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    • 3. 发明授权
    • Direct one-step synthesis of CF3-I
    • 直接一步合成CF3-I
    • US07071367B1
    • 2006-07-04
    • US11007919
    • 2004-12-09
    • Sudip MukhopadhyayHsueh Sung Tung
    • Sudip MukhopadhyayHsueh Sung Tung
    • C07C17/00
    • C07C17/093C07C17/158C07C17/204C07C19/16
    • The present invention provides a process for the preparation of trifluoromethyl iodide. The process includes the step of: contacting in a reactor a compound represented by the formula: CF3—W and a compound represented by the formula: Z-I wherein W is selected from CF3, hydrogen and bromine; Z is selected from hydrogen, iodine and chlorine. The step of contacting is carried out, optionally in the presence of a catalyst and further optionally in the presence of air, at a temperature, pressure and for a length of time sufficient to produce the trifluoromethyl iodide.
    • 本发明提供了制备三氟甲基碘的方法。 该方法包括以下步骤:在反应器中接触由下式表示的化合物:<?in-line-formula description =“In-line Formulas”end =“lead”?> CF 3 - W <?in-line-formula description =“In-line Formulas”end =“tail”?>和由以下公式表示的化合物:<?in-line-formula description =“In-line Formulas”end =“lead “?”ZI <?in-line-formula description =“In-line Formulas”end =“tail”?>其中W选自CF 3,氢和溴; Z选自氢,碘和氯。 任选地在催化剂存在下进一步任选地在空气存在下,在足以产生三氟甲基碘的温度,压力和一段时间内进行接触步骤。
    • 6. 发明授权
    • One-step synthesis of CF3-1
    • 一步合成CF3-1
    • US07132578B1
    • 2006-11-07
    • US11181311
    • 2005-07-14
    • Sudip MukhopadhyayHsueh Sung Tung
    • Sudip MukhopadhyayHsueh Sung Tung
    • C07C17/00
    • C07C17/204C07C17/093C07C17/10C07C17/158C07C17/361C07C19/07
    • A process for the preparation of trifluoromethyl iodide is provided. The process includes the step of contacting in a reactor a compound represented by the formula: CF3—W and a compound represented by the formula: IFn wherein W can be H, Br, Cl, COOH, COCl, COOCH3, COOC2H5, COCH3, COPh, CF3, Si(CH3)3, SPh, SCH3, SSCF3, SSPh, SSCH3, or SO2Cl, wherein n is 1, 3, 5, or 7, and wherein the step of contacting is carried out, at a temperature, pressure and for a length of time sufficient to produce trifluoromethyl iodide. The contacting step can be carried out in the presence or absence of a catalyst and the contacting step can be carried out in the presence or absence of air.
    • 提供了制备三氟甲基碘的方法。 该方法包括在反应器中接触由下式表示的化合物的步骤:<?in-line-formula description =“In-line Formulas”end =“lead”?> CF 3 -W <?in-line-formula description =“In-line Formulas”end =“tail”?>和由下式表示的化合物:<?in-line-formula description =“In-line Formulas”end =“lead” 其中W可以是H,Br,Cl,COOH,COCl,COOCH CO 3,H 3,COCH 3,CO 2,CO 3,SO 3, 3,3个,3个,3个,3个,3个,3个,3个,3个,3个,3个,3个,3个,3个,3个, SUB或SO 2 Cl,其中n为1,3,5或7,并且其中接触步骤在温度,压力和时间长度下进行,足以 产生三氟甲基碘。 接触步骤可以在催化剂存在或不存在下进行,并且接触步骤可以在空气存在或不存在下进行。