    • C30B29/62B22F2998/00C30B1/02B22F1/004B22F1/02
    • A method for whisker formation on the surface of aluminum-containing metallic alloy fibers and substrates provides a support structure for many technical, medical and pharmaceutical applications. The novel surface modification of metallic alloy fibers and other metallic substrates involves heating the fiber or substrate in air at temperatures ranging from approximately 800° C. to approximately 1000° C. for a period of time ranging from approximately 10 hours to approximately 100 hours to form whiskers. The use of a metal oxide coating with large ions, such as zirconium oxide, allows the formation of alumina whiskers while preserving the structural integrity of the metallic alloy substrate. Uses of the present invention include, but are not limited to an advanced catalyst support, a highly efficient filter medium, a support for implants and the like.
    • 在含铝金属合金纤维和基材的表面上形成晶须的方法为许多技术,医疗和制药应用提供了支撑结构。 金属合金纤维和其它金属基底的新型表面改性涉及将空气中的纤维或基底在约800℃至约1000℃的温度范围内加热约10小时至约100小时的时间, 形成晶须 使用具有大离子的金属氧化物涂层,例如氧化锆,允许形成氧化铝晶须,同时保持金属合金基底的结构完整性。 本发明的用途包括但不限于高级催化剂载体,高效过滤介质,用于植入物的载体等。