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    • 7. 发明授权
    • Process for making pen/pet blends and transparent articles therefrom
    • 制造笔/宠物混合物和透明制品的方法
    • US06395865B2
    • 2002-05-28
    • US09791361
    • 2001-02-23
    • Steven L. SchmidtBrian LynchAmit S. Agrawal
    • Steven L. SchmidtBrian LynchAmit S. Agrawal
    • C08G6302
    • C08G63/80C08L67/02C08L2666/18
    • Process for controlling the change of intrinsic viscosity and transesterification during solid stating of a polyethylene terephthalate (PET) and polyethylene naphthalate (PEN) blend, with an effective amount of an ethylene glycol compound. The process enables the production of a copolymer based on predefined initial and final IV's and final transesterification level, by varying the solid-stating time and/or effective amount of ethylene glycol. In one embodiment, a relatively greater amount of post-consumer PET (e.g., 70%) having an IV of on the order of 0.72-0.73, is incorporated in the blend to provide a final IV on the order of 0.80-0.85, and a moderate, controlled level of transesterification; the blend is used to injection mold a sleeve layer of a preform. In another embodiment, a substantially transparent neck finish for a preform is made from a PEN/PET blend having an amount of ethylene glycol which enables substantial transesterification, without excessive increase in IV.
    • 用于控制聚对苯二甲酸乙二醇酯(PET)和聚萘二甲酸乙二醇酯(PEN)共混物固化期间的特性粘度和酯交换的变化与有效量的乙二醇化合物的方法。 该方法可以通过改变固体时间和/或有效量的乙二醇来制备基于预定义的初始和最终IV和最终酯交换水平的共聚物。 在一个实施方案中,将具有大约0.72-0.73的IV的相对较大量的消费后PET(例如,70%)掺入共混物中以提供大约0.80-0.85的最终IV,以及 中等,受控的酯交换水平; 该混合物用于注射成型预成型件的套筒层。 在另一个实施方案中,用于预成型件的基本上透明的颈部精加工由具有一定量的乙二醇的PEN / PET共混物制成,其能够进行实质的酯交换,而不会过多地增加IV。